Effect of ionizing radiation on the kinetics of hydrogenation on the Ni-MgO mixed catalyst

1982 ◽  
Vol 47 (7) ◽  
pp. 1780-1786 ◽  
Author(s):  
Rostislav Kudláček ◽  
Jan Lokoč
Keyword(s):  
Experimental Data ◽  
Activation Energy ◽  
Liquid Phase ◽  
Ionizing Radiation ◽  
Oxide Catalyst ◽  
Absorbed Dose ◽  
Hydrogenation Rate ◽  
Solution Composition ◽  
Mixed Catalyst ◽  
Kinetics Of

The effect of gamma pre-irradiation of the mixed nickel-magnesium oxide catalyst on the kinetics of hydrogenation of maleic acid in the liquid phase has been studied. The changes of the hydrogenation rate are compared with the changes of the adsorbed amount of the acid and with the changes of the solution composition, activation energy, and absorbed dose of the ionizing radiation. From this comparison and from the interpretation of the experimental data it can be deduced that two types of centers can be distinguished on the surface of the catalyst under study, namely the sorption centres for the acid and hydrogen and the reaction centres.

scholarly journals Drying Kinetics of Noni Seeds

2019 ◽  
Vol 11 (5) ◽  
pp. 250 ◽  
Author(s):  
Wellytton Darci Quequeto ◽  
Osvaldo Resende ◽  
Patrícia Cardoso Silva ◽  
Fábio Adriano Santos e Silva ◽  
Lígia Campos de Moura Silva
Keyword(s):  
Experimental Data ◽  
Activation Energy ◽  
Diffusion Coefficient ◽  
Moisture Content ◽  
Mathematical Models ◽  
Effective Diffusion Coefficient ◽  
Effective Diffusion ◽  
Information Criterion ◽  
Drying Kinetics ◽  
Kinetics Of

Noni seeds have been used for years as an important medicinal source, with wide use in the pharmaceutical and food industry. Drying is a fundamental process in the post-harvest stages, where it enables the safe storage of the product. Therefore, the present study aimed to fit different mathematical models to experimental data of drying kinetics of noni seeds, determine the effective diffusion coefficient and obtain the activation energy for the process during drying under different conditions of air temperature. The experiment used noni seeds with initial moisture content of 0.46 (decimal, d.b.) and dehydrated up to equilibrium moisture content. Drying was conducted under different controlled conditions of temperature, 40; 50; 60; 70 and 80 ºC and relative humidity, 24.4; 16.0; 9.9; 5.7 and 3.3%, respectively. Eleven mathematical models were fitted to the experimental data. The parameters to evaluate the fitting of the mathematical models were mean relative error (P), mean estimated error (SE), coefficient of determination (R2), Chi-square test (c2), Akaike Information Criterion (AIC) and Schwarz’s Bayesian Information Criterion (BIC). Considering the fitting criteria, the model Two Terms was selected to describe the drying kinetics of noni seeds. Effective diffusion coefficient ranged from 8.70 to 23.71 × 10-10 m2 s-1 and its relationship with drying temperature can be described by the Arrhenius equation. The activation energy for noni seeds drying was 24.20 kJ mol-1 for the studied temperature range.

Study of Donor Centres in n-InSb due to the Temperature Annealing

2005 ◽  
Vol 480-481 ◽  
pp. 197-200
Author(s):  
Y. Sayad ◽  
A. Nouiri
Keyword(s):  
Experimental Data ◽  
Activation Energy ◽  
Annealing Time ◽  
Annealing Temperature ◽  
Theoretical Study ◽  
Donor Concentration ◽  
Model Based ◽  
Proposed Model ◽  
Kinetics Of ◽  
Best Fit

An increasing of donor centres has been detected in n-InSb when it was submitted to anneal/quench with various annealing temperature (450 °C - 850 °C) and various annealing time (5 - 100 hours). A theoretical study of the kinetics of the conduction conversion of n-InSb at temperature annealing above 250 °C has been made. The present analysis indicates that the donor concentration increases with increasing of annealing time. In order to study this variation and to give a model for donor centres generated, a proposed model based on the simple kinetic is used to fit the variation of donor concentration as a function of annealing time. However, from the best fit of experimental data using the proposed model, the activation energy is determined.

scholarly journals Drying kinetics of baru flours as function of temperature

2018 ◽  
Vol 22 (10) ◽  
pp. 713-719 ◽  
Author(s):  
Douglas R. Reis ◽  
Fabrício B. Brum ◽  
Eduardo J. O. Soares ◽  
Jessiana R. Magalhães ◽  
Fabrício S. Silva ◽  
...  
Keyword(s):  
Experimental Data ◽  
Activation Energy ◽  
Food Industry ◽  
Nutritional Value ◽  
Effective Diffusivity ◽  
Drying Kinetics ◽  
Statistical Parameters ◽  
Noticeable Effect ◽  
Different Temperatures ◽  
Kinetics Of

