scholarly journals Water Absorption Behaviour and Its Effect on the Mechanical Properties of Flax Fibre Reinforced Bioepoxy Composites

2015 ◽  
Vol 2015 ◽  
pp. 1-10 ◽  
Author(s):  
E. Muñoz ◽  
J. A. García-Manrique

In the context of sustainable development, considerable interest is being shown in the use of natural fibres like as reinforcement in polymer composites and in the development of resins from renewable resources. This paper focuses on eco-friendly and sustainable green composites manufacturing using resin transfer moulding (RTM) process. Flax fibre reinforced bioepoxy composites at different weight fractions (40 and 55 wt%) were prepared in order to study the effect of water absorption on their mechanical properties. Water absorption test was carried out by immersion specimens in water bath at room temperature for a time duration. The process of water absorption of these composites was found to approach Fickian diffusion behavior. Diffusion coefficients and maximum water uptake values were evaluated; the results showed that both increased with an increase in fibre content. Tensile and flexural properties of water immersed specimens were evaluated and compared to dry composite specimens. The results suggest that swelling of flax fibres due to water absorption can have positive effects on mechanical properties of the composite material. The results of this study showed that RTM process could be used to manufacture natural fibre reinforced composites with good mechanical properties even for potential applications in a humid environment.

2021 ◽  
Vol 11 (1) ◽  
Author(s):  
Sekar Sanjeevi ◽  
Vigneshwaran Shanmugam ◽  
Suresh Kumar ◽  
Velmurugan Ganesan ◽  
Gabriel Sas ◽  
...  

AbstractThis investigation is carried out to understand the effects of water absorption on the mechanical properties of hybrid phenol formaldehyde (PF) composite fabricated with Areca Fine Fibres (AFFs) and Calotropis Gigantea Fibre (CGF). Hybrid CGF/AFF/PF composites were manufactured using the hand layup technique at varying weight percentages of fibre reinforcement (25, 35 and 45%). Hybrid composite having 35 wt.% showed better mechanical properties (tensile strength ca. 59 MPa, flexural strength ca. 73 MPa and impact strength 1.43 kJ/m2) under wet and dry conditions as compared to the other hybrid composites. In general, the inclusion of the fibres enhanced the mechanical properties of neat PF. Increase in the fibre content increased the water absorption, however, after 120 h of immersion, all the composites attained an equilibrium state.


Author(s):  
Bojan Poletanovic ◽  
Katalin Kopecsko ◽  
Ildikó Merta

The aim of this study was to examine the influence of flax fibre protection with the linseed oil and a matrix modification with cement substitution with metakaolin (in 10wt% and 15wt%) on the mechanical properties of cement-based mortars under severe environmental conditions of freeze/thaw cycles. Cement-based mortars (with the dimension of 40x40x160 mm3) were reinforced by 10mm long discrete flax fibres (Linumusitatissimum) and exposed to 51 freeze/thaw cycles under laboratory condition. Their compressive and flexural strengths, as well as specific energy absorption capacity were measured after freeze/thaw cycles and compared to the results of mortars cured for same time in water. Under freeze/thaw cycles mortars reinforced with linseed oil-treated fibres showed the same range of degradation of the compressive and flexural strengths, however, a more pronounced degradation of energy absorption capacity compared to non-treated fibre reinforced mortars was observed. The matrix modification, by partial cement substitution with metakaolin showed optimistic results under freeze/thaw cycles. The compressive strength when cement was partially substituted with metakaolin (in both dosages) increased whereas the flexural strength was slightly lower in case of 10wt% substitution and markedly lower under higher (15wt%) cement substitution. The most relevant is that the decrease of the energy absorption capacity of the fibre reinforced mortar was completely prevented when cement was substituted with metakaolin. It is shown that the energy absorption of the non-treated fibre reinforced mortars increases by 27% when cement was substituted with metakaolin (both 10wt% and 15wt%).


