Effect of calcined magnesite on soil and Pinus radiata foliage magnesium in pumice soils of New Zealand

Soil Research ◽  
1999 ◽  
Vol 37 (3) ◽  
pp. 545 ◽  
Author(s):  
A. D. Mitchell ◽  
P. Loganathan ◽  
T. W. Payn ◽  
R. W. Tillman
Keyword(s):  
New Zealand ◽  
Soil Solution ◽  
Soil Layer ◽  
Tree Breeding ◽  
Solution Ph ◽  
Mg Deficiency ◽  
Exchangeable Al ◽  
Forest Regions ◽  
New Type ◽  
Fertiliser Application

Magnesium (Mg) deficiency is common in a number of forest regions in the world. It has been linked to a condition in P. radiata called ‘upper mid crown yellowing’ (UMCY) in New Zealand and ‘new type forest decline’ in Europe. Mg concentrations are low in many of New Zealand"s forest soils. With increases in the number of rotations and increased growth rates through tree breeding, Mg deficiency is expected to increase. This study was conducted to determine the fate of calcined magnesite (calmag) fertiliser applied at 150 kg Mg/ha at 2 sites in the Kaingaroa Forest near Rotorua, New Zealand. It also investigated the effectiveness of calmag in increasing the soil solution and soil exchangeable Mg in pumice soils and Mg concentrations in the pine needles, and in reducing the likelihood of UMCY 2 and 3 years after fertiliser application. In both sites and for both years of sampling the application of calmag fertiliser resulted in a significant increase in soil exchangeable and soil solution Mg in the 0–5 cm soil layer. Soil and soil solution pH had also been increased in the top 5 cm soil layer. Two years after application about 90% of the fertiliser applied had dissolved and about 70–80% of the Mg remained in a plant-available form (ammonium acetate exchangeable Mg) in the top 10 cm of soil. Calculations suggest that 3–10% of applied fertiliser had been lost due to leaching. Magnesium fertiliser application also resulted in significant reduction in the exchangeable K: Mg ratio and reduced exchangeable Al in the 0–5 cm soil layer. After 3 years, foliar Mg concentrations increased at all sites in the fertilised trees compared with the control trees, although differences were not yet significant. UMCY severity in the trees was also not significantly affected by the application of Mg fertiliser.

Effects of biochar and/or dolomitic limestone application on the properties of Ultisol cropped to maize under glasshouse conditions

2015 ◽  
Vol 95 (1) ◽  
pp. 37-47 ◽  
Author(s):  
M. A. Rabileh ◽  
J. Shamshuddin ◽  
Q. A. Panhwar ◽  
A. B. Rosenani ◽  
A. R. Anuar
Keyword(s):  
Soil Solution ◽  
Dolomitic Limestone ◽  
Solution Ph ◽  
Maize Production ◽  
Maize Growth ◽  
Exchangeable Al ◽  
Glasshouse Condition ◽  
The Tropics ◽  
Critical Ph ◽  
Changes In Soil Properties

Rabileh, M. A., Shamshuddin, J., Panhwar, Q. A., Rosenani, A. B. and Anuar, A. R. 2015. Effects of biochar and/or dolomitic limestone application on the properties of Ultisol cropped to maize under glasshouse conditions. Can. J. Soil Sci. 95: 37–47. Ultisols in the tropics are characterized by low pH and high exchangeable Al. Maize grown on them produces low yield. A study was conducted to determine changes in soil properties and their subsequent effects on maize growth, resulting from oil palm empty fruit bunch (EFB) biochar and/or dolomitic limestone application. The results show that the application of the EFB biochar improved soil fertility by increasing soil pH. The Al3+activities in the soil solution decreased exponentially with increasing rate of the biochar application. The decrease in Al in the biochar-treated soil occurred because: (1) at the rate of>5 t ha−1, soil solution pH increased significantly, precipitating Al as gibbsite; and (2) the biochar was able to fix some of the Al by chelation. Application of the biochar alone or in combination with lime significantly improved maize growth. The critical Al3+activity for maize grown on Ultisol was 10 µM, while critical pH was 4.7–4.8. Maize grown on the EFB biochar-amended soils produced greater root length compared with that of the control. The optimal rate of EFB biochar application to improve the productivity of the Ultisol for maize production under glasshouse condition was 5–10 t ha−1.

