An X-ray Technique for Distinguishing Between Detrital and Secondary Quartz in the Fine-grained Fraction of Sedimentary Rocks

Author(s):  
Eric V. Eslinger (3), Lawrence M. M
Keyword(s):  
X Ray ◽  
2020 ◽  
Author(s):  
Rocky D. Barker ◽  
Shaun L.L. Barker ◽  
Siobhan A. Wilson ◽  
Elizabeth D. Stock

Abstract Mineral distributions can be determined in drill core samples from a Carlin-type gold deposit, using micro-X-ray fluorescence (µXRF) raster data. Micro-XRF data were collected using a Bruker Tornado µXRF scanner on split drill core samples (~25 × 8 cm) with data collected at a spatial resolution of ~100 µm. Bruker AMICS software was used to identify mineral species from µXRF raster data, which revealed that many individual sample spots were mineral mixtures due to the fine-grained nature of the samples. In order to estimate the mineral abundances in each pixel, we used a linear programming (LP) approach on quantified µXRF data. Quantification of µXRF spectra was completed using a fundamental parameters (FP) standardless approach. Results of the FP method compared to standardized wavelength dispersive spectrometry (WDS)-XRF of the same samples showed that the FP method for quantification of µXRF spectra was precise (R2 values of 0.98–0.97) although the FP method gave a slight overestimate of Fe and K and an underestimate of Mg abundance. Accuracy of the quantified µXRF chemistry results was further improved by using the WDS-XRF data as a calibration correction before calculating mineralogy using LP. The LP mineral abundance predictions were compared to Rietveld refinement results using X-ray diffraction (XRD) patterns collected from powders of the same drill core samples. The root mean square error (RMSE) for LP-predicted mineralogy compared to quantitative XRD results ranges from 0.91 to 7.15% for quartz, potassium feldspar, pyrite, kaolinite, calcite, dolomite, and illite. The approaches outlined here demonstrates that µXRF maps can be used to determine mineralogy, mineral abundances, and mineralogical textures not visible with the naked eye from fine-grained sedimentary rocks associated with Carlin-type Au deposits. This approach is transferrable to any ore deposit, but particularly useful in sedimentary-hosted ore deposits where ore and gangue minerals are often fine grained and difficult to distinguish in hand specimen.


Minerals ◽  
2019 ◽  
Vol 9 (10) ◽  
pp. 620 ◽  
Author(s):  
Min ◽  
Zhang ◽  
Li ◽  
Zhao ◽  
Li ◽  
...  

The albitization of K-feldspar is a common diagenetic process that has thus far received little attention and is not fully understood in fine-grained sedimentary rocks. To better understand the albitization of K-feldspar, studies in organic- and silt-rich fine-grained rocks of the lower Cambrian Qiongzhusi Formation in the southwestern Upper Yangtze region, China, were carried out via X-ray diffractometry (XRD) and field emission scanning electron microscopy (FE-SEM). The results show that five types of albitized K-feldspar textures have developed: microcrystal albite replacement, irregular blocky replacement along margins, cleavage planes or microcracks of K-feldspars, complete pseudomorphic replacement, albite overgrowth, and albite pore filling. Organic- and silt-rich fine-grained rocks differ from sandstones and mudstones in terms of the rock structure and mineral assemblage, which results in differences in the textures and degree of albitization of K-feldspar. Illitization of clay has an impact on the albitization of K-feldspar. In provenance analyses using feldspar, fine-grained rocks, especially those that underwent mesogenesis, should be treated with caution because detrital feldspars have been destroyed. Theoretically, the albitization of K-feldspar could increase the porosity of reservoirs, although, from our observations, most of the related secondary pores are cancelled out or became isolated pores due to other diagenetic processes (compaction, cementation, etc.) in organic- and silt-rich fine-grained rocks.


Author(s):  
Thomas R. McKee ◽  
Peter R. Buseck

Sediments commonly contain organic material which appears as refractory carbonaceous material in metamorphosed sedimentary rocks. Grew and others have shown that relative carbon content, crystallite size, X-ray crystallinity and development of well-ordered graphite crystal structure of the carbonaceous material increases with increasing metamorphic grade. The graphitization process is irreversible and appears to be continous from the amorphous to the completely graphitized stage. The most dramatic chemical and crystallographic changes take place within the chlorite metamorphic zone.The detailed X-ray investigation of crystallite size and crystalline ordering is complex and can best be investigated by other means such as high resolution transmission electron microscopy (HRTEM). The natural graphitization series is similar to that for heat-treated commercial carbon blacks, which have been successfully studied by HRTEM (Ban and others).


Metals ◽  
2021 ◽  
Vol 11 (3) ◽  
pp. 461
Author(s):  
Konrad Kosiba ◽  
Konda Gokuldoss Prashanth ◽  
Sergio Scudino

The phase and microstructure formation as well as mechanical properties of the rapidly solidified Mg67Ag33 (at. %) alloy were investigated. Owing to kinetic constraints effective during rapid cooling, the formation of equilibrium phases is suppressed. Instead, the microstructure is mainly composed of oversaturated hexagonal closest packed Mg-based dendrites surrounded by a mixture of phases, as probed by X-ray diffraction, electron microscopy and energy dispersive X-ray spectroscopy. A possible non-equilibrium phase diagram is suggested. Mainly because of the fine-grained dendritic and interdendritic microstructure, the material shows appreciable mechanical properties, such as a compressive yield strength and Young’s modulus of 245 ± 5 MPa and 63 ± 2 GPa, respectively. Due to this low Young’s modulus, the Mg67Ag33 alloy has potential for usage as biomaterial and challenges ahead, such as biomechanical compatibility, biodegradability and antibacterial properties are outlined.


1970 ◽  
Vol 37 (290) ◽  
pp. 705-707 ◽  
Author(s):  
L. C. Hodge

SummaryRussellite Bi2O3. WO3 occurs in a small pegmatite near Poona, Western Australia. The fine-grained yellow to pale green material is an inseparable mixture of russellite, bismite, koechlinite, and bismutite. X-ray powder diffraction, physical, and chemical data agree in general with the original description of the mineral from Cornwall, England. The original analyses made on micro quantities are now supplemented by analyses on macro quantities.


1972 ◽  
Vol 9 (1) ◽  
pp. 36-42 ◽  
Author(s):  
Calvert C. Bristol

X-ray powder diffraction methods, successful in quantitative determination of silicate minerals in fine-grained rocks, have been applied to the determination of calcite, dolomite, and magnesite in greenschist facies meta-volcanic rocks. Internal standard graphs employing two standards (NaCl and Mo) have been determined.Carbonate mineral modes (calcite and dolomite) for 6 greenschist facies meta-volcanic rocks obtained by the X-ray powder method have been compared to normative carbonate mineral contents calculated for the same rocks. This comparison showed a maximum variation of 7.7 wt.% between the X-ray modes and the normative carbonate mineral contents of the rocks. Maximum standard deviation for the X-ray modes of these rocks was equivalent to 4.4 wt.%.


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