scholarly journals Processing and Validation of Whey-Protein-Coated Films and Laminates at Semi-Industrial Scale as Novel Recyclable Food Packaging Materials with Excellent Barrier Properties

2013 ◽  
Vol 2013 ◽  
pp. 1-10 ◽  
Author(s):  
E. Bugnicourt ◽  
M. Schmid ◽  
O. Mc. Nerney ◽  
J. Wildner ◽  
L. Smykala ◽  
...  
Keyword(s):  
Whey Protein ◽  
Food Packaging ◽  
Raw Materials ◽  
Transmission Rate ◽  
Barrier Properties ◽  
Industrial Scale ◽  
Ethylene Vinyl Alcohol ◽  
Plastic Films ◽  
Coating Application ◽  
Plastic Recycling

A biopolymer coating for plastic films was formulated based on whey protein, and its potential to replace current synthetic oxygen barrier layers used in food packaging such as ethylene vinyl alcohol copolymers (EVOH) was tested. The whey-coating application was performed at semi-industrial scale. High barrier to oxygen with transmission rate down to ranges of 1 cm3(STP) m−2d−1bar−1at and 50% relative humidity (r.h.) but interesting humidity barrier down to ranges of 3 g m−2d−1(both normalized to 100 μm thickness) were reached, outperforming most existing biopolymers. Coated films were validated for storing various food products showing that the shelf life and sensory attributes were maintained similar to reference packaging films while complying with food safety regulations. The developed whey coating could be enzymatically removed within 2 hours and is therefore compatible with plastic recycling operations to allow multilayer films to become recyclable by separating the other combined layers. A life cycle assessment was performed showing a significant reduction in the environmental impact of the packaging thanks in particular to the possibility of recycling materials as opposed to incinerating those containing EVOH or polyamide (PA), but due to the use of biosourced raw materials.

scholarly journals Properties of Whey-Protein-Coated Films and Laminates as Novel Recyclable Food Packaging Materials with Excellent Barrier Properties

2012 ◽  
Vol 2012 ◽  
pp. 1-7 ◽  
Author(s):  
Markus Schmid ◽  
Kerstin Dallmann ◽  
Elodie Bugnicourt ◽  
Dario Cordoni ◽  
Florian Wild ◽  
...  
Keyword(s):  
Whey Protein ◽  
Barrier Layer ◽  
Food Packaging ◽  
Mechanical Load ◽  
Barrier Properties ◽  
Packaging Materials ◽  
Renewable Materials ◽  
Multilayer Material ◽  
Ethylene Vinyl Alcohol ◽  
Barrier Materials

In case of food packaging applications, high oxygen and water vapour barriers are the prerequisite conditions for preserving the quality of the products throughout their whole lifecycle. Currently available polymers and/or biopolymer films are mostly used in combination with barrier materials derived from oil based plastics or aluminium to enhance their low barrier properties. In order to replace these non-renewable materials, current research efforts are focused on the development of sustainable coatings, while maintaining the functional properties of the resulting packaging materials. This article provides an introduction to food packaging requirements, highlights prior art on the use of whey-based coatings for their barriers properties, and describes the key properties of an innovative packaging multilayer material that includes a whey-based layer. The developed whey protein formulations had excellent barrier properties almost comparable to the ethylene vinyl alcohol copolymers (EVOH) barrier layer conventionally used in food packaging composites, with an oxygen barrier (OTR) of <2 [cm³(STP)/(m²d bar)] when normalized to a thickness of 100 μm. Further requirements of the barrier layer are good adhesion to the substrate and sufficient flexibility to withstand mechanical load while preventing delamination and/or brittle fracture. Whey-protein-based coatings have successfully met these functional and mechanical requirements.

scholarly journals Compostable Polylactide and Cellulose Based Packaging for Fresh-Cut Cherry Tomatoes: Performance Evaluation and Influence of Sterilization Treatment

Materials ◽  
2020 ◽  
Vol 13 (15) ◽  
pp. 3432 ◽  
Author(s):  
Marco Rapisarda ◽  
Cristina Patanè ◽  
Alessandra Pellegrino ◽  
Angelo Malvuccio ◽  
Valeria Rizzo ◽  
...  
Keyword(s):  
Food Packaging ◽  
Transmission Rate ◽  
Chemical Properties ◽  
Oxygen Demand ◽  
Barrier Properties ◽  
Attenuated Total Reflection ◽  
Cherry Tomato ◽  
Plastic Materials ◽  
Before And After ◽  
Fresh Cut