Free aluminium and related parameters in soil solution from a South Island (New Zealand) high country site under contrasting S and P fertilisation

Soil Research ◽  
1997 ◽  
Vol 35 (1) ◽  
pp. 175 ◽  
Author(s):  
H. K. J. Powell ◽  
D. J. Hawke ◽  
D. Scott
Keyword(s):  
Organic Matter ◽  
New Zealand ◽  
Soil Solution ◽  
Natural Organic Matter ◽  
Ph Dependence ◽  
Application Rate ◽  
Solution Ph ◽  
Trial Site ◽  
P Application

Soil solution samples were taken from 7 plots of varying Hieracium infestation at the AgResearch (NZ) Mt John trial site, Lake Tekapo. The soils, which had been fertilised, oversown, and grazed, were analysed for free (reactive) Al, total Al, pH, NOM (natural organic matter), and phosphate. The plots had received annual fertiliser combinations of 0–100 kg P and 0–20 kg S/ha·year. Soil solution pH was in the range 4·33-5·76 and total Al concentrations were in the range 13–68 µM. Free Al concentrations were in the range 0·48–4·8 µM. The pH dependence of log (free[Al]) (slope: –0·69±0·37) indicated control of soluble Al by NOM rather than Al(OH)3 solubility. Soil solution phosphate concentrations depended strongly on P application rate, reaching over 100 mM. At high P concentrations, the product [Al3+][PO3-4] indicated approximate saturation with respect to variscite. One comparison indicated that effects on pH and NOM in the upper 5 cm were due to the presence or absence of grazing.

The relationship between soil solution pH and Al3+concentrations in a range of South Island (New Zealand) soils

Soil Research ◽  
2000 ◽  
Vol 38 (1) ◽  
pp. 141 ◽  
Author(s):  
M. L. Adams ◽  
D. J. Hawke ◽  
N. H. S. Nilsson ◽  
K. J. Powell
Keyword(s):  
New Zealand ◽  
Soil Solution ◽  
Chelating Resin ◽  
Curvilinear Relationship ◽  
Published Data ◽  
Solution Ph ◽  
Resultant Data ◽  
Soil Solutions ◽  
Ph Range ◽  
The Relationship

Concentrations of Al3+ were calculated in soil solutions from concentrations of the monomeric ‘reactive Al’ species ([Al3+] + [Al(OH)2+] + [Al(OH)2+] + [AlF2+]) obtained using a recently reported flow injection analysis (FIA) chelating resin technique. Soil solution samples came from 7 sites encompassing a range of New Zealand soils (Brown, Gley, Pallic, Podzol, and Recent Soils) and vegetation types (pasture, shrub lands, and indigenous and exotic forest). Previously published data from a further 7 sites, obtained using a rapid (7 s) FIA technique, were transformed to give compatible results. The resultant data (n = 85) covered the pH range 2.7–7.6, and showed a single curvilinear relationship for log [Al3+] v. soil solution pH, regardless of vegetation or soil type. At pH >5.6, the data had a slope of –2.98 and fell between the amorphous Al(OH)3 and gibbsite solubility lines. At pH <5.0, the data had a slope of –0.46; further, the soil solutions were under-saturated with respect to both minerals. These results are interpreted as indicating control of Al solubility by Al(OH)3 (s) (at pH >5.6) and soil organic matter (at pH <5.0), respectively. This interpretation is supported by data from a pH-dependent Al–fulvic acid binding curve, for which calculated values of [Al3+] follow the same curvilinear relationship determined from the soil solution samples.

scholarly journals Assessing the impact of acid rain and forest harvest intensity with the HD-MINTEQ model – Soil chemistry of three Swedish conifer sites from 1880 to 2080

