Impact of phthalocyanine structure as photosensitizer for ZnO nanophotocatalyst under natural solar irradiation

2021 ◽  
pp. A-H
Author(s):  
Basma Ghazal ◽  
Saad Makhseed
Keyword(s):  
Methylene Blue ◽  
Zinc Oxide ◽  
Solar Radiation ◽  
Copper Phthalocyanine ◽  
Solar Irradiation ◽  
Solar Light ◽  
Analytical Measurements ◽  
Copper Phthalocyanines ◽  
Wastewater Pollutants ◽  
Natural Solar Radiation

Novel composites of zinc oxide (ZnO) and copper phthalocyanines (CuTriPc and CuPc) were synthesized as efficient natural solar light photocatalysts for the photodegradation of organic wastewater pollutants. Spectroscopic and analytical measurements confirmed that both bulky triazolo copper phthalocyanine (CuTriPc) and unsubstituted planer (CuPc) were successfully coupled with ZnOnanoparticles. The synthesized nanocomposites were investigated as natural solar radiation photocatalysts toward the photodegradation of methylene blue (MB) analogue dye. The prepared CuTriPc/ZnO nanocomposite was proven to be an efficient solar light photocatalyst compared to pure ZnO and the unsubstituted CuPc/ZnO.

Photocatalytic degradation of p-nitrophenol by zinc oxide particles

2012 ◽  
Vol 65 (10) ◽  
pp. 1882-1886 ◽  
Author(s):  
M. Sugiyama ◽  
Z. Salehi ◽  
M. Tokumura ◽  
Y. Kawase
Keyword(s):  
Zinc Oxide ◽  
Degradation Rate ◽  
Uv Light ◽  
Particle Diameter ◽  
Solar Irradiation ◽  
Solar Light ◽  
Uv Light Irradiation ◽  
Zno Particles ◽  
Oxide Particles ◽  
Zinc Oxide Particles

The degradation of p-nitrophenol (PNP) by ZnO particles has been studied. With increasing PNP loading the degradation rate decreased. The mineralization of PNP was rather slow compared with the degradation. With a decrease in particle diameter or an increase in surface area, the degradation rate significantly increased. The degradation capability with solar irradiation was found to be superior to UV light irradiation. It was found that 30 mg L−1 of PNP was completely degraded by solar light with the accumulated UV light of around 23 kJ L−1 at ZnO dosage of 5 g L−1. The degradation PNP by ZnO with UV light or solar light was faster than that by TiO2.

scholarly journals Photocatalytic-Fenton Process under Simulated Solar Radiation Promoted by a Suitable Catalyst Selection

Catalysts ◽  
2021 ◽  
Vol 11 (8) ◽  
pp. 885
Author(s):  
Aida M. Díez ◽  
Helen E. Valencia ◽  
Maria Meledina ◽  
Joachim Mayer ◽  
Yury V. Kolen'ko
Keyword(s):  
Methylene Blue ◽  
Solar Radiation ◽  
Water Scarcity ◽  
Published Data ◽  
Fenton Process ◽  
Optimal Conditions ◽  
Operational Conditions ◽  
The Future ◽  
Simulated Solar Radiation ◽  
Catalyst Selection

Considering water scarcity, photo-based processes have been presented as a depollution technique, which should be optimized in order to be applied in the future. For that, the addition of an active photocatalyst and the usage of solar radiation are mandatory steps. Thus, Fe3O4–SiO2–TiO2 was synthesized, and its performance was evaluated using simulated solar radiation and methylene blue as a model pollutant. Under optimal conditions, 86% degradation was attained in 1 h. These results were compared to recent published data, and the better performance can be attributed to both the operational conditions selection and the higher photocatalyst activity. Indeed, Fe3O4–SiO2–TiO2 was physico-chemically characterized with techniques such as XRD, N2 isotherms, spectrophotometry, FTIR, electrochemical assays and TEM.

