LAYERED SYNTHETIC MICROSTRUCTURES AS OPTICAL ELEMENTS FOR THE EXTREME ULTRAVIOLET AND SOFT X-RAYS

1991 ◽  
Vol 05 (13) ◽  
pp. 2133-2228 ◽  
Author(s):  
PURUSHOTTAM CHAKRABORTY

In recent years, the availability of intense continuous radiation sources, such as electron synchrotrons and laser-induced hot plasmas, has given rise to a renewed interest in soft x-ray and x-uv reflectivity measurements. Such studies were, for a long time, hindered because of mainly two reasons. First, it was really difficult to generate soft x-rays in the laboratories and second, there was no possibility for practical implementation and design of optical systems, such as focusing elements, mirrors, etc. associated with that particular wavelength region. Soft x-rays, with wavelength range usually from 10 to about 200 angstroms, can produce images of higher resolution than visible light due to their shorter wavelength. For years, physicists have wanted to construct an x-ray microscope that would exploit the ability of soft x-rays to detect small structures. The need for such an instrument is clear. The resolution of light microscopes is limited by the comparatively long wavelength of visible light. Although transmission electron microscopes have much higher resolution, they are weak in penetrating power and are, therefore, limited to very thin specimens. Therefore, transmission electron microscopy involves extreme care in sample preparation. Such preparations which might alter the very structure of a biological sample, would not be required in x-ray microscopy. The difficulties in constructing an x-ray microscope, however, have proved to be irresistible, because of the fact that soft x-rays cannot be brought together to form an image. In other words, soft x-rays cannot be made reflected from any known single surface at normal or near-normal incidence. The only possibility that existed until now employs grazing incidence, the only form of focusing x-ray optics. But their quality (resolution) has been limited because they must be machined in the form of a paraboloid or hyperboloid. Lenses of the kind used in ordinary optical microscopes cannot be made for use at wavelengths less than about 1000 angstroms. There are two reasons for this. First, there is only a tiny difference in the refractive indices among the different materials at soft x-ray wavelengths. Second, soft x-rays are strongly absorbed by all materials and cannot penetrate any conceivable lens, used in ordinary optical microscopes or telescopes. A major advance in x-ray optics holds a great promise both in the fields of high resolution scanning x-ray microscopy, lithography and substantial improvements in the quality of x-ray telescopes. Recent improvements in the techniques for quality control of evaporated and sputtered films have led to the interest in the controlled fabrication of multilayered structures known as 'Layered Synthetic Microstructures', to be used as mirrors for the extreme ultraviolet and soft x-ray regions. These can be produced with virtually any layer spacing greater than approximately 10 angstroms and they have a considerably high diffraction efficiency at normal or near-normal incidence. This remarkable enhancement in normal-incidence reflectivities at x-uv domain of the electromagnetic spectrum leads to another innovative application of these microstructures, i.e. the production of x-ray lasers with high gain-length products, where the enhanced normal-incidence reflectivity of the multilayers has been applied for multiple pass gain of the laser media by increasing the effective path lengths of the plasma columns. The present article covers the theoretical considerations, development and different techniques of controlled fabrication of layered synthetic microstructures along with their potential applications in the fields of x-ray spectroscopy, microscopy, x-ray laser production and lithography.

1988 ◽  
Vol 102 ◽  
pp. 303
Author(s):  
A.V. Vinogradov

SummaryTi, Si, C, Be and LiF have been studied as coatings for normal incidence (multilayers) and grazing incidence (steering many-fold reflection mirrors) optical elements. The multilayers have been tested with soft (130+250 Å and hard (1.54 Å) X-rays. From these measurements the multilayer parameters have been deduced.The carbon and lithium fluorine steering mirrors showed the reflection of 10+60% for the turning angles of 30 and 45 degrees and two wavelengths of 44.7 Å and 67.6 Å. The perspectives of other materials are also discussed.


Author(s):  
Shawn Williams ◽  
Xiaodong Zhang ◽  
Susan Lamm ◽  
Jack Van’t Hof

The Scanning Transmission X-ray Microscope (STXM) is well suited for investigating metaphase chromosome structure. The absorption cross-section of soft x-rays having energies between the carbon and oxygen K edges (284 - 531 eV) is 6 - 9.5 times greater for organic specimens than for water, which permits one to examine unstained, wet biological specimens with resolution superior to that attainable using visible light. The attenuation length of the x-rays is suitable for imaging micron thick specimens without sectioning. This large difference in cross-section yields good specimen contrast, so that fewer soft x-rays than electrons are required to image wet biological specimens at a given resolution. But most imaging techniques delivering better resolution than visible light produce radiation damage. Soft x-rays are known to be very effective in damaging biological specimens. The STXM is constructed to minimize specimen dose, but it is important to measure the actual damage induced as a function of dose in order to determine the dose range within which radiation damage does not compromise image quality.