2018 ◽  
Author(s):  
Eric McGivney ◽  
Salim Belyazid ◽  
Therese Zetterberg ◽  
Stefan Löfgren ◽  
Jon Petter Gustafsson
Keyword(s):  
Acid Rain ◽  
Soil Solution ◽  
Tree Growth ◽  
Soil Chemistry ◽  
Soil Layer ◽  
Base Cations ◽  
Mineral Weathering ◽  
Solution Ph ◽  
Weathering Rates ◽  
The Impact

Abstract. Forest soils are susceptible to anthropogenic acidification. In the past, acid rain was a major contributor to soil acidification, but now that atmospheric levels of S have dramatically declined, concern has shifted towards biomass-induced acidification, i.e., decreasing soil solution pH due to tree growth and harvesting events that permanently remove base cations (BC) from forest stands. We use a novel dynamic model, HD-MINTEQ, to investigate the long-term impacts of two theoretical future harvesting scenarios in the year 2020, a conventional harvest (CH, which removes stems only) and a whole-tree harvest (WTH, which removes 100 % of the above-ground biomass except for stumps), on soil chemistry and weathering rates at three different Swedish forest sites (Aneboda, Gårdsjön, and Kindla). Furthermore, acidification following the harvesting events is compared to the historical acidification that took place during the 20th century due to acid rain. Our results indicate that historical acidification due to acid rain had a larger impact on pore water chemistry and mineral weathering than tree growth and CH or WTH events, at least if nitrification remained at a low level. However, compared to a no-harvest scenario (NH), WTH and CH significantly impacted soil chemistry and weathering rates. Directly after a harvesting event (CH or WTH), the soil solution pH sharply increased for 5 to 10 years before slowly declining over the remainder of the simulation (until year 2080). WTH acidified soils slightly more than CH, with the largest effects being seen for the B1 horizons by the year 2080. Even though the pH values in the WTH and CH scenario decreased with time as compared to NH, they did not drop to the levels observed around the peak of historic acidification (1980–1990), indicating that the pH decrease due to tree growth and harvesting would be less impactful than that of historic atmospheric acidification. Weathering rates differed across locations and soil layers in response to historic acidification, but at several sites and layers, annual weathering rates decreased in tandem with decreasing pH, which is likely due to Al3+ weathering brakes. Weathering rates after the harvesting scenarios in 2020 generally increased although the dynamics were quite different depending on the site and soil layer.

Outflows of Organic Halide Precursors from Forest Regions

1989 ◽  
Vol 21 (12) ◽  
pp. 1877-1880 ◽  
Author(s):  
S. Saito ◽  
K. Hattori ◽  
T. Okumura
Keyword(s):  
Water Quality ◽  
River Basin ◽  
Surface Soil ◽  
Soil Layer ◽  
Water Quality Monitoring ◽  
Quality Monitoring ◽  
Deep Soil ◽  
Organic Halide ◽  
Forest Regions ◽  
Surface Soil Layer

Outflows of organic halide precursors (OXPs) from forest regions were studied in relation to water quality monitoring in the Yodo River basin. Firstly, the contribution of outflows from forest regions relative to the total was roughly estimated. Then equations for flows of these substances were formulated, divided into four different subflow categories: precipitation; throughfall; surface soil layer; and, deep soil layer. Finally, annual outflow loads were calculated for a test forest area.

Corrosion behaviors of X70 steel under direct current interference

2019 ◽  
Vol 66 (3) ◽  
pp. 307-316 ◽  
Author(s):  
Jun Wang ◽  
Zili Li ◽  
Gan Cui ◽  
JianGuo Liu ◽  
Chuanping Kong ◽  
...  
Keyword(s):  
Weight Loss ◽  
Corrosion Rate ◽  
Soil Solution ◽  
Direct Current ◽  
Polarization Curves ◽  
Solution Ph ◽  
Corrosion Morphology ◽  
Content Type ◽  
Tafel Polarization ◽  
Corrosion Behaviors

