Soil zinc and its uptake by plants. I. Isotopic exchange equilibria and the application of tracer techniques. II. Soil chemistry in relation to prediction of availability

Soil Research ◽  
1972 ◽  
Vol 10 (2) ◽  
pp. 151 ◽  
Author(s):  
KG Tiller ◽  
JL Honeysett ◽  
Vries MPC De

Isotopic exchange studies were applied to the laboratory and glasshouse measurement of labile zinc in 25 soils from nine Great Soil Groups. The laboratory equilibration procedures worked well with acidic and most near neutral soils, but may overestimate labile zinc values for the lateritic podzolic soils. The values for some acidic soils were also compromised because of lack of isotopic equilibrium. The laboratory method gave erratic and unrealistic data when applied to alkaline soils due to fixation of the added zinc. The procedures based on the specific activity of zinc absorbed by plants from soils equilibrated with carrier-free 65Zn gave reproducible values of the total amount of plant available zinc for all soils. These values agree well with the corresponding laboratory data for acidic soils. Furthermore, the specific activity data showed that magnesium chloride and EDTA extractions had equilibrated with the same chemical form or forms of zinc as that absorbed by the plants.

Soil Research ◽  
1972 ◽  
Vol 10 (2) ◽  
pp. 165 ◽  
Author(s):  
KG Tiller ◽  
JL Honeysett ◽  
Vries MPC De

Representatives of nine soil groups were extracted with reagents that have been used to predict zinc deficiency. The amounts of soil zinc removed were discussed in terms of specific and non-specific bonding in relation to the reagent used. The desorption of natural zinc was also described in terms of the quantity/intensity (Q/I) relation and an equilibrium zinc concentration (ZnQ) at natural pH. The ZnQ values varied from 1 to 4 �gI. for the alkaline soils and 8-190 pg/l. for the acidic soils. The Q/I ratio was derived by radioisotopic and chemical isotherm procedures. Log Q/I (I = total soluble zinc) approximated closely a linear relation of unit slope with pH. This was ascnbed to a common reation of zinc with all soils by specific sorption dominated by ZnOHA ions such that Q/I� = constant where I' = (ZnOH+aq). Deviations from this relation are discussed. The relations between soil and plant (clover and wheat) variables were studied by simple and multiple regression analysis. Single values of intensity variables, and, to a lesser extent, Q/I variables, correlated well with plant data but not the quantity variables. The improved correlations of Q variables when combined with Q/I variables accorded with published work. The problem of predicting zinc availability on alkaline soils which are dominated by very high Q/I values, is discussed.


Author(s):  
Garrison Sposito

In Section 3.4, the cation exchange capacity, or CEC, of particulate soil humus is defined as the maximum number of moles of proton charge per kilogram that can be desorbed by a metal cation under prescribed conditions. Thus, CEC for particulate humus is equal to the maximum absolute value of the negative net proton charge. Operationally, this maximum value is measured typically as the surface excess of Ba2+ adsorbed by humus at pH 8.2 (Eq. 3.5). Extending this concept to soils, one can define the CEC as the maximum number of moles of readily exchangeablemetal cation charge per unit mass of dry soil that can be extracted under prescribed conditions. In this more general context, CEC refers to metal cations that adsorb on soil particles in either outer sphere surface complexes or the diffuse ion swarm (Fig. 7.2). In alkaline soils, the common readily exchangeable cations are Ca2+, Mg2+, Na+, and K+, whereas in acidic soils, this group expands to include Al3+, and its complexes AlOH2+, Al(OH)2+, and AlSO+4. Following the operational paradigm for soil humus, one concludes that the measurement of soil CEC involves not only the desorption of protons, but also the replacement of the population of readily exchangeable adsorbed metal cations at a selected pH value (usually pH 7–8) by a chosen cation. Laboratory procedures for measuring CEC are described in Methods of Soil Analysis, listed in For Further Reading at the end of this chapter. In alkaline soils, the replacing cation chosen is often Na+ or Ca2+, whereas in acidic soils and for soil humus, the replacing cation of choice is Ba2+. These cations, in turn, are typically displaced from soil particle surfaces by Mg2+ to measure the surface excess. A conceptual definition of CEC can be developed in terms of the surface charge balance concepts introduced in Chapter 7. Consider first a soil in which a net positive surface excess of anions does not occur, such as the Mollisol example discussed in Section 8.1. In this case, the only adsorbed ions are Ca2+ and Cl-. The CEC of this soil may be defined by a special case of the charge-balance condition in Eq. 7.3a: ∆qex (max) ≡ CEC


