Corrosive wear and electrochemical corrosion performances of arc sprayed Al coating in 3.5% NaCl solution

2021 ◽  
Vol ahead-of-print (ahead-of-print) ◽  
Author(s):  
Peng Li ◽  
Xiya Huang ◽  
Dejun Kong

Purpose The purpose of this paper is to investigate the effects of load and speed on the corrosive wear performance of Al coating in 3.5% NaCl solution, which provided an experimental reference for the anti-corrosion engineering on offshore platforms. Design/methodology/approach A layer of Al coating was prepared on S355 steel using an arc spraying. The corrosive wear test was carried out with CFT–1 type surface property tester. The effects of load and speed on the corrosive wear performance of Al coating were investigated and the wear mechanism was also discussed. The electrochemical tests were conducted using a CHI660E type electrochemical workstation, the anti-corrosion mechanism was analyzed. Findings The average coefficient of frictions (COFs) of Al coating under loads of 1.5, 2.5 and 3.5 N are 0.745, 0.847 and 0.423, the wear mechanism is abrasive wear. The average COFs of Al coating at the speeds of 200, 400 and 600 rpm are 0.745, 0.878 and 0.617, respectively, the wear mechanism at the speeds of 200 and 400 rpm are abrasive wear, while that at the speed of 600 rpm is abrasive wear and fatigue wear. The anti-corrosion mechanism is the isolation of Cl– corrosion and cathodic protection of sacrificial anode. Originality/value This paper mainly studied corrosive wear and electrochemical corrosion performances of Al coating. This study hereby confirms that this manuscript is the original work and has not been published nor has it been submitted simultaneously elsewhere. This paper further confirms that all authors have checked the manuscript and have agreed to the submission.

2019 ◽  
Vol 66 (5) ◽  
pp. 537-543 ◽  
Author(s):  
Zhou Weitong ◽  
Kong Dejun

Purpose This paper aims to enhance the corrosive wear and electrochemical corrosion of Ti–6Al–4V alloy. Design/methodology/approach A CoCrAlYTaSi alloy coating was fabricated on Ti–6Al–4V alloy using a laser thermal spraying (LTS). The surface and cross-section morphologies, chemical elements, phases and bonding strength of the obtained coating were analyzed using a scanning electron microscope, energy dispersive spectroscope, X-ray diffraction and scratch test, respectively, The corrosive wear and electrochemical corrosion of CoCrAlYTaSi coating in 3.5 Wt.% NaCl solution were investigated using a wear tester and electrochemical workstation, respectively. Findings The average coefficient of frictions (COFs) of CoCrAlYTaSi coating under the wear loads of 2, 4 and 6 N are 1.31, 1.02 and 0.88, respectively; and the corresponding wear rates are 0.66 × 10−4, 1.10 × 10−4 and 1.30 × 10−4 mm3·N–1·m–1, respectively. The wear mechanism under the wear load of 2 N is abrasive wear, while those under the wear loads of 4 and 6 N are adhesive wear and abrasive wear. The charge transfer resistance of CoCrAlYTaSi coating is 5.368 × 105 Ω·cm2, higher than 2.193 × 105 of the substrate. Originality/value In this study, a CoCrAlYTaSi coating was firstly fabricated on Ti–6Al–4V alloy using a LTS. Its corrosive wear and electrochemical corrosion in 3.5 Wt.% NaCl solution were investigated, which played a protective role of corrosive wear on Ti–6Al–4V alloy.


