scholarly journals Identification of processes controlling chemical composition of pit lakes waters located in the eastern part of Muskau Arch (Polish-German borderland) / Identyfikacja procesów kształtujących skład chemiczny wód zbiorników zlokalizowanych na obszarach pogórniczych we wschodniej części Łuku Mużakowa (pogranicze polsko-niemieckie)

2015 ◽  
Vol 41 (3) ◽  
pp. 60-69 ◽  
Author(s):  
Sylwia Lutyńska ◽  
Krzysztof Labus
Keyword(s):  
Cluster Analysis ◽  
Chemical Composition ◽  
Water Regime ◽  
Mine Drainage ◽  
Speciation Analysis ◽  
Factor Analyses ◽  
Similar Chemical ◽  
Pit Lakes ◽  
Acidification Of Lake ◽  
Lake Waters

Abstract Exploitation of lignite within the area of Muskau Arch, carried out from the mid-nineteenth century, contributed to the transformation of the natural environment and changes in water regime. In the post-mining subsidences pit lakes were formed. The chemical composition of waters is a consequence of the intensive weathering of pyrite (FeS2), which is present in Miocene lignite-bearing rock forming the embankments of the lakes. This process leads to the formation of Acid Mine Drainage (AMD) and finally acidification of lake waters. This paper presents results of the identification of hydrogeochemical processes affecting the chemistry of waters from these reservoirs carried out using the speciation and statistical (cluster and factor) analyses. Cluster analysis allowed to separate from the analyzed group of anthropogenic reservoirs 7 subgroups characterized by a similar chemical composition of waters. The major processes affecting the chemistry of waters were identified and interpreted with help of factor and speciation analysis of two major parameters (iron and sulfur).

scholarly journals Cluster analysis in determining subsoil water areas of similar chemical composition in Shyraz and Horamabad intermountain troughs of Iran

2014 ◽  
pp. 54-61
Author(s):  
Aziz Amjadi ◽  
D. Chomko
Keyword(s):  
Cluster Analysis ◽  
Chemical Composition ◽  
Water Supply ◽  
Ground Water ◽  
Analysis Data ◽  
Chemical Components ◽  
Similar Chemical Composition ◽  
Chemical Zoning ◽  
Ground Waters ◽  
Similar Chemical

Ground waters of Shyraz Intermountain Trough are widely used for water-supply, watering crops, in industry, and for other purposes. It is currently being planned to make extensive use of ground waters of the Horamabad Trough. Discriminating large areas of ground waters of similar chemical composition and compounds containing over 10 elements is becoming a challenging task. Chemical composition of ground waters results from a number of natural and anthropogenic processes, which affect both interchange of chemical components and the nature of their bonds. However, these bonds do not remain unaffected, and are, virtually, the outcome of a number of processes. We offer a new method that is based on the use of cluster analysis, the application of which will make it possible to discriminate ground waters of similar chemical composition in different areas. This will enable both revealing similarities and differences in the processes of water supply and discharge, which define the chemical make-up of the ground waters, threats of pollution and depletion, and taking measures on ground water preservation. The method was tested on sampling chemical composition of ground waters of Shyraz and Horamabad Intermountain Troughs in Iran. Based on the cluster analysis data of the first matrix (Shyraz Intermountain Trough) and the second matrix (Horamabad Intermountain Trough) step-by-step diagrams of merging intervals are built, and dendrograms, namely. The claster analysis data being processed, the following conclusions can be made: 1. within Shyraz Intermountain Trough, there are discriminated three areas of ground waters bearing similar chemical composition in claster 1; two areas located in claster 2; three areas in claster 3; two areas in claster 4; and one area in claster 5; 2. within Horamabad Intermountain Trough, there are discriminated two areas of ground waters bearing similar chemical composition in claster 1; three areas located in claster 2; two areas in claster 3; four areas in claster 4; and per one area in clasters 5 and 6, correspondingly; 3. changes in ground water chemical composition in Shyraz and Horamabad Intermountain Troughs are interdependent; 4. the method mentioned can be used for chemical zoning of the ground waters.

scholarly journals Hydrochemistry of pit lakes in the Portuguese sector of the Iberian Pyrite Belt

