scholarly journals Diagenetic Modifications and Reservoir Heterogeneity Associated with Magmatic Intrusions in the Devonian Khyber Limestone, Peshawar Basin, NW Pakistan

Geofluids ◽  
2021 ◽  
Vol 2021 ◽  
pp. 1-18
Author(s):  
Mumtaz M. Shah ◽  
Saifullah Afridi ◽  
Emad U. Khan ◽  
Hamad Ur Rahim ◽  
Muhammad R. Mustafa

In the present study, an attempt has been made to establish the relationship between diagenetic alterations resulting from magmatic intrusions and their impact on the reservoir properties of the Devonian Khyber Limestone (NW Pakistan). Field observations, petrographic studies, mineralogical analyses, porosity-permeability data, and computed tomography were used to better understand the diagenetic history and petrophysical property evolution. Numerous dolerite intrusions are present in the studied carbonate successions, where the host limestone was altered to dolomite and marble, and fractures and faults developed due to the upwelling of the magmatic/hydrothermal fluids along pathways. Petrographic studies show an early phase of coarse crystalline saddle dolomite (Dol. I), which resulted from Mg-rich hydrothermal fluids originated from the dolerite dykes. Coarse crystalline marble formed due to contact metamorphism at the time of dolerite emplacement. The second phase of dolomitisation (Dol. II) postdates the igneous intrusions and was followed by dedolomitisation, dissolution, and cementation by meteoric calcite. Stable isotope studies likewise confirm two distinct dolomite phases. Dol. I exhibits more depleted δ18O (-15.8 to -9.1‰ V-PDB) and nondepleted δ13C (-2.05 to +1.85‰ V-PDB), whereas Dol. II shows a relatively narrow range of depleted δ18O (-13.9 to -13.8‰) signatures and nondepleted δ13C (+1.58 to +1.89‰ V-PDB). Dolomitic marble shows a marked depletion in δ18O and δ13C (-13.7 to -8.5‰ and -2.3 to 1.95‰, respectively). The initial phase of dolomitisation (Dol. I) did not alter porosity (5.4-6.6%) and permeability (0.0-0.1 mD) with respect to the unaltered limestone (5.6-6.9%; 0.1-0.2 mD). Contact metamorphism resulted in a decrease in porosity and permeability (3.3-4.7%; 0.1 mD). In contrast, an increase in porosity and permeability in Dol. II (7.7-10.5%; 0.8-2.5 mD) and dolomitic marble (6.6-14.7%; 8.2-13.3 mD) is linked to intercrystalline porosity and retainment of fracture porosity in dolomitic marble. Late-stage dissolution and dedolomitization also positively affected the reservoir properties of the studied successions. In conclusion, the aforementioned results reveal the impact of various diagenetic processes resulting from magmatic emplacement and their consequent reservoir heterogeneity.

Minerals ◽  
2020 ◽  
Vol 10 (9) ◽  
pp. 757
Author(s):  
Temitope Love Baiyegunhi ◽  
Kuiwu Liu ◽  
Oswald Gwavava ◽  
Christopher Baiyegunhi

The Cretaceous sandstone in the Bredasdorp Basin is an essential potential hydrocarbon reservoir. In spite of its importance as a reservoir, the impact of diagenesis on the reservoir quality of the sandstones is almost unknown. This study is undertaken to investigate the impact of digenesis on reservoir quality as it pertains to oil and gas production in the basin. The diagenetic characterization of the reservoir is based on XRF, XRD SEM + EDX, and petrographic studies of 106 thin sections of sandstones from exploration wells E-AH1, E-AJ1, E-BA1, E-BB1 and E-D3 in the basin. The main diagenetic processes that have affected the reservoir quality of the sandstones are cementation by authigenic clay, carbonate and silica, growth of authigenic glauconite, dissolution of minerals and load compaction. Based on the framework grain–cement relationships, precipitation of the early calcite cement was either accompanied or followed up by the development of partial pore-lining and pore-filling clay cements, particularly illite. This clay acts as pore choking cement, which reduces porosity and permeability of the reservoir rocks. The scattered plots of porosity and permeability versus cement + clays show good inverse correlations, suggesting that the reservoir quality is mainly controlled by cementation and authigenic clays.