Catalysts ◽  
2021 ◽  
Vol 11 (8) ◽  
pp. 899
Author(s):  
Murendeni P. Ravele ◽  
Opeyemi A. Oyewo ◽  
Damian C. Onwudiwe

Pure-phase Cu2−xS (x = 1, 0.2) nanoparticles have been synthesized by the thermal decomposition of copper(II) dithiocarbamate as a single-source precursor in oleylamine as a capping agent. The compositions of the Cu2−xS nanocrystals varied from CuS (covellite) through the mixture of phases (CuS and Cu7.2S4) to Cu9S5 (digenite) by simply varying the temperature of synthesis. The crystallinity and morphology of the copper sulfides were studied using X-ray diffraction (XRD), scanning electron microscopy (SEM), and transmission electron microscopy (TEM), which showed pure phases at low (120 °C) and high (220 °C) temperatures and a mixture of phases at intermediate temperatures (150 and 180 °C). Covellite was of a spherical morphology, while digenite was rod shaped. The optical properties of these nanocrystals were characterized by UV−vis–NIR and photoluminescence spectroscopies. Both samples had very similar absorption spectra but distinguishable fluorescence properties and exhibited a blue shift in their band gap energies compared to bulk Cu2−xS. The pure phases were used as catalysts for the photocatalytic degradation of tetracycline (TC) under visible-light irradiation. The results demonstrated that the photocatalytic activity of the digenite phase exhibited higher catalytic degradation of 98.5% compared to the covellite phase, which showed 88% degradation within the 120 min reaction time using 80 mg of the catalysts. The higher degradation efficiency achieved with the digenite phase was attributed to its higher absorption of the visible light compared to covellite.


NANO ◽  
2016 ◽  
Vol 11 (10) ◽  
pp. 1650114 ◽  
Author(s):  
Dan Li ◽  
Jianwei Li ◽  
Caiqin Han ◽  
Xinsheng Zhao ◽  
Haipeng Chu ◽  
...  

Few-layered MoS2 nanostructures were successfully synthesized by a simple hydrothermal method without the addition of any catalysts or surfactants. Their morphology, structure and photocatalytic activity were characterized by X-ray diffraction, scanning electron microscopy, energy dispersive X-ray spectroscopy, transmission electron microscopy, electrochemical impedance spectra and UV-Vis absorption spectroscopy, respectively. These results show that the MoS2 nanostructures synthesized at 180[Formula: see text]C exhibit an optimal visible light photocatalytic activity (99%) in the degradation of Rhodamine B owing to the relatively easier adsorption of pollutants, higher visible light absorption and lower electron–hole pair recombination.


2013 ◽  
Vol 21 (2) ◽  
pp. 7-7
Author(s):  
Charles Lyman

Using X rays to produce magnified images of objects has been a goal for 150 years. Ever since Ernst Abbe declared in 1873 that light microscope resolution was limited by the wavelength of light, the search was on for a microscopy medium with a wavelength shorter than visible light (<500 nm). When Roentgen discovered X rays in 1895, it was thought that the new medium may have been found. Soon it was clear, however, that it was not easy to construct a physical lens for X rays because the rays penetrated all lens construction materials. X-ray “radiography images” of a few times magnification were possible but only as projection images, formed as X rays from millimeter-sized sources traveled in straight lines through the specimen to be captured on film. Unfortunately, even in the best cases, useful magnification was limited by the relatively large “point source” of X rays and the large grain size of X-ray film (both about 0.1–1.0 mm).


2021 ◽  
Vol 28 (6) ◽  
Author(s):  
Yuri Shvyd'ko ◽  
Sergey Terentyev ◽  
Vladimir Blank ◽  
Tomasz Kolodziej

Next-generation high-brilliance X-ray photon sources call for new X-ray optics. Here we demonstrate the possibility of using monolithic diamond channel-cut crystals as high-heat-load beam-multiplexing narrow-band mechanically stable X-ray monochromators with high-power X-ray beams at cutting-edge high-repetition-rate X-ray free-electron laser (XFEL) facilities. The diamond channel-cut crystals fabricated and characterized in these studies are designed as two-bounce Bragg reflection monochromators directing 14.4 or 12.4 keV X-rays within a 15 meV bandwidth to 57Fe or 45Sc nuclear resonant scattering experiments, respectively. The crystal design allows out-of-band X-rays transmitted with minimal losses to alternative simultaneous experiments. Only ≲2% of the incident ∼100 W X-ray beam is absorbed in the 50 µm-thick first diamond crystal reflector, ensuring that the monochromator crystal is highly stable. Other X-ray optics applications of diamond channel-cut crystals are anticipated.


2021 ◽  
Vol 11 (5) ◽  
pp. 706-716
Author(s):  
Nada D. Al-Khthami ◽  
Tariq Altalhi ◽  
Mohammed Alsawat ◽  
Mohamed S. Amin ◽  
Yousef G. Alghamdi ◽  
...  

