Infrared Multiple Specular Reflectance of Mono- and Submonomolecular Layers of p-Bromobenzoic Acid on Oxidized Metals

1989 ◽  
Vol 43 (1) ◽  
pp. 107-113 ◽  
Author(s):  
A. H. M. Sondag ◽  
M. C. Raas

The advantages of Multiple Specular Reflection (MSR) over single reflection grazing incidence infrared spectroscopy are discussed in this paper. A calculation which incorporates the experimental constraints for a multiple reflection setup is performed. The results concerning the angular dependence are confirmed by experiment. The main advantages are a wide angular acceptance and a release of the grazing angle of incidence geometry. Approximately the same sensitivity can be obtained as is theoretically possible with a single reflection at grazing incidence. However, in practice a somewhat higher sensitivity can be obtained with multiple specular reflectance spectroscopy. The sensitivity is illustrated by the measurement of submonolayers of p-bromobenzoic acid chemi-sorbed on an oxidized aluminium flat surface. Comparison with neutron activation analysis data shows that the reflection-absorption intensities are proportional to the surface coverage. A dependence of spectral features on surface coverage can be observed.

The paper presents thorough theoretical and numerical analysis of the anomalies accompanying light diffraction on periodical structures (gratings). We have developed appropriate theoretical approach allowing to consider strong anomalous effects. Obtained results are presented in the form of analytical expressions for the quntities of interest, both diffracted field amplitudes and the outgoing waves energy fluxes. It is proved existence of the fluxes extrema at the specific grazing angle of incidenceб or wavelength. Namely, the specular reflection can be suppressed even for rather shallow gratings up to approximately total suppression.This effect is accompanied by essential energy redistribution between all outgoing waves depending on the grating profile. It is of essence that the energy maxima exist in all nonspecular diffraction orders at the same point (angle, wavelength) as the minimal specular reflectivity. For small period gratings, such that there do not exist other outgoing waves except the specular one, the reflectance minimum is attended by approximately total absorption of the incident radiation. Thus, we show that the grazing anomaly (GA) can be accompanied by redirection of the incident wave energy into nonspecular diffraction channels and into absorption. The results are applicable in the wide spectral region, from visible and near-infrared to terahertz and high-frequency regions for metals and semiconductors with high permittivity. The anomaly considered is well expressed for high electromagnetic contrast of the adjacent media, say, air and metal or semiconductor. Then the high contrast is due to the high value of the metal/semiconductor dielectric permittivity  ,  1 , and the anomaly corresponds to incidence of TM polarized wave. It is shown that the grazing anomaly (GA) is of rather general type and can take place if other than the specular diffraction order experiencies grazing propagation also. This property follows from the results obtained by strict application of the optical reciprocity theorem to the geometry under consideration. The specific case of harmonic relief grating is discussed in detail. It is demomstrated existence of the characteristic inclination, cr a , of the relief inclinatuion for the grating period comparable with the incident radiation wavelength, 1 cr a  , where  stays for the surface impedance,  1  . The condition cr a a , or greater, corresponds to highly expressed GA. The theoretical results are illustrated by numerical applications to gratings on Cu\vacuum (air) interface in THz region. The results obtained can be simply transferred to the TE polarized waves. For this we have to consider the adjacent media with high contrast magnetic properties, i.e., high value of the magnetic permeability  ,  1 . This case is of high interest for nowaday applications in nanophotonics and metamaterials development. As compared with other anomalies GA is attributed to the resonance-type behaviour of the energy flux, not wave amplitudes, the latter change monotonically within this anomaly contrary to the well known Rayleigh and resonance anomalies, where the wave amplitude experiences fast nonmonotonous dependence on the angle of incidence and wavelength.


2017 ◽  
Vol 50 (4) ◽  
pp. 1066-1074 ◽  
Author(s):  
Shirin Nouhi ◽  
Maja S. Hellsing ◽  
Vassilios Kapaklis ◽  
Adrian R. Rennie

Changes of scattering are observed as the grazing angle of incidence of an incoming beam increases and probes different depths in samples. A model has been developed to describe the observed intensity in grazing-incidence small-angle neutron scattering (GISANS) experiments. This includes the significant effects of instrument resolution, the sample transmission, which depends on both absorption and scattering, and the sample structure. The calculations are tested with self-organized structures of two colloidal samples with different size particles that were measured on two different instruments. The model allows calculations for various instruments with defined resolution and can be used to design future improved experiments. The possibilities and limits of GISANS for different studies are discussed using the model calculations.


