Perturbations of Thermodynamic State Functions

Author(s):  
Robert H. Swendsen

Because small changes in thermodynamic quantities will play a central role in much of the development of thermodynamics, the key concepts are introduced in this short chapter. The First Law (conservation of energy) can be expressed simply in terms of infinitesimal quantities: a small change in the energy of a system is equal to the heat added plus the work done on the system. The theories of statistical mechanics and thermodynamics deal with the same physical phenomena. Exact and inexact differentials are defined, along with the important concept of an integrating factor that relates them. The useful equation relating small changes in heat to corresponding changes in entropy is derived.

1885 ◽  
Vol 176 ◽  
pp. 307-342 ◽  

1. The tendency to apply dynamical principles and methods to explain physical phenomena has steadily increased ever since the discovery of the principle of the Conservation of Energy. This discovery called attention to the ready conversion of the energy of visible motion into such apparently dissimilar things as heat and electric currents, and led almost irresistibly to the conclusion that these too are forms of kinetic energy, though the moving bodies must be infinitesimally small in comparison with the bodies which form the moving pieces of any of the structures or machines with which we are acquainted. As soon as this conception of heat and electricity was reached mathematicians began to apply to them the dynamical method of the Con­servation of Energy, and many physical phenomena were shown to be related to each other, and others predicted by the use of this principle; thus, to take an example, the induction of electric currents by a moving magnet was shown by von Helmholtz to be a necessary consequence of the fact that an electric current produces a magnetic field. Of late years things have been carried still further; thus Sir William Thomson in many of his later papers, and especially in his address to the British Association at Montreal on “Steps towards a Kinetic Theory of Matter,” has devoted a good deal of attention to the description of machines capable of producing effects analogous to some physical phenomenon, such, for example, as the rotation of the plane of polarisation of light by quartz and other crystals. For these reasons the view (which we owe to the principle of the Conservation of Energy) that every physical phenomenon admits of a dynamical explanation is one that will hardly be questioned at the present time. We may look on the matter (including, if necessary, the ether) which plays a part in any physical phenomenon as forming a material system and study the dynamics of this system by means of any of the methods which we apply to the ordinary systems in the Dynamics of Rigid Bodies. As we do not know much about the structure of the systems we can only hope to obtain useful results by using methods which do not require an exact knowledge of the mechanism of the system. The method of the Conservation of Energy is such a method, but there are others which hardly require a greater knowledge of the structure of the system and yet are capable of giving us more definite information than that principle when used in the ordinary way. Lagrange's equations and Hamilton's method of Varying Action are methods of this kind, and it is the object of this paper to apply these methods to study the transformations of some of the forms of energy, and to show how useful they are for coordinating results of very different kinds as well as for suggesting new phenomena. A good many of the results which we shall get have been or can be got by the use of the ordinary principle of Thermodynamics, and it is obvious that this principle must have close relations with any method based on considerations about energy. Lagrange’s equations were used with great success by Maxwell in his ‘Treatise on Electricity and Magnetism,’ vol. ii., chaps. 6, 7, 8, to find the equations of the electromagnetic field.