Purpose The purpose of this paper is to study the corrosion behaviors of X70 steel under direct current (DC) interference at 0-1,200 A/m2 in simulated soil solution. Design/methodology/approach The Tafel polarization curves of X70 steel under DC interference were tested using electrochemical method, the corrosion rate was calculated using weight-loss method and the change in steel surface was analyzed by optical microscopy. Findings The results showed that E-I polarization curves under 200-1,200 A/m2 interference were linear; with an increase in the DC density, the corrosion potential of X70 steel shifted positively, solution pH after the weight-loss tests increased and corrosion rate increased linearly. A mathematical relationship between polarization resistance Rp and current density was established. Corrosion morphology indicated that pitting corrosion and crevice corrosion occurred on the X70 steel under DC interference in simulated soil solution. Originality/value All tests were conducted at a relative higher DC density (200-1,200 A/m2). The linear fitting method is proposed to fit data of Tafel polarization curves under DC interference. This study provides guidelines for safe operation of X70 steel pipelines.

scholarly journals Effect of Soil Solution pH during the Tetracycline Intercalation on the Structural Properties of a Dioctahedral Smectite: Microstructural Analysis

2019 ◽  
Vol 2019 ◽  
pp. 1-17
Author(s):  
Walid Oueslati
Keyword(s):  
Soil Solution ◽  
Structural Changes ◽  
Ph Value ◽  
Microstructural Analysis ◽  
Xrd Analysis ◽  
Deformation Bands ◽  
Solution Ph ◽  
Hydration Properties ◽  
In Situ Xrd

The aim of this work is to quantitatively characterize the structural response to a chemical disruption of saturated montmorillonite crystallites by organic molecules (tetracycline (TC)), derived from pharmaceutical waste. The chemical disturbance is performed by varying the surrounding soil solution pH. To show the effect of this chemical perturbation on the interlamellar space (IS) configuration and the hydration properties, an “in situ” XRD analysis, based on the modeling of the 00l reflections, is carried out. The “in situ” XRD analysis is performed by varying the relative humidity conditions (%RH). FTIR SEM and BET- (Brunauer-Emmett-Teller-) BJH (Barrett-Joyner-Halenda) analyses are used as complementary techniques to confirm the structural changes accompanying the intercalation process. Results showed a dependence between solution acid character and the TC adsorption mechanism. From pH values close to 7, the deprotonation of the TC molecule within IS is accelerated by an increasing %RH rate. IR spectroscopy shows that the structure is preserved versus pH value and only a shift of the water deformation bands ascribed to interlamellar water molecule abundance and TC conformation is observed. The surface morphology studied by SEM shows the increase in the surface porosity by increasing the pH value. BET-specific surface area and BJH pore size distribution (PSD) analyses confirm the SEM observations.

Effects of aluminium and calcium in the soil solution of acid soils on root elongation of Glycine max cv. Forrest

1988 ◽  
Vol 39 (3) ◽  
pp. 319 ◽  
Author(s):  
RC Bruce ◽  
LA Warrell ◽  
DG Edwards ◽  
LC Bell
Keyword(s):  
Root Growth ◽  
Soil Solution ◽  
Soil Ph ◽  
Activity Ratio ◽  
Acid Soils ◽  
Exchange Capacity ◽  
Al Toxicity ◽  
Solution Ph ◽  
Diagnostic Indices ◽  
Exchangeable Ca

In the course of three experiments, soybean (Glycerine max (L.) Merr.) cv. Forrest was grown in 21 soils (four surface soils and 17 subsoils) amended with liming materials (CaCO3 and Mg CO3) and soluble Ca salts (CaSO4.2H20 and CaCl2.2H2O). In most soils, the soluble salts increased concentrations and activities of Al species in solution to levels that restricted root growth, and MgCO3, induced a Ca limitation to root growth. Root lengths after three days were related to so11 and soil solution attributes.Suitable diagnostic indices for the prediction of Ca limitations to root growth were either Ca saturation of the effective cation exchange capacity or Ca activity ratio of the soil solution, which was defined as the ratio of the activity of Ca to the sum of the activities of Ca, Mg, Na, and K. Values corresponding to 90% relative root length (RRL) of soybean were 0.05 for the Ca activity ratio and 11% for Ca saturation. Calcium activity and Ca concentration in the soil solution and exchangeable Ca were less useful for this purpose.Soil Al saturation was not a good predictor of Al toxicity, but soil solution measurements were. The activities of Al3+ and AlOH2+ gave the best associations with RRL, and values corresponding to 90% RRL were 4 8M and 0.5 8M respectively. The results suggested that Al(OH)3� , Al(OH)2+, and AlSO4+, were not toxic species. Soil solution pH and soil pH measured in water were more sensitive indicators of root growth than soil pH measured in 0.01 M CaCl2.Using a Ca activity ratio of 0.05 and an Al3+ activity of 4 8M as diagnostic indices, none of the 20 soils in two experiments were toxic in Al, while 13 (all subsoils) were deficient in Ca. Thus the first limitation on root growth was Ca deficiency and not Al toxicity, in spite of high Al saturations and relatively low pH in these soils. However, Al toxicity could be induced by increasing the ionic strengths of soil solutions.

