La viabilité des bétons du Québec: le rôle des granulats

1986 ◽  
Vol 13 (1) ◽  
pp. 12-24 ◽  
Author(s):  
Jean Bérard ◽  
Richard Roux
Keyword(s):  
Key Words ◽  
Silica Gel ◽  
Cement Paste ◽  
Chemical Reactions ◽  
Mechanical Deformation ◽  
Granitic Rocks ◽  
Concrete Aggregate ◽  
Coarse Aggregates ◽  
Rock Types ◽  
Petrographic Study

The petrographic study of numerous concrete structures in Quebec has revealed the extent of postconstruction chemical reactions. Those reactions between the aggregates, which form 70% of the volume of the concrete, and the cement paste result in early deterioration and undesirable mechanical deformation of the structures. From this study, it appears that the coarse aggregates can react in three different ways: (a) by peripheral reaction, which is the case for massive granitic rocks, (b) by bulk swelling, as illustrated by the Potsdam orthoquartzite, and (c) by formation of silica gel veinules within the aggregate, as shown by some Trenton limestone. Considering these three mechanisms, it is easy to understand why certain aggregates react rapidly, that is within a few months, whereas others show signs of distress only after scores of years. Using the three rock types cited above, we have also tried to evaluate existing concrete standards and their capability to detect the most important pathologies encountered in concrete. Key words: concrete, aggregate, alkalis, disintegration, expansion, testing, durability.

Layered Granitic Rocks at Chebucto Head, Halifax County, Nova Scotia

1975 ◽  
Vol 12 (3) ◽  
pp. 456-463 ◽  
Author(s):  
T. E. Smith
Keyword(s):  
Grain Size ◽  
Nova Scotia ◽  
Granitic Rocks ◽  
Textural Characteristics ◽  
Rock Types ◽  
Flow Sorting

Structural, mineralogical and textural characteristics of some layered granitic rocks are described. The layers result from the segregation of minerals into bands and lenses of contrasting color and grain size. They were formed near the roof of the pluton prior to final crystallization by flow sorting during episodic shearing generated during intrusion. Comparison of the mineralogy and textures of the layered rocks with those of the main rock types of the pluton shows that the differentiation of the pluton as a whole took place after the formation of the layers by interaction of felsic components concentrated in residual liquids with earlier formed crystals.

Synthesis and aldol cyclotrimerization of 4,7-di-tert-butylacenaphthenone

2006 ◽  
Vol 84 (10) ◽  
pp. 1268-1272 ◽  
Author(s):  
Aaron W Amick ◽  
Keith S Griswold ◽  
Lawrence T Scott
Keyword(s):  
Key Words ◽  
Crystal Structures ◽  
Silica Gel ◽  
Room Temperature ◽  
Titanium Tetrachloride ◽  
X Ray ◽  
Synthetic Intermediates

An efficient gram scale synthesis of the previously unknown 4,7-di-tert-butylacenaphthenone (3b) is reported. The facile isomerization of epoxide 9b to ketone 3b occurs simply on stirring a solution of 9b with silica gel at room temperature. Aldol cyclotrimerization of 3b with titanium tetrachloride gives 2,5,8,11,14,17-hexa-tert-butylde cacyclene (1b) in 58% isolated yield. X-ray crystal structures have been obtained for the synthetic intermediates 4,7-di-tert-butylacenaphthene (2b) and 4,7-di-tert-butylacenaphthylene (8b).Key words: aromatic, decacyclene, hydrocarbon, nonalternant, polycyclic.

Study of the pozzolanic activity and hydration products of cement pastes with addition of natural zeolites

Clay Minerals ◽  
2011 ◽  
Vol 46 (2) ◽  
pp. 241-250 ◽  
Author(s):  
V. Lilkov ◽  
O. Petrov ◽  
V. Petkova ◽  
N. Petrova ◽  
Y. Tzvetanova
Keyword(s):  
Surface Area ◽  
Cement Paste ◽  
Chemical Reactions ◽  
Natural Zeolite ◽  
Early Stage ◽  
Pozzolanic Activity ◽  
Large Surface Area ◽  
Natural Zeolites ◽  
Hydration Products ◽  
Cement Pastes

AbstractThis paper presents results from comparative thermogravimetric, calorimetric and pozzolanic activity analyses of five natural zeolite samples from Bulgaria, Slovakia, Philippines, USA and North Korea. The zeolites actively participate in the hydration processes of cement. Their activity in the early stage of hydration is based mainly on the large surface area of the particles while, in the later stages of activation, chemical reactions occur between the products of the hydration of cement and the soluble SiO2 that is present in the bulk of the zeolites. It has been shown that in all cement pastes which contain zeolite additives, the quantity of portlandite is lower than that in pure cement paste or is even totally absent. The amounts of hydration products are greater when 30% zeolite is used than when 10% zeolite is added (excluding the sample with chabazite). The lowest pozzolanic activity is shown by chabazite, which possessed the lowest SiO2/Al2O2 ratio.

