Marscoite and related rocks of the Western Red Hills complex, Isle of Skye

The rock from Skye which Harker called marscoite was recognized by him to be hybrid in origin because of the close association in the rock of basic plagioclase, quartz and orthoclase. The position of marscoite in the sequence of rocks forming the Western Red Hills Tertiary complex has now been defined, and evidence for its parentage and the mechanics of its formation obtained. The Western Red Hills intrusive centre, developed after the Cuillin and before the Broadford centres, as suggested by J. E. Richey, consists of five different, high-level granitic intrusions which were followed by a southern and northern series of late intrusions, including marscoites, ferrodiorites, and various additional granitic rocks. The high-level granitic rocks of Skye, which have so far been loosely termed granophyres, cannot all properly be described as such, and the term epigranite is proposed as a general name for them. The earliest rocks belonging to the southern late intrusions are porphyritic epigranites and felsites, having quartz and potash felspar phenocrysts resembling the xenocrysts of these minerals in the marscoite. Then came marscoite, somewhat chilled against the felsite but also back-veined by it. The marscoite in Harker’s Gully, and in other places on Marsco, passes gradually into ferrodiorite which sometimes contains basic andesine phenocrysts similar to the xenocrysts of the marscoite. The ferrodiorite has a composition suggesting that it was derived by extreme fractional crystallization of basic magma. The xenocrysts of the marscoite are highly characteristic and indicate that marscoite was formed by the mixing of a porphyritic acid magma, like that which produced the Southern Porphyritic Felsite, and a porphyritic basic magma, like that which produced the porphyritic ferrodiorite of Marsco. The chemical compositions of the presumed parent materials and marscoite support this view. Because of the even distribution of the xenocrysts in marscoite, the mixing must have been largely effected by the mechanical stirring together of two liquids, in both of which were suspended crystals. Diffusion within the liquid phase must also have contributed in some degree to the ultimate homogeneity of the liquid part of the mixture. The origin of the marscoite of the northern late intrusions is presumably similar to that of the southern, except that the basic parent is believed to be represented by the porphyritic hawaiite blocks in the northern marscoite. The northern marscoite cuts through, and is chilled against, the Glamaig, Eas Mor, and Maol na Gainmhich epigranites. Inwards from the contacts, the marscoite gives place, in a distance of 30 to 50 yd., to a rock here called glamaigite, which consists of rounded, dark patches, usually an inch or so across, and a less dark matrix, in approximately equal amounts. In both dark and light material there are xenocrysts of andesine, potash felspar and quartz, as in the marscoite. The difference in composition of the darker and lighter parts of the rock is not great, but is such as to suggest that the darker would have had a slightly higher temperature range of crystallization. The glamaigite is believed to have originated from a less well-homogenized mixture of basic and acid porphyritic magmas. From the mixture, the slightly more basic parts solidified first, and then flow movements of the magma resulted in rounding of the early semi-solid clots of hybrid material. The central parts of the composite, northern, late intrusions consist of a rock resembling glamaigite but tending to be more uniform and acid in composition. The greater homogeneity of this rock, distinguished as dioritic glamaigite, may be due to its central position within the intrusions, where slower cooling would allow more time for diffusion. It is suggested that the epigranites of the Hebridean igneous province originated by melting of crustal rocks of broadly granitic composition. The heat to produce the melting is believed to have been derived from basic magma intruded into the earth’s crust, the upward transfer of heat being aided by convection in the magma and bottom accumulation of early formed crystals. At some stage, a residual layer of ferrodiorite or hawaiite liquid, produced by fractionation, may have underlain a granitic liquid produced by melting. Two separate systems of convection currents are envisaged in the two liquids, because of the differing densities. At the junction of the two systems of currents, where they would be flowing in opposite directions, there would be an opportunity for mechanical mixing. Ultimately, a mass of hybrid magma may have developed, annular in form and with a forced circulation, which was the source of the marscoite and related rocks.

