scholarly journals Adsorption Equilibria of Single-Component and Multi-Component Metal Ions on to Scrap Rubber

1998 ◽  
Vol 16 (6) ◽  
pp. 493-502 ◽  
Author(s):  
Mahmoud A. Zarraa
Keyword(s):  
Aqueous Solutions ◽  
Metal Ions ◽  
Linear Trend ◽  
Correlation Coefficients ◽  
Single Component ◽  
Experimental Results ◽  
The Other ◽  
Adsorption Equilibria ◽  
Other Hand ◽  
Competitive Uptake

The ability of scrap rubber to adsorb the three metal ions, copper, cadmium and zinc, in single-component and multi-component mixtures in aqueous solutions has been studied. A comparison has been made between the single-component saturation uptake and the multi-component uptakes. The experimental results were fitted to the Langmuir, Freundlich and Redlich–Peterson isotherms. The correlation coefficients obtained from plotting these isotherms gave a measure of the conformity of the data to a linear trend and corresponded to a perfect fit. The isotherms indicated a competitive uptake, with copper being preferentially adsorbed by scrap rubber in multi-component solutions. The capacity of scrap rubber for the single-component metals was in the order: Cd > Cu > Zn. On the other hand, the order of preference of scrap rubber for metals in multi-component mixtures was: Cu > Cd > Zn.

Natural Vulcanization Accelerators in Hevea Latex

1948 ◽  
Vol 21 (4) ◽  
pp. 853-859
Author(s):  
R. F. A. Altman
Keyword(s):  
Amino Acids ◽  
Experimental Results ◽  
The Other ◽  
Active Nitrogen ◽  
Nitrogen Bases ◽  
Other Hand ◽  
Decomposition Processes ◽  
Volatile Products ◽  
Nitrogenous Substances ◽  
The One

Abstract As numerous investigators have shown, some of the nonrubber components of Hevea latex have a decided accelerating action on the process of vulcanization. A survey of the literature on this subject points to the validity of certain general facts. 1. Among the nonrubber components of latex which have been investigated, certain nitrogenous bases appear to be most important for accelerating the rate of vulcanization. 2. These nitrogen bases apparently occur partly naturally in fresh latex, and partly as the result of putrefaction, heating, and other decomposition processes. 3. The nitrogen bases naturally present in fresh latex at later stages have been identified by Altman to be trigonelline, stachhydrine, betonicine, choline, methylamine, trimethylamine, and ammonia. These bases are markedly active in vulcanization, as will be seen in the section on experimental results. 4. The nitrogenous substances formed by the decomposition processes have only partly been identified, on the one hand as tetra- and pentamethylene diamine and some amino acids, on the other hand as alkaloids, proline, diamino acids, etc. 5. It has been generally accepted that these nitrogenous substances are derived from the proteins of the latex. 6. Decomposition appears to be connected with the formation of a considerable amount of acids. 7. The production of volatile nitrogen bases as a rule accompanies the decomposition processes. These volatile products have not been identified. 8. The active nitrogen bases, either already formed or derived from complex nitrogenous substances, seem to be soluble in water but only slightly soluble in acetone.

scholarly journals Comparison of the Fungicidal Properties of Different Humectants in a Tobacco Blend / Vergleich der fungistatischen Wirkung verschiedener Feuchthaltemittel bei einer ungesoßten Tabakmischung

1966 ◽  
Vol 3 (7) ◽  
Author(s):  
H. van Nooy
Keyword(s):  
Experimental Results ◽  
The Other ◽  
Other Hand ◽  
Tobacco Treatment

AbstractThe experimental results indicated in the present paper reveal that among all humectants admitted 1,3-butyleneglycol alone has marked fungicidal properties satisfying the requirements of practical tobacco treatment, and that, on the other hand, diethyleneglycol and glycerine practically do not have such qualities

scholarly journals Elastic Properties of Magnetorheological Elastomers in a Heterogeneous Uniaxial Magnetic Field

2018 ◽  
Vol 19 (10) ◽  
pp. 3045 ◽  
Author(s):  
Takehito Kikuchi ◽  
Yusuke Kobayashi ◽  
Mika Kawai ◽  
Tetsu Mitsumata
Keyword(s):  
Magnetic Field ◽  
Elastic Properties ◽  
Uniform Magnetic Field ◽  
Large Strain ◽  
Small Strain ◽  
Experimental Results ◽  
The Other ◽  
Magnetorheological Elastomers ◽  
Other Hand ◽  
Strain Model