For food packaging, plastic materials display large appeal, mostly due to their versatility, mechanical, optical and barrier properties. However, they play an important role in environmental concerns and waste management issue. Compostable bioplastics represent alternative materials designed for a lower environmental impact. In this work, a biobased compostable packaging, constituted by polylactide (PLA) trays and NatureFlex™ film, was evaluated for fresh-cut cherry tomato. A comparative analysis was accomplished using traditional packaging materials, that is, polyethylene terephtalate (PET) trays and polypropylene (PP Coex) film. Structural stability under food contact conditions, mechanical and physical-chemical properties were investigated. Tensile mechanical properties, puncture resistance, contact angle (CA) and attenuated total reflection Fourier-transform infrared spectroscopy (ATR-FTIR), before and after UV or radiofrequency (RF) sterilization treatment, were evaluated. UV irradiation method resulted the less invasive one. Therefore, oxygen and water vapor transmission rate (OTR and WVTR), overall chemical migration test, biodegradation assessment by biochemical oxygen demand (BOD) according to ISO 14851 and disintegration test by ISO 20200 were carried out to establish the further influence of UV sterilization on the packaging. Overall, data showed that the biobased compostable packaging for a prolonged shelf-life of fresh-cut cherry tomato has better properties that were surprisingly enhanced by the UV treatment.

scholarly journals Developed Chitosan/Oregano Essential Oil Biocomposite Packaging Film Enhanced by Cellulose Nanofibril

Polymers ◽  
2020 ◽  
Vol 12 (8) ◽  
pp. 1780
Author(s):  
Shunli Chen ◽  
Min Wu ◽  
Caixia Wang ◽  
Shun Yan ◽  
Peng Lu ◽  
...  
Keyword(s):  
Tensile Strength ◽  
Essential Oil ◽  
Food Packaging ◽  
Transmission Rate ◽  
Cellulose Nanofibrils ◽  
Barrier Properties ◽  
Light Transmittance ◽  
Rate Reduction ◽  
Packaging Film ◽  
Oregano Essential Oil

The use of advanced and eco-friendly materials has become a trend in the field of food packaging. Cellulose nanofibrils (CNFs) were prepared from bleached bagasse pulp board by a mechanical grinding method and were used to enhance the properties of a chitosan/oregano essential oil (OEO) biocomposite packaging film. The growth inhibition rate of the developed films with 2% (w/w) OEO against E. coli and L. monocytogenes reached 99%. With the increased levels of added CNFs, the fibrous network structure of the films became more obvious, as was determined by SEM and the formation of strong hydrogen bonds between CNFs and chitosan was observed in FTIR spectra, while the XRD pattern suggested that the strength of diffraction peaks and crystallinity of the films slightly increased. The addition of 20% CNFs contributed to an oxygen-transmission rate reduction of 5.96 cc/m2·day and water vapor transmission rate reduction of 741.49 g/m2·day. However, the increase in CNFs contents did not significantly improve the barrier properties of the film. The addition of 60% CNFs significantly improved the barrier properties of the film to light and exhibited the lowest light transmittance (28.53%) at 600 nm. Addition of CNFs to the chitosan/OEO film significantly improved tensile strength and the addition of 60% CNFs contributed to an increase of 16.80 MPa in tensile strength. The developed chitosan/oregano essential oil/CNFs biocomposite film with favorable properties and antibacterial activity can be used as a green, functional material in the food-packaging field. It has the potential to improve food quality and extend food shelf life.

scholarly journals Effect of Different Formulations on Characteristic of Biobased Alginate Edible Films as Biodegradable Packaging

2020 ◽  
Vol 147 ◽  
pp. 03003
Author(s):  
Novia Racmayani ◽  
Amir Husni
Keyword(s):  
Tensile Strength ◽  
Water Vapor ◽  
Olive Oil ◽  
Food Packaging ◽  
Raw Materials ◽  
Transmission Rate ◽  
Edible Films ◽  
Edible Film ◽  
Water Vapor Transmission Rate ◽  
Water Vapor Transmission