2019 ◽  
Vol 66 (5) ◽  
pp. 565-572
Author(s):  
Xiaoxiao Liu ◽  
Dejun Kong

Purpose This study aims to investigate the salt spray corrosion (SSC) and electrochemical corrosion of obtained Zn–Al coating, which provided a basis for comprehensive analysis of corrosion behavior of Zn–Al coating. Design/methodology/approach A Zn–Al coating was fabricated on Q235A steel using a Dacromet method. The SSC and electrochemical corrosion performances in 3.5 Wt.% NaCl solution were investigated using an SSC chamber and electrochemical workstation, respectively, and the corrosion mechanism of Zn–Al coating was discussed. Findings The Dacromet fabricated Zn–Al coating is primarily composed of Zn and Al phases, its residual stress of −11.1 ± 4 MPa is compressive stress, which is beneficial to improve its corrosion resistance. In the SSC process, the corrosion product of Zn5(OH)8Cl2H2O enhances the corrosion resistance of Zn–Al coating, which provides sufficient cathodic protection for the substrate. The corrosion potential of Zn–Al coating is lower than that of substrate, which provides sufficient cathodic protection to the substrate, the Zn–Al coating in the immersion periods is protected by the corrosion product and Zn–Al sheets. Originality/value In this study, a Zn–Al coating was first fabricated on Q235A steel using a Dacromet method.


2020 ◽  
Vol 72 (10) ◽  
pp. 1199-1204
Author(s):  
Hilmi Amiruddin ◽  
Mohd Fadzli Bin Abdollah ◽  
Muhamad Aliff Danial Mohamad Nizar

Purpose This study aims to introduce a novel technique which helped in quantifying the wear performance of a roller chain which was lubricated by using the palm oil-based hexagonal boron nitride (hBN) nanoparticles (nano-biolubricant). Design/methodology/approach The efficiency of the nano-biolubricant was evaluated by using a custom-made roller chain tribometer, at different resistance torque values at a constant speed and running time. Prior to the test, 2 different lubrication conditions were applied. The mass loss and elongation behaviour of a roller chain was selected as a degradation metric for monitoring the amount of the chain wear. The predominant wear mechanism of a roller chain was identified by surface morphological analysis. Findings Regardless of the lubrication conditions, the wear performance of the roller chain was significantly increased, at increasing resistance torque values. Higher wear was noted when the roller chain was lubricated using a nano-biolubricant, however, the wear curve showed a promising high chain life. The predominant wear mechanism involved is abrasive wear. Originality/value Although an increase in the elongation during running is based on the wear between the pins and roller, none of the earlier studies quantified the wear performance of a roller chain under differing lubrication conditions. Hence, for bridging the gap, this study described a new method for measuring the wear performance of the roller chain which was lubricated using the palm oil-based hBN nanoparticles or a nano-biolubricant. Peer review The peer review history for this article is available at: https://publons.com/publon/10.1108/ILT-02-2020-0061/


2017 ◽  
Vol 69 (6) ◽  
pp. 919-924
Author(s):  
Dawit Zenebe Segu ◽  
Pyung Hwang

Purpose This study aims to compare the friction and wear behaviors of Fe68.3C6.9Si2.5 B6.7P8.8Cr2.2Al2.1Mo2.5 bulk metallic glass (BMG) under sliding using dry, deionized water-lubricated and oil-lubricated conditions. The comparison was performed using a unidirectional ball-on-flat tribometer under different applied loads, and the results were compared to the properties of a conventional material, SUJ2. Fe-based BMG materials have recently been attracting a great deal of attention for prospective engineering applications. Design/methodology/approach As a part of the development of Fe-based BMGs that can be cost-effectively produced in large quantities, an Fe-based BMG Fe68.8C7.0Si3.5B5.0P9.6 Cr2.1Mo2.0Al2.0 with high glass forming ability was fabricated. In the present study, the friction and wear properties of Fe-based BMG has been comparatively evaluated under dry sliding, deionized water- and oil-lubricated conditions using a unidirectional ball-on-flat tribometer under different applied loads, and the results were compared to the properties of conventional material SUJ2. Findings The results show that the Fe-based BMG had better friction performance than the conventional material. Both the friction coefficient and wear mass loss increased with increasing load. The sliding wear mechanism of the BMG changed with the sliding conditions. Under dry sliding conditions, the wear scar of the Fe-based BMG was characterized by abrasive wear, plastic deformation, micro-cracks and peeling-off wear. Under water- and oil-lubricated conditions, the wear scar was mainly characterized by abrasive wear and micro-cutting. Originality/value In this investigation, the authors developed a new BMG alloy Fe68.8C7.0Si3.5B5.0P9.6Cr2.1Mo2.0Al2.0 to improve the friction and wear performance under dry sliding, deionized water- and oil- lubricated conditions.