2021 ◽  
Vol 28 (1) ◽  
pp. 224-230
Author(s):  
P. Sarkar ◽  
A. Biswas ◽  
N. Abharana ◽  
S. Rai ◽  
M. H. Modi ◽  
...  

The influence of a carbon barrier layer to improve the reflectivity of Cr/Ti multilayers, intended to be used in the water window wavelength regime, is investigated. Specular grazing-incidence X-ray reflectivity results of Cr/Ti multilayers with 10 bilayers show that interface widths are reduced to ∼0.24 nm upon introduction of a ∼0.3 nm C barrier layer at each Cr-on-Ti interface. As the number of bilayers increases to 75, a multilayer with C barrier layers maintains almost the same interface widths with no cumulative increase in interface imperfections. Using such interface-engineered Cr/C/Ti multilayers, a remarkably high soft X-ray reflectivity of ∼31.6% is achieved at a wavelength of 2.77 nm and at a grazing angle of incidence of 16.2°, which is the highest reflectivity reported so far in the literature in this wavelength regime. Further investigation of the multilayers by diffused grazing-incidence X-ray reflectivity and grazing-incidence extended X-ray absorption fine-structure measurements using synchrotron radiation suggests that the improvement in interface microstructure can be attributed to significant suppression of inter-diffusion at Cr/Ti interfaces by the introduction of C barrier layers and also due to the smoothing effect of the C layer promoting two-dimensional growth of the multilayer.


2020 ◽  
Vol 1004 ◽  
pp. 393-400
Author(s):  
Tuerxun Ailihumaer ◽  
Hongyu Peng ◽  
Balaji Raghothamachar ◽  
Michael Dudley ◽  
Gilyong Chung ◽  
...  

Synchrotron monochromatic beam X-ray topography (SMBXT) in grazing incidence geometry shows black and white contrast for basal plane dislocations (BPDs) with Burgers vectors of opposite signs as demonstrated using ray tracing simulations. The inhomogeneous distribution of these dislocations is associated with the concave/convex shape of the basal plane. Therefore, the distribution of these two BPD types were examined for several 6-inch diameter 4H-SiC substrates and the net BPD density distribution was used for evaluating the nature and magnitude of basal plane bending in these wafers. Results show different bending behaviors along the two radial directions - [110] and [100] directions, indicating the existence of non-isotropic bending. Linear mapping of the peak shift of the 0008 reflection along the two directions was carried out using HRXRD to correlate with the results from the SMBXT measurements. Basal-plane-tilt angle calculated using the net BPD density derived from SMBXT shows a good correlation with those obtained from HRXRD measurements, which further confirmed that bending in basal plane is caused by the non-uniform distribution of BPDs. Regions of severe bending were found to be associated with both large tilt angles (95% black contrast BPDs to 5% white contrast BPDs) and abrupt changes in a and c lattice parameters i.e. local strain.


1964 ◽  
Vol 86 (2) ◽  
pp. 193-199 ◽  
Author(s):  
R. C. Birkebak ◽  
E. M. Sparrow ◽  
E. R. G. Eckert ◽  
J. W. Ramsey

Measurements have been made of the hemispherical and specular reflectance of metallic surfaces of controlled roughness. The surfaces, which were ground nickel rectangles, were irradiated at various angles of incidence by a beam of black-body radiation, the temperature of which was also varied. The instrumentation which was devised to perform the experiments is described. The measurements show that beyond a certain surface roughness, the hemispherical reflectance is virtually independent of further increases in roughness. On the other hand, the specular reflectance decreases steadily with increasing roughness. Additionally, the hemispherical reflectance is found to be quite insensitive to the angle of incidence, while the specular reflectance increases with angle of incidence for the rougher surfaces.