Edible film can be used for food packaging. The main raw materials for edible film were alginates and plasticizers including glycerol and olive oil. This study aims to determine the characteristics of edible film composed of alginate, glycerol and olive oil. The study was carried out through the manufacture of edible films composed of alginates with various concentrations (2, 3, 4, 5 and 6%, w / v), 10% glycerol and 0.01% olive oil. Characteristics of edible film was observed including thickness, tensile strength, water vapor transmission rate, solubility and elongation. The results showed that the products met the edible film standard of the Japanese Industrial Standard. Concentration of alginate used had significant effect on thickness, tensile strength, solubility and elongation of the edible film. The films with 6% concentration of alginate showed optimum results with thickness 0,227 ± 0,008 mm, tensile strength 3,097 ± 0,384 MPa, elongation 86,682 ± 5,090 %, solubility 8,690 ± 2,892 % and water vapor transmission rate 45,477 ± 6,262 g/m2/24 h.

scholarly journals Effect of Overlapping Eco-Friendly Cellulose Nanofibrils and Nanoclay Layers on Mechanical and Barrier Properties of Spray-Coated Papers

2021 ◽  
Author(s):  
Maria Luiza Cafalchio de Oliveira ◽  
Seyedmohammad Mirmehdi ◽  
Mário Vanoli Scatolino ◽  
Mario Guimarães Júnior ◽  
Anand Ramesh Sanadi ◽  
...  
Keyword(s):  
Tensile Strength ◽  
Raw Materials ◽  
Transmission Rate ◽  
Cellulose Nanofibrils ◽  
Spray Coating ◽  
Barrier Properties ◽  
Contact Angles ◽  
Renewable Raw Materials ◽  
Coated Papers ◽  
Lower Contact

Abstract This work proposes to evaluate the effect of spray-coating in papers using eco-friendly cellulose nanofibrils (CNFs) and nanoclay (NC) on mechanical and barrier properties for application as reinforced bags. Sack kraft papers of 60 g m-² (C60) were coated with CNFs + CNFs/NC in 4 layers (L5), 40 g m-² of CNFs + CNFs/NC in 3 layers (L4), 30 g m-² with CNFs/NC in 2 layers (L3) and 10 g m-² of CNFs in 1 layer (L2), and compared to uncoated sack kraft papers with basis weight of 60 g m-² (C60), 80 g m-² (C80) and 120 g m-² (C120). The coated papers L2; L3; L4 and L5 obtained a decrease in water vapor transmission rate (WVTR) of 3.5%; 17%; 14% and 14%, respectively, when compared to C60. Comparing L2 and L3, CNF layer induced lower contact angles on the coated paper than CNF/NC layer. When compared coated papers with C120, it was observed an increase of around 66% in tensile strength for L2, around 44% for L3, and decrease of ~ 18% for L5 coated papers. L4 achieved the same tensile strength (when divided by basis weight) than C120. L2 and L3 coated papers led to the highest values of Young’s modulus, with increase of 56% and 38%, respectively, when compared to C60. Spray-coating in the present conditions improved the mechanical and barrier properties of the coated papers, being a possible alternative to produce papers with lower basis weight and using renewable raw materials.

Barrier and physical properties of polypropylene/highbarrier ethylene vinyl alcohol copolymer blends compatibilized with a sodium ionomer

e-Polymers ◽  
2009 ◽  
Vol 9 (1) ◽  
Author(s):  
Ana Ares ◽  
María J Abad ◽  
Luis Barral ◽  
Sandra García-Garabal
Keyword(s):  
Transmission Rate ◽  
Barrier Properties ◽  
Processing Technique ◽  
Ethylene Vinyl Alcohol ◽  
Know How ◽  
Oxygen Transmission Rate ◽  
Copolymer Blends ◽  
Packaging Industry ◽  
Potential Use ◽  
Oxygen Transmission

