scholarly journals Radar Z–RRelationship for Summer Monsoon Storms in Arizona

2005 ◽  
Vol 20 (4) ◽  
pp. 672-679 ◽  
Author(s):  
Efrat Morin ◽  
Robert A. Maddox ◽  
David C. Goodrich ◽  
Soroosh Sorooshian
Keyword(s):  
Hydrologic Model ◽  
Storm Events ◽  
Convective Storm ◽  
Convective Storms ◽  
Discharge Rates ◽  
Wide Range ◽  
Gauge Data ◽  
R Relation ◽  
Initial Results ◽  
Good Agreement

Abstract Radar-based estimates of rainfall rates and accumulations are one of the principal tools used by the National Weather Service (NWS) to identify areas of extreme precipitation that could lead to flooding. Radar-based rainfall estimates have been compared to gauge observations for 13 convective storm events over a densely instrumented, experimental watershed to derive an accurate reflectivity–rainfall rate (i.e., Z–R) relationship for these events. The resultant Z–R relationship, which is much different than the NWS operational Z–R, has been examined for a separate, independent event that occurred over a different location. For all events studied, the NWS operational Z–R significantly overestimates rainfall compared to gauge measurements. The gauge data from the experimental network, the NWS operational rain estimates, and the improved estimates resulting from this study have been input into a hydrologic model to “predict” watershed runoff for an intense event. Rainfall data from the gauges and from the derived Z–R relation produce predictions in relatively good agreement with observed streamflows. The NWS Z–R estimates lead to predicted peak discharge rates that are more than twice as large as the observed discharges. These results were consistent over a relatively wide range of subwatershed areas (4–148 km2). The experimentally derived Z–R relationship may provide more accurate radar estimates for convective storms over the southwest United States than does the operational convective Z–R used by the NWS. These initial results suggest that the generic NWS Z–R relation, used nationally for convective storms, might be substantially improved for regional application.

Biases in the Prediction of Convective Storm Characteristics with a Convection Allowing Ensemble

2021 ◽  
Author(s):  
Joseph A. Grim ◽  
James O. Pinto ◽  
Thomas Blitz ◽  
Kenneth Stone ◽  
David C. Dowell
Keyword(s):  
Warm Season ◽  
Storm Events ◽  
Convective Storm ◽  
Convective Storms ◽  
Convective Systems ◽  
Object Based ◽  
Mesoscale Convective ◽  
Macrophysical Properties ◽  
Storm Characteristics ◽  
Convective Mode

AbstractThe severity, duration, and spatial extent of thunderstorm impacts is related to convective storm mode. This study assesses the skill of the High Resolution Rapid Refresh Ensemble (HRRR-E) and its deterministic counterpart (HRRRv4) at predicting convective mode and storm macrophysical properties using 35 convective events observed during the 2020 warm season across the eastern U.S. Seven cases were selected from each of five subjectively-determined convective organization modes: tropical cyclones, mesoscale convective systems (MCSs), quasi-linear convective systems, clusters, and cellular convection. These storm events were assessed using an object-based approach to identify convective storms and determine their individual size. Averaged across all 35 cases, both the HRRR-E and HRRRv4 predicted storm areas were generally larger than observed, with this bias being a function of storm lifetime and convective mode. Both modeling systems also under-predicted the rapid increase in storm counts during the initiation period, particularly for the smaller-scale storm modes. Interestingly, performance of the HRRRv4 differed from that of the HRRR-E, with the HRRRv4 generally having a larger bias in total storm area than the HRRR-E due to HRRRv4 predicting up to 66% more storm objects than the HRRR-E. The HRRR-E accurately predicted the convective mode 65% of the time, with complete misses being very rare (<5% of the time overall). However, an evaluation of rank histograms across all 35 cases revealed that the HRRR-E tended to be under-dispersive when predicting storm size for all but the MCS mode.

