Mechanical and thermal properties of polymer micro- and nanocomposites

2011 ◽  
Vol 31 (2-3) ◽  
Author(s):  
Stephan J. Picken ◽  
Alexander V. Korobko ◽  
Eduardo Mendes ◽  
Ben Norder ◽  
Veronika V. Makarova ◽  
...  

Abstract We have analyzed the thermal conductivity and the tensile modulus of composite materials within the framework of the Halpin-Tsai and Lewis-Nielsen models. The parameter linking thermal conductivity and tensile modulus together is the shape factor of the (nano)filler. Model analysis based on experimental data shows that particle aggregation into a weak mechanical network may be required to achieve good correlation between thermal conductivity and the Young’s modulus when analyzing the data within the framework of a single model and requiring the same value of the shape factor. We believe this approach will make quantitative analysis of nanocomposite thermal properties possible.

2013 ◽  
Vol 1510 ◽  
Author(s):  
Selina Mala ◽  
Leonid Tsybeskov ◽  
Jean-Marc Baribeau ◽  
Xiaohua Wu ◽  
David J. Lockwood

ABSTRACTWe present comprehensive quantitative analysis of Raman spectra in two-(Si/SiGe superlattices) and three-(Si/SiGe cluster multilayers) dimensional nanostructures. We find that the Raman spectra baseline is due to the sample surface imperfection and instrumental response associated with the stray light. The Raman signal intensity is analyzed, and Ge composition is calculated and compared with the experimental data. The local sample temperature and thermal conductivity are calculated, and the spectrum of longitudinal acoustic phonons is explained.


2021 ◽  
Vol 320 ◽  
pp. 181-185
Author(s):  
Elvija Namsone ◽  
Genadijs Sahmenko ◽  
Irina Shvetsova ◽  
Aleksandrs Korjakins

Because of low calcination temperature, magnesia binders are attributed as low-CO2 emission materials that can benefit the environment by reducing the energy consumption of building sector. Portland cement in different areas of construction can be replaced by magnesia binder which do not require autoclave treatment for hardening, it has low thermal conductivity and high strength properties. Magnesium-based materials are characterized by decorativeness and ecological compatibility.The experimental part of this research is based on the preparation of magnesia binders by adding raw materials and calcinated products and caustic magnesia. The aim of this study was to obtain low-CO2 emission and eco-friendly material using local dolomite waste materials, comparing physical, mechanical, thermal properties of magnesium binders.


BioResources ◽  
2020 ◽  
Vol 15 (3) ◽  
pp. 6080-6094
Author(s):  
Muhammed Said Fidan ◽  
Murat Ertaş

The procedure for the liquefaction of apricot stone shells was reported in Part 1. Part 2 of this work determines the morphological, mechanical, and thermal properties of the bio-based rigid polyurethane foam composites (RPUFc). In this study, the thermal conductivity, compressive strength, compressive modulus, thermogravimetric analysis, flammability tests (horizontal burning and limited oxygen index (LOI)) in the flame retardants), and scanning electron microscope (SEM) (cell diameter in the SEM) tests of the RPUFc were performed and compared with control samples. The results showed the thermal conductivity (0.0342 to 0.0362 mW/mK), compressive strength (10.5 to 14.9 kPa), compressive modulus (179.9 to 180.3 kPa), decomposition and residue in the thermogravimetric analysis (230 to 491 °C, 15.31 to 21.61%), UL-94 and LOI in the flame retardants (539.5 to 591.1 mm/min, 17.8 to 18.5%), and cell diameter in the SEM (50.6 to 347.5 μm) of RPUFc attained from liquefied biomass. The results were similar to those of foams obtained from industrial RPUFs, and demonstrated that bio-based RPUFc obtained from liquefied apricot stone shells could be used as a reinforcement filler in the preparation of RPUFs, specifically in construction and insulation materials. Moreover, liquefied apricot stone shell products have potential to be fabricated into rigid polyurethane foam composites.


Author(s):  
Mazhar Hussain ◽  
Daniel Levacher ◽  
Nathalie Leblanc ◽  
Hafida Zmamou ◽  
Irini Djeran Maigre ◽  
...  

