Synthesis of the in situ aluminum matrix composite through pyrolysis of high temperature vulcanization silicone

2017 ◽  
Vol 52 (1) ◽  
pp. 123-134 ◽  
Author(s):  
Mohammad Senemar ◽  
Behzad Niroumand ◽  
Ali Maleki ◽  
Pradeep K Rohatgi

In this study, in situ aluminum matrix composites were synthesized through pyrolysis of high temperature vulcanization silicone in commercially pure aluminum melt. For this purpose, 1 to 4 wt% of high temperature vulcanization silicone was added to a vortex of molten aluminum at 750℃ and the resulting slurries were cast in steel dies. Microstructure, hardness, and tensile properties of the as-cast samples were examined at ambient and high temperatures. The results revealed the in situ formation and distribution of reinforcement particles in the matrix. Energy-dispersive X-ray analysis indicated that the formed reinforcement particles consisted of O and Si elements. This confirms the in situ reinforcement formation by pyrolysis of high temperature vulcanization silicone in the melt. The size of the in situ formed particles was mostly in the range of 200–2000 nm. It was shown that the composites synthesized by the addition of 4 wt% high temperature vulcanization had the highest mechanical properties both at ambient and high temperatures. Room temperature hardness, tensile strength, and yield strength of this sample were increased by about 50%, 23%, and 19% compared to the monolithic sample, respectively.

2014 ◽  
Vol 21 (1) ◽  
pp. 29-38
Author(s):  
Oscar Marcelo Suárez ◽  
Natalia Cortes-Urrego ◽  
Sujeily Soto-Medina ◽  
Deborah Marty-Flores

AbstractAn aluminum-copper matrix composite reinforced with aluminum diboride particles was studied at high temperature via thermomechanometry experiments. The matrix contained 2 wt% Cu, whereas the amount of boron forming AlB2 ranged from 0 to 4 wt%, i.e., 0 to 8.31 vol% of diboride particles. In the first segment of the research, we demonstrated that larger amounts of AlB2 particles raised the composite hardness even at 300°C. To assess the material creep behavior, another set of specimens were tested under 1 N compression at 400°C and 500°C for 12 h. Higher levels of AlB2 allowed the composites to withstand compression creep deformations at those temperatures. By using existing creep models developed for metal matrix composites we were able to determine that viscous slip deformation was the dominant deformation mechanism for the temperatures and stress levels used in our experiments. Additionally, the computed creep activation energy for these aluminum matrix composites were found comparable to the energies reported for other similar materials, for instance, Al/SiCp composites.


2016 ◽  
Vol 256 ◽  
pp. 81-87 ◽  
Author(s):  
Ju Fu Jiang ◽  
Ying Wang ◽  
Shou Jing Luo

Semisolid slurries of 7075 aluminum matrix composite reinforced with nano-sized SiC particles were fabricated by ultrasonic assisted semisolid stirring (UASS) method. Rheoforming and thixoforming of typical cylindrical parts were investigated. The results show that high-quality semisolid slurries with spheroidal solid grain of 38 µm were fabricated by UASS. The nano-sized SiC particles were dispersed uniformly due to transient cavitation and acoustic streaming of ultrasonic wave and high and controllable viscosity of semisolid slurry. Typical cylindrical composite parts with good surface quality and complete filling were rheoformed and thixoformed successfully. Ultimate tensile strength (UTS) of the rheoformed and thixoformed composite parts are enhanced due to addition of nano-sized SiC particles. However, elongation decreased as compared to those of the matrix parts. Maximum UTS of 550 MPa was achieved in the thixoformed composite part with T6 treatment. Increase of dislocation density around the reinforcement particles leads to improvement of the strength and wear resistance of the composite.


2017 ◽  
Vol 898 ◽  
pp. 917-932 ◽  
Author(s):  
Yong Wang ◽  
Ji Xue Zhou ◽  
Kai Ming Cheng ◽  
Jian Hua Wu ◽  
Yuan Sheng Yang

Graphene with unique two-dimensional structure and excellent mechanical properties, is one of the most ideal reinforcements. With the increasing progress of aluminum matrix composites, graphene reinforced aluminum matrix composites have attracted great interests. This paper mainly reviews the latest progress on preparation of graphene reinforced aluminum matrix composites, and especially discusses the effective dispersion technique of graphene. Meanwhile, the microstructure and interfacial structure of graphene reinforced aluminum matrix composites are also emphasized and discussed. The results showed that graphene can significantly improve the mechanical properties of composites and refine the matrix grain. By controlling preparation parameters, the graphene agglomeration can be effectively solved, and the adverse interface reaction between graphene and substrate can be avoided. Finally, the current challenges and solutions of graphene reinforced aluminum matrix composites were presented.