Stereospecific, Palladium-catalyzed C(sp3)–H Alkenylation and Alkynylation of a Proline Derivative Enabled by 8-Aminoquinoline as a Directing Group

2020 ◽  
Author(s):  
Aleksandra Balliu ◽  
Aaltje Roelofje Femmigje Strijker ◽  
Michael Oschmann ◽  
Monireh Pourghasemi Lati ◽  
Oscar Verho
Keyword(s):  
Carboxylic Acid ◽  
Building Blocks ◽  
Wide Range ◽  
Palladium Catalyzed ◽  
Directing Group ◽  
High Yields ◽  
Vinyl Iodides ◽  
Initial Results

<p>In this preprint, we present our initial results concerning a stereospecific Pd-catalyzed protocol for the C3 alkenylation and alkynylation of a proline derivative carrying the well utilized 8‑aminoquinoline directing group. Efficient C–H alkenylation was achieved with a wide range of vinyl iodides bearing different aliphatic, aromatic and heteroaromatic substituents, to furnish the corresponding C3 alkenylated products in good to high yields. In addition, we were able show that this protocol can also be used to install an alkynyl group into the pyrrolidine scaffold, when a TIPS-protected alkynyl bromide was used as the reaction partner. Furthermore, two different methods for the removal of the 8-aminoquinoline auxiliary are reported, which can enable access to both <i>cis</i>- and <i>trans</i>-configured carboxylic acid building blocks from the C–H alkenylation products.</p>

scholarly journals Separate Universe calibration of the dependence of halo bias on cosmic web anisotropy

2020 ◽  
Vol 499 (3) ◽  
pp. 4418-4431 ◽  
Author(s):  
Sujatha Ramakrishnan ◽  
Aseem Paranjape
Keyword(s):  
Dark Matter ◽  
High Precision ◽  
Gaussian Distribution ◽  
Initial Perturbation ◽  
Analytical Framework ◽  
Web Environment ◽  
Wide Range ◽  
Galaxy Assembly ◽  
Very High ◽  
Good Agreement

ABSTRACT We use the Separate Universe technique to calibrate the dependence of linear and quadratic halo bias b1 and b2 on the local cosmic web environment of dark matter haloes. We do this by measuring the response of halo abundances at fixed mass and cosmic web tidal anisotropy α to an infinite wavelength initial perturbation. We augment our measurements with an analytical framework developed in earlier work that exploits the near-lognormal shape of the distribution of α and results in very high precision calibrations. We present convenient fitting functions for the dependence of b1 and b2 on α over a wide range of halo mass for redshifts 0 ≤ z ≤ 1. Our calibration of b2(α) is the first demonstration to date of the dependence of non-linear bias on the local web environment. Motivated by previous results that showed that α is the primary indicator of halo assembly bias for a number of halo properties beyond halo mass, we then extend our analytical framework to accommodate the dependence of b1 and b2 on any such secondary property that has, or can be monotonically transformed to have, a Gaussian distribution. We demonstrate this technique for the specific case of halo concentration, finding good agreement with previous results. Our calibrations will be useful for a variety of halo model analyses focusing on galaxy assembly bias, as well as analytical forecasts of the potential for using α as a segregating variable in multitracer analyses.

scholarly journals A NEW RAMPED PYROXIDATION/COMBUSTION FACILITY AT 14CHRONO, BELFAST: SETUP DESCRIPTION AND INITIAL RESULTS

Radiocarbon ◽  
2021 ◽  
pp. 1-14
Author(s):  
Evelyn M Keaveney ◽  
Gerard T Barrett ◽  
Kerry Allen ◽  
Paula J Reimer
Keyword(s):  
Bulk Material ◽  
Correction Method ◽  
Source Attribution ◽  
Radiocarbon Age ◽  
Targeted Analysis ◽  
Consensus Values ◽  
Background Material ◽  
Initial Results ◽  
Blank Correction ◽  
Good Agreement

ABSTRACT The Belfast Ramped Pyroxidation/Combustion (RPO/RC) facility was established at the 14CHRONO Centre (Queen’s University Belfast). The facility was created to provide targeted analysis of bulk material for refined chronological analysis and carbon source attribution for a range of sample types. Here we report initial RPO results, principally on background material, but also including secondary standards that are routinely analyzed at 14CHRONO. A description of our setup, methodology, and background (blank) correction method for the system are provided. The backgrounds (anthracite, spar calcite, Pargas marble) reported by the system are in excess of 35,000 14C years BP with a mean age of 39,345 14C years BP (1σ = 36,497–43,800 years BP, N=44) with F14C = 0.0075 ± 0.0032. Initial results for standards are also in good agreement with consensus values: TIRI-B pine radiocarbon age = 4482 ± 47 years BP (N=13, consensus = 4508 years BP); IAEA-C6 ANU Sucrose F14C= 1.5036 ± 0.0034 (N=10, consensus F14C = 1.503). These initial tests have allowed problematic issues to be identified and improvements made for future analyses.