Materials ◽  
2020 ◽  
Vol 13 (20) ◽  
pp. 4529
Author(s):  
Hanna M. Brodowsky ◽  
Anne Hennig ◽  
Michael Thomas Müller ◽  
Anett Werner ◽  
Serge Zhandarov ◽  
...  

Natural fibres have a high potential as reinforcement of polymer matrices, as they combine a high specific strength and modulus with sustainable production and reasonable prices. Modifying the fibre surface is a common method to increase the adhesion and thereby enhance the mechanical properties of composites. In this study, a novel sustainable surface treatment is presented: the fungal enzyme laccase was utilised with the aim of covalently binding the coupling agent dopamine to flax fibre surfaces. The goal is to improve the interfacial strength towards an epoxy matrix. SEM and AFM micrographs showed that the modification changes the surface morphology, indicating a deposition of dopamine on the surface. Fibre tensile tests, which were performed to check whether the fibre structure was damaged during the treatment, showed that no decrease in tensile strength or modulus occurred. Single fibre pullout tests showed a 30% increase in interfacial shear strength (IFSS) due to the laccase-mediated bonding of the coupling agent dopamine. These results demonstrate that a laccase + dopamine treatment modifies flax fibres sustainably and increases the interfacial strength towards epoxy.


Polymers ◽  
2019 ◽  
Vol 11 (4) ◽  
pp. 699 ◽  
Author(s):  
Erik Valentine Bachtiar ◽  
Katarzyna Kurkowiak ◽  
Libo Yan ◽  
Bohumil Kasal ◽  
Torsten Kolb

In this study, ammonium polyphosphate (APP) and aluminum hydroxide (ALH) with different mass contents were used as fire retardants (FRs) on plant-based natural flax fabric-reinforced polymer (FFRP) composites. Thermogravimetric analysis (TGA), limited oxygen index (LOI), and the Underwriters Laboratories (UL)-94 horizontal and vertical tests were carried out for evaluating the effectiveness of these FR treatments. Flat-coupon tensile test was performed to evaluate the effects of FR treatment on the mechanical properties of the FFRP composites. For both fire retardants, the results showed that the temperature of the thermal decomposition and the LOI values of the composites increased as the FR content increases. Under the UL-94 vertical test, the FFRP composites with 20% and 30% APP (i.e., by mass content of epoxy polymer matrix) were self-extinguished within 30 and 10 s following the removal of the flame without any burning drops, respectively. However, the mechanical tensile tests showed that the APP treated FFRP composites reduced their elastic modulus and strength up to 24% and 18%, respectively. Scanning electronic microscopic (SEM) for morphology examination showed an effective coating of the flax fibres with the FRs, which improved the flame retardancy of the treated composites.


2011 ◽  
Vol 675-677 ◽  
pp. 427-430 ◽  
Author(s):  
Jin Hua Jiang ◽  
Ze Xing Wang ◽  
Nan Liang Chen

In the past decade, natural fibre composites with thermoplastic matrices had attracted many composites manufactures for the superiority of lightweight and low-cost. A major challenge for natural fibre composites was to achieve high mechanical performance at a competitive price. Composites constructed from yarn and fabric structure preforms were better than composites made from random nonwoven mats. However, the twist structure of conventional ring spun yarns prevented the full utilization of fibre mechanical properties in the final composites. In this paper, the wrapped yarns were produced by wrap spun method with flax and polypropylene (PP), in which all flax fibres were twistless, then woven to be fabric preforms. The PP fibres served as a carrier for flax fibres during processing and became the polymer matrix in the final composites. The homogenous distribution of fibre and thermoplastic matrix in preforms could be achieved before hot pressing, so that not lead to impregnate difficultly, and prevented damage to the reinforced nature fibres during processing. Composites made from the wrapped yarn demonstrated significant tensile and peeling properties. The fabric structures (include plain, twill, and basket weave) and yarn tensile orientation (in 0°, 90°, 45°), had great influence on tensile strength and elongation of preforms. The cavity thickness of hot pressing mould had different influence on the tensile strength and peeling strength of thermoplastic composites, and the mechanical properties were superior when the thickness was 0.8-1.2 mm. The microstructure of thermoplastic composites showed uniform infiltration between layers, and had good bonding interface between flax fibre and PP matrix in composites.