2019 ◽  
Vol 98 ◽  
pp. 09007
Author(s):  
Patrícia Gomes ◽  
Teresa Valente ◽  
Mayara Cordeiro ◽  
Filipa Moreno
Keyword(s):  
Mine Drainage ◽  
Iberian Pyrite Belt ◽  
Ore Deposits ◽  
Metallogenic Province ◽  
Waste Dumps ◽  
Volcanogenic Massive Sulphide ◽  
Roman Time ◽  
Pit Lakes ◽  
World Class ◽  
Lake Waters

The Iberian Pyrite Belt (IPB) is a world-class metallogenic province with volcanogenic massive sulphide ore deposits. Most ore exploitation occurred since pre-Roman time, creating extensive galleries, wells, waste-dumps and pit lakes. These last structures are a concern for their potential environmental impact because they accumulate large volumes of mine water affected acid mine drainage. The present work classifies the pit lakes based on the surface water hydrochemistry. Using the Ficklin diagram for classification, pit lake waters vary from acid, high-metal to high-acid, extreme-metal and exhibit similarities with other pit lakes from the Spanish sector of the IPB.

scholarly journals Effects of SO<sub>2</sub> oxidation on ambient aerosol growth in water and ethanol vapours

2005 ◽  
Vol 5 (3) ◽  
pp. 767-779 ◽  
Author(s):  
T. Petäjä ◽  
V.-M. Kerminen ◽  
K. Hämeri ◽  
P. Vaattovaara ◽  
J. Joutsensaari ◽  
...  
Keyword(s):  
Chemical Composition ◽  
Sulphuric Acid ◽  
Cloud Condensation Nuclei ◽  
Aerosol Particles ◽  
The Arctic ◽  
Ambient Conditions ◽  
Similar Chemical ◽  
Ethanol Vapours ◽  
Hygroscopic Particles ◽  
Ultrafine Aerosol

Abstract. Hygroscopicity (i.e. water vapour affinity) of atmospheric aerosol particles is one of the key factors in defining their impacts on climate. Condensation of sulphuric acid onto less hygroscopic particles is expected to increase their hygrocopicity and hence their cloud condensation nuclei formation potential. In this study, differences in the hygroscopic and ethanol uptake properties of ultrafine aerosol particles in the Arctic air masses with a different exposure to anthropogenic sulfur pollution were examined. The main discovery was that Aitken mode particles having been exposed to polluted air were more hygroscopic and less soluble to ethanol than after transport in clean air. This aging process was attributed to sulphur dioxide oxidation and subsequent condensation during the transport of these particle to our measurement site. The hygroscopicity of nucleation mode aerosol particles, on the other hand, was approximately the same in all the cases, being indicative of a relatively similar chemical composition despite the differences in air mass transport routes. These particles had also been produced closer to the observation site typically 3–8 h prior to sampling. Apparently, these particles did not have an opportunity to accumulate sulphuric acid on their way to the site, but instead their chemical composition (hygroscopicity and ethanol solubility) resembled that of particles produced in the local or semi-regional ambient conditions.

Characteristics of the Al-Brasses Affected Corrosion Properties

2016 ◽  
Vol 844 ◽  
pp. 38-45 ◽  
Author(s):  
Tatiana Liptáková ◽  
Martin Lovíšek ◽  
Branislav Hadzima
Keyword(s):  
Mechanical Properties ◽  
Chemical Composition ◽  
Research Work ◽  
Construction Materials ◽  
Experimental Methods ◽  
Energy Industry ◽  
Corrosion Properties ◽  
Corrosion Resistant ◽  
Operation Conditions ◽  
Similar Chemical

The Al-brasses are considered corrosion resistant construction materials often used to pipe systems in energy industry, where they are exposed to flowing liquids environments. In that system the brasses are loaded chemically and mechanically. The aim of our research work is to compare corrosion properties of four Al-brasses produced by different manufactures because in operation conditions they have dissimilar reliability and durability. The examined Al-brasses have similar chemical composition but differ in microstructure, surface state what affects their corrosion and mechanical properties. The effect of the mentioned parameters on corrosion and mechanical susceptibility to degradation are investigated by chosen experimental methods.