scholarly journals Straightforward Synthesis of Mn3O4/ZnO/Eu2O3-Based Ternary Heterostructure Nano-Photocatalyst and Its Application for the Photodegradation of Methyl Orange and Methylene Blue Dyes

Molecules ◽  
2021 ◽  
Vol 26 (15) ◽  
pp. 4661
Author(s):  
Jayachamarajapura Pranesh Shubha ◽  
Haralahalli Shivappa Savitha ◽  
Syed Farooq Adil ◽  
Mujeeb Khan ◽  
Mohammad Rafe Hatshan ◽  
...  
Keyword(s):  
Methylene Blue ◽  
Methyl Orange ◽  
Irradiation Time ◽  
Solar Irradiation ◽  
Anionic Dyes ◽  
One Pot ◽  
Sunlight Irradiation ◽  
Ft Ir ◽  
Degradation Activity ◽  
Ecological Applications

Zinc oxide-ternary heterostructure Mn3O4/ZnO/Eu2O3 nanocomposites were successfully prepared via waste curd as fuel by a facile one-pot combustion procedure. The fabricated heterostructures were characterized utilizing XRD, UV–Visible, FT-IR, FE-SEM, HRTEM and EDX analysis. The photocatalytic degradation efficacy of the synthesized ternary nanocomposite was evaluated utilizing model organic pollutants of methylene blue (MB) and methyl orange (MO) in water as examples of cationic dyes and anionic dyes, respectively, under natural solar irradiation. The effect of various experimental factors, viz. the effect of a light source, catalyst dosage, irradiation time, pH of dye solution and dye concentration on the photodegradation activity, was systematically studied. The ternary Mn3O4/ZnO/Eu2O3 photocatalyst exhibited excellent MB and MO degradation activity of 98% and 96%, respectively, at 150 min under natural sunlight irradiation. Experiments further conclude that the fabricated nanocomposite exhibits pH-dependent photocatalytic efficacy, and for best results, concentrations of dye and catalysts have to be maintained in a specific range. The prepared photocatalysts are exemplary and could be employed for wastewater handling and several ecological applications.

scholarly journals Calibration and Validation of ArcGIS Solar Radiation Tool for Photovoltaic Potential Determination in the Netherlands

Energies ◽  
2021 ◽  
Vol 14 (7) ◽  
pp. 1865
Author(s):  
Bala Bhavya Kausika ◽  
Wilfried G. J. H. M. van Sark
Keyword(s):  
Solar Radiation ◽  
The Netherlands ◽  
Urban Areas ◽  
Input Data ◽  
Solar Irradiation ◽  
Energy Yield ◽  
Atmospheric Parameters ◽  
Factors Affecting ◽  
Calibration And Validation ◽  
Solar Radiation Model

Geographic information system (GIS) based tools have become popular for solar photovoltaic (PV) potential estimations, especially in urban areas. There are readily available tools for the mapping and estimation of solar irradiation that give results with the click of a button. Although these tools capture the complexities of the urban environment, they often miss the more important atmospheric parameters that determine the irradiation and potential estimations. Therefore, validation of these models is necessary for accurate potential energy yield and capacity estimations. This paper demonstrates the calibration and validation of the solar radiation model developed by Fu and Rich, employed within ArcGIS, with a focus on the input atmospheric parameters, diffusivity and transmissivity for the Netherlands. In addition, factors affecting the model’s performance with respect to the resolution of the input data were studied. Data were calibrated using ground measurements from Royal Netherlands Meteorological Institute (KNMI) stations in the Netherlands and validated with the station data from Cabauw. The results show that the default model values of diffusivity and transmissivity lead to substantial underestimation or overestimation of solar insolation. In addition, this paper also shows that calibration can be performed at different time scales depending on the purpose and spatial resolution of the input data.