ABSTRACT Several types of seeds have been initially used in the food industry due to the great potential that vegetable proteins have. Baru is a fruit commonly found in the Cerrado biome, having a high nutritional value. This paper aimed to determine and analyze the drying kinetics of whole and defatted baru almond flours at different temperatures. The flour resulting from almond milling was defatted using petroleum ether. The drying processes were performed at temperatures of 40, 50 and 60 ºC. The mathematical models of Page, Henderson and Pabis, Midilli & Kucuk, Thompson and Approximation of Diffusion were fitted to the experimental data. The results showed a noticeable effect of air temperature on the drying kinetics of whole and defatted baru almond flours. According to the statistical parameters of analysis, the models Midilli & Kucuk and Page were the ones with the best fits to the experimental data. The effective diffusivity values found ranged from 8.02 × 10–10 to 19.90 × 10–10 m2 s-1 and for the activation energy were 22.39 and 39.37 KJ mol-1 for whole and defatted almonds, respectively.

Research on Pyrolysis Kinetics of Shenhua Coal and Direct Liquefaction Residue

2012 ◽  
Vol 550-553 ◽  
pp. 2758-2762 ◽  
Author(s):  
Xi Jie Chu ◽  
Yong Gang Wang ◽  
Li Hong Zhao
Keyword(s):  
Experimental Data ◽  
Activation Energy ◽  
Kinetic Parameters ◽  
Heating Rate ◽  
Coal Pyrolysis ◽  
Pyrolysis Kinetics ◽  
Differential Heating ◽  
Pyrolysis Behavior ◽  
Direct Liquefaction ◽  
Kinetics Of

The pyrolysis tests of Shenhua coal and Shenhua direct liquefaction residue have been carried out using thermogravimetric at the differential heating rate. The kinetic parameters k and E were calculated using DAEM method. Results show DAME model can describe the pyrolysis behavior of Shenhua coal within the range of 20% to 95%, the activation energy of coal pyrolysis ranges from 53.98 to 279.38 kJ/mol, and DAME model can describe the behavior of Shenhua direct liquefaction residue within the range of 10% to 80%, the activation energy of residue pyrolysis is about 170 kJ/mol. The results of which are basically consistent with the experimental data.

Generalized Activation Energy Spectrum Theory: A New Approach for modeling Structural Relaxation in Amorphous Solids

1993 ◽  
Vol 321 ◽  
Author(s):  
Jung H. Shin ◽  
Harry A. Atwater
Keyword(s):  
Experimental Data ◽  
Activation Energy ◽  
Structural Relaxation ◽  
Ad Hoc ◽  
Amorphous Solids ◽  
Nucleation Kinetics ◽  
Crystal Silicon ◽  
Time Resolved ◽  
New Approach ◽  
Kinetics Of

ABSTRACTA general approach to the dynamics of structural relaxation in amorphous solids is developed. A form of the recombination kinetics of defects is chosen which removes the ad hoc assumption made in previous theories that defects recombine only with others of identical activation energy. The generalized theory is tested quantitatively by modelling the structural relaxation of amorphous silicon, and comparing the results with the experimental data on structural relaxation. It is found that the generalized theory is necessary in order to accurately describe the time-resolved relaxation data. The generalized theory is also applied to estimate the effect of irradiation on the nucleation kinetics of crystal silicon, and is found to agree well with experimental data.

Pseudo-Homogenous Kinetics Model for the Synthesis of Dimethyl Carbonate from Urea and Methanol with Heterogeneous Catalyst

2011 ◽  
Vol 233-235 ◽  
pp. 481-486
Author(s):  
Wen Bo Zhao ◽  
Ning Zhao ◽  
Fu Kui Xiao ◽  
Wei Wei
Keyword(s):  
Experimental Data ◽  
Activation Energy ◽  
Dimethyl Carbonate ◽  
Side Reaction ◽  
Order Reaction ◽  
Zero Order ◽  
Kinetics Model ◽  
First Order ◽  
Zero Order Reaction ◽  
Kinetics Of

The synthesis of dimethyl carbonate (DMC) from urea and methanol includes two main reactions: one amino of urea is substituted by methoxy to produce the intermediate methyl carbamate (MC) which further converts to DMC via reaction with methanol again. In a stainless steel autoclave, the kinetics of these reactions was separately investigated without catalyst and with Zn-containing catalyst. Without catalyst, for the first reaction, the reaction kinetics can be described as first order with respect to the concentrations of methanol and methyl carbamate (MC), respectively. For the second reaction, the results exhibit characteristics of zero-order reaction. Over Zn-containing catalyst, the first reaction is neglected in the kinetics model since its rate is much faster than second reaction. After the optimization of reaction condition, the macro-kinetic parameters of the second reaction are obtained by fitting the experimental data to a pseudo-homogenous model, in which a side reaction of DMC synthesis is incorporated since it decreases the yield of DMC drastically at high temperature. The activation energy of the reaction from MC to DMC is 104 KJ/mol while that of the side reaction of DMC is 135 KJ/mol.