Crystalline rocks, particularly granitic rocks and basalts, are one of the principal rock types under consideration as a potential host rock for a high-level radioactive waste repository. Permeability in such rocks is related to discontinuities of various scales, and the quantification and prediction of groundwater flow within both the fractures and the intact rock between the fractures is the major goal of field experiments. The Canadian Underground Research Laboratory is unique in that the hydrogeological conditions within a large volume of rock surrounding the experimental shaft are being monitored before, during and after excavation and the results compared with model predictions. In Switzerland twelve deep boreholes are being drilled to over 1000 m to investigate crystalline basement rocks beneath a cover of sediments. The Stripa Mine in Sweden has hosted a major experimental programme including heater tests to stimulate the thermal effect of radioactive waste and hydrogeological tests at various scales down to individual fractures. The United States of America, the United Kingdom, France and Finland have also embarked on major experimental programmes. Continuing research is needed, with an emphasis on field experiments and research in underground rooms, to provide the data on which detailed risk assessments can be based.


2019 ◽  
Vol 30 (3) ◽  
pp. 1357-1365 ◽  
Author(s):  
Jiahe Zhang ◽  
Lianne H Scholtens ◽  
Yongbin Wei ◽  
Martijn P van den Heuvel ◽  
Lorena Chanes ◽  
...  

Abstract Degree centrality is a widely used measure in complex networks. Within the brain, degree relates to other topological features, with high-degree nodes (i.e., hubs) exhibiting high betweenness centrality, participation coefficient, and within-module z-score. However, increasing evidence from neuroanatomical and predictive processing literature suggests that topological properties of a brain network may also be impacted by topography, that is, anatomical (spatial) distribution. More specifically, cortical limbic areas (agranular and dysgranular cortices), which occupy an anatomically central position, have been proposed to be topologically central and well suited to initiate predictions in the cerebral cortex. We estimated anatomical centrality and showed that it positively correlated with betweenness centrality, participation coefficient, and communicability, analogously to degree. In contrast to degree, however, anatomical centrality negatively correlated with within-module z-score. Our data suggest that degree centrality and anatomical centrality reflect distinct contributions to cortical organization. Whereas degree would be more related to the amount of information integration performed by an area, anatomical centrality would be more related to an area’s position in the predictive hierarchy. Highly anatomically central areas may function as “high-level connectors,” integrating already highly integrated information across modules. These results are consistent with a high-level, domain-general limbic workspace, integrated by highly anatomically central cortical areas.


2020 ◽  
Vol 20 (1) ◽  
Author(s):  
Huan Zhang ◽  
Dianyun Ren ◽  
Xin Jin ◽  
Heshui Wu

Abstract Background Several studies were conducted to explore the prognostic value of modified Glasgow Prognostic Score (mGPS) in pancreatic cancer, which reported contradictory results. The purpose of this meta-analysis was to summarize and further investigate the correlation between mGPS and overall survival (OS) in pancreatic cancer. Methods A systematic literature search was performed in PubMed, EMBASE, ISI Web of Science, Cochrane library databases and OVID to identify eligible studies published from Jan 1, 2011 to June 20, 2020. Pooled hazard ratios (HRs) with corresponding 95% confidence intervals (CIs) were used to detect the prognostic significance of mGPS in patients with pancreatic cancer. Results A total of 222 non-repetitive studies were identified, and 20 related studies that explored the association between survival outcomes and mGPS in pancreatic cancer patients were finally enrolled in this meta-analysis. The results showed a significant correlation between high level of mGPS and poor OS (HR = 1.50, 95% CI 1.20–1.89, P < 0.0001). Similar results were observed in the subgroup analyses based on the treatment regimen and research region. Conclusions Our study suggested the close association between poor prognosis and high level of mGPS, which will be helpful for future clinical applications in patients with pancreatic cancer.