1967 ◽  
Vol 15 (1) ◽  
pp. 95 ◽  
Author(s):  
RF Parsons ◽  
RL Specht

In southern Australia, deep calcareous and deep siliceous sands each carry a distinctive assemblage of eucalypts. Three of these species with contrasting edaphic ranges were investigated: Eucalyptus baxteri, which is widespread on acidic soils and is never found on highly alkaline soils like the calcareous sands; E. incrassata, which is widespread on acidic and neutral soils, occurs occasionally on some highly alkaline soils, but is also absent from calcareous beach sands; and E. diversifolia, which is found on both acidic and highly alkaline soils and is widespread on calcareous beach sands. All three species occur on siliceous sands, with E. baxteri in wetter areas than the other two species. Comparative pot experiments in which typical calcareous and siliceous sands were used showed that: (1) E. baxteri is stunted by severe lime chlorosis when grown on calcareous sand, while the other two species are not affected. (2) E. baxteri markedly outyields the other two species on siliceous sands. It is suggested that E. baxteri is absent from calcareous sands because it is physiologically intolerant of highly alkaline soils, and that E. baxteri replaces the other two species on the wetter siliceous sands because its faster growth rate enables it to outcompete them when rainfall is adequate. However, the slower growth rates of E. diversifolia and E. incrassata will be accompanied by slower rates of water use and this may give them an advantage over E. baxteri on drier siliceous sands. The wide edaphic range of E. diversifolia is considered to be the outcome of the wide physiological tolerance of individual plants rather than of intraspecific differentiation.


Soil Research ◽  
1963 ◽  
Vol 1 (1) ◽  
pp. 74 ◽  
Author(s):  
KG Tiller

The mineralogy and chemistry of weathering and soil formation have been studied at 17 widely separated sites with contrasting climatic conditions on comparatively uniform dolerite in Tasmania. The clay and fine sand mineralogy of the soils has been related to their degree of weathering. These studies have shown large chemical and mineralogical changes accompanying the initial stages of weathering in some krasnozem soils. The reorganization of cobalt, zirconium, nickel, copper, molybdenum, manganese, and zinc during genesis of four soil groups has been considered in terms of the factors involved. Some of these results indicate that the clay horizon of the podzolic soils has probably been formed by weathering in situ. Seasonal waterlogging in certain horizons has strongly mfluenced the chemistry and mineralogy of weathering in many of these soils. This study has shown that the composition of the parent material has only influenced the geochemistry of trace elements in less weathered soils and that pedogenic factors assumed greater significance as the soils became more strongly weathered. Geomorphic processes had a marked influence on the geochemistry of some soils by the truncation of mature soil profiles.


Blood ◽  
2009 ◽  
Vol 114 (22) ◽  
pp. 545-545 ◽  
Author(s):  
Jennifer A Dumont ◽  
George D Kamphaus ◽  
Cara Fraley ◽  
Tamera Ashworth ◽  
Helen Franck ◽  
...  

Abstract Abstract 545 A recombinant B-domain-deleted factor VIII-Fc (rFVIIIFc) fusion protein was created as an approach to extend the half-life of FVIII. The pharmacokinetics and pharmacodynamics of rFVIIIFc were evaluated in the Chapel Hill colony of hemophilia A dogs. These dogs have a severe hemophilic phenotype comparable to the severe form of human disease with F.VIII < 1%. A single intravenous dose (125 IU/kg) was administered to four dogs and immediately corrected the clotting to normal as measured by whole blood clotting time (WBCT) and aPTT. The WBCT remained below 20 min, the time consistent with FVIII:C > 1%, through approximately 96 h. The range of WBCT in our normal dogs is 8 to 12 min. The concentration of rFVIIIFc in the plasma was measured by ELISA and the terminal half-life was 15.7 ± 1.7 hr. Similar results were obtained when rFVIIIFc was measured using a FVIII-specific chromogenic activity assay (half-life was 15.4 ± 0.3 hr). The concentration vs. time curves were similar using both methods. The activity data were converted to ng/mL using the specific activity of the test article that was used to dose the animals, and these data correlated well with the ELISA data, thus demonstrating that the protein that was measured by ELISA was fully active. Two of the dogs also received a single dose of recombinant B-domain deleted FVIII (rBDD-FVIII, ReFacto®), 114 IU/kg for one dog and 120 IU/kg rBDD-FVIII for the other, and then received rFVIIIFc (125 IU/kg) 72 hr later in a cross over design. Clotting was corrected to normal immediately after dosing with both rBDD-FVIII and rFVIIIFc (determined by WBCT and clotting activity measured using an aPTT assay). However, the WBCT normalization after rFVIIIFc lasted for approximately twice as long compared to rBDD-FVIII and the half-lives determined from the ELISA data for FVIIIFc (15.7 ± 1.7 hr) were twice those determined for rBDD-FVIII (7.0 hr and 6.7 hr). No adverse clinical signs were detected with any of the infusions. Therefore construction of an Fc fusion of FVIII produces a molecule with a defined mechanism of action that has an increased half life and the potential to provide prolonged protection from bleeding. Disclosures: Dumont: Biogen Idec (Syntonix Subsidiary): Employment. Kamphaus:Biogen Idec (Syntonix Subsidiary): Employment. Fraley:Biogen Idec/Syntonix Subsidiary: Employment. Ashworth:Biogen Idec (Syntonix Subsidiary): Employment. Bitonti:Biogen Idec/Syntonix Subsidiary: Employment.