Polymers ◽  
2021 ◽  
Vol 13 (17) ◽  
pp. 2964
Author(s):  
Cionita Tezara ◽  
Agung Efriyo Hadi ◽  
Januar Parlaungan Siregar ◽  
Zalinawati Muhamad ◽  
Mohammad Hazim Mohamad Hamdan ◽  
...  

Recently, the most critical issue related to the use of natural fibre-reinforced polymer composites (NFRPC) is the degradation properties of composites exposed to the environment. NFRPC’s moisture absorption behaviour has adverse effects on the composite’s mechanical properties and dimensional stability. The purpose of this study is to analyse the mechanical properties of epoxy composites reinforced by jute–ramie hybridisation. This study also analysed the effect of stacking sequence hybridisation of the jute–ramie composite on water absorption behaviour. A five-layer different type of stacking sequence of single and hybrid jute–ramie is produced with the hand lay-up method. The results obtained from this study found that the mechanical properties and water absorption behaviour of a single jute fibre are lower compared to a single ramie fibre. The hybrid of jute–ramie has been able to increase the performance of composite compared to pure jute composites. The mechanical properties of the hybrid jute–ramie composite show a reduction effect after exposure to an aqueous environment due to the breakdown of fibre matrix interfacial bonding. However, after 28 days of immersion, all types of the stacking sequence’s mechanical properties are still higher than that of pure epoxy resin. In conclusion, the appropriate sequence of stacking and selecting the material used are two factors that predominantly affect the mechanical properties and water absorption behaviour. The hybrid composites with the desired and preferable properties can be manufactured using a hand-lay-up technique and used in the various industrial applications.


Polymers ◽  
2020 ◽  
Vol 12 (2) ◽  
pp. 437 ◽  
Author(s):  
Elena Mastalygina ◽  
Ivetta Varyan ◽  
Natalya Kolesnikova ◽  
Maria Isabel Cabrera Gonzalez ◽  
Anatoly Popov

Compounding natural additives with synthetic polymers allows developing more eco-friendly materials with enhanced biodegradability. The composite films based on low-density polyethylene (PE) with different content of natural rubber (NR) (10–30 wt%) were investigated. The influence of NR content on structural features, water absorption and mechanical properties of the composites were studied. The 70PE/30NR composite is characterized by the uniform distribution and the smallest size of NR domains (45 ± 5 μm). A tensile test was satisfied by the mechanical properties of the biocomposites, caused by elasticity of NR domains. The tensile strength of 70PE/30NR composite film is 5 ± 0.25 MPa. Higher water absorption of PE/NR composites (1.5–3.7 wt%) compared to neat PE facilitates penetrating vital activity products of microorganisms. Mycological test with mold fungi and full-scale soil test detected the composite with 30 wt% of NR as the most biodegradable (mass loss was 7.2 wt% for 90 days). According to infrared spectroscopy and differential scanning calorimetry analysis, NR consumption and PE structural changes in the biocomposites after exposure to soil occurred. The PE/NR composites with enhanced biodegradability as well as satisfied mechanical and technological properties have potential applications in packaging and agricultural films.


2003 ◽  
Vol 12 (3) ◽  
pp. 096369350301200 ◽  
Author(s):  
J. S. Szabo ◽  
G. Romhany ◽  
T. Czigany ◽  
J. Karger-Kocsis

Vinylester/epoxy (VE/EP) hybrid resins of interpenetrating network (IPN) structure were reinforced by needled flax fibre mat. The flax content of the composites was kept constant (20 wt%) whereas the VE/EP ratio varied (70/30, 50/50, and 30/70). The mechanical properties of the composites, produced by resin transfer moulding, were determined in tensile and flexural loading. The mechanical anisotropy detected was traced to the orientation of the flax fibres during carding. The higher was the VE content of the hybrid IPN resin the better the mechanical performance was.


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