2009 ◽  
Vol 46 (4) ◽  
pp. 247-261 ◽  
Author(s):  
James Conliffe ◽  
Karem Azmy ◽  
Ian Knight ◽  
Denis Lavoie

The Watts Bight Formation in western Newfoundland consists of a Lower Ordovician succession of shallow-water carbonates and has been extensively dolomitized. These dolomites occur as both replacements and cements and are associated with complex changes in the rock porosity and permeability. Early replacement micritic dolomites (D1) are finely crystalline and indicate that dolomitization began during early stages of diagenesis. The calculated δ18O values of the earliest (D1) dolomitizing fluids (–6.4‰ to –9.5‰ VSMOW, Vienna Standard Mean Ocean Water) fall between the estimated δ18O values of Tremadocian seawater and meteoric waters and suggest mixing-zone dolomitization. A second phase of coarsely crystalline (up to 400 μm) dolomite (D2) replaces D1 dolomite and early calcite and is associated with enhancement in porosity and permeability through the development of intercrystalline pores. A late-stage saddle dolomite (D3) and late burial calcite cements significantly occluded the pores in some horizons. Petrography, fluid inclusions, and geochemistry show that D2 and D3 dolomites formed from warm (65–125 °C) saline (10 to 25 eq. wt.% NaCl + CaCl2) hydrothermal fluids. The calculated δ18Ofluid of D2 ranges from –4.5‰ to 3.6‰ VSMOW, and for D3 dolomites, calculated δ18Ofluid ranges from 1.4‰ to 8.4‰ VSMOW, suggesting an influx of basinal brines. The occurrence of high porosity associated with D2, combined with the laterally sealing tight limestone beds, presence of favourable source rocks, and thermal maturation, may suggest that the Watts Bight carbonates are possible potential hydrocarbon reservoirs and suitable targets for future hydrocarbon exploration in western Newfoundland.


2021 ◽  
Author(s):  
Osita Robinson Madu ◽  
Jerry Orrelo Athoja ◽  
Amarachi Queen Kalu ◽  
Obi Mike Onyekonwu

Abstract In-depth knowledge of geostatistical analysis, environment of deposition and reservoir facies types is important for optimal distribution of reservoir properties across the reservoir grid. Geostatistics is a veritable tool that is quantitatively used to model spatial continuity, anisotropy direction and capture reservoir heterogeneity for optimal distribution of reservoir properties. When spatial continuity and heterogeneity level of the reservoir are adequately understood and modeled, representative property distribution becomes possible. In the face of limited well data, modeling major and minor directions of horizontal variogram is highly impaired and it becomes difficult to adequately distribute properties within the reservoir grid with enough control. This study is focused on the integration of seismic data, core data, well logs and geological knowledge to carry out geostatistical analysis to optimally distribute facies, porosity and permeability properties within the grid. The degree of reservoir heterogeneity was determined quantitatively using semivariogram and Lorenz plots of core porosity and permeability data. Variogram map generated from seismic attribute was used in combination with the sparse well data points to determine the horizontal variogram. The available well data was adequate enough to model the vertical variogram. The environment of deposition was interpreted as lower to upper shoreface with channel deposits and some shallow marine influence. The properties were normal-scored and modeled with the determined variogram parameters while biasing them with facies. Results of the semivariogram and Lorenz plots showed that the reservoir is fairly heterogenous in terms of spatial continuity. Major direction of the geological continuity is in the Northeast-Southwest direction while the minor direction is orthogonal to it. Final result of the modeled properties was in consonance with the facies types described from the environment of deposition.


Healthcare ◽  
2021 ◽  
Vol 9 (2) ◽  
pp. 170
Author(s):  
Encarna Hernández ◽  
Marcos Camacho ◽  
César Leal-Costa ◽  
María Ruzafa-Martínez ◽  
Antonio Jesús Ramos-Morcillo ◽  
...  

