Non-Catalytic Plasma-Arc Reforming of Natural Gas With Carbon Dioxide as the Oxidizing Agent for the Production of Synthesis Gas or Hydrogen

Author(s):  
Gert W. Basson ◽  
P. W. E. Blom

The world’s energy consumption is increasing constantly due to the growing population of the world. The increasing energy consumption has a negative effect on the fossil fuel reserves of the world. Hydrogen has the potential to provide energy for all our needs by making use of fossil fuel such as natural gas and nuclear-based electricity. Hydrogen can be produced by reforming methane with carbon dioxide as the oxidizing agent. Hydrogen can be produced in a Plasma-arc reforming unit making use of the heat energy generated by a 500 MWt Pebble Bed Modular Reactor (PBMR). The reaction in the unit takes place stoichiometrically in the absence of a catalyst. Steam can be added to the feed stream together with the Carbon Dioxide, which make it possible to control the H2/CO ratio in the synthesis gas between 1/1 and 3/1. This ratio of H2/CO in the synthesis gas is suitable to be used as feed gas to almost any chemical and petrochemical process. To increase the hydrogen production further, the Water-Gas Shift Reaction can be applied. A techno-economic analysis was performed on the non-catalytic plasma-arc reforming process. The capital cost of the plant is estimated at $463 million for the production of 1132 million Nm3/year of hydrogen. The production cost of hydrogen is in the order of $12.81 per GJ depending on the natural gas cost and the price of electricity.

Molecules ◽  
2020 ◽  
Vol 25 (4) ◽  
pp. 802 ◽  
Author(s):  
Manuel Antonio Díaz-Pérez ◽  
Juan Carlos Serrano-Ruiz

Concerns about depleting fossil fuels and global warming effects are pushing our society to search for new renewable sources of energy with the potential to substitute coal, natural gas, and petroleum. In this sense, biomass, the only renewable source of carbon available on Earth, is the perfect replacement for petroleum in producing renewable fuels. The aviation sector is responsible for a significant fraction of greenhouse gas emissions, and two billion barrels of petroleum are being consumed annually to produce the jet fuels required to transport people and goods around the world. Governments are pushing directives to replace fossil fuel-derived jet fuels with those derived from biomass. The present mini review is aimed to summarize the main technologies available today for converting biomass into liquid hydrocarbon fuels with a molecular weight and structure suitable for being used as aviation fuels. Particular emphasis will be placed on those routes involving heterogeneous catalysts.


2016 ◽  
Vol 19 (1) ◽  
pp. 59-74 ◽  
Author(s):  
Olabanji Benjamin Awodumi ◽  
Adebowale Musefiu Adeleke

Abstract This study adopted two-stage DEA to estimate the technical efficiency scores and assess the impact of the two most important components of fossil fuel associated with oil production on macroeconomic efficiency of Seven oil producing African countries during 2005-2012. Our results showed that increasing the consumption of natural gas would improve technical efficiency. Furthermore, increasing the share of fossil fuel in total energy consumption has negative effect on the efficiency of the economies of the top African oil producers. Also, we found that increasing the consumption of primary energy improves efficiency in these economies. We therefore, recommend that governments and other stakeholders in the energy industry should adopt inclusive strategies that will promote the use of natural gas in the short term. However, in the long-run, efforts should be geared towards increasing the use of primary energy, thereby reducing the percentage share of fossil fuel in total energy consumption.


2016 ◽  
Vol 23 (3) ◽  
pp. 377-386 ◽  
Author(s):  
Peter Burri

Abstract In spite of great progress in energy efficiency and in the development of renewable energy the world is likely to need significant amounts of fossil fuel throughout this century and beyond (the share of fossil fuels in the world mix has remained at about 86% of primary energy from 1990 to today). Gas, being the by far cleanest fossil fuel is the ideal bridging fuel to a world with predominantly renewable supplies. Thanks to the recent perfection of unconventional technologies there is no shortage of gas for this bridging function for at least the next 100-200 years. EASAC and several other European Institutions, notably the German Academy of Technical Sciences (acatech) have in the last few years carried out expert studies to assess the alleged environmental risks of unconventional hydrocarbon exploration and production. All these studies have, in agreement with other competent studies worldwide, come to the conclusion that there exists no scientific reason for a ban on hydraulic fracturing. With good practices, clear standards and adequate control the method causes no enhanced risks to the environment or the health of humans. Special attention has to be paid to the surface handling of drilling and fracking fluids. In Europe alone many thousand frac jobs have been carried out by the industry in the last 60 years without any severe accidents. The mishaps in North America have largely been the cause of unprofessional operations and human error. Especially in places with high air pollution, like many megacities of Asia, natural gas has to be seen as a unique chance to achieve a rapid improvement of the air quality and a significant reduction of CO2 emissions. This is also true for Europe where especially the use of domestic natural gas brings important benefits to the environment. The alternative to gas is in many regions of the world an increased consumption of coal, with all negative consequences.