scholarly journals Geology and Petrographic Study of the Granitic Rocks of Kaltungo Inlier, Northeastern Nigeria

2017 ◽  
Vol 05 (01) ◽  
pp. 75-83
Author(s):  
A. S. Sa’ad ◽  
S. Baba
Keyword(s):  
Granitic Rocks ◽  
Petrographic Study

The oxygen isotope composition of the surface crystalline rocks of the Canadian Shield

1978 ◽  
Vol 15 (11) ◽  
pp. 1773-1782 ◽  
Author(s):  
Yuch-Ning Shieh ◽  
Henry P. Schwarcz
Keyword(s):  
Isotope Composition ◽  
Crystalline Rocks ◽  
Canadian Shield ◽  
Granitic Rocks ◽  
Baffin Island ◽  
Grenville Province ◽  
Metasedimentary Rocks ◽  
Rock Types ◽  
Northern District ◽  
Basic Rocks

The average 18O/16O ratios of the major rock types of the surface crystalline rocks in different parts of the Canadian Precambrian Shield have been determined, using 47 composite samples prepared from 2221 individual rock specimens. The sampling areas include Baffin Island, northern and southwestern Quebec, Battle Harbour – Cartwright, northern District of Keewatin, Fort Enterprise, Snowbird Lake, Kasmere Lake, and Saskatchewan, covering approximately 1 400 000 km2. The granitic rocks from the Superior, Slave, and Churchill Provinces vary only slightly from region to region (δ18O = 6.9–8.4‰) and are significantly lower in 18O than similar rock types from the younger Grenville Province (δ = 9.2–10.0‰). The sedimentary and metasedimentary rocks have δ18O = 9.0–11.7‰ and hence are considerably lower than their Phanerozoic equivalents, possibly reflecting the presence of a high percentage of little-altered igneous rock detritus in the original sediments. The basic rocks in most regions fall within a δ18O range of 6.8–7.6‰, except in northern and southwestern Quebec where the δ-values are abnormally high (8.5–8.9‰). The overall average 18O/16O ratio of the surface crystalline rocks of the Canadian Shield is estimated to be 8.0‰, which represents an enrichment with respect to probable mantle derived starting materials by about 2‰.

Determination of the characteristics of crystalline rocks by field experiments: a review

1986 ◽  
Vol 319 (1545) ◽  
pp. 139-156 ◽  
Keyword(s):  
Radioactive Waste ◽  
Field Experiments ◽  
The United States ◽  
Crystalline Rocks ◽  
Granitic Rocks ◽  
Rock Types ◽  
Basement Rocks ◽  
Deep Boreholes ◽  
High Level ◽  
Underground Research Laboratory

Crystalline rocks, particularly granitic rocks and basalts, are one of the principal rock types under consideration as a potential host rock for a high-level radioactive waste repository. Permeability in such rocks is related to discontinuities of various scales, and the quantification and prediction of groundwater flow within both the fractures and the intact rock between the fractures is the major goal of field experiments. The Canadian Underground Research Laboratory is unique in that the hydrogeological conditions within a large volume of rock surrounding the experimental shaft are being monitored before, during and after excavation and the results compared with model predictions. In Switzerland twelve deep boreholes are being drilled to over 1000 m to investigate crystalline basement rocks beneath a cover of sediments. The Stripa Mine in Sweden has hosted a major experimental programme including heater tests to stimulate the thermal effect of radioactive waste and hydrogeological tests at various scales down to individual fractures. The United States of America, the United Kingdom, France and Finland have also embarked on major experimental programmes. Continuing research is needed, with an emphasis on field experiments and research in underground rooms, to provide the data on which detailed risk assessments can be based.

Syneresis in Silica Gel

1988 ◽  
Vol 121 ◽  
Author(s):  
George W. Scherer
Keyword(s):  
Fluid Flow ◽  
Sample Size ◽  
Silica Gel ◽  
Chemical Reactions ◽  
Driving Force ◽  
Viscoelastic Behavior ◽  
Accurate Representation ◽  
Flow Through ◽  
Kinetics Of ◽  
Gel Network

ABSTRACTThe driving force for syneresis is generally attributed to the same chemical reactions that produce gelation, but it has also been proposed that shrinkage could be driven by interracial energy. The latter possibility is explored and discounted. The kinetics of syneresis depend on the driving force, the mobility of the gel network, and the rate of fluid flow through the contracting gel. A model that allows for viscoelastic behavior of the gel and fluid flow according to Darcy's law is shown to provide a quantitatively accurate representation of the shape of the shrinkage curves and the dependence of the shrinkage rate on sample size.

scholarly journals The effect of coarse aggregate hardness on the fracture toughness and compressive strength of concrete

2019 ◽  
Vol 258 ◽  
pp. 04011
Author(s):  
Atur P. N. Siregar ◽  
Emma L. Pasaribu ◽  
I Wayan Suarnita
Keyword(s):  
Fracture Toughness ◽  
Compressive Strength ◽  
Los Angeles ◽  
Coarse Aggregate ◽  
Concrete Aggregate ◽  
Beam Size ◽  
Intensity Factors ◽  
Coarse Aggregates ◽  
Los Angeles Abrasion ◽  
Compressive Strength Of Concrete