Evaluation of Trinder's Glucose Oxidase Method for Measuring Glucose in Serum and Urine

1975 ◽  
Vol 21 (12) ◽  
pp. 1754-1760 ◽  
Author(s):  
John A Lott ◽  
Kathie Turner
Keyword(s):  
Glucose Oxidase ◽  
Oxidase Activity ◽  
Color Reaction ◽  
Critical Variable ◽  
Wide Range ◽  
Serum And Urine ◽  
Good Agreement

Abstract Trinder's method for glucose has nearly all the attributes of an ideal automated colorimetric glucose oxidase procedure. The chemicals used in the color reaction with peroxidase are readily available, the solutions are stable and can be prepared by the user, the method is highly specific and largely free of interferences, the sensitivity can be adjusted by the user to cover a wide range of glucose concentrations, and the reagents are not hazardous. We found very good agreement between results by this method and by the hexokinase and Beckman Glucose Analyzer methods. The method has been modified and adapted to the AutoAnalyzer I and SMA 6/60 (Technicon) with manifolds that give very little interaction between specimens. A study of the method by the simplex technique revealed that the glucose oxidase activity in the reagent is the most critical variable.

Estimation of the Thermodynamic Properties of Branched Hydrocarbons

2000 ◽  
Vol 122 (3) ◽  
pp. 147-152 ◽  
Author(s):  
Hui He ◽  
Mohamad Metghalchi ◽  
James C. Keck
Keyword(s):  
Thermodynamic Properties ◽  
Degrees Of Freedom ◽  
Statistical Thermodynamic ◽  
Motion Modes ◽  
Branched Alkanes ◽  
Branched Hydrocarbons ◽  
Wide Range ◽  
On Line ◽  
Kinetic Calculations ◽  
Good Agreement

A simple model has been developed to estimate the sensible thermodynamic properties such as Gibbs free energy, enthalpy, heat capacity, and entropy of hydrocarbons over a wide range of temperatures with special attention to the branched molecules. The model is based on statistical thermodynamic expressions incorporating translational, rotational and vibrational motions of the atoms. A method to determine the number of degrees of freedom for different motion modes (bending and torsion) has been established. Branched rotational groups, such as CH3 and OH, have been considered. A modification of the characteristic temperatures for different motion mode has been made which improves the agreement with the exact values for simple cases. The properties of branched alkanes up to 2,3,4,-trimthylpentane have been calculated and the results are in good agreement with the experimental data. A relatively small number of parameters are needed in this model to estimate the sensible thermodynamic properties of a wide range of species. The model may also be used to estimate the properties of molecules and their isomers, which have not been measured, and is simple enough to be easily programmed as a subroutine for on-line kinetic calculations. [S0195-0738(00)00902-X]

scholarly journals Rate Equation Modelling of Nonlinear Dynamics in Directly Modulated Multiple Quantum Well Laser Diodes

VLSI Design ◽  
1998 ◽  
Vol 8 (1-4) ◽  
pp. 355-360 ◽  
Author(s):  
Stephen Bennett ◽  
Christopher M. Snowden ◽  
Stavros Iezekiel
Keyword(s):  
Nonlinear Dynamics ◽  
Quantum Well ◽  
Multiple Quantum Well ◽  
Period Doubling ◽  
Rate Equations ◽  
Multiple Quantum ◽  
Quantum Well Laser ◽  
Wide Range ◽  
Multiple Quantum Well Laser ◽  
Good Agreement

A theoretical (using rate equations) and experimental study of the nonlinear dynamics of a distributed feedback multiple quantum well laser diode is presented. The analysis is performed under direct modulation. Period doubling and period tripling are identified in both the measurements and simulations. Period doubling is found over a wide range of modulation frequencies in the laser. Computational results using rate equations show good agreement with the experimental results.

scholarly journals DFT calculation and assignment of vibrational spectra of aryl and alkyl chlorophosphates

2014 ◽  
Vol 12 (2) ◽  
pp. 153-163
Author(s):  
Viktor Anishchenko ◽  
Vladimir Rybachenko ◽  
Konstantin Chotiy ◽  
Andrey Redko
Keyword(s):  
Vibrational Spectra ◽  
Basis Sets ◽  
Heavy Atoms ◽  
Wide Range ◽  
Complete Assignment ◽  
Key Factor ◽  
Polarization Functions ◽  
Experimental Values ◽  
Semi Empirical ◽  
Good Agreement

AbstractDFT calculations of vibrational spectra of chlorophosphates using wide range of basis sets and hybrid functionals were performed. Good agreement between calculated and experimental vibrational spectra was reached by the combination of non-empirical functional PBE0 with both middle and large basis sets. The frequencies of the stretching vibrations of the phosphate group calculated using semi-empirical functional B3LYP for all basis sets deviate significantly from the experimental values. The number of polarization functions on heavy atoms was shown to be a key factor for the calculation of vibrational frequencies of organophosphates. The importance of consideration of all the stable rotamers for a complete assignment of fundamental modes was shown.