Crude bricks are composite materials manufactured with sediments and natural fibers. Natural fibers are waste materials and used in construction materials for reinforcement. Their reuse in manufacturing reinforced crude bricks is eco-friendly and improves mechanical and thermal characteristics of crude bricks. Factors such as type of fibers, percentage of fibers, length of fibers and distribution of fibers inside the bricks have significant effect on mechanical, physical and thermal properties of biobased composite materials. It can be observed by tests such as indirect tensile strength, compressive strength for mechanical characteristics, density, shrinkage, color for physical properties, thermal conductivity and resistivity for thermal properties, and inundation test for durability of crude bricks. In this study, mechanical and physical characteristics of crude bricks reinforced with palm oil fibers are investigated and effect of change in percentage and length of fibers is observed. Crude bricks of size 4*4*16 cm3 are manufactured with dredged sediments from Usumacinta River, Mexico and reinforced with palm oil fibers at laboratory scale. For this purpose, sediments and palm oil fibers characteristics were studied. Length of fibers used is 2cm and 3cm. Bricks manufacturing steps such as sediments fibers mixing, moulding, compaction and drying are elaborated. Dynamic compaction is opted for compaction of crude bricks due to energy control. Indirect tensile strength and compressive strength tests are conducted to identify the mechanical characteristics of crude bricks. Physical properties of bricks are studied through density and shrinkage. Durability of crude bricks is observed with inundation test. Thermal properties are studied with thermal conductivity and resistivity test. Distribution and orientation of fibers and fibers counting are done to observe the homogeneity of fibers inside the crude bricks. Finally, comparison between the mechanical characteristics of crude bricks manufactured with 2cm and 3cm length with control specimen was made.


2018 ◽  
Vol 149 ◽  
pp. 01076
Author(s):  
Guendouz Mohamed ◽  
Boukhelkhal Djamila

Over the past twenty years, the rubber wastes are an important part of municipal solid waste. This work focuses on the recycling of rubber waste, specifically rubber waste of used shoes discharged into the nature and added in the mass of crushed sand concrete with percentage (10%, 20%, 30% and 40%). The physical (workability, fresh density), mechanical (compressive and flexural strength) and thermal (thermal conductivity) of different crushed sand concrete made are analyzed and compared to the respective controls. The use of rubber waste in crushed sand concrete contributes to reduce the bulk density and performance of sand concrete. Nevertheless, the use of rubber aggregate leads to a significant reduction in thermal conductivity, which improves the thermal insulation of crushed sand concrete.


Author(s):  
Yuanxin Zhou ◽  
Mohammad Monirul Hasan ◽  
Shaik Jeelani

In the present study, effect of vapor grown carbon nanofiber on the mechanical and thermal properties of polypropylene was investigated. Firstly, nanofibers were dry-mixed with polypropylene powder and extruded into filaments by using a single screw extruder. Then the tensile tests were performed on the single filament at the strain rate range from 0.02/min to 2/min. Experiments results show that both neat and nano-phased polypropylene were strain rate strengthening material. The tensile modulus and yield strength both increased with increasing strain rate. Experimental results also show that infusing nanofiber into polypropylene can increase tensile modulus and yield strength, but decrease the failure strain. At the same time, thermal properties of neat and nano-phased polypropylene were characterized by TGA. TGA results have showed that the nanophased system is more thermally stable. At last, a nonlinear constitutive equation has been developed to describe strain rate sensitive behavior of neat and nano-phased polypropylene.


Author(s):  
Gurminder Singh ◽  
Pulak M Pandey

In the present paper, mechanical and thermal properties of rapidly manufactured copper parts were studied. The combination of three-dimensional printing and ultrasonic assisted pressureless sintering was used to fabricate copper parts. First, the ultimate tensile strength and thermal conductivity were compared between ultrasonic assisted and conventional pressureless sintered samples. The homogenously mixing of particles and local heat generation by ultrasonic vibrations promoted the sintering driving process and resulted in better mechanical and thermal properties. Furthermore, response surface methodology was adopted for the comprehensive study of the ultrasonic sintering parameters (sintering temperature, heating rate, and soaking time with ultrasonic vibrations) on ultimate tensile strength and thermal conductivity of the fabricated sample. Analysis of variance was performed to identify the significant factors and interactions. The image processing method was used to identify the surface porosity at different parameter levels to analyse the experimental results. High ultimate tensile strength was obtained at high sintering temperature, long soaking time, and slow heating rate with low surface porosity. After 60 min of soaking time, no significant effect was observed on the thermal conductivity of the fabricated sample. The significant interactions revealed less effect of soaking time at low sintering temperatures for ultimate tensile strength and less effect of heating rate at low sintering temperatures for thermal conductivity. Multi-objective optimization was carried out to identify parameters for maximum ultimate tensile strength and maximum thermal conductivity.


2020 ◽  
Vol 8 (16) ◽  
pp. 5380-5388
Author(s):  
Chao Liu ◽  
Wei Wu ◽  
Dietmar Drummer ◽  
Wanting Shen ◽  
Yi Wang ◽  
...  

The needle-like Al2O3–ZnO nanowire hybrid filler endows polymer composites with high thermal conductivity, mechanical and thermal properties.


Author(s):  
Ashok K. Ahirwar ◽  
Mahendra Aynyas ◽  
Sankar P. Sanyal

The crystal structural, mechanical and thermal properties of UXLa1-XS compound with different concentrations (x= 0.00, 0.08 and 0.40) are investigated using modified inter-ionic potential theory (MIPT), which parametrically includes the effect of coulomb screening by the delocalized f-electrons. Our calculated values of phase transition pressure, bulk modulus and volume change are agree well with the theoretical and experimental data. We have also calculated the second order elastic constants and Debye temperature of these three concentrations.


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