Alloy Digest ◽  
1997 ◽  
Vol 46 (12) ◽  

Abstract This pure aluminum matrix composite contains 60 volume% alumina. The aluminum ceramic fiber is Nextel 610. The fiber effects the longitudinal direction, resulting in a high longitudinal specific modulus and a specific strength with good off-axis properties. This datasheet provides information on composition, physical properties, elasticity, tensile properties, and compressive and shear strength. It also includes information on corrosion resistance as well as casting. Filing Code: AL-344. Producer or source: 3M.


2020 ◽  
Vol 988 ◽  
pp. 17-22
Author(s):  
Suryana ◽  
Indah Uswatun Hasanah ◽  
Muhammad Fikri Fadhillah ◽  
Yordan Valentino Putra

The effects of graphite and magnesium (Mg) addition on mechanical properties and microstructure of aluminum matrix composites (AMCs) have been investigated in this work. Aluminum alloy (ADC-12) was combined with graphite and Mg produced by stir casting. The effect of addition of graphite into the matrix has been studied with variation 2, 4 and 6 wt-% for each composite. The addition of Mg as wetting agent was introduced wit 0.4, 0.6 and 0.8 wt-% to promote wettability between ADC-12 and graphite. All composites were characterized both microstructures analysis and mechanical properties include tensile strength and hardness. The higher reinforcement content, the higher porosity formed, due to the tendency of de-wetting as well as particles agglomeration. One of the main intermetallic phase present evenly in aluminum matrix is Mg2Si. The addition of magnesium in the material that will form Mg2Si primary phases which have a high hardness value of these composites.


2012 ◽  
Vol 476-478 ◽  
pp. 122-125 ◽  
Author(s):  
Zhu Rui ◽  
Yu Tao Zhao ◽  
Song Li Zhang ◽  
Zhi Hong Jia

Abstract:Aluminum matrx composites reinforced by in situ ZrB2 particles are fabricated from A356-AlB-K2ZrF6 system via in-situ melt reaction method, and the morphologies, sizes and distributions of the in situ particles as well as the microstructures, mechanical mechanisms of the composites are investigated by XRD,SEM,TEM and tensile tests. The results indicate that the morphologies of the in situ particles are mainly with ball-shape, the sizes are in nanometer scale and the distributions in the matrix are uniform. The interfaces between the in situ particles and the aluminum matrix are net and no interfacial outgrowth is observed.


2014 ◽  
Vol 905 ◽  
pp. 119-122
Author(s):  
He Guo Zhu ◽  
Hao Sun ◽  
Bo Hua ◽  
Guan Hong Guo ◽  
Jie Wen Huang ◽  
...  

In situ aluminum matrix composites were fabricated through exothermic dispersive (XD) reaction from a powder mixture of Al and Cr2O3. The reaction mechanism was investigated by using X-ray diffraction (XRD), scanning electron microscopy (SEM), X-ray energy dispersive spectroscopy (EDS) and differential scanning calorimetry (DSC) analysis. When the temperature increases to around 1050K, Al can react with Cr2O3to form the reinforcments Al2O3particles and CrAl4blocks. With the increase of heating rate, DSC analysis shows that the reaction peak shifts to a higher temperature and the corresponding ignition temperature also increases. Based on DSC curves with different heating rates, the activation energy can be calculated and its value is 191.8 kJ/mol.


2015 ◽  
Vol 787 ◽  
pp. 583-587 ◽  
Author(s):  
V. Mohanavel ◽  
K. Rajan ◽  
K.R. Senthil Kumar

In the present study, an aluminum alloy AA6351 was reinforced with different percentages (1, 3 and 5 wt %) of TiB2 particles and they were successfully fabricated by in situ reaction of halide salts, potassium hexafluoro-titanate and potassium tetrafluoro-borate, with aluminium melt. Tensile strength, yield strength and hardness of the composite were investigated. In situ reaction between the inorganic salts K2TiF6 and KBF4 to molten aluminum leads to the formation of TiB2 particles. The prepared aluminum matrix composites were characterized using X-ray diffraction and scanning electron microscope. Scanning electron micrographs revealed a uniform dispersal of TiB2 particles in the aluminum matrix. The results obtained indicate that the hardness and tensile strength were increased with an increase in weight percentages of TiB2 contents.


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