Clinical simulation in obstetrics has turned out to be a tool that can reduce the rate of perinatal morbidity and mortality. The objective of this study was to analyze the impact and evaluate the effects of training with high-fidelity simulation of obstetric emergencies on a multidisciplinary group. The quasi-experimental research study was structured in three phases: a first phase where the most important obstetric emergencies were determined, a second phase of design and development of the selected cases for simulation training, and a third and final phase where the abilities and satisfaction of the multidisciplinary team were analyzed. Three scenarios and their respective evaluation tools of obstetric emergencies were selected for simulation training: postpartum hemorrhage, shoulder dystocia, and breech delivery. The health professionals significantly improved their skills after training, and were highly satisfied with the simulation experience (p < 0.05). An inter-observer agreement between good and excellent reliability was obtained. Regarding conclusions, we can state that high-fidelity obstetric emergency simulation training improved the competencies of the health professionals.


2021 ◽  
Vol 19 (6) ◽  
pp. 2483-2504
Author(s):  
Luigi Di Sarno ◽  
Jing-Ren Wu

AbstractThis paper presents the fragility assessment of non-seismically designed steel moment frames with masonry infills. The assessment considered the effects of multiple earthquakes on the damage accumulation of steel frames, which is an essential part of modern performance-based earthquake engineering. Effects of aftershocks are particularly important when examining damaged buildings and making post-quake decisions, such as tagging and retrofit strategy. The procedure proposed in the present work includes two phase assessment, which is based on incremental dynamic analyses of two refined numerical models of the case-study steel frame, i.e. with and without masonry infills, and utilises mainshock-aftershock sequences of natural earthquake records. The first phase focuses on the undamaged structure subjected to single and multiple earthquakes; the effects of masonry infills on the seismic vulnerability of the steel frame were also considered. In the second phase, aftershock fragility curves were derived to investigate the seismic vulnerability of infilled steel frames with post-mainshock damage caused by mainshocks. Comparative analyses were conducted among the mainshock-damaged structures considering three post-mainshock damage levels, including no damage. The impact of aftershocks was then discussed for each mainshock-damage level in terms of the breakpoint that marks the onset of exceeding post-mainshock damage level, as well as the probability of exceeding of superior damage level due to more significant aftershocks. The evaluation of the efficiency of commonly used intensity measures of aftershocks was also carried out as part of the second phase of assessment.


2020 ◽  
Vol 41 (S1) ◽  
pp. s200-s201
Author(s):  
Mariana Melo ◽  
Raquel Bandeira ◽  
lio de Castro Giselle Dias ◽  
Braulio Couto