DairyMod and EcoMod: biophysical pasture-simulation models for Australia and New Zealand

2008 ◽  
Vol 48 (5) ◽  
pp. 621 ◽  
Author(s):  
I. R. Johnson ◽  
D. F. Chapman ◽  
V. O. Snow ◽  
R. J. Eckard ◽  
A. J. Parsons ◽  
...  
Keyword(s):  
New Zealand ◽  
Nutrient Dynamics ◽  
Irrigation Management ◽  
Management Strategies ◽  
Simulation Models ◽  
Nutrient Status ◽  
Pasture Management ◽  
Management Options ◽  
Recent Developments ◽  
Fertiliser Application

DairyMod and EcoMod, which are biophysical pasture-simulation models for Australian and New Zealand grazing systems, are described. Each model has a common underlying biophysical structure, with the main differences being in their available management options. The third model in this group is the SGS Pasture Model, which has been previously described, and these models are referred to collectively as ‘the model’. The model includes modules for pasture growth and utilisation by grazing animals, water and nutrient dynamics, animal physiology and production and a range of options for pasture management, irrigation and fertiliser application. Up to 100 independent paddocks can be defined to represent spatial variation within a notional farm. Paddocks can have different soil types, nutrient status, pasture species, fertiliser and irrigation management, but are subject to the same weather. Management options include commonly used rotational grazing management strategies and continuous grazing with fixed or variable stock numbers. A cutting regime simulates calculation of seasonal pasture growth rates. The focus of the present paper is on recent developments to the management routines and nutrient dynamics, including organic matter, inorganic nutrients, leaching and gaseous nitrogen losses, and greenhouse gases. Some model applications are presented and the role of the model in research projects is discussed.

Cercicladia australis, a new carnivorous sponge with novel chelae from the Tasman Basin and the Argentine Patagonian Margin (Porifera, Cladorhizidae)

Zootaxa ◽  
2011 ◽  
Vol 3131 (1) ◽  
pp. 52 ◽  
Author(s):  
PILAR RIOS ◽  
MICHELLE KELLY ◽  
JEAN VACELET
Keyword(s):  
New Species ◽  
New Zealand ◽  
New Genus ◽  
New Genus And Species ◽  
Carnivorous Species ◽  
New Type

Recent expeditions around New Zealand have revealed a surprising diversity of carnivorous sponges (Demospongiae, Poecilosclerida, Cladorhizidae). This is especially true for the Macquarie Ridge to the southwest of New Zealand, with high numbers of new species recently recorded. In this work we describe a new genus and species of Cladorhizidae Dendy, 1922 from the Macquarie Ridge, Cercicladia australis gen. nov. sp. nov., which has also, surprisingly, been found in the deep Atlantic off the coast of Patagonia. In addition to the mycalostyles and sigmancistras typical of Cladorhizidae, this presumably carnivorous species is characterized by the presence of toxas, microxeas, and a new type of spicule termed 'cercichelae' hereafter. The new genus Cercicladia gen. nov. has been named for these spicules, which resemble the shuttle-shaped chelae of Cercidochela lankesteri Kirkpatrick, 1907, now synonymised with Isodictya Bowerbank, 1864. The specimens from these disjunct locations are almost identical, except for the presence of acanthosubtylostyles in a few specimens from Patagonia.

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