1997 ◽  
Vol 506 ◽  
Author(s):  
V. M. Oversby

ABSTRACTThe conditions that are needed to achieve criticality in a high level waste repository for spent nuclear reactor fuel are reviewed. The effect of initial enrichment of the fuel, burnup, and of mixed oxide fuels on the conditions for criticality are discussed. The situations that produced criticality at Oklo, Gabon, 2000 million years ago are summarized. A model based on the Oklo conditions is presented for estimating the amount of fissile material that must be assembled to create a critical mass in typical granitic rocks. Mechanisms for movement of uranium and plutonium to achieve a critical configuration are discussed and compared to the conditions that are likely to occur in a repository in granite. The sequences of events needed to produce a critical assemblage are shown to be in conflict with the conditions expected in the repository and, in some cases, to require internally inconsistent assumptions to produce the postulated sequence of events. No credible scenario for achieving criticality in a high level waste repository has been found.


2015 ◽  
Vol 220-221 ◽  
pp. 813-817
Author(s):  
Anna Kawałek ◽  
Monika Magiera ◽  
Henryk Dyja ◽  
Marcin Knapiński ◽  
Bartosz Koczurkiewicz ◽  
...  

The Institute of Metal Forming and Safety Engineering has developed technology for manufacturing grade X80 pipeline plates according to European standard EN 10208-2. Experimental chemical compositions ensuring a high level of yield strength have been developed. The article describes a method for selecting chemical composition [1]. The advancement of rolling technology takes much time and many calculations. Thus, using numerical simulations provides a possibility of a theoretical analysis of the plates made from new materials [4], [5]. Preliminary studies [1] have disclosed a large volume of deformations during the rolling process, which causes the distortion of rolls and generates heavy loads. For the theoretical analysis of rolling plates, Forge 2008® was used. The paper presents the obtained results of energy analysis and strength parameters displayed in Figure 1. The article considers a total amount of pressure on metal rollers and changes in the rolling moment.


2016 ◽  
Vol 1 (1) ◽  
pp. 30-32
Author(s):  
Тагиров ◽  
Khamit Tagirov ◽  
Долженкова ◽  
Galina Dolzhenkova

The purpose of research focused on post-slaughter evaluation of meat productivity and meat quality the Kazakh White-headed breed when introduced into the diet of feed additives BioDarin. Presents the results of the control slaughter heifers 18 months old as well as the results of studies of morphological and chemical compositions of the carcass. The research was conducted post-slaughter evaluation of meat productivity and meat quality of heifers of Kazakh White-headed breed when introduced into the diet of feed additives BioDarin. Scientific and economic experiment was carried out on the basis of JSC AIC «Alga+» Tuimazinsk district of the Republic of Bashkortostan. For the experiment there were formed 4 groups of heifers of Kazakh white-headed breed: group I – control; group II heifers in addition to the basic diet received a feed additive in a dose of 0.5 kg per 100 kg of grain mixture, the animals of group III received 1 kg of the feed additive per 100 kg of grain mixture, peers IV groups received 1.5 kg of a grain mixture. Among the studied groups, heifers of the III experienced group receiving feed additive at a dose of 1.0 kg per 100 kg of grain mixture, had a high level of meat productivity. It was found that meat products of the best quality was got also from animals of group III.


This paper is concerned with the existence of solutions of the Dirichlet problem for quasilinear elliptic partial differential equations of second order, the conclusions being in the form of necessary conditions and sufficient conditions for this problem to be solvable in a given domain with arbitrarily assigned smooth boundary data. A central position in the discussion is played by the concept of global barrier functions and by certain fundamental invariants of the equation. With the help of these invariants we are able to distinguish an important class of ‘ regularly elliptic5 equations which, as far as the Dirichlet problem is concerned, behave comparably to uniformly elliptic equations. For equations which are not regularly elliptic it is necessary to impose significant restrictions on the curvatures of the boundaries of the underlying domains in order for the Dirichlet problem to be generally solvable; the determination of the precise form of these restrictions constitutes a second primary aim of the paper. By maintaining a high level of generality throughout, we are able to treat as special examples the minimal surface equation, the equation for surfaces having prescribed mean curvature, and a number of other non-uniformly elliptic equations of classical interest.


