The Effect of Grain Boundaries and Second-Phase Particles on Hydride Precipitation in Zirconium Alloys

MRS Advances ◽  
2018 ◽  
Vol 3 (31) ◽  
pp. 1749-1754 ◽  
Author(s):  
Said El Chamaa ◽  
Mitesh Patel ◽  
Catrin M. Davies ◽  
Mark R. Wenman
Keyword(s):  
Grain Size ◽  
Grain Boundaries ◽  
Zirconium Alloys ◽  
Second Phase ◽  
Distribution Profile ◽  
Grain Sizes ◽  
Hydride Precipitation ◽  
Nucleation Sites ◽  
Wide Range ◽  
Pure Zirconium

ABSTRACTUnderstanding the precipitation of brittle hydride phases is crucial in establishing a failure criterion for various zirconium alloy nuclear fuel cladding. Accordingly, it is important to quantify the sensitivity of hydride precipitation to the component microstructure. This experimental investigation focuses on two microstructural characteristics and their role as hydride nucleation sites: The grain size and the alloy chemical composition. Samples of commercially pure zirconium (Zr-702) and Zircaloy-4, each with a wide range of grain sizes, were hydrided to 100 ppm and micrographs of the hydride distribution were optically analyzed for inter-granular and intra-granular precipitate sites. For most grain sizes, it was found that a significantly lower fraction of the precipitated hydrides nucleated at grain boundaries in Zircaloy-4 than in Zr-702, suggesting that a higher SPP content encourages the formation of intra-granular hydrides. Moreover, this effect became more prominent as the grain size increased; large-grain specimens contained a higher fraction of intra-granular hydrides than small-grain specimens of both Zr-702 and Zircaloy-4, highlighting the potency of grain boundaries as nucleation sites and how SPPs can influence the hydride distribution profile.

The Processing of Ultrafine-Grained Materials Using High-Pressure Torsion

2007 ◽  
Vol 558-559 ◽  
pp. 1283-1294 ◽  
Author(s):  
Cheng Xu ◽  
Z. Horita ◽  
Terence G. Langdon
Keyword(s):  
Plastic Deformation ◽  
Grain Size ◽  
High Pressure ◽  
High Pressure Torsion ◽  
Metallic Materials ◽  
Grain Sizes ◽  
Ultrafine Grained ◽  
Wide Range ◽  
Ultrafine Grained Materials ◽  
Thin Disks

It is now well-established that processing through the application of severe plastic deformation (SPD) leads to a significant reduction in the grain size of a wide range of metallic materials. This paper examines the fabrication of ultrafine-grained materials using high-pressure torsion (HPT) where this process is attractive because it leads to exceptional grain refinement with grain sizes that often lie in the nanometer or submicrometer ranges. Two aspects of HPT are examined. First, processing by HPT is usually confined to samples in the form of very thin disks but recent experiments demonstrate the potential for extending HPT also to bulk samples. Second, since the strains imposed in HPT vary with the distance from the center of the disk, it is important to examine the development of inhomogeneities in disk samples processed by HPT.

Grain Subdivision Fission Gas Swelling Model for UO2

MRS Advances ◽  
2016 ◽  
Vol 1 (35) ◽  
pp. 2465-2470
Author(s):  
Thomas Winter ◽  
Richard Hoffman ◽  
Chaitanya S. Deo
Keyword(s):  
Grain Size ◽  
Grain Boundaries ◽  
Gas Diffusion ◽  
Fine Grain ◽  
Fuel Pellets ◽  
Model And Simulation ◽  
Nucleation Sites ◽  
Fission Gas ◽  
High Burnup ◽  
Swelling Model

ABSTRACTUnder high burnup UO2 fuel pellets can experience high burnup structure (HBS) at the rim also known as rim effect. The HBS is exceptionally porous with fine grain sizes. HBS increases the swelling further than it would have achieved at a larger grain size. A theoretical swelling model is used in conjunction with a grain subdivision simulation to calculate the swelling of UO2. In UO2 the nucleation sites are at vacancies and the bubbles are concentrated at grain boundaries. Vacancies are created due to irradiation and gas diffusion is dependent on vacancy migration. In addition to intragranular bubbles, there are intergranular bubbles at the grain boundaries. Over time as intragranular bubbles and gas atoms accumulate on the grain boundaries, the intergranular bubbles grow and cover the grain faces. Eventually they grow into voids and interconnect along the grain boundaries, which can lead to fission gas release when the interconnection reaches the surface. This is known as the saturation point. While the swelling model used does not originally incorporate a changing grain size, the simulation allows for more accurate swelling calculations by introducing a fractional HBS based on the temperature and burnup of the pellet. The fractional HBS is introduced with a varying grain size. Our simulations determine the level of swelling and saturation as a function of burnup by combining an independent model and simulation to obtain a more comprehensive model.

scholarly journals Effect of Grain Size on Carburization Characteristics of the High-Entropy Equiatomic CoCrFeMnNi Alloy