Different organic pollutants have been remediated photo catalytically by applying perovskite photocatalysts. Atrazine (ATR) is a pesticide commonly detected as a pollutant in drinking, surface and ground water. Herein, FeYO3@rGO heterojunction was synthesized and applied for photooxidation decomposition of ATR. First, FeYO 3nanoparticles (NPs) were prepared via routine sol-gel. After that, FeYO3 NPs were successfully incorporated with different percentages (5, 10, 15 and 20 wt.%) of reduced graphene oxide (rGO) in the synthesis of novel FeYO3@rGO photocatalyst. Morphological, structural, surface, optoelectrical and optical characteristics of constructed materials were identified via X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS), Transmission electron microscopy (TEM), adsorption/desorption isotherms, diffusive reflectance (DR) spectra, and photoluminescence response (PL). Furthermore, photocatalytic achievement of the constructed materials was evaluated via photooxidative degradation of ATR. Various investigations affirmed the usefulness of rGO incorporation on the advancement of formed photocatalysts. Actually, novel nanocomposite containing rGO (15 wt.%) possessed diminished bandgap energy, as well as magnified visible light absorption. Furthermore, such nanocomposite presented exceptional photocatalytic achievement when exposed to visible light as ATR was perfectly photooxidized over finite amount (1.6 g · L-1) from the optimized photocatalyst when illuminated for 30 min. The advanced photocatalytic performance of constructed heterojunctions could be accredited mainly to depressed recombination amid induced charges. The constructed FeYO3@rGO nanocomposite is labelled as efficient photocatalyst for remediation of herbicides from aquatic environments.


2021 ◽  
Vol 1035 ◽  
pp. 1043-1049
Author(s):  
Di Xiang ◽  
Chang Long Shao

A simple route has been developed for the synthesis of Ag2O/ZnO heterostructures and the samples were characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM), transmission electron microscopy (TEM), energy dispersive X-ray spectroscopy (EDS) and photoluminescence (PL) spectroscopy analysis. Considering the porous structure of Ag2O/ZnO, the photocatalytic degradation for the organic dyes, such as eosin red (ER), methyl orange (MO), methylene blue (MB) and rhodamine B (RhB), under visible light irradiation was investigated in detail. Noticeably, Ag2O/ZnO just took 40 min to degrade 96 % MB. The rate of degradation using the Ag2O/ZnO heterostructures was 2.3 times faster than that of the bare porous ZnO nanospheres under visible light irradiation due to that the recombination of the photogenerated charge was inhibited greatly in the p-type Ag2O and n-type ZnO semiconductor. So the Ag2O/ZnO heterostuctures showed the potential application on environmental remediation.


Instruments ◽  
2019 ◽  
Vol 3 (3) ◽  
pp. 47 ◽  
Author(s):  
Vittoria Petrillo ◽  
Michele Opromolla ◽  
Alberto Bacci ◽  
Illya Drebot ◽  
Giacomo Ghiringhelli ◽  
...  

Fine time-resolved analysis of matter—i.e., spectroscopy and photon scattering—in the linear response regime requires fs-scale pulsed, high repetition rate, fully coherent X-ray sources. A seeded Free Electron Laser (FEL) driven by a Linac based on Super Conducting cavities, generating 10 8 – 10 10 coherent photons at 2–5 keV with 0.2–1 MHz of repetition rate, can address this need. Three different seeding schemes, reaching the X-ray range, are described hereafter. The first two are multi-stage cascades upshifting the radiation frequency by a factor of 10–30 starting from a seed represented by a coherent flash of extreme ultraviolet light. This radiation can be provided either by the High Harmonic Generation of an optical laser or by an FEL Oscillator operating at 12–14 nm. The third scheme is a regenerative amplifier working with X-ray mirrors. The whole chain of the X-ray generation is here described by means of start-to-end simulations.


2018 ◽  
Vol 9 (1) ◽  
pp. 111 ◽  
Author(s):  
Chenguang Ma ◽  
Xianhong Wang ◽  
Shixia Zhan ◽  
Xuemei Li ◽  
Xiao Liu ◽  
...  

Photocatalytic activity of monosized AuZnO composite nanoparticles with different compositions were synthesized by the one-pot polyol procedure, using the triblock copolymer poly(ethylene glycol)-block-poly(propylene glycol)-blockpoly(ethylene glycol) (PEO-PPO-PEO) as the surfactant. The structure and morphology of the composite nanoparticles were analyzed by X-ray diffraction (XRD), energy dispersive X-ray analysis (EDX), selected area electron diffraction (SAED), a transmission electron microscope (TEM) and high resolution transmission electron microscopy (HRTEM). The characterization showed that the AuZnO composite nanoparticles were spherical, with narrow particle size distribution and high crystallinity. The Fourier transform infrared spectroscopy (FTIR) study confirms the PEO-PPO-PEO molecules on the surface of the composite nanoparticles. The investigations by ultraviolet-visible light absorbance spectrometer (UV-Vis) and photoluminescence spectrophotometer (PL) demonstrate well the dispersibility and excellent optical performance of the AuZnO composite nanoparticles. Photocatalytic activity and reusability of the AuZnO nanoparticles in UV and visible light regions was evaluated by the photocatalytic degradation of Rhodamine B (RhB). The experimental results show that the AuZnO composite nanoparticles with a suitable amount of Au loading have stability and improved photocatalytic activity. AuZnO composite nanoparticles are effective and stable for the degradation of organic pollutants in aqueous solution.


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