1958 ◽  
Vol 36 (9) ◽  
pp. 985-991 ◽  
Author(s):  
W. B. McConnell ◽  
A. K. Mitra ◽  
A. S. Perlin

Tracer techniques have been used to examine the pattern by which the straight-chain and branched components of wheat starch are laid down in the maturing kernel. The starches were isolated from kernels of wheat plants to which had been administered glucose-1-C14, acetate-1-C14, or acetate-2-C14 at different periods of active growth under field conditions. Fractionation of the starches gave amylose and amylopectin and, in addition, a minor fraction of amylopectin, all labelled with carbon-14. Notable differences were found in the specific activity of these starch fractions, and in the distribution of carbon-14 within the monomeric units of samples labelled via glucose-1-C14. These findings indicate that the process of starch deposition in the kernel is not extensively reversible. Amylopectin appears to be formed from amylose, in agreement with current views, and it is suggested that the minor amylopectin component is an intermediate in this conversion process.


2007 ◽  
Vol 18 (6) ◽  
pp. 2085-2089 ◽  
Author(s):  
Esther Schirrmacher ◽  
Björn Wängler ◽  
Marek Cypryk ◽  
Gerrit Bradtmöller ◽  
Martin Schäfer ◽  
...  

2020 ◽  
Vol 21 (4) ◽  
pp. 369-378
Author(s):  
O. A. Simonova ◽  
M. V. Simonov ◽  
E. V. Tovstik

Manganese belongs to the group of heavy metals, which at high concentrations can have a negative effect on plant development. Typical soils of the Kirov region are acid podzolic and sod-podzolic soils, which are characterized by high content of manganese compounds available for plants. Studied was the effect of manganese(II) ions at the concentrations of 30.0, 60.0 and 90.0 mg/l on the growth and antioxidant activity (AOA) of the superoxide dismutase enzyme (SOD) in the organs of 7 and 14-day-old barley plants grown in aquatic culture. Varieties and forms of barley 346-09, 29-11, Farmer 198-12, Forward and Bionik, resistant to acidic soils (Al3 +, H+) served as objects for the research; Belgorodskij 100 variety was used as standard. When manganese was added to the solution for growing, a decrease in root length and an increase in AOA of SOD in plant roots were noted. It was concluded that increased concentrations of manganese had an effect on the morphometric parameters and on AOA SOD of barley seedlings. It has been established that increasing the dose of manganese in the solution for growing leads to a decrease in the length of the roots. AOA SOD varied in different organs of plants of some varieties, and its more significant change in the experiment compared with the control was revealed in the roots. Judging by morphometric indicators, the Belgorodskij 100 variety was the least resistant to Mn2+ ionic toxicity, the root length of which in the control was 15.7±0.4 cm, and in the experiment 13.2±0.3; 12.2±0.1; 11.5±0.3 cm in accordance with the dose of manganese 30, 60 and 90 mg / l. According to the level of AOA SOD, the most sensitive variety was Farmer 198-12, its change of AOA SOD in the roots (% of control) was 158.8; 167.2 and 169.4% in accordance with the dose of manganese 30.0; 60.0 and 90.0 mg / l (AOA SOD in the control was 52.4±0.4%; in the experiment 83.2±2.2; 87.6±2.0 and 88.7±0.6, respectively), and in the shoots ˗ 121.0; 128.3 and 125.6 %, respectively (66.7±7.9 % in the control and 80.7±0.5; 85.6±1.4; 83.8±0.6 % in the experiment in accordance with the dose of Mn 2+).


Atmosphere ◽  
2021 ◽  
Vol 12 (11) ◽  
pp. 1372
Author(s):  
Felipe Cifuentes ◽  
Carlos M. González ◽  
Erika M. Trejos ◽  
Luis D. López ◽  
Francisco J. Sandoval ◽  
...  

