Geochemistry of diorites and associated plutonic rocks of SE Jersey, Channel Islands

1987 ◽  
Vol 51 (360) ◽  
pp. 217-229 ◽  
Author(s):  
C. H. Key

AbstractThe plutonic complex in SE Jersey consists of a late Precambrian gabbro-diorite mass which has been intruded by several granites. The status of the diorites which, like the gabbros, often possess a layered structure, is not clear. New geochemical data, including rare earth and trace element analyses, suggest that acid-basic magma mixing was not responsible for the variety of intermediate rocks. Amphibole-controlled fractional crystallization of hydrous basic magma is also unlikely in view of the REE and HFS (high field strength) element distribution. The model which best fits all the available field, petrographic and geochemical evidence is one in which the chemical variation was initially produced by fractional crystallization of anhydrous basic magma and subsequently overprinted by granitic metasomatism. This superimposed calc-alkaline characteristics on the complex and produced hybrid diorites which, because they were above their solidus temperature, recrystallized with textures indicative of a magmatic origin.

2017 ◽  
Vol 50 (4) ◽  
pp. 2057
Author(s):  
C. Uyanık ◽  
K. Koçak

Late Miocene to Pliocene volcanism produced lava domes with mafic microgranular enclaves (MMEs), nuée ardentes and pyroclastic fall and flow (ignimbrites) deposits in the WSW and NW of Konya city. All samples are predominantly high K-calc alkaline in composition but calc-alkaline and shoshonitic composition also exist. The felsic volcanics are mainly dacite, andesite, basaltic trachyandesite and rare trachyandesite in compositon. But, the MMEs have basaltic andesite and andesite compositon. SiO2 increases with decreasing TiO2, FeOt, MgO and CaO, suggesting fractional crystallization of mafic minerals. All samples have fractionated chondritenormalised REE pattern (La/YbN: 6.7-18.1), and negative Eu anomaly (Eu/Eu*: 0.67- 0.89), indicating plagioclase fractionation. In primitive mantle-normalized spider diagram, the samples show an enrichment in large ion litophile elements (LILE) such as Cs and Ba, and depletion in high field strength elements (HFSE), e.g. Dy and Y. They show negative Nb, Ta and Ti anomalies, indicating a subduction signature for their genesis. Based on geochemical data, the volcanics are suggested to have been formed by Assimilation-Fractional Crystallization (AFC) and/or magma mixing process. Various geotectonic diagrams imply volcanic arc to post collisional setting for the samples.


2020 ◽  
Vol 57 (4) ◽  
pp. 506-523
Author(s):  
Jin-hua Qin ◽  
Cui Liu ◽  
Jin-fu Deng

We present systematic U–Pb age data collected by laser ablation multi-collector inductively coupled plasma mass spectrometry, precise geochemical data, and Nd isotope data for igneous rocks from the southeastern Lesser Xing’an Range (SE LXR). The results indicate that the formation ages as follows: Maojiatun alkaline granite, 207.2 ± 0.84 Ma and 204.6 ± 0.93 Ma; Diorite porphyrite, 164.5 ± 0.97 Ma; and Tieli syenogranite, 186.7 ± 1.50 Ma. The alkaline granite has high silicon, potassium, alkali, and FeOT contents; it is enriched in high field strength elements, Zr, Hf, Th, Rb, and U; is depleted in Ba, Sr, Nb, Ta, P, Ti, etc.; and has high ratios of 10000Ga/Al. It shows an A2-type granite affinity. The Tieli alkali-feldspar granite has high total alkali contents and is enriched in high field strength elements and rare earth elements and depleted in Sr, Ba, Ti, and P, and shows varying degrees of alkalinity. Rocks from SE LXR display similar εNd (t) values with corresponding to Nd model ages of 1095 to 813 Ma. The igneous rocks from the SE LXR are proposed to be derived from melting of the Neoproterozoic lower crust and potential magma mixing with ancient crystalline basement. The formation of the Maojiatun alkaline granite occurred in response to a postorogenic event following the closure of the Paleo-Asian Ocean. However, the SE LXR exhibited an extensional back-arc tectonic setting in the Early Jurassic. The Middle Jurassic diorite porphyrite could be related to the temporary stagnation of the westward subduction of the Paleo-Pacific plate.