Background: Carbapenem-resistant GNB infections are a serious public health problem worldwide, particularly due to the high mortality associated with them and the low number of therapeutic options. One approach to this challenge is the development of antimicrobial stewardship programs. Objective: We evaluated the impact of a carbapenem restriction program on reducing of bacterial resistance in an intensive care unit (ICU). Methods: A retrospective study conducted in 2 phases in the 80-bed ICU of an acute-care public hospital in Minas Gerais, Brazil. The preintervention phase lasted 16 months (January 2018–April 2019) and the second phase (carbapenem restriction), after the intervention, lasted 4 months (May–August 2019). The intervention was defined as carbapenem-sparing and the use of meropenem was authorized in 3 situations: (1) treatment of serious infections documented by extended-spectrum β-lactamase–producing Enterobacteriacea (ESBL); (2) therapeutic failure with the use of another antimicrobial; and (3) infectious disease recommendation. Data were obtained through consultation of electronic medical records and microbiological results, as standardized by the CLSI, for patients with a >48-hour stay in the ICU and who met the criteria for healthcare-associated infection (HAI) according to the CDC NHSN definition. Results: Before the intervention, on average, 50 cultures were obtained with positive results for multidrug-resistant GNB–MER-GNB (SD, 12.2) and in the intervention phase, this number was 31 cultures (SD, 12.8; P = .010). Average carbapenem consumption decreased significantly with corresponding increase in cefepime consumption in the same period (Fig. 1). The ATB (DDD per 1,000 patient days) before the intervention for carbapenems was 110.6 (SD, 97.1) and for cefepime was 8.2 (SD, 5.9). In the intervention phase, the ATB for carbapenems was 44.7 (SD, 38.5; P = .015) and for cefepime it was 32.0 (SD, 20.3; P < .001). In terms of multidrug resistance rate, before the intervention, 95 of 149 of Acinetobacter (64%) were resistant and during the intervention, 13 of 30 Acinetobacter (43%) were resistant (P = .043). Other GNB (Klebsiella, Proteus, Escherichia coli, and Pseudomonas) reduced the resistance rate, but without statistical significance. We observed a reduction in the HAI rate per MDR-GNB (Fig. 2): before the intervention, it was 22.7 (SD, 5.5) and during the intervention phase it was 16.5 (SD, 7.7; P = .07), although this change did not reach statistical significance. Nevertheless, the ICU Klebsiella infection rate did significantly decrease; it was 5.5 (SD, 1.9) before the intervention and 2.4 (SD, 1.8) after the intervention (P = .009). Conclusions: Short-term carbapenem restriction may be an effective strategy to reduce the incidence of carbapenem-resistant GNB infections in the ICU. The scarce arsenal available for the treatment of MDR-GNB and the high mortality rate justify the growing need for stewardship programs in Brazilian ICUs.Funding: NoneDisclosures: None


2012 ◽  
Vol 9 (3) ◽  
pp. 1033-1040 ◽  
Author(s):  
M. Barlett ◽  
K. Zhuang ◽  
R. Mahadevan ◽  
D. Lovley

Abstract. Enhancing microbial U(VI) reduction with the addition of organic electron donors is a promising strategy for immobilizing uranium in contaminated groundwaters, but has yet to be optimized because of a poor understanding of the factors controlling the growth of various microbial communities during bioremediation. In previous field trials in which acetate was added to the subsurface, there were two distinct phases: an initial phase in which acetate-oxidizing, U(VI)-reducing Geobacter predominated and U(VI) was effectively reduced and a second phase in which acetate-oxidizing sulfate reducing bacteria (SRB) predominated and U(VI) reduction was poor. The interaction of Geobacter and SRB was investigated both in sediment incubations that mimicked in situ bioremediation and with in silico metabolic modeling. In sediment incubations, Geobacter grew quickly but then declined in numbers as the microbially reducible Fe(III) was depleted whereas the SRB grow more slowly and reached dominance after 30–40 days. Modeling predicted a similar outcome. Additional modeling in which the relative initial percentages of the Geobacter and SRB were varied indicated that there was little to no competitive interaction between Geobacter and SRB when acetate was abundant. Further simulations suggested that the addition of Fe(III) would revive the Geobacter, but have little to no effect on the SRB. This result was confirmed experimentally. The results demonstrate that it is possible to predict the impact of amendments on important components of the subsurface microbial community during groundwater bioremediation. The finding that Fe(III) availability, rather than competition with SRB, is the key factor limiting the activity of Geobacter during in situ uranium bioremediation will aid in the design of improved uranium bioremediation strategies.


2021 ◽  
Author(s):  
S Al Naqbi ◽  
J Ahmed ◽  
J Vargas Rios ◽  
Y Utami ◽  
A Elila ◽  
...  