Author(s):  
Maicon Basso dos Santos ◽  
Jefferson Candido ◽  
Sofia De Souza Baulé ◽  
Yuri Mello Müller de Oliveira ◽  
Liseane Padilha Thives

Hot-mix asphalt used in pavement layers is produced by asphalt plants. In Brazil, despite the fact that these industrial units produce greenhouse gases, no control or measurement protocol has yet been established. This study aims to quantify emissions in different asphalt plants, in terms of carbon dioxide equivalent (CO2eq) and energy consumption. Asphalt plants were selected according to their type (batch or drum mix); production capacity (80 to 340 t/h), and whether mobile or fixed. In each plant, emissions were quantified and the energy consumption spent on drying and heating aggregates in the dryer drum was evaluated. The fuels used in the drier drum such as low pour point (LPP) oil, liquefied petroleum gas (LPG), and natural gas (NG) were evaluated and compared. The methodology consisted of surveying the thermal power of the dryer drum specified on the suppliers' catalog to calculate the volume of fuel required per ton of asphalt mixture produced. Based on the criterion of the lower calorific value of each fuel, the volume of fuel used was calculated according to the production of the asphalt plants. Through the GHC protocol tool, the quantification of emissions of carbon dioxide (CO2), methane (CH4), and nitrous oxide (N2O) gases was obtained, and then transformed into CO2eq emissions. As a result, lower energy consumption was observed in the mobile batch plants and higher consumption in the mobile counterflow drum mix plants. On average, 27.69% less energy per ton of processed aggregate was needed compared to the mobile counterflow plants. The use of natural gas in the dryer drum and for all plant models was the least emissive fuel. The results showed that for the mobile batch type with a capacity of 140 t/h, the emission was 13.62 kg of CO2eq / t. On the other hand, with the mobile counterflow type with a capacity of 200 t/h, 13.64 kg of CO2eq/t was produced. Finally, with the fixed counterflow type with a production capacity of 240 t/h and 300 t/h, emissions of 13.67 kg of CO2eq/t were obtained. Through this study, the mobile batch plant with a capacity of 140 t/h using natural gas showed the least environmental impact. When natural gas was used, this model obtained energy consumption and emissions 54.5% lower than the mobile counterflow model with a capacity of 50 t/h which showed the worst environmental performance.


2014 ◽  
Vol 68 (2) ◽  
pp. 139-148
Author(s):  
Veselin Batalovic ◽  
Dusan Danilovic ◽  
Marija Zivkovic

Natural gas is becoming more and more a commodity in the global energy consumption. New technologies like the conversion from gas to liquid, contribute to this. But more than 16 % of the currently known global gas reserves cannot be produced due to severe CO2 and/or H2S contamination: (CO2 > 10% and H2S> 5%). The traditional technology of amine treatment is not able to economically remove these contaminants. The objective of this article is to investigate the possibilities of centrifugal separation to resolve the problem. After analyzing the existing situation, in the centrifugal separation of natural gas, some innovations in separators design and theory are suggested. The aim of the presented theoretical considerations is that the complex theory of separation to adapt to the needs of engineers engaged on the design, development and operation of these devices.


2021 ◽  
Author(s):  
Stephen Mayfield ◽  
Michael Burkart

Algae made our world possible, and it can help us make the future more sustainable; but we need to change the way we live and adopt new more efficient production systems, and we need to do that now. When the world was new, the atmosphere was mainly carbon dioxide, and no animal life was possible. Along came algae with the process of photosynthesis, and things began to change. Ancient cyanobacteria algae turned carbon dioxide into enormous sums of lipids, proteins and carbohydrates, while they secreted oxygen into the atmosphere. Over a billion years, as oxygen filled the air and algae filled the seas, animal life became possible. Eventually all that algae biomass became petroleum and natural gas, which for eons sat undisturbed in vast underground reservoirs, holding enormous sums of untapped energy. Less than 200 years ago humans learned to tap these energy reserves to create the world we know today, but in so doing, we have released millions of years of stored CO2 back into the atmosphere. Algae can again help make the world a better place, but this will require new thinking and new ways of producing our food, feed and fuels. We need an algae revolution 2.0.


1999 ◽  
Vol 147 (1-2) ◽  
pp. 47-54 ◽  
Author(s):  
Guolin Xu ◽  
Keying Shi ◽  
Ying Gao ◽  
Hengyong Xu ◽  
Yongde Wei

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