Predictions of the Effect of Roughness on Heat Transfer From Turbine Airfoils

1998 ◽  
Author(s):  
Anil K. Tolpadi ◽  
Michael E. Crawford
Keyword(s):  
Heat Transfer ◽  
Side Surface ◽  
Suction Side ◽  
Reynolds Numbers ◽  
Surface Finishing ◽  
Transfer Coefficients ◽  
Average Roughness ◽  
Wide Range ◽  
Turbine Airfoils ◽  
Good Agreement

The heat transfer and aerodynamic performance of turbine airfoils are greatly influenced by the gas side surface finish. In order to operate at higher efficiencies and to have reduced cooling requirements, airfoil designs require better surface finishing processes to create smoother surfaces. In this paper, three different cast airfoils were analyzed: the first airfoil was grit blasted and codep coated, the second airfoil was tumbled and aluminide coated, and the third airfoil was polished further. Each of these airfoils had different levels of roughness. The TEXSTAN boundary layer code was used to make predictions of the heat transfer along both the pressure and suction sides of all three airfoils. These predictions have been compared to corresponding heat transfer data reported earlier by Abuaf et al. (1997). The data were obtained over a wide range of Reynolds numbers simulating typical aircraft engine conditions. A three-parameter full-cone based roughness model was implemented in TEXSTAN and used for the predictions. The three parameters were the centerline average roughness, the cone height and the cone-to-cone pitch. The heat transfer coefficient predictions indicated good agreement with the data over most Reynolds numbers and for all airfoils-both pressure and suction sides. The transition location on the pressure side was well predicted for all airfoils; on the suction side, transition was well predicted at the higher Reynolds numbers but was computed to be somewhat early at the lower Reynolds numbers. Also, at lower Reynolds numbers, the heat transfer coefficients were not in very good agreement with the data on the suction side.

scholarly journals Impacts of Polarimetric Radar Observations on Hydrologic Simulation

2010 ◽  
Vol 11 (3) ◽  
pp. 781-796 ◽  
Author(s):  
Jonathan J. Gourley ◽  
Scott E. Giangrande ◽  
Yang Hong ◽  
Zachary L. Flamig ◽  
Terry Schuur ◽  
...  
Keyword(s):  
Pearson Correlation ◽  
Extreme Rainfall ◽  
Rain Gauge ◽  
Hydrologic Model ◽  
Laboratory Research ◽  
Model Parameters ◽  
Polarimetric Radar ◽  
Storm Events ◽  
Hydrologic Simulation ◽  
Radar Observations

Abstract Rainfall estimated from the polarimetric prototype of the Weather Surveillance Radar-1988 Doppler [WSR-88D (KOUN)] was evaluated using a dense Micronet rain gauge network for nine events on the Ft. Cobb research watershed in Oklahoma. The operation of KOUN and its upgrade to dual polarization was completed by the National Severe Storms Laboratory. Storm events included an extreme rainfall case from Tropical Storm Erin that had a 100-yr return interval. Comparisons with collocated Micronet rain gauge measurements indicated all six rainfall algorithms that used polarimetric observations had lower root-mean-squared errors and higher Pearson correlation coefficients than the conventional algorithm that used reflectivity factor alone when considering all events combined. The reflectivity based relation R(Z) was the least biased with an event-combined normalized bias of −9%. The bias for R(Z), however, was found to vary significantly from case to case and as a function of rainfall intensity. This variability was attributed to different drop size distributions (DSDs) and the presence of hail. The synthetic polarimetric algorithm R(syn) had a large normalized bias of −31%, but this bias was found to be stationary. To evaluate whether polarimetric radar observations improve discharge simulation, recent advances in Markov Chain Monte Carlo simulation using the Hydrology Laboratory Research Distributed Hydrologic Model (HL-RDHM) were used. This Bayesian approach infers the posterior probability density function of model parameters and output predictions, which allows us to quantify HL-RDHM uncertainty. Hydrologic simulations were compared to observed streamflow and also to simulations forced by rain gauge inputs. The hydrologic evaluation indicated that all polarimetric rainfall estimators outperformed the conventional R(Z) algorithm, but only after their long-term biases were identified and corrected.

Sign in / Sign up

Export Citation Format

Share Document