Effect of Air Velocity and Temperature on the Drying Kinetics of Drumstick Leaves (Moringa Oleifera)

2012 ◽  
Vol 8 (4) ◽  
Author(s):  
Monica Premi ◽  
Harish Sharma ◽  
Ashutosh Upadhyay
Keyword(s):  
Experimental Data ◽  
Activation Energy ◽  
Moringa Oleifera ◽  
Moisture Diffusivity ◽  
Drying Kinetics ◽  
Drying Rate ◽  
Air Velocity ◽  
Drying Time ◽  
Effective Moisture ◽  
Kinetics Of

Abstract The present study examines the effect of air velocity on drying kinetics of the drumstick leaves in a forced convective dryer. The drumstick leaves were dried in the temperature range of 50–800 C, at different air velocity (Dv) of 0.5 and 1.3 m/s. The results indicated that drying temperature and air velocity are the factors in controlling the drying rate. Experimental data obtained for the samples for color, drying rate and drying time proved that air velocity of 1.3 m/s yielded the product superior in terms of both quality and energy efficiency as compared to the samples at 0.5 m/s. Activation energy for drumstick leaves dried with air velocity, 0.5 and 1.3 m/s was 12.50 and 32.74 kJ/mol respectively. The activation energy relates similarly with the effective moisture diffusivity which also increased with increase in air velocity and temperature.

scholarly journals Kinetics of barite reduction from refractory barite-sulphide ore

10.30544/237 ◽  
2016 ◽  
Vol 22 (4) ◽  
pp. 261-268 ◽  
Author(s):  
Miroslav D Sokić ◽  
Vladislav Matković ◽  
Jovica Stojanović ◽  
Branislav Marković ◽  
Vaso Manojlović
Keyword(s):  
Experimental Data ◽  
Activation Energy ◽  
Kinetic Model ◽  
Copper Sulphide ◽  
Influence Of Temperature ◽  
Sulphide Ore ◽  
Lead Zinc ◽  
Complex Structural ◽  
Kinetics Of ◽  
Maximum Removal

Refractory sulphide–barite ore was reduced with carbon in order to release lead, zinc, and copper sulphide from barite-pyrite base. Mineralogical investigations showed that due to the complex structural-textural relationships of lead, copper and zinc minerals with gangue minerals, it is not possible to enrich the ore using the conventional methods of mineral processing. The influence of temperature and time was studied to optimize the conditions, and to determine the kinetics of the barite reduction. The maximum removal of barite from ore was 96.7% at 900oC after 180 min. Chemically controlled kinetic model showed the best compliance with the experimental data. An activation energy of 142 kJ/mol was found.

Kinetic Study of the Dehydrogenation of Isobutane over V-K-O /ZSM5 Catalyst

2013 ◽  
Vol 798-799 ◽  
pp. 174-177 ◽  
Author(s):  
Teng Teng Wu ◽  
Cheng Xue Wang
Keyword(s):  
Experimental Data ◽  
Activation Energy ◽  
Kinetic Model ◽  
Atmospheric Pressure ◽  
Contact Time ◽  
Model Parameters ◽  
Isobutane Dehydrogenation ◽  
Dehydrogenation Reaction ◽  
Reaction Pressure ◽  
Kinetics Of

The reaction kinetics of the dehydrogenation of isobutane over V-K-O /ZSM5 catalyst was investigated. The powerfunction model was established;The isobutane dehydrogenation reaction tests were carried out between 833-863K and reaction pressure to atmospheric pressure by changing the contact time(w/F=0.464-0.532gh/mol) ,through the experimental data the kinetics of model parameters were analyzed.The results show that the power-function kinetic model is reasonable,the apparent activation energy is 177.7492KJ/mol.

scholarly journals Temperature and pH effects on the kinetics of 2-aminophenol auto-oxidation in aqueous solution

2003 ◽  
Vol 1 (3) ◽  
pp. 233-241 ◽  
Author(s):  
Dumitru Oancea ◽  
Mihaela Puiu
Keyword(s):  
Experimental Data ◽  
Activation Energy ◽  
Aqueous Solution ◽  
Ph Effects ◽  
Influence Of Temperature ◽  
First Order ◽  
Incremental Methods ◽  
First Order Kinetics ◽  
Ph Range ◽  
Kinetics Of

AbstractThe kinetics of the auto-oxidation of 2-aminophenol (OAP) to 2-amino-phenoxazin-3-one (APX) was followed in air-saturated aqueous solutions and the influence of temperature and pH on the auto-oxidation rate was studied. The kinetic analysis was based on a spectrophotometric method following the increase of the absorbance of APX. The process follows first order kinetics according to the rate law—d[OAP]/dt=k′[OAP]. The experimental data, within the pH range 4–9.85, were analyzed using both differential and incremental methods. The temperature variation of the overall rate constant was studied at pH=9.85 within the range 25–50°C and the corresponding activation energy was evaluated.

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