Materials ◽  
2021 ◽  
Vol 14 (23) ◽  
pp. 7199
Author(s):  
Hyunbin Nam ◽  
Jeongwon Kim ◽  
Namkyu Kim ◽  
Sangwoo Song ◽  
Youngsang Na ◽  
...  
Keyword(s):  
Grain Size ◽  
Grain Boundaries ◽  
Face Centered Cubic ◽  
High Entropy ◽  
Grain Sizes ◽  
Fine Grain ◽  
Cast Specimen ◽  
Vacuum Carburization ◽  
Cold Rolled ◽  
Face Centered

In this study, the carburization characteristics of cast and cold-rolled CoCrFeMnNi high-entropy alloys (HEAs) with various grain sizes were investigated. All specimens were prepared by vacuum carburization at 940 °C for 8 h. The carburized/diffused layer was mainly composed of face-centered cubic structures and Cr7C3 carbide precipitates. The carburized/diffused layer of the cold-rolled specimen with a fine grain size (~1 μm) was thicker (~400 μm) than that of the carburized cast specimen (~200 μm) with a coarse grain size (~1.1 mm). In all specimens, the carbides were formed primarily through grain boundaries, and their distribution varied with the grain sizes of the specimens. However, the carbide precipitates of the cast specimen were formed primarily at the grain boundaries and were unequally distributed in the specific grains. Owing to the non-uniform formation of carbides in the carburized cast specimen, the areas in the diffused layer exhibited various carbide densities and hardness distributions. Therefore, to improve the carburization efficiency of equiatomic CoCrFeMnNi HEAs, it is necessary to refine the grain sizes.

Simulation of the interaction of plastic zone dislocations with the grain boundary at brittle-plastic transition temperatures in molybdenum

2021 ◽  
Vol 2021 (3) ◽  
pp. 77-85
Author(s):  
K. M. Borysovska ◽  
◽  
N. M. Marchenko ◽  
Yu. M. Podrezov ◽  
S. O. Firstov ◽  
...  
Keyword(s):  
Fracture Toughness ◽  
Grain Size ◽  
Grain Boundary ◽  
Plastic Zone ◽  
Grain Boundaries ◽  
Crack Tip ◽  
Dynamics Simulation ◽  
Density Of Dislocations ◽  
Grain Sizes ◽  
Pile Up

The (DD) method was used to model the formation of the plastic zone of the top of the cracks in polycrystalline molybdenum. Special attention was paid to take into account the interaction of dislocations in the plastic zone with grain boundaries. Structural sensitivity of fracture toughness was analyzed under brittle-ductile condition. Simulations were performed for a range of grain sizes from 400 to 100 μm, at which a sudden increase in fracture toughness with a decrease of grain size was experimentally shown. We calculated the value of K1c taking into account the shielding action of dislocations. The position of all dislocations in the plastic zone at fracture moment was calculated. Based on these data, we obtained the dependences of dislocation density on the distance from the crack tip thereby confirming significant influence of the grain boundaries on plastic zone formation. At large grain sizes, when the plastic zone does not touch the boundary, the distribution of dislocations remained unchanged. As grains reduce their size to size of the plastic zone, they start formating a dislocation pile – up near the boundaries. Dislocations on plastic zone move slightly toward the crack tip, but the density of dislocations in the middle of the grain remains unchanged, and fracture toughness remains almost unchanged. Further reduction of the grain size leads to the Frank-Reed source activation on the grain boundary Forming dislocation pile-up of the neighbor grains. Its stress concentration acts on dislocations of the first grain and causes redistribution of plastic zone dislocations. If the reduction in grain size is not enough to form a strong pile-up, density of dislocations on plastic zone increases slightly and crack resistance increases a few percent. Further reduction of grains promotes strong pile-up, dislocations move to crack tip, and its density on plastic zone increases. Crack is shielded and fracture toughness increases sharply. The calculation showed that the fracture toughness jump is observed at grain sizes of 100—150 μm, in good agreement with the experiment. Keywords: dislocation dynamics simulation, molybdenum, fracture toughness, grain size, plastic zone, brittle-ductile transition.

Effect of surface area of grain boundaries on stress relaxation behavior in pure copper over wide range of grain sizes

2020 ◽  
Vol 794 ◽  
pp. 139585
Author(s):  
Yurina Suzuki ◽  
Kota Ueno ◽  
Kodai Murasawa ◽  
Yoshinori Kusuda ◽  
Masato Takamura ◽  
...  
Keyword(s):  
Stress Relaxation ◽  
Grain Boundaries ◽  
Surface Area ◽  
Pure Copper ◽  
Relaxation Behavior ◽  
Stress Relaxation Behavior ◽  
Grain Sizes ◽  
Wide Range ◽  
Effect Of Surface

Environmental magnetism as a stream sediment tracer: an interpretation of the methodology and some case studies

Soil Research ◽  
1998 ◽  
Vol 36 (1) ◽  
pp. 167 ◽  
Author(s):  
R. H. Crockford ◽  
P. M. Fleming
Keyword(s):  
Grain Size ◽  
Case Studies ◽  
Environmental Magnetism ◽  
Extensive Discussion ◽  
Remanent Magnetisation ◽  
Grain Sizes ◽  
South Wales ◽  
Wide Range ◽  
River Confluences ◽  
The Difference