Author(s):  
Shao Lifan ◽  
Ge Yuan ◽  
Kong Dejun

In order to improve the friction and wear properties of Cu10Al–MoS2 coating, the addition of CeO2 is one of the present research hot spots. In this work, Cu10Al–MoS2 coatings with different CeO2 mass fractions were successfully fabricated on Q235 steel using a laser cladding. The microstructure and phase compositions of obtained coatings were analyzed using an ultra-depth of field microscope and X-ray diffraction, respectively. The friction-wear test was carried out under oil lubrication using a ball-on-disk wear tester, and the effects of CeO2 mass fraction on the microstructure, hardness, and friction-wear properties were studied, and the wear mechanism was also discussed. The results show that the laser cladded Cu10Al–MoS2 coatings with the different CeO2 mass fractions were mainly composed of Cu9Al4, Cu, AlFe3, Ni, MoS2, and CeO2 phases. The Vickers-hardness (HV) of Cu10Al–8MoS2–3CeO2, Cu10Al–8MoS2–6CeO2, and Cu10Al–8MoS2–9CeO2 coatings was 418, 445, and 457 HV0.3, respectively, which indicates an increase in hardness with the increase of CeO2 mass fraction. The average coefficients of friction (COF) and wear rates decrease with the increase of CeO2 mass fraction, presenting the outstanding friction reduction and wear resistance performances. The wear mechanism of Cu10Al–MoS2 coatings is changed from abrasive wear with slight fatigue wear to abrasive wear with the increase of CeO2 mass fraction.


2019 ◽  
Vol 11 (1) ◽  
pp. 56-61
Author(s):  
Wei Yuan ◽  
Shengkai Mei ◽  
Song Li ◽  
Zhiwen Wang ◽  
Jie Yu ◽  
...  

Background: Grooves may inevitably occur on the surface of the friction pair caused by severe wear or residual stress, which will play an important role on the reliability of machine parts during operation. Objective: The effect of the micro-grooves perpendicular to sliding direction on the wear performance of the friction pairs should be studied. Method: Micro-grooves can be machined on discs of friction pairs using electrical discharge machining. On-line visual ferrograph method was used to monitor the wear process to research the wear rate changing characteristic. Profilemeter and metallurgical microscope were used to observe the wear scars. Results: Comparing to the non-groove test, i) in one-groove test, wear volume and rate were approximate the same, and the wear scar was smooth, ii) when the grooves more than 4, the test running-in stage will be obviously prolonged, particularly for the test with 8 grooves on the disc, the duration of running-in stage is 4 times than that without grooves on specimen, and the wear rate and volume increase significantly, and then decrease with fluctuation, iii) the abrasive wear can be avoid with the debris stagnating in the groove, however, fatigue wear will significantly emerge. Conclusion: Abrasive wear can be avoided and smooth running-in surfaces can be obtained with proper amount of initial radial micro-grooves.