Photocatalytic degradation of methylene blue dye by porous zinc oxide nanofibers prepared via electrospinning: when defects become merits

2021 ◽  
pp. 149830
Author(s):  
Fabiola Pantò ◽  
Zainab Dahrouch ◽  
Abhirup Saha ◽  
Salvatore Patanè ◽  
Saveria Santangelo ◽  
...  
Keyword(s):  
Methylene Blue ◽  
Zinc Oxide ◽  
Photocatalytic Degradation ◽  
Blue Dye ◽  
Methylene Blue Dye

scholarly journals SnS2/TiO2 Nanocomposites for Hydrogen Production and Photodegradation Under Extended Solar Irradiation

Catalysts ◽  
2021 ◽  
Vol 11 (5) ◽  
pp. 589
Author(s):  
Sivagowri Shanmugaratnam ◽  
Balaranjan Selvaratnam ◽  
Aravind Baride ◽  
Ranjit Koodali ◽  
Punniamoorthy Ravirajan ◽  
...  
Keyword(s):  
Methylene Blue ◽  
Photocatalytic Activity ◽  
Hydrogen Evolution ◽  
Environmental Remediation ◽  
High Performance ◽  
Degradation Mechanism ◽  
Solar Irradiation ◽  
Earth Abundant ◽  
Improved Performance ◽  
Chalcogenide Materials

Earth–abundant transition metal chalcogenide materials are of great research interest for energy production and environmental remediation, as they exhibit better photocatalytic activity due to their suitable electronic and optical properties. This study focuses on the photocatalytic activity of flower-like SnS2 nanoparticles (composed of nanosheet subunits) embedded in TiO2 synthesized by a facile hydrothermal method. The materials were characterized using different techniques, and their photocatalytic activity was assessed for hydrogen evolution reaction and the degradation of methylene blue. Among the catalysts studied, 10 wt. % of SnS2 loaded TiO2 nanocomposite shows an optimum hydrogen evolution rate of 195.55 µmolg−1, whereas 15 wt. % loading of SnS2 on TiO2 exhibits better performance against the degradation of methylene blue (MB) with the rate constant of 4.415 × 10−4 s−1 under solar simulated irradiation. The improved performance of these materials can be attributed to the effective photo-induced charge transfer and reduced recombination, which make these nanocomposite materials promising candidates for the development of high-performance next-generation photocatalyst materials. Further, scavenging experiments were carried out to confirm the reactive oxygen species (ROS) involved in the photocatalytic degradation. It can be observed that there was a 78% reduction in the rate of degradation when IPA was used as the scavenger, whereas around 95% reduction was attained while N2 was used as the scavenger. Notably, very low degradation (<5%) was attained when the dye alone was directly under solar irradiation. These results further validate that the •OH radical and the superoxide radicals can be acknowledged for the degradation mechanism of MB, and the enhancement of degradation efficiency may be due to the combined effect of in situ dye sensitization during the catalysis and the impregnation of low bandgap materials on TiO2.

scholarly journals Biosynthesis of Tithonia diversifolia leaf mediated Zinc Oxide Nanoparticles loaded with flamboyant pods (Delonix regia) for the treatment of Methylene Blue Wastewater

2021 ◽  
pp. 103363
Author(s):  
Kehinde Shola Obayomi ◽  
Ayomide Elizabeth Oluwadiya ◽  
Sie Yon Lau ◽  
Adewumi Oluwasogo Dada ◽  
Divine Akubuo-Casmir ◽  
...  
Keyword(s):  
Methylene Blue ◽  
Zinc Oxide ◽  
Zinc Oxide Nanoparticles ◽  
Oxide Nanoparticles ◽  
Tithonia Diversifolia ◽  
Delonix Regia

scholarly journals Biomimetic Synthesis, Characterization, and Evaluation of Fluorescence Resonance Energy Transfer, Photoluminescence, and Photocatalytic Activity of Zinc Oxide Nanoparticles