2021 ◽  
Vol 34 (2) ◽  
pp. 236-247
Author(s):  
Huawang Li

In this paper, we conjecture that gravitation, electromagnetism, and strong nuclear interactions are all produced by particle collisions by determining the essential concept of force in physics (that is, the magnitude of change in momentum per unit time for a group of particles traveling in one direction), and further speculate the existence of a new particle, Yizi. The average kinetic energy of Yizi is considered to be equal to Planck’s constant, so the mass of Yizi is calculated to be <mml:math display="inline"> <mml:mrow> <mml:mn>7.37</mml:mn> <mml:mo>×</mml:mo> <mml:msup> <mml:mrow> <mml:mn>10</mml:mn> </mml:mrow> <mml:mrow> <mml:mo>−</mml:mo> <mml:mn>51</mml:mn> </mml:mrow> </mml:msup> </mml:mrow> </mml:math> kg and the average velocity of Yizi is <mml:math display="inline"> <mml:mrow> <mml:mn>4.24</mml:mn> <mml:mo>×</mml:mo> <mml:msup> <mml:mrow> <mml:mn>10</mml:mn> </mml:mrow> <mml:mn>8</mml:mn> </mml:msup> </mml:mrow> </mml:math> m/s. The universe is filled with Yizi gas, the number density of Yizi can reach <mml:math display="inline"> <mml:mrow> <mml:mn>1.61</mml:mn> <mml:mo>×</mml:mo> <mml:msup> <mml:mrow> <mml:mn>10</mml:mn> </mml:mrow> <mml:mrow> <mml:mn>64</mml:mn> </mml:mrow> </mml:msup> </mml:mrow> </mml:math> /m3, and Yizi has no charge. After abandoning the idealism of physics, I try to construct a physical framework from three elementary particles: Protons, electrons, and Yizis. (The elementary particles mentioned here generally refer to the indivisible particles that constitute objects.) The effects of Yizi on the conversion of light, electricity, magnetism, mass, and energy as well as the strong nuclear and electromagnetic forces are emphasized. The gravitation of electromagnetic waves is measured using a Cavendish torsion balance. It is shown experimentally that electromagnetic waves not only produce pressure (repulsion) but also gravitational forces upon objects. The universe is a combination of three fundamental particles. Motion is eternal and follows the laws of conservation of energy and momentum. There is only one force: The magnitude of change in momentum per unit time for a group of particles traveling in one direction. Furthermore, this corresponds to the magnitude of the force that the group of particles exerts in that direction. From this perspective, all physical phenomena are relatively easy to explain.


Author(s):  
Sergii Tereschuk ◽  
Vira Kolmakova

The concept of "sensor" in the system of physical experiment at school is considered in the article. The possibility of using sensors in physics lessons is substantiated: transformation of an input signal into an output is accompanied by transformation of one type of energy into another (according to the law of conservation of energy), and the functioning of the sensors are based on physical phenomena (physical effects or principles), which are described by the relevant physical laws. The article deals with the methodical aspects of using the Google Science Journal mobile application in physics lessons. This application allows you to use the sensors of your mobile device for a physical experiment. As an example we consider the frontal laboratory work "Determination of the period of oscillation of the mathematical pendulum". The method of its carrying out is offered in two approaches: the first one involves the traditional technique of conducting the experiment, and the second approach is using the mobile application Google Science Journal. The article shows that the use of smartphone sensors in physics lessons has perspectives in the context of STEM education. Thus, the use of the considered application is of current importance and requires further scientific and methodological research on its use in the high school physical experimentation system. The Science Journal mobile application can be used to connect external sensors, which will have a positive impact on the introduction of STEM education, and to use Arduino in the demonstration of physical experiments by a physics teacher. Connecting sensors using an Arduino microcontroller is particularly promising in creative lab work on physics.


2018 ◽  
Author(s):  
Georgios C. Boulougouris

In this work a geometrical representation of equilibrium and near equilibrium statistical mechanics is proposed. Using a formalism consistent with the Bra-Ket notation and the definition of inner product as a Lebasque integral, we describe the macroscopic equilibrium states in classical statistical mechanics by “properly transformed probability Euclidian vectors” that point on a manifold of spherical symmetry. Furthermore, any macroscopic thermodynamic state “close” to equilibrium is described by a triplet that represent the “infinitesimal volume” of the points, the Euclidian probability vector at equilibrium that points on a hypersphere of equilibrium thermodynamic state and a Euclidian vector a vector on the tangent bundle of the hypersphere. The necessary and sufficient condition for such representation is expressed as an invertibility condition on the proposed transformation. Finally, the relation of the proposed geometric representation, to similar approaches introduced under the context of differential geometry, information geometry, and finally the Ruppeiner and the Weinhold geometries, is discussed. It turns out that in the case of thermodynamic equilibrium, the proposed representation can be considered as a Gauss map of a parametric representation of statistical mechanics.


Author(s):  
Daniel L. Stein ◽  
Charles M. Newman

This chapter introduces the basic concepts and language that will be needed later on: order, symmetry, invariance, broken symmetry, Hamiltonian, condensed matter, order parameter, ground state, and several thermodynamic terms. It also presents the necessary concepts from thermodynamics and statistical mechanics that will be needed later. It boils down the latter to its most elemental and essential ingredient: that of temperature as controlling the relative probabilities of configurations of different energies. For much of statistical mechanics, all else is commentary. This is sufficient to present an intuitive understanding of why and how matter organizes itself into different phases as temperature varies, and leads to the all-important concept of a phase transition.