2019 ◽  
Vol 66 (3) ◽  
pp. 352-359
Author(s):  
Li Jiahong ◽  
Kong Dejun

Purpose The purpose of this paper is to improve the salt spray corrosion and electrochemical corrosion performances of H13 hot work mould steel, Cr–Ni coatings with the different Cr and Ni mass ratios are fabricated using a laser cladding (LC), which provides an experimental basis for the surface modification treatment of H13 steel. Design/methodology/approach Cr–Ni coatings with the different Cr and Ni mass ratios were firstly fabricated on H13 hot work mould steel using a laser cladding (LC). The salt spray corrosion (SSC) and electrochemical corrosion performances of Cr–Ni coatings in 3.5 Wt.% NaCl solution were investigated to analyze the corrosion mechanism, and the effect of mass ratios of Cr and Ni on their corrosion mechanism was discussed. Findings The laser cladded Cr–Ni coatings with the different Cr and Ni mass ratios are composed of Cr–Ni compounds, which are metallurgically combined with the substrate. The SSC resistance of Cr–Ni coating with the Cr and Ni mass ratios of 24:76 is the highest. The electrochemical corrosion resistance of Cr–Ni coating with the Cr and Ni mass ratio of 24:76 is the best among the three kinds of coatings. Originality/value In this study, the corrosion resistance of laser cladded Cr–Ni coatings with the Cr and Ni mass ratios of 17: 83, 20: 80 and 24: 76 was first evaluated using salt spray corrosion (SSC) and electrochemical tests, and the effect of mass ratios of Cr and Ni on their corrosion mechanism was discussed.


Materials ◽  
2020 ◽  
Vol 13 (20) ◽  
pp. 4678
Author(s):  
Jiapeng Liu ◽  
Yingqi Li ◽  
Yinhua Zhang ◽  
Yue Hu ◽  
Lubing Shi ◽  
...  

This study aims to deeply understand the effect of contact stress and slip ratio on wear performances of bainitic rail steels. The results showed that the wear loss increased as the contact stress and slip ratio increased. Based on the surface damage morphology and microstructural analyses, it revealed that the rolling contact fatigue wear mechanism played a significant role under the low slip ratio, but the dominant wear mechanism transferred to the abrasive wear at the high slip ratio. Meanwhile, the bainitic steel specifically presented worse wear resistance under the abrasive wear mode. Compared with the influence of a slip ratio, the increase in contact stress led to severer plastic flows and contributed to the propagation of cracks. In addition, the contact stress and slip ratio had the opposite effect on the friction coefficient, that is, the friction coefficient of bainitic steels behaved the inverse proportion with the contact stress, but positive proportion with the slip ratio. At last, the increase in slip ratio had more significant effect on the reduction of retained austenite (RA) than the enlargement of contact stress due to the fact that the RA would probably be removed before the martensitic transformation occurred under the abrasive wear mechanism.


2021 ◽  
Vol ahead-of-print (ahead-of-print) ◽  
Author(s):  
Yabao Hu ◽  
Hanning Chen ◽  
Xiaodan Liang ◽  
Jianbo Lei

Purpose Studies on titanium implants have shown that the mechanical properties of the parts are affected by the microstructure characteristic derived from the manufacturing process. The properties of different orientations of specimens under the same process parameters will be different, which should be considered in the application of bone implants. This paper aims to understand the influence of microstructure on micro-hardness, wear and corrosion resistance in different orientations. Design/methodology/approach The authors manufactured titanium parts and carried out micro-hardness, wear tests and electrochemical corrosion of different orientations under the same process conditions. Then, finally studied the evolution mechanism of the microstructure in different orientations and its influence mechanism on wear and corrosion mechanism. Findings The melting method makes the grains on the surface in XY orientation finer. The wear mechanism of XY orientation is abrasive wear, that of XZ and YZ orientations are adhesive wear. During corrosion, XY orientation forms a stable passivation film earlier. Compared with XZ and YZ orientations, XY orientation has higher micro-hardness, better wear and corrosion resistance. Originality/value In this paper, the microstructure, wear and corrosion resistance of selective laser melted parts were discussed and the differences in different orientations under the same experimental conditions were discussed. The evolution mechanism of the microstructure in different orientations and its influence mechanism on wear mechanism and corrosion mechanism was studied. The mechanical anisotropy of selective laser melted components was discussed.


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