AbstractThe aim of this work is to investigate the properties of the PP/EVOH films for their potential use in the packaging industry. Besides, the barrier properties, the mechanical parameters and the morphology of the PP/EVOH films have been studied as function of their composition and the processing technique used for their manufacture. In these applications, the package is frequently in contact with humidity environments and for this, it is necessary to know how environments with different humidity contents, affect the O2 permeability of the polymer material. For these reasons, the influence of the moisture in the values of permeability was evaluated too. The data showed that the oxygen transmission rate (O2TR) decreased with the amount of EVOH, and if the copolymer mass is maintained constant, the O2TR diminished with the quantity of the ionomer in the compositions. Besides, the films obtained by extrusion and following unidirectional stretching, presented better barrier properties to the oxygen molecules than the compression moulded films. When the ionomer is added to the compositions the permeability is reduced even for the films maintained in wet atmosphere. The micrographs obtained by SEM showed that the films have a biphasic structure, where the EVOH particles are dispersed in the PP matrix.

scholarly journals Methylation of guar gum for improving mechanical and barrier properties of biodegradable packaging films

2019 ◽  
Vol 9 (1) ◽  
Author(s):  
Jyoti Tripathi ◽  
Rupali Ambolikar ◽  
Sumit Gupta ◽  
Dheeraj Jain ◽  
Jitendra Bahadur ◽  
...  
Keyword(s):  
Mechanical Properties ◽  
Food Packaging ◽  
Guar Gum ◽  
Transmission Rate ◽  
Average Molecular Weight ◽  
Barrier Properties ◽  
Partial Replacement ◽  
Radius Of Gyration ◽  
Biodegradable Films ◽  
Gradual Improvement

Abstract Improving functional properties of biopolymers for use as environment friendly packaging is an area of current interest. Biodegradable films with improved barrier and mechanical properties were prepared from methylated guar gum. Methylation resulted in structural modification of guar gum (GG) promoting greater crystallization thereby enhancing thermal stability towards decomposition. Reduction in radius of gyration (Rg), weight average molecular weight (Mw), and an increase in polydispersity index (PDI) were also observed due to methylation. Methylated guar gum (MGG) films exhibited 40% lower water vapor transmission rate (WVTR) as compared to control purified guar gum (PGG) films. Films prepared by partial replacement of PGG with MGG (10, 25, 50, 75 and 100% w/w) showed gradual improvement in percent elongation. The study gives an insight on the role of methylation in enhancing barrier and mechanical properties of GG based biodegradable films for possible application in food packaging.

scholarly journals Renewable cellulosic nanocomposites for food packaging to avoid fossil fuel plastic pollution: a review

2020 ◽  
Author(s):  
Umair Qasim ◽  
Ahmed I. Osman ◽  
Ala’a H. Al-Muhtaseb ◽  
Charlie Farrell ◽  
Mohammed Al-Abri ◽  
...  
Keyword(s):  
Mechanical Properties ◽  
Lignocellulosic Biomass ◽  
Food Packaging ◽  
Transmission Rate ◽  
Barrier Properties ◽  
Environmental Damage ◽  
Vapor Permeability ◽  
Plastic Pollution ◽  
Oxygen Transmission Rate ◽  
Cellulose Nanoparticles

Abstract The extensive use of petroleum-based synthetic and non-biodegradable materials for packaging applications has caused severe environmental damage. The rising demand for sustainable packaging materials has encouraged scientists to explore abundant unconventional materials. For instance, cellulose, extracted from lignocellulosic biomass, has gained attention owing to its ecological and biodegradable nature. This article reviews the extraction of cellulose nanoparticles from conventional and non-conventional lignocellulosic biomass, and the preparation of cellulosic nanocomposites for food packaging. Cellulosic nanocomposites exhibit exceptional mechanical, biodegradation, optical and barrier properties, which are attributed to the nanoscale structure and the high specific surface area, of 533 m2 g−1, of cellulose. The mechanical properties of composites improve with the content of cellulose nanoparticles, yet an excessive amount induces agglomeration and, in turn, poor mechanical properties. Addition of cellulose nanoparticles increases tensile properties by about 42%. Barrier properties of the composites are reinforced by cellulose nanoparticles; for instance, the water vapor permeability decreased by 28% in the presence of 5 wt% cellulose nanoparticles. Moreover, 1 wt% addition of filler decreased the oxygen transmission rate by 21%. We also discuss the eco-design process, designing principles and challenges.

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