Magnetorheological elastomers (MREs) are stimulus-responsive soft materials that consist of polymeric matrices and magnetic particles. In this study, large-strain response of MREs with 5 vol % of carbonyl iron (CI) particles is experimentally characterized for two different conditions: (1) shear deformation in a uniform magnetic field; and (2), compression in a heterogeneous uniaxial magnetic field. For condition (1), dynamic viscoelastic measurements were performed using a rheometer with a rotor disc and an electric magnet that generated a uniform magnetic field on disc-like material samples. For condition (2), on the other hand, three permanent magnets with different surface flux densities were used to generate a heterogeneous uniaxial magnetic field under cylindrical material samples. The experimental results were mathematically modeled, and the relationship between them was investigated. We also used finite-element method (FEM) software to estimate the uniaxial distributions of the magnetic field in the analyzed MREs for condition (2), and developed mathematical models to describe these phenomena. By using these practicable techniques, we established a simple macroscale model of the elastic properties of MREs under simple compression. We estimated the elastic properties of MREs in the small-strain regime (neo–Hookean model) and in the large-strain regime (Mooney–Rivlin model). The small-strain model explains the experimental results for strains under 5%. On the other hand, the large-strain model explains the experimental results for strains above 10%.

Effect of Manganese Addition on Strength and Fracture Toughness in Mg-6Al-1Zn Alloy

2006 ◽  
Vol 306-308 ◽  
pp. 857-862 ◽  
Author(s):  
Taisuke Sasaki ◽  
Tokuteru Uesugi ◽  
Yorinobu Takigawa ◽  
Kenji Higashi
Keyword(s):  
Fracture Toughness ◽  
Magnesium Alloy ◽  
Yield Strength ◽  
Ductile Fracture ◽  
Manganese Content ◽  
Experimental Results ◽  
The Other ◽  
Excessive Amount ◽  
Void Coalescence ◽  
Other Hand

The effect of manganese on strength and fracture toughness was investigated using five kinds of Mg-6Al-1Zn alloys. From the experimental results, the yield strength increased with increasing in manganese content until manganese content reached 0.14 wt. %. On the other hand, further increase in yield strength was not observed in case larger than 0.14 % of manganese was added. In addition, fracture toughness decreases with increasing manganese content. Fracture of magnesium alloy was ductile fracture by void coalescence. Adding excessive amount of manganese caused the increase in the presence of inclusions. This kind of particle easily became the nucleus of microvoid. As a conclusion, manganese should be added so that coarse manganese-bearing particle is not formed. Thus, 0.14 wt. % of manganese should be added to Mg-6Al-1Zn alloy in order to develop the alloy with well-balanced relationship between strength and fracture toughness.

Effects of Mandarin Cultivar on Quality of Mandarin Juice

2008 ◽  
Vol 14 (4) ◽  
pp. 307-313 ◽  
Author(s):  
F. Beltrán ◽  
A.J. Perez-López ◽  
J.M. López-Nicolás ◽  
A.A. Carbonell-Barrachina
Keyword(s):  
Vitamin C ◽  
Volatile Compounds ◽  
Experimental Results ◽  
The Other ◽  
Total Volatile ◽  
Color Coordinates ◽  
Juice Processing ◽  
Other Hand ◽  
Cielab Color

Eight mandarin cultivars have been analyzed for their content of vitamin C, minerals (Ca, Mg, K, Na, Fe, Cu, Mn, and Zn), CIELab color coordinates (L*, a*, b*, C*, and h ab), total volatile compounds content and sensory aroma intensity of juice. Experimental results proved that no important enough differences were found in the minerals contents to decide which mandarin cultivar was of higher quality. Clemenules provided the darkest juice with the highest vitamin C content and with the most intense mandarin aroma. On the other hand, Nova and Hernandina mandarin could be considered as the worst cultivars for juice production. Finally if Clemenules mandarins were not available for juice processing, Orogrande, Clemenpons, Ellendale, and Marisol could also be good options.