Vehicular emissions are a predominant source of pollution in urban environments. However, inherent complexities of vehicular behavior are sources of uncertainties in emission inventories (EIs). We compare bottom-up and top-down approaches for estimating road transport EIs in Manizales, Colombia. The EIs were estimated using a COPERT model, and results from both approaches were also compared with the official top-down EI (estimated from IVE methodology). The transportation model PTV-VISUM was used for obtaining specific activity information (traffic volumes, vehicular speed) in bottom-up estimation. Results from COPERT showed lower emissions from the top-down approach than from the bottom-up approach, mainly for NMVOC (−28%), PM10 (−26%), and CO (−23%). Comparisons showed that COPERT estimated lower emissions than IVE, with higher differences than 40% for species such as PM10, NOX, and CH4. Furthermore, the WRF–Chem model was used to test the sensitivity of CO, O3, PM10, and PM2.5 predictions to the different EIs evaluated. All studied pollutants exhibited a strong sensitivity to the emission factors implemented in EIs. The COPERT/top-down was the EI that produced more significant errors. This work shows the importance of performing bottom-up EI to reduce the uncertainty regarding top-down activity data.


Literature overview. The parameterization of hydrological models requires knowledge of the soil filtration properties. Generally, soil profiles are characterized by properties such as sand, silt and clay content, bulk density, organic carbon fraction or humus content, and no data on filtration properties are available. Ukrainian soil database, created in Geoecophysics of soil laboratory of National Scientific Center “Institute for Soil Science and Agrochemistry Researched named after O.N. Sokolovsky” (Laktionova et al., 2012), among other properties has extensive data on texture and bulk density for more than 2000 profiles, less on organic carbon content, and almost no data on saturated hydraulic conductivity (Ksat). The most probable ranges of Ksat for most types of Ukrainian soils are given in the Atlas of natural conditions and natural resources of the Ukrainian SSR (“Pochvenno-meliorativnoye rayonirovaniye. Masshtab 1:4000000,” 1978), however, the data doesn’t present Ksat for different textures inside one soil type. To fill this gap, the best solution is the applying of pedotransfer function (PTF). The purpose of this work is to synthesize the most realistic Ksat of the main soil groups of Ukraine, corresponding to a scale map of 1:2 500 000 (Krupskiy, 1977), as well as their genetic horizons, on the basis of calculated and experimental values available in the literature. Material and methods. Ten PTFs used in the study are based on regression equations (Cosby et al., 1984; Saxton & Rawls, 2006; Weynants et al., 2009; Wösten et al., 1999), decision tree (Tóth et al., 2015), or neural network (Zhang & Schaap, 2017). Ksat was estimated for 942 horizons of 171 profiles which represented all 40 soil groups (corresponding to the legend of 1:2 500 000 map) of Ukraine according to Dokuchaev classification. Results. Wösten and Rosetta3 PTFs are determined as the most relevant by comparing the calculated Ksat values with the available data of the bottom (horizons A2, B, C) and top (A0, A1) soil layers of Ukraine. In particular, they are relevant for widespread soils such as Soddy podzolic soils (WRB – Eutric podzoluvisols), dark gray podzolized soils (Phaeozems Albic), chernozems podzolized (Chernozems Chernic), chernozems southern (Chernozems Calcic), meadow-chernozemic soils (Phaeozems Haplic), dark chestnut and chestnut soils (Kastanozems Haplic and Kastanozems Luvic), meadow soils (Umbrisols Gleic, Fluvisols Dystrict, Fluvisols Eutryc, Leptosols Umbric), mountain soils (Cambisols), and top layer of Chernozems ordinary (Chernozems Chernic). Unfortunately, all ten PTFs underestimate 2-4 times Ksat of bottom layer of ordinary and typical chernozems (Chernozems Chernic) and overestimate 2-5 times for relatively impermeable horizons (< 2 mm/h). Conclusions. Based on the calculated and experimental values, the map of Ksat of the top and bottom soil layers was obtained. Sandy soils, common in Polissia, have the highest filtration rate. Ksat of loam and clay soils of forest-steppe and steppe can differ between different types by an order. The highest Ksat have soils with high structural properties (Chernozems Luvic, Chernozems Chernic). The lowest Ksat (0.2-3 mm/h) have Phaeozems Sodic, Solonetz, Solonchaks, Planosols Albic, and bottom layer of soddy manly gley (Arenosols Protic/ Haplic) and loamy soddy podzolic soils (Albeluvisols Umbric). The estimated values should be considered as the most probable because Ksat depends on landscape location of soil profile, tillage operations, and soil temperate. The results are acceptable to use in hydrological calculations and modeling.


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