1999 ◽  
Vol 36 (5) ◽  
pp. 819-831 ◽  
Author(s):  
J B Thomas ◽  
A K Sinha

The quartz dioritic Quottoon Igneous Complex (QIC) is a major Paleogene (65-56 Ma) magmatic body in northwestern British Columbia and southeastern Alaska that was emplaced along the Coast shear zone. The QIC contains two different igneous suites that provide information about source regions and magmatic processes. Heterogeneous suite I rocks (e.g., along Steamer Passage) have a pervasive solid-state fabric, abundant mafic enclaves and late-stage dikes, metasedimentary screens, and variable color indices (25-50). The homogeneous suite II rocks (e.g., along Quottoon Inlet) have a weak fabric developed in the magmatic state (aligned feldspars, melt-filled shears) and more uniform color indices (24-34) than in suite I. Suite I rocks have Sr concentrations <750 ppm, average LaN/YbN = 10.4, and initial 87Sr/86Sr ratios that range from 0.70513 to 0.70717. The suite II rocks have Sr concentrations >750 ppm, average LaN/YbN = 23, and initial 87Sr/86Sr ratios that range from 0.70617 to 0.70686. This study suggests that the parental QIC magma (initial 87Sr/86Sr approximately 0.706) can be derived by partial melting of an amphibolitic source reservoir at lower crustal conditions. Geochemical data (Rb, Sr, Ba, and LaN/YbN) and initial 87Sr/86Sr ratios preclude linkages between the two suites by fractional crystallization or assimilation and fractional crystallization processes. The suite I rocks are interpreted to be the result of magma mixing between the QIC parental magma and a mantle-derived magma. The suite II rocks are a result of assimilation and fractional crystallization processes.


1984 ◽  
Vol 21 (4) ◽  
pp. 415-427 ◽  
Author(s):  
Kent C. Condie ◽  
Craig A. Shadel

The Green Mountain Formation of early Proterozoic age in the Sierra Madre Range of southeastern Wyoming comprises a bimodal mafic and felsic volcanic assemblage. The rocks, which are chiefly breccias, agglomerates, flows, and volcaniclastic sediments, represent both subaerial and submarine eruptions and in part were redeposited in fluvial and nearshore marine environments. Volcanic rocks are clearly calc-alkaline in character and share a large number of geochemical features in common with continental-margin arcs or evolved oceanic-arc systems.The low Mg numbers and Ni contents of the basalts require 30–40% olivine fractional crystallization, and the high contents of the most incompatible elements, high (La/Sm)N ratios, and low Zr/Nb ratios require an undepleted or enriched mantle source. Geochemical data are consistent with an origin for the felsic volcanics and associated Encampment River granodiorite by shallow fractional crystallization of calc-alkaline basalt in a tectonic setting similar to modern arc systems. The near absence of andesites may reflect the retention of andesitic magma in crustal reservoirs during fractional cyrstallization.


Geosciences ◽  
2018 ◽  
Vol 8 (7) ◽  
pp. 266 ◽  
Author(s):  
Kristoffer Szilas

The present contribution reviews bulk-rock geochemical data for mid-Archaean (ca. 3075–2840 Ma) metavolcanic rocks from the North Atlantic Craton of southwest Greenland. The data set includes the most recent high quality major and trace element geochemical analyses for ten different supracrustal/greenstone belts in the region. When distilling the data set to only include the least altered metavolcanic rocks, by filtering out obviously altered samples, mafic/ultramafic cumulate rocks, late-stage intrusive sheets (dolerites) and migmatites, the remaining data (N = 427) reveal two fundamentally distinct geochemical suites. The contrasting trends that emerge from the filtered geochemical data set, which best represents the melt compositions for these mid-Archaean metavolcanic rocks are: (1) tholeiitic (mainly basaltic) versus (2) calc-alkaline (mainly andesitic). These two rock suites are effectively separated by their La/Sm ratios (below or above three, respectively). It is demonstrated by geochemical modelling that the two contrasting suites cannot be related by either fractional crystallization or crustal assimilation processes, despite occurring within the same metavolcanic sequences. The tholeiitic basaltic rocks were directly mantle-derived, whereas the petrogenesis of the calc-alkaline andesitic rocks involve a significant (>50%) felsic component. The felsic contribution in the calc-alkaline suite could either represent slab-melt metasomatism of their mantle source, mafic-felsic magma mixing, or very large degrees of partial melting of mafic lower crust. At face value, the occurrence of andesites, and the negative Nb-Ta-Ti-anomalies of both suites, is consistent with a subduction zone setting for the origin of these metavolcanic rocks. However, the latter geochemical feature is inherent to processes involving crustal partial melts, and therefore independent lines of evidence are needed to substantiate the hypothesis that plate tectonic processes were already operating by the mid-Archaean.