Abstract The Thamama group of reservoirs consist of porous carbonates laminated with tight carbonates, with pronounced lateral heterogeneities in porosity, permeability, and reservoir thickness. The main objective of our study was mapping variations and reservoir quality prediction away from well control. As the reservoirs were thin and beyond seismic resolution, it was vital that the facies and porosity be mapped in high resolution, with a high predictability, for successful placement of horizontal wells for future development of the field. We established a unified workflow of geostatistical inversion and rock physics to characterize the reservoirs. Geostatistical inversion was run in static models that were converted from depth to time domain. A robust two-way velocity model was built to map the depth grid and its zones on the time seismic data. This ensured correct placement of the predicted high-resolution elastic attributes in the depth static model. Rock physics modeling and Bayesian classification were used to convert the elastic properties into porosity and lithology (static rock-type (SRT)), which were validated in blind wells and used to rank the multiple realizations. In the geostatistical pre-stack inversion, the elastic property prediction was constrained by the seismic data and controlled by variograms, probability distributions and a guide model. The deterministic inversion was used as a guide or prior model and served as a laterally varying mean. Initially, unconstrained inversion was tested by keeping all wells as blind and the predictions were optimized by updating the input parameters. The stochastic inversion results were also frequency filtered in several frequency bands, to understand the impact of seismic data and variograms on the prediction. Finally, 30 wells were used as input, to generate 80 realizations of P-impedance, S-impedance, Vp/Vs, and density. After converting back to depth, 30 additional blind wells were used to validate the predicted porosity, with a high correlation of more than 0.8. The realizations were ranked based on the porosity predictability in blind wells combined with the pore volume histograms. Realizations with high predictability and close to the P10, P50 and P90 cases (of pore volume) were selected for further use. Based on the rock physics analysis, the predicted lithology classes were associated with the geological rock-types (SRT) for incorporation in the static model. The study presents an innovative approach to successfully integrate geostatistical inversion and rock physics with static modeling. This workflow will generate seismically constrained high-resolution reservoir properties for thin reservoirs, such as porosity and lithology, which are seamlessly mapped in the depth domain for optimized development of the field. It will also account for the uncertainties in the reservoir model through the generation of multiple equiprobable realizations or scenarios.


2017 ◽  
Vol 88 (15) ◽  
pp. 1776-1787 ◽  
Author(s):  
Mohamed Habibi ◽  
Édu Ruiz ◽  
Gilbert Lebrun ◽  
Luc Laperrière

This paper presents an experimental study and modeling of the influence of surface density and fiber length on the permeability of novel nonwoven flax fiber manufactured by the paper making process. Firstly, the relation between surface density, fiber lengths and pore size distribution measured with a porometer capillary instrument is reported in this study. The results show that higher surface density gives a denser fibrous network with a low porosity rate and longer fiber decreases the total number of fibers and increases the pore size for a given surface density. A liquid permeability study was then carried out to identify the impact of surface density, short fiber length and fiber volume fraction on in-plane impregnation of the reinforcement. Permeability was found to be inversely proportional to the reinforcement of surface density. In contrast, an increase of the fiber length increases the in-plane permeability of the reinforcement. Finally, a mathematical modeling is proposed to predict the permeability behavior of these innovative natural fiber webs.


2017 ◽  
Vol 888 ◽  
pp. 413-417 ◽  
Author(s):  
Zulaikha Abdullah ◽  
Sufizar Ahmad ◽  
Musfirah Ramli

Metal foams are a cellular structure that has a solid matrix made of metal and has pores in their structure. Metal foams offer excellent combination of properties which led researchers interested in investigation in recent years. Closed-cell stainless steel (SS316L) foams for biomedical application were prepared by space holder method and the physical and morphological properties of SS316L foams were studied. Stainless steel (SS316L) powders as metallic material, polyethylene glycol (PEG) as a binder and Urea as a space holder material were mixed homogenously to avoid the particle wrecked. This mixture was compacted using uniaxial pressing machine and pressurized to 8 tons to formed the green body. By using tube furnace, the SS316L foams was two-stage sintered, the first phase at 600°C for 2 hours to decompose the urea, and the second phase at 1000°C, 1100°C, and 1200°C respectively to sinter the steel. The porosity and density test was carried out by applying Archimedean principles, while morphological observation was done by using Field Emission Scanning Electron (FESEM). The samples with 40wt.% SS316L composition and sintered at temperature of 1100°C, leads to porosities of about 44.539% and show the potential as the best metal foams.


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