Dermatoglyphics in Twins

1973 ◽  
Vol 22 (1) ◽  
pp. 91-98 ◽  
Author(s):  
Heloisa F. Peña ◽  
F.M. Salzano ◽  
Sidia M. Callegari
Keyword(s):  
Correlation Coefficients ◽  
The Other ◽  
Ridge Count ◽  
Genetic Determination ◽  
Qualitative Traits ◽  
Quantitative Measurements ◽  
Other Hand ◽  
Adult Twins

SummaryThe degree of genetic determination of 4 digital and 16 palmar characteristics was investigated in an unselected series of 49 MZ and 51 DZ adult twins. Low indications of heritability were obtained for the qualitative traits, but 6 of the 8 h2 estimates calculated for the quantitative measurements gave values above 0.70. In general, the results reported here are in agreement with those presented by other authors; however, the correlation coefficients observed for the A′d ridge count were lower than those of two other series. All palmar ridge counts seemed to be intercorrelated in a given individual; other expected relationships, however, were not observed. The fingerprints of MZ and DZ twins on the other hand, showed an unexplained difference.

Polypyrrole Actuator Operating Characteristicsin Electrolyte Solution Mixed with Methanol

2013 ◽  
Vol 300-301 ◽  
pp. 1352-1355 ◽  
Author(s):  
Futo Tsumuji ◽  
Daiki Hoshino ◽  
Shou Ogihara ◽  
Zong Fan Duan ◽  
Yutaro Suzuki ◽  
...  
Keyword(s):  
Aqueous Solutions ◽  
Electrolyte Solution ◽  
Marked Improvement ◽  
Electrolyte Solutions ◽  
Rapid Decrease ◽  
The Other ◽  
Other Hand ◽  
Deformation Behaviors

In this work, a PPy actuator was fabricated by galvanostatic electropolymerization. The electrochemical deformation behaviors of the PPy actuator were investigated in aqueous solutions of an electrolyte, lithium bis(trifluoromethanesulphonyl)imide (LiTFSI), containing different concentrations of methanol. Marked improvement of the actuating strain of approximately 9% was achieved when the actuator was driven by a potential between –1 and 1 V in the LiTFSI electrolyte containing 40 to 50% of methanol under a load stress of 0. 3 MPa. On the other hand, the actuator functioned in the electrolyte solutions containing more than 60% of methanol showed rapid decrease of the actuating strain and the electrochemical creep after repeated actuations. Possible mechanisms for these behaviors were discussed.

Interactions between cations and sugars. III. Free energies, enthalpies, and entropies of association of Ca2+, Sr2+, Ba2+, La3+, Gd3+ with D-ribose in water at 25 °C

1987 ◽  
Vol 65 (11) ◽  
pp. 2656-2660 ◽  
Author(s):  
Alfredo Maestre Alvarez ◽  
Nicole Morel-Desrosiers ◽  
Jean-Pierre Morel
Keyword(s):  
Thermodynamic Properties ◽  
Aqueous Solutions ◽  
Equilibrium Constant ◽  
The Other ◽  
Free Energies ◽  
Mean Values ◽  
Enthalpies Of Transfer ◽  
Other Hand ◽  
Solutions Of Electrolytes

The standard enthalpies of transfer of ribose and arabinose from water to aqueous solutions of electrolytes (CaCl2, SrCl2, BaCl2, LaCl3, and GdCl3) have been measured at 25 °C. A method is described to calculate from these data the equilibrium constant and the enthalpy for the association between the cations and the complexing isomers of ribose. Mean values relative to these isomers are given: the constants vary from 2.0 to 4.3 and the enthalpies from −5.9 to −17.9 kJ mol−1 for the different cations studied. The thermodynamic properties of association are not related to the size nor to the charge of the complexed cation in a simple way. On the other hand, the enthalpies of reaction are linearly correlated to the entropies of reaction.

scholarly journals Modeling of Rate-Independent and Symmetric Hysteresis Based on Madelung’s Rules

Sensors ◽  
2019 ◽  
Vol 19 (2) ◽  
pp. 352 ◽  
Author(s):  
Kairui Cao ◽  
Rui Li
Keyword(s):  
Phenomenological Models ◽  
Turning Points ◽  
Modeling Method ◽  
Experimental Results ◽  
The Other ◽  
Other Hand ◽  
The Relationship ◽  
With Memory

Hysteresis is a kind of nonlinearity with memory, which is usually unwanted in practice. Many phenomenological models have been proposed to describe the observed hysteresis. For instance, the Prandtl-Ishlinskii (PI) model, which consists of several backlash operators, is the most widely used. On the other hand, the well-known Madelung’s rules are always used to validate hysteresis models. It is worth pointing out that the PI model obeys Madelung’s rules. In this paper, instead of considering these rules as criteria, we propose a modeling method for symmetric hysteresis by directly constructing the trajectory based on Madelung’s rules. In the proposed method, turning points are recorded and wiped out according to the input value. After the implementation of the recording and wiping-out mechanisms, the curve which the current trajectory moves along can be determined and then the trajectory can be described. Furthermore, the relationship between the proposed method and the PI model is also investigated. The effectiveness of the presented method is validated by simulation and experimental results.