2021 ◽  
pp. 1-27
Author(s):  
Nora G Abdel Wanees ◽  
Mohamed M El-Sayed ◽  
Khalil I Khalil ◽  
Hossam A Khamis

Abstract The Abu Kharif area in the Northern Eastern Desert consists of contrasting granitic magma suites: a Cryogenian granodiorite suite (850–635 Ma), an Ediacaran monzogranite suite (635–541 Ma) and a Cambrian alkali riebeckite granite suite (541–485 Ma). Tungsten mineralization occurs within W-bearing quartz veins and a disseminated type confined to the monzogranite. Whole-rock geochemical data classify the granodiorite as a late-orogenic I-type with calc-alkaline affinity, while the monzogranite and alkali riebeckite granite represent respectively a post-orogenic highly fractionated I-type with calc-alkaline affinity and an anorogenic A1-subtype with alkaline affinity. Geochemical modelling indicates that the three intrusions represent separate magmatic pulses where the granodiorite was generated by ∼75 % batch partial melting of an amphibolitic source followed by fractional crystallization of hornblende, biotite, apatite and titanite. The monzogranite was formed by 62 % batch partial melting of the normal ‘non-metasomatized’ Pan-African crust of calc-alkaline granite composition followed by fractional crystallization of plagioclase, biotite, K-feldspar, magnetite, ilmenite, with minor apatite and titanite. The alkali riebeckite granite was generated by 65 % batch partial melting of metasomatized Pan-African granite source followed by fractional crystallization of plagioclase, K-feldspar, amphibole and biotite with minor magnetite, apatite and titanite. In general, the parent magmas of the three intrusions were originally enriched in W, but with different concentrations. This W-enrichment would be caused by magmatic-related hydrothermal volatile-rich fluids and concentrated within the monzogranite.


1999 ◽  
Vol 63 (1) ◽  
pp. 85-104 ◽  
Author(s):  
J. A. Ramirez ◽  
L. G. Menendez

AbstractIn this paper we present new petrological and geochemical data for two peraluminous granite batholiths (Nisa Alburquerque and Jalama batholiths) representative of the ‘Araya-type’ granites of the Central-Iberian Zone. Both granites are composite with several facies (monzogranites and leucogranites) that can be grouped into two main granite units: the external units and central units. Intrusive relationships and lack of geochemical coherence between the central and external units indicate that they are not comagmatic but represent different pulses. The central units of both batholiths are petrologically and geochemically different. On the other hand, external units show a lot of similarities and are the main object of this study. The main characteristics of the external granites can be interpreted in terms of an incomplete fractional crystallization process of early mineral phases (plg + Kf + bt) which probably took place at the level of emplacement. Other possible mechanisms of magmatic differentiation (magma mixing, restite unmixing, sequential melting) can be discarded based on field, petrography and geochemical data. We propose that the ‘Araya-type’ granites are formed by the intrusion of distinct magma pulses (central and external). Further evolution within each pulse can be due to incomplete fractional crystallization possibly taking place at the emplacement level.


1986 ◽  
Vol 23 (4) ◽  
pp. 561-578 ◽  
Author(s):  
Christian Picard ◽  
Michel Piboule