1969 ◽  
Vol 106 (6) ◽  
pp. 531-541 ◽  
Author(s):  
D. H. Blake

SUMMARYThe ‘Maelifell caldera’ is the name given to a separate collapse area situated on the southern margin of the main caldera of the Tertiary Alftafjordur volcano. It is 2 km in diameter and is made up of inward dipping welded tuffs, agglomerate (including patches of welded agglomerate), tuffaceous sediments and rhyolite and andesite lavas. The welded tuffs occur as thin pitchstone sheets and as much thicker felsitic masses: the former contain inclusions of basalt glass and are good examples of the simultaneous eruption of acid and basic magmas. It is suggested that the caldera represents the core of a parasitic volcano, beneath which there was a high level acid magma chamber, the immediate source of the local acid rocks. The magma chamber was intersected by numerous intrusions of basic magma, and these caused explosive eruptions and the emission of acid and basic magma to form thin pitchstone sheets. Decreased pressure in the magma chamber after eruptions caused repeated collapse within the cal


Author(s):  
Vojtěch Janoušek ◽  
Fritz Finger ◽  
Malcolm Roberts ◽  
Jiří Frýda ◽  
Christian Pin ◽  
...  

ABSTRACTThe prominent felsic granulites in the southern part of the Bohemian Massif (Gföhl Unit, Moldanubian Zone), with the Variscan (∼340 Ma) high-pressure and high-temperature assemblage garnet+quartz+hypersolvus feldspar ± kyanite, correspond geochemically to slightly peraluminous, fractionated granitic rocks. Compared to the average upper crust and most granites, the U, Th and Cs concentrations are strongly depleted, probably because of the fluid and/or slight melt loss during the high-grade metamorphism (900–1050°C, 1·5–2·0 GPa). However, the rest of the trace-element contents and variation trends, such as decreasing Sr, Ba, Eu, LREE and Zr with increasing SiO2 and Rb, can be explained by fractional crystallisation of a granitic magma. Low Zr and LREE contents yield ∼750°C zircon and monazite saturation temperatures and suggest relatively low-temperature crystallisation. The granulites contain radiogenic Sr (87Sr/86Sr340 = 0·7106–0·7706) and unradiogenic Nd ( = − 4·2 to − 7·5), indicating derivation from an old crustal source. The whole-rock Rb–Sr isotopic system preserves the memory of an earlier, probably Ordovician, isotopic equilibrium.Contrary to previous studies, the bulk of felsic Moldanubian granulites do not appear to represent separated, syn-metamorphic Variscan HP–HT melts. Instead, they are interpreted as metamorphosed (partly anatectic) equivalents of older, probably high-level granites subducted to continental roots during the Variscan collision. Protolith formation may have occurred within an Early Palaeozoic rift setting, which is documented throughout the Variscan Zone in Europe.


2021 ◽  
Vol 11 (16) ◽  
pp. 7739
Author(s):  
Hekmat AL-Hmadi ◽  
Ridha El Mokni ◽  
Rajesh K. Joshi ◽  
Mohamed L. Ashour ◽  
Saoussen Hammami

Essential oils are generally produced to confer the protection of medicinal plants against several natural enemies. Variations of chemical and physical environmental factors exert significant influences on plant development. They hence may affect the quality and quantity of volatile organic metabolites of interest and, therefore, the economic applications of essential oils. This research focused on the effects of the harvest region on the production and analytes present in Tunisian Pimpinella lutea Desf. Apiaceae that were collected in three different growing environments (North and South Bizerta and Tabarka). Essential oils extracted from a variety of genotypes were analyzed, for the first time, using gas chromatography and mass spectrometry (GC/FID and GC/MS). The determination of the percentage of essential oil components allowed the recognition of three chemotypes: α-trans-Bergamotene quantified at a percentage of 18.1% in North Bizerta (NBEO), muurola-4,10(14)-dien-1-β-ol identified in South Bizerta (10.1%, SBEO) and acora-3,7(14)-dien present in a high level of 29.1% in Tabarka population (TEO). The richness of different populations in sesquiterpenes (60.2–78.1%) suggests that Pimpinella lutea Desf. may be used in different industrial segments.


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