Coarse aggregate is the dominant constituent in concrete. Aggregate hardness is a variable needed to investigate in determining its effect on the critical stress intensity factors (KIC), dissipated fracture energy (Gf) and compressive strength (fc’) of the concrete. The hardness of coarse aggregate based on Los Angeles abrasion values of 16.7%., 22.6%, and 23.1% was used incorporated with Portland Composite Cement (PCC), and superplasticizer to create specimens. Cubes of 150x150x150 mm were employed to determine the fc’, and four beam sizes: 50x100x350 mm, 50x150x500 mm, 50x300x950 mm and 50x450x1250 mm were engaged to determine KIC and Gf. The fc’ and Gf of specimens manufactured by three different hardness of coarse aggregates were 45, 43, 40 MPa and 89.4, 54.0, 56.3 N/m respectively. KIC of specimens was 138.9, 119.4 and 114.1 MPa.mm1/2 for beam size of 50x100x350 mm; 148.2, 115.8 and 108.8 MPa.mm1/2 for beam size of 50x150x500 mm; 230.9, 183.1 and 157.9 MPa.mm1/2 for beam size of 50x300x950 mm; and 293.2, 248.1 and 244.3 MPa.mm1/2 for beam size of 50x450x1250 mm. Experimental results showed that decreasing hardness of coarse aggregate was found to have significant effect on the fracture toughness rather than on the compressive strength of concrete.

scholarly journals SEM Image Analysis in Permeable Recycled Concretes with Silica Fume. A Quantitative Comparison of Porosity and the ITZ

Materials ◽  
2019 ◽  
Vol 12 (13) ◽  
pp. 2201 ◽  
Author(s):  
Manuel J. Chinchillas-Chinchillas ◽  
Carlos A. Rosas-Casarez ◽  
Susana P. Arredondo-Rea ◽  
José M. Gómez-Soberón ◽  
Ramón Corral-Higuera
Keyword(s):  
Image Analysis ◽  
Silica Fume ◽  
Cement Paste ◽  
Chemical Elements ◽  
Energy Dispersive Spectrometer ◽  
Recycled Aggregates ◽  
Porous Network ◽  
Transition Zones ◽  
Sem Image ◽  
Coarse Aggregates

Recycled aggregates (RA) from construction and demolition can be used in permeable concretes (PC), improving the environment. PCs have a significant porous network, their cement paste and the interaction between the paste and the RA establishing their strength. Therefore, it is important to evaluate the porosity in the interfacial transition zones. The porosity of the cement paste, the aggregate and the interfacial transitional zones (ITZ) of a PC with recycled coarse aggregates (RCA) and silica fume (SF) is measured by means of image analysis–scanning electron microscope (IA)-(SEM) and by mapping the chemical elements with an SEM-EDS (energy dispersive spectrometer) detector microanalysis linked to the SEM and, as a contrast, the mercury intrusion porosimetry technique (MIP). In the IA process, a “mask” was created for the aggregate and another for the paste, which determined the porosity percentage (for the anhydrous material and the products of hydration). The results showed that using SF caused a reduction (32%) in the cement paste porosity in comparison with the PC with RA. The use of RA in the PC led to a significant increase (190%) in the porosity at different thicknesses of ITZ compared with the reference PC. Finally, the MIP study shows that the use of SF caused a decrease in the micropores, mesopores and macropores.

Two-stage evolution in an Archean tonalite suite: the Taschereau stock, Abitibi (Quebec, Canada)

1991 ◽  
Vol 28 (2) ◽  
pp. 172-183 ◽  
Author(s):  
Michel Jébrak ◽  
Luc Harnois
Keyword(s):  
Rare Earth ◽  
Rare Earth Elements ◽  
Trace Element ◽  
Greenstone Belt ◽  
Shear Zones ◽  
Granitic Rocks ◽  
Element Abundances ◽  
Abitibi Greenstone Belt ◽  
Rock Types ◽  
End Members

The Taschereau stock occurs north of Timmins and Val-d'Or, Quebec, in the Abitibi greenstone belt of the Superior Province. This late Archean composite pluton is composed mainly of diorite–tonalite–trondhjemite cut by granitic rocks. Gold–molybdenum occurrences are associated with a zone of albite-rich rocks surrounding the granitic rocks. Diabase dykes and shear zones postdate all rock units. Field and geochemical evidence suggests that the Taschereau stock was emplaced diachronously. Trace-element geochemical modelling shows that trace-element abundances (rare-earth elements, Ti, Zr) of Taschereau granitic rocks are consistent with partial melting of preexisting Taschereau tonalitic rocks and implies that these two rock types are not end members of a single magma that evolved through fractional crystallization.

Sign in / Sign up

Export Citation Format

Share Document