Angiopoietin-1 and Osteopontin Expression by CD138+ Myeloma Cells Rather Than VEGF and CD45 Correlates with Bone Marrow Angiogenesis in Multiple Myeloma Patients at the Diagnosis.

Blood ◽  
2005 ◽  
Vol 106 (11) ◽  
pp. 2501-2501
Author(s):  
Nicola Giuliani ◽  
Simona Colla ◽  
Francesca Morandi ◽  
Sabrina Bonomini ◽  
Mirca Lazzaretti ◽  
...  
Keyword(s):  
Multiple Myeloma ◽  
Bone Marrow ◽  
Linear Trend ◽  
The Other ◽  
Vegf Mrna ◽  
Myeloma Cells ◽  
Other Hand ◽  
Significant Difference ◽  
Angiopoietin 1

Abstract Bone marrow (BM) angiogenesis is increased in Multiple Myeloma (MM) patients and correlates with disease progression and patient survival. Myeloma cells secrete the main endothelial growth factor VEGF. In mouse models VEGF secretion as well as the angiogenic properties of MM cells correlate with the lack of CD45 expression by MM cells. However, recent data indicate that VEGF plasma cell expression is similar between MGUS and MM patients suggesting that other molecules could be involved. In line with this hypothesis we have recently demonstrated that myeloma cells may also produce factors with angiogenic properties as angiopoietin-1 (ANG-1) and osteopontin (OPN) that are involved in myeloma induced angiogenesis in vitro. In order to identify which factors correlate with BM angiogenesis in MM patients, we have investigated in a cohort of 121 newly diagnosed MM patients (stage I–III) the expression of the angiogenic molecules VEGF, ANG-1 and OPN and their correlation with bone marrow (BM) angiogenesis and CD45 expression by MM cells. We found that 90% of CD138+ MM cells tested were positive for VEGF mRNA. On the other hand we found that 50% and 40 % of MM patients were positive for ANG-1 and OPN mRNA respectively. Using the previously published cut off for CD45 expression we found that 61 out of 121 MM patients were positive for CD45 and 60 out of 121 were negative for CD45 expression. Any correlation was not observed between VEGF expression and BM angiogenesis in MM patients (p=0.5), whereas the number of microvessels X field was higher in Ang-1 positive patients in comparison with Ang-1 negative ones (mean±SE: 6.23±0.2 vs. 2.94±0.1, median: 6.21 vs. 2.79; p=0.001,) and the microvascular density (MVD) was significantly increased (32.98±1.7 vs. 14.55±1.3, median: 34.69 vs. 13.04; p<0.01; capillaries: 26.73±1.3 vs. 10.42±0.8, median: 24.06 vs. 9.04; p<0.01, small venules: 9.56 ±0.5 vs. 4.14±0.5, median: 10.60 vs. 3.65; p<0.01). Furthermore a significantly positive correlation between Ang-1 expression and MVD was found (Pearson Chi-square: p=0.036, Cochran’s Linear Trend: p=0.01). A significantly higher MVD was also observed in the group of patients positive for OPN, (mean±SE: 29.1±0.7 vs. 17.55±0.37; p<0.01) and similarly, the number of microvessels per field was higher in OPN positive patients in comparison with OPN negative ones (mean±SE: 6.7±0.15 vs. 4.28±0.04; p=0.05). On the other hand, any significant difference was not observed between CD45 positive and CD45 negative patients for the expression of VEGF (p=0.4), ANG-1 (p=0.3) and OPN (p=0.09). Consistently we did not find any significant difference in both MVD and number of vessels X field between CD45 positive patients as compared with CD45 negative ones (p=0.5 and p=0.4, respectively). Finally, a multivariate analysis confirmed that VEGF and CD45 did not correlate with the BM angiogenesis showing that ANG-1 expression by MM cells was more tightly correlated with MVD and the number of vessels X field as compared to OPN. Our data indicate that ANG-1 and in part OPN rather than VEGF and CD45 expression by MM cells are the critical determinants correlated with the increase of BM angiogenesis that occurs in MM patients at the diagnosis.

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