2021 ◽  
Vol 13 (4) ◽  
pp. 2004
Author(s):  
Udari Wijesinghe ◽  
Gobika Thiripuranathar ◽  
Haroon Iqbal ◽  
Farid Menaa
Keyword(s):  
Electron Microscopy ◽  
Zinc Oxide ◽  
Photocatalytic Activity ◽  
Energy Transfer ◽  
Fluorescence Resonance Energy Transfer ◽  
Resonance Energy Transfer ◽  
Resonance Energy ◽  
Solar Irradiation ◽  
Zno Nps ◽  
Fluorescence Resonance

Owing to the development of nanotechnology, biosynthesis of nanoparticles (NPs) is gaining considerable attention as a cost-effective and eco-friendly approach that minimizes the effects of toxic chemicals used in NP fabrication. The present work reports low-cost phytofabrication of zinc oxide (ZnO) NPs employing aqueous extracts of various parts (leaves, stems, and inflorescences) of Tephrosia purpurea (T. purpurea). The formation, structure, morphology, and other physicochemical properties of ZnO NPs were characterized by ultraviolet–visible (UV–Vis) spectroscopy, X-ray diffraction (XRD), scanning electron microscopy (SEM), transmission electron microscopy (TEM), Fourier transform infrared (FTIR) spectroscopy, and dynamic light scattering (DLS). UV–Vis spectral analysis revealed sharp surface plasmon resonance (SPR) at around 250–280 nm, while the XRD patterns confirmed distinctive peaks indices to the crystalline planes of hexagonal wurtzite ZnO NPs. TEM analysis confirmed the presence of spherical-shaped ZnO NPs with average particle sizes (PS) between 25–35 nm, which was in agreement with the XRD results. FTIR analysis revealed that phenolics, flavonoids, amides, alkaloids, and amines present in the plant extract are responsible for the stabilization of the ZnO NPs. Further, the hydrodynamic diameter in the range of 85–150 nm was measured using the DLS technique. The fluorescence resonance energy transfer (FRET) ability of biogenic ZnO NPs was evaluated, and the highest efficiency was found in ZnO NPs synthesized via T. purpurea inflorescences extract. Photoluminescence (PL) spectra of biogenic ZnO NPs showed three emission peaks consisting of a UV–Vis region with high-intensity compared to that of chemically synthesized ZnO NPs. The biosynthesized ZnO NPs showed photocatalytic activity under solar irradiation by enhancing the degradation rate of methylene blue (MB). Among the prepared biogenic ZnO NPs, T. purpurea leaves mediated with NPs acted as the most effective photocatalyst, with a maximum degradation efficiency of 98.86% and a half-life of 84.7 min. This is the first report related to the synthesis of multifunctional ZnO NPs using T. purpurea, with interesting characteristics for various potential applications in the future.

Photocatalytic Degradation of Methylene Blue by NiO Thin Films under Solar Light Irradiation

2019 ◽  
Vol 56 ◽  
pp. 152-157 ◽  
Author(s):  
Abdelouahab Noua ◽  
Hichem Farh ◽  
Rebai Guemini ◽  
Oussama Zaoui ◽  
Tarek Diab Ounis ◽  
...  
Keyword(s):  
Thin Films ◽  
Methylene Blue ◽  
Photocatalytic Activity ◽  
Sol Gel ◽  
Visible Region ◽  
Optical Transmittance ◽  
Dip Coating ◽  
Light Irradiation ◽  
Solar Light ◽  
Solar Light Irradiation

Nickel oxide (NiO) thin films were successfully deposited by sol-gel dip-coating method on glass substrates. The structural, morphological and optical properties in addition to the photocatalytic activity of the prepared films were investigated. The results show that the films have a polycrystalline NiO cubic structure with dense NiO grains and average optical transmittance in the visible region. The photocatalytic properties of the films were studied through the degradation of methylene blue and 89% of degradation was achieved for 4.5h of solar light irradiation exposure which indicates the capability of NiO photocatalytic activity.

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