Contract Law ◽  
2020 ◽  
pp. 444-471
Author(s):  
Ewan McKendrick

This chapter focuses on Part 2 of the Consumer Rights Act 2015. The Act gives to the courts much broader powers to regulate terms in contracts which have been concluded between traders and consumers. Section 2 examines the individual sections of Part 2 of the Act and the leading cases decided under the Regulations which preceded the Act. Particular attention is given to key concepts such as ‘significant imbalance’, ‘good faith’, the exclusion of certain terms from assessment for fairness, the indicative and non-exhaustive list of terms that may be regarded as unfair, and the role of regulators in the enforcement of the legislation. Section 3 draws on work done by Professor Susan Bright in relation to the role of the Unfair Contract Terms Unit in the early days of the enforcement of the legislation.


1. The two laws of Thermodynamics have proved by far the most powerful, indeed almost the only, means we possess of connecting the phenomena in one branch of Physics with those in another. Though the two laws are usually grouped together, it should not be forgotten that they differ essentially in character. The First Law is a direct application to Physics of one of the most important dynamical principles, that of the Conservation of Energy; while the Second Law, which for the purpose of connecting various physical phenomena is even more important than the first, is not, strictly speaking, a dynamical principle at all, since its statement involves a reference to quantities which never occur in abstract Dynamics. Clausius and Sir William Thomson, the two physicists to whom the Second Law owes its importance, have connected it with other principles which seem more axiomatic.


Entropy ◽  
2019 ◽  
Vol 21 (9) ◽  
pp. 884 ◽  
Author(s):  
Rodrigo Cofré ◽  
Leonardo Videla ◽  
Fernando Rosas

Although most biological processes are characterized by a strong temporal asymmetry, several popular mathematical models neglect this issue. Maximum entropy methods provide a principled way of addressing time irreversibility, which leverages powerful results and ideas from the literature of non-equilibrium statistical mechanics. This tutorial provides a comprehensive overview of these issues, with a focus in the case of spike train statistics. We provide a detailed account of the mathematical foundations and work out examples to illustrate the key concepts and results from non-equilibrium statistical mechanics.


2014 ◽  
Vol 783-786 ◽  
pp. 2284-2289 ◽  
Author(s):  
J.Y. Hascoet ◽  
K.P. Karunakaran ◽  
S. Marya

Additive Manufacturing (AM), also designated as 3D Printing (3DP), is one of the most visionary and friendly approaches for flexible manufacturing with conservation of energy and material resources. It is a factory in a box that can generate multiple objects. It requires little manpower to bring virtual innovations into the real world. AM for metals can be mechanistically associated with welding. The technique employs a variety of energy sources (laser, electron beam, electric Arc, ...), feed stocks (powder, wire and ribbon) and motion kinematics & control (articulated robot and 3-5 axes CNC machine ). From the materials perspectives, akin to fusion welding in many respects, AM involves a multitude of complex and interacting physical phenomena such as heat transfer, fluid flow, discrete and continuum mechanics, sintering, melting, solidification, solid state transformations, grain growth, diffusion, textures etc. The desired process performance can be achieved by controlling the parameters of energy, feed stock and motion. The effect of successive thermal cycles along with the epitaxial relations between substratum and deposits constitute some of the challenging tasks for developing optimized parts. This paper reviews the state of the art and presents some challenges facing metal product development for service applications.


Author(s):  
Brian Cantor

Thermodynamics describes the relationship between heat, work, energy and motion. The key concepts are the conservation of energy and the maximisation of entropy (or disorder) as given by the first and second laws of thermodynamics. Boltzmann’s equation explains how the entropy of a material is related to the disorder of its atoms or molecules, as measured by the probability or the number of equivalent atomic or molecular structures. This chapter examines thermodynamic properties such as internal energy, enthalpy and Gibbs and Helmholtz free energy; physical properties such as specific heat and thermal expansion coefficient; and the application of thermodynamics to chemical reactions, solid and liquid solutions, and phase separation. Ludwig Boltzmann’s early life as the son of a minor tax official in Austria is described, as are: his scientific career in a series of Austrian and German universities; his philosophical arguments with Ernst Mach and the phenomenalists about whether atoms do or do not exist; his increasing moodiness, paranoia and bipolar disorder; and his ultimate suicide while trying to recuperate from depression in Trieste.


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