1987 ◽  
Vol 65 (5) ◽  
pp. 919-923 ◽  
Author(s):  
A. Scott Hinman ◽  
Brad J. Pavelich

A versatile thin layer spectroelectrochemical cell employing specular reflection of the incident light beam from the electrode surface is described. Its application to in-situ uv–vis and FTIR characterization of the products of electrochemical reactions and to thin layer voltammetry and coulometry as well as conventional cyclic voltammetry is demonstrated for the oxidation of tetraphenylporphinatozinc in dichloroethane/tetrabutylammonium perchlorate solution. The advantages and disadvantages of this type of cell as compared to more conventional sandwich type optically transparent thin layer electrodes are discussed.


1995 ◽  
Vol 49 (3) ◽  
pp. 354-360 ◽  
Author(s):  
Stephen V. Pepper

A grazing angle objective on an infrared microspectrometer is studied for quantitative spectroscopy by considering the angular dependence of the incident intensity within the objective's angular aperture. The assumption that there is no angular dependence is tested by comparing the experimental reflectance of Si and KBr surfaces with the reflectance calculated by integrating the Fresnel reflection coefficient over the angular aperture under this assumption. Good agreement was found, indicating that the specular reflectance of surfaces can straightforwardly be quantitatively integrated over the angular aperture without considering nonuniform incident intensity. This quantitative approach is applied to the thickness determination of dipcoated Krytox on gold. The infrared optical constants of both materials are known, allowing the integration to be carried out. The thickness obtained is in fair agreement with the value determined by ellipsometry in the visible. Therefore, this paper illustrates a method for more quantitative use of a grazing angle objective for infrared reflectance microspectroscopy.


Soft Matter ◽  
2014 ◽  
Vol 10 (36) ◽  
pp. 6999-7007 ◽  
Author(s):  
Antonio Stocco ◽  
Ge Su ◽  
Maurizio Nobili ◽  
Martin In ◽  
Dayang Wang

Contact angles and surface coverage of nanoparticles adsorbing at the fluid interface are assessed by ellipsometry. Results reveal the competition between wetting and colloidal interactions.


2021 ◽  
Author(s):  
Andriy E. Serebryannikov ◽  
Diana C. Skigin ◽  
Guy A. E. Vandenbosch ◽  
Ekmel Ozbay

Abstract The concept of multifunctional reflection-mode gratings based on rod-type photonic crystals with C2 symmetry is introduced and examined. The specific modal properties lead to the vanishing dependence of the first-negative-order maximum on the angle of incidence within a wide range, and the nearly sinusoidal redistribution of the incident-wave energy between zero order (specular reflection) and first negative diffraction order (deflection) at frequency variation that are the key features enabling various functionalities in one structure and functionality merging. The elementary functionalities offered by the studied structures, of which multifunctional scenarios can be designed, include but are not restricted to multiband spatial filtering, multiband splitting, and demultiplexing. The proposed structures are shown to be capable in multifunctional operation in case of an obliquely incident polychromatic wave. The generalized demultiplexing is demonstrated for the case when several polychromatic wavesare incident at different angles. The same deflection properties yield multiband splitting, and merging demultiplexing and splitting functionalties in one functionality, which may contribute to various multifunctional scenarios. The proposed gratings arealso studied in transmissive configuration.


2022 ◽  
Vol 14 (2) ◽  
pp. 247
Author(s):  
Zbigniew Otremba ◽  
Jacek Piskozub

The article presents the results of simulations that take into account the optical parameters of the selected sea region (from literature data on the southern Baltic Sea) and two optically extreme types of crude oil (from historical data) which exist in the form of a highly watered-down oil-in-water emulsion (10 ppm). The spectral index was analyzed based on the results of modeling the radiance reflectance distribution for almost an entire hemisphere of the sky (zenith angle from 0 to 80°). The spectral index was selected and is universal for all optically different types of oil (wavelengths of 650 and 412 nm). The possibility of detecting pollution in the conditions of the wavy sea surface (as a result of wind of up to 10 m/s) was studied. It was also shown that if the viewing direction is close to a direction perpendicular to the sea surface, observations aimed at determining the spectral index are less effective than observations under the zenith angle of incidence of sunlight for all azimuths excluding the direction of sunlight’s specular reflection.


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