In the northeastern part of the Abitibi orogenic belt, the Archean Matagami–Chibougamou greenstone belt (2700 Ma) includes a basal volcanic sequence named the Roy Group, unconformably overlain by a volcano-sedimentary series called the Opemisca Group.The Roy Group, to the west of the town of Chapais, consists of a thick, stratified, and polycyclic volcanic series (thickness = 11 000 m) resembling the large, western Abitibi submarine stratovolcanoes constructed by three mafic to felsic magmatic cycles. The first cycle (Chrissie Formation) shows lateral spreading and is composed only of a meta-andesite and felsic pyroclastite sequence of calc-alkaline affinity. The other two cycles (Obatogamau and Waconichi formations; then Gilman, Blondeau, and Scorpio formations) are characterized by a sequence of repeated MORB type basaltic lava flows of tholeiitic affinity and by intermediate to acid lava and pyroclastic sequences calc-alkaline affinity.The stratigraphic and petrographic data suggest emplacement of mafic lavas on an abyssal plain (Obatogamau Formation) or at a later time on the flanks of a large submarine volcanic shield (Gilman and Blondeau formations). The lava and felsic pyroclastite flows were formed by very explosive eruptions from central spreading type volcanoes above a pre-existing continental crust. In particular, the Scorpio volcanic rocks were emplaced on volcanic islands later dismantled by erosion.The contents and distribution of trace elements and rare earths show that basaltic lavas resulted from an equilibrium partial melting (F = 15–35%) of spinel lherzolite type mantle sources depleted to weakly enriched in Th, Ta, Nb, and light rare-earth elements (LREE), and from fractional crystallization at low pressure of feldspar, clinopyroxene, and olivine. The lavas and the felsic pyroclastites of the Waconichi and Scorpio formations appear to result from partial melting of a mantle source of lherzolite type enriched in LREE and involving some garnet. At a late stage, the melts were probably contaminated by some continental crust materials and then differentiated by fractional crystallization of plagioclase, amphibole, biotite, and magnetite. The lavas in the Chrissie Formation and the middle member of the Gilman Formation seem to result from partial melting of a mantle source enriched in LREE with a composition between the two described above. They were subsequently modified by fractional crystallization of the plagioclase, clinopyroxene, olivine, and titanomagnetite.In general, the mafic to felsic magmatic cycles observed are characterized by a thick sequence of repeated tholeiitic basalt flows similar to those of modern mid-oceanic ridges and by a lava and felsic pyroclastite sequence of calc-alkaline affinity comparable to those occurring in orogenic belts. The transition from one lava sequence to another is marked by a significant chemical discontinuity, and the mantle sources exhibit an increasing enrichment in LREE during a given magmatic cycle. A model is proposed to satisfactorily explain all the stratigraphic, petrographic, and geochemical data implying a hot spot type mechanism, which could be responsible for the cyclic, rising diapirs inside the stratified Archean mantle and for initiating the repeated mantle source meltings, depleted and enriched in LREE, respectively. [Journal Translation]


2009 ◽  
Vol 73 (1) ◽  
pp. 1-16 ◽  
Author(s):  
R. Macdonald ◽  
B. Bagiński

The review focuses on the evolution of five contiguous peralkaline salic complexes in the south-central Kenya Rift Valley, stressing new developments of general significance to peralkaline magmatism. The complexes have evolved dominantly by combinations of fractional crystallization and magma mixing; volatile-melt interactions, remobilization of plutonic rocks and crystal mushes, and carbonate-silicate liquid immiscibility have been additional petrogenetic processes. Geochemical and experimental studies have shown that pantelleritic magmas can be generated by fractional crystallization of trachyte and high-silica rhyolite. Melts of comenditic composition were also formed by fractionation of trachyte but also locally by partial meltingof syenites. Studies of apparent partition coefficients have provided some of the first data on element distribution between phenocrysts and peralkaline silicic melts. Compositional zonation has been ubiquitous in the complexes, probably a result of the very low viscosity of the magmas.


2004 ◽  
Vol 36 (1) ◽  
pp. 482 ◽  
Author(s):  
Κ. Αρίκας ◽  
Π. Βουδούρης ◽  
M. R. Kloos ◽  
Ch. Tesch

The penological, mineralogical and geochemical study of tertiary volcanic rocks from Petrota Graben/Maronia, resulted in the distinction of the following pétrographie groups: a) a high-K calcalkaline group (andesites-dacites), b) a shoshonitic group (shoshonitic andésites, trachytic lavas, c) rhyodacitic ignimbrites and ignimbritic tuffs with high-K calc-alkaline to shoshonitic affinity, and d) rhyolites. The shoshonitic volcanic rocks and the rhyolites are probably originated from the neighbouring Maronia plutonio complex. In addition the calc-alkaline group is related to similar volcanics outcroping in the Mesti-Kassiteres area (the northeastern extension of the Graben). The petrogenesis of the volcanic rocks of the Petrota gragen is attibuted to fractional crystallization and/or magma mixing processes. Epithermal style mineralizations in Mavrokoryfi, Perama Hill and Odontoto are believed to be genetically related to the rhyolitic magmatism in the area.


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