The Thermal Volatilization of Petrodisel/Biodiesel from Waste Oil

2011 ◽  
Vol 347-353 ◽  
pp. 2656-2660
Author(s):  
Xiu Chen ◽  
Yin Nan Yuan ◽  
Yong Bin Lai
Keyword(s):  
Chemical Composition ◽  
Methyl Esters ◽  
Gas Chromatography Mass Spectrometry ◽  
Waste Oil ◽  
Compression Ignition Engine ◽  
Yield Information ◽  
Composition And Structure ◽  
Similar Chemical ◽  
Ignition Quality ◽  
Long Chain

Thermogravimetry (TG) has been employed to yield information on the thermal volatilization of the fuels since the volatility influences the ignition quality of the fuels in a compression ignition engine. The chemical composition of -10 petrodiesel (-10PD) and waste oil biodiesel (WME) was analyzed by gas chromatography-mass spectrometry. The thermal volatilization of biodiesel and its blends was investigated by TG and liquid volatile theory. Volatile index was put forward for describing biodiesel/petrodisel volatility. A good correlation model was proposed for calculate the biodiesel/petrodiesel volatility by biodiesel blending ratio. The study showed that -10PD and WME had similar chemical composition and structure. -10PD was mainly composed of long chain alkanes: C8–C26. WME was mainly composed of long chain fatty acid methyl esters: C14:0–C22:0, C16:1–C22:1, C18:2 and C18:3. The volatile indexes of WME and -10PD were 1.47E-04 and 3.64E-05, respectively. The biodiesel was considerably more volatile in comparison to the petrodiesel. The WME/-10PD volatility was better with increasing the biodiesel blending ratio.

scholarly journals The impact of acid mine drainage (AMD) on the distribution of selected radionuclides in the sediments of two pit lakes in the Muskau Arch (western Poland)

2021 ◽  
Author(s):  
Ilona Sekudewicz ◽  
Michał Gąsiorowski ◽  
Šárka Matoušková ◽  
Jan Rohovec ◽  
Karolina Kaucha
Keyword(s):  
Acid Mine Drainage ◽  
Mine Drainage ◽  
Acid Mine ◽  
Pit Lakes ◽  
The Impact

scholarly journals Mineralization of rare metals in the lakes of East Kazakhstan

2020 ◽  
pp. 16-21
Author(s):  
B. B Amralinova ◽  
O. V Frolova ◽  
I. E Mataibaeva ◽  
B. B Agaliyeva ◽  
S. V Khromykh
Keyword(s):  
Chemical Composition ◽  
Inductively Coupled Plasma ◽  
Digital Terrain Model ◽  
Rare Metal ◽  
Rare Metals ◽  
Inductively Coupled ◽  
Terrain Model ◽  
Digital Terrain ◽  
East Kazakhstan ◽  
Lake Waters

Purpose. Study on the chemical composition of lake waters, salt brines, brine and bottom sediments to identify the mineralization of rare metals and other types of minerals. Methodology. Mass spectrometric studies (mass spectrometer with inductively coupled plasma ICP-MS 7500cx from AgilentTechnologies) for the purpose of high-precision analytical studies on the chemical composition of salt lake water in order to assess the content of rare elements. The use of unmanned aerial vehicles for linking and geometrizing lakes. Findings. Field surveys on the geometrization and linking of lakes were carried out. From the materials obtained with the help of the drone, orthophotoplans were created (with a measurement accuracy of up to 1 centimeter), as well as a digital terrain model and a digital terrain model. A complex of analytical works was carried out using inductively coupled plasma spectrometry. When analyzing the distribution graphs of the absolute content of micro-components in the waters of the lakes of the Delbegeteysky massif, it was found that all samples were enriched with sodium, phosphorus, iron, magnesium and barium. The results of the analyses revealed the predominance of sulfates and chlorides in the composition of the surface waters of most of the water bodies of the Delbegeteysky massif. At the Burabai site, lake waters are characterized by an alkaline reaction of the environment (on average = 8.71). At the same time, the salinity of water bodies varies from 05 to 9 g/dm3. Originality. Large-scale outcrops of granites of the Kalba complex (P1), with which a rare-metal type of mineralization is genetically associated, are known to be on the selected study sites. Quartz-wire-greisen and quartz-wire tin, tin-tungsten and tungsten formations are also widely developed. Considering the large geochemical migration ability of rare alkaline elements in the thickness of loose sediments as a result of intensive geodynamic processes in the East Kazakhstan region, it is possible to assume the possibility of their migration to the upper horizons and accumulation in salt lakes localized within the area of development of granite intrusions of Permian age and associated deep tectonic faults. Practical value. The results of the research can serve as a revival of the rare metal industry in the region, which will allow developing new high-tech industries and creating new jobs in this area. The obtained results can be used for setting up further exploration and operational work on the selected promising areas.

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