A comprehensive sediment sampling program was undertaken in the upper Molonglo catchment in south-eastern New South Wales to determine if mineral magnetics could be used to estimate sidestream contribution at river confluences in this environment. Some 12 confluences were examined over 1400 km 2 in 2 major basins and over 2 contrasting geological types. Sediment samples were divided into 7 size classes and the following magnetic properties measured: magnetic susceptibility at 2 frequencies, isothermal remanent magnetisation at 3 flux densities, and anhysteristic remanent magnetisation. The sidestream inputs were calculated for each particle size class from the range of magnetic parameters. Significant discrepancies and differences appeared in the resultant sidestream inputs, and this paper outlines the conclusions as to the reliability of the different analytical procedures. It is shown that both the concentration and magnetic grain size of ferrimagnetic minerals in the sediments must be taken into account. Where the difference in magnetic grain size between the upstream and sidestream sediments is small, the use of parameter crossplots or bulked magnetic ratios is generally not appropriate. The use of mass (concentration) magnetic values may be better. The difference in the demands of the crossplots and mass values methods is that crossplots require a wide range of mass magnetic concentrations in each branch, with the upstream and sidestream sediments having different magnetic grain sizes, whereas the mass values procedure does best with a very limited (but different) range of concentrations at the upstream and sidestream branches, but similar magnetic grain sizes. This paper provides an extensive discussion of the estimation technique using different parameter combinations, and uses 3 contrasting confluences as case studies.

Polycrystalline Si Films Fabricated by Low Temperature Selective Nucleation and Solid Phase Epitaxy Process

1997 ◽  
Vol 485 ◽  
Author(s):  
Claudine M. Chen ◽  
Harry A. Atwater
Keyword(s):  
Thin Film ◽  
Grain Size ◽  
Crystal Growth ◽  
Incubation Time ◽  
Solid Phase ◽  
Solid Phase Epitaxy ◽  
Grain Sizes ◽  
Random Nucleation ◽  
Nucleation Sites ◽  
Si Films

AbstractWith a selective nucleation and solid phase epitaxy (SNSPE) process, grain sizes of 10 μm have been achieved to date at 620°C in 100 nrm thick silicon films on amorphous SiO2, with potential for greater grain sizes. Selective nucleation occurs via a thin film reaction between a patterned array of 20 rnm thick indium islands which act as heterogeneous nucleation sites on the amorphous silicon starting material. Crystal growth proceeds by lateral solid phase epitaxy from the nucleation sites, during the incubation time for random nucleation. The largest achievable grain size by SNSPE is thus approximately the product of the incubation time and the solid phase epitaxy rate. Electronic dopants, such as B, P, and Al, are found to enhance the solid phase epitaxy rate and affect the nucleation rate.

Kinetics of the C49 TO C54 Phase Transformation in TiSi2 thin Films on Deep-Sub-Micron Lines

1995 ◽  
Vol 402 ◽  
Author(s):  
J. A. Kittl ◽  
D. A. Prinslow ◽  
P. P Apte ◽  
M. F. Pas
Keyword(s):  
Thin Films ◽  
Grain Size ◽  
Phase Transformation ◽  
Full Time ◽  
Two Dimensional ◽  
One Dimensional ◽  
Grain Sizes ◽  
Nucleation Sites ◽  
Dimensional Growth ◽  
Kinetics Of

AbstractThe kinetics of the TiSi2 C49 to C54 phase transformation in thin films on patterned deepsub- micron lines, were studied to obtain the full time, temperature and linewidth dependence of the fraction transformed during rapid thermal annealing. A Johnson-Mehl-Avrami kinetic analysis was performed, obtaining Avrami exponents of 0.8±0.2 for all sub-micron lines and 1. 9±0.2 for a 40 μm side square structure, indicating heterogeneous nucleation followed by one dimensional growth for the narrow lines, and two dimensional growth for the square structure. The activation energy, of 3.9 eV, was independent of linewidth in the sub-micron range. Transformation times increased dramatically for decreasing linewidth, as the linewidth approached the grain size of the starting C49 phase. A kinetic model based on the density of nucleation sites as a function of linewidth and C49 grain size is proposed and shown to fit the data, for samples with two different C49 grain sizes.

High-resolution TEM and analytical study of second-phase particles in Al2O3

1983 ◽  
Vol 41 ◽  
pp. 46-47
Author(s):  
K. J. Morrissey ◽  
Y. Kouh ◽  
C. B. Carter
Keyword(s):  
Grain Size ◽  
High Resolution ◽  
Grain Boundaries ◽  
Hot Pressing ◽  
Analytical Study ◽  
Second Phase ◽  
Initial Powder ◽  
Compact Density ◽  
Second Phase Particles ◽  
High Resolution Tem

The influence of additives such as MgO, NiO, and ZrO2 and impurities such as Na, K, and Ca on the sintering of alumina compacts has been the focus of a considerable amount of research. Since these additives affect compact density and grain size it is of interest to determine the behavior of the elements during processing. That is, it is important to know whether Ca and Mg segregate to grain boundaries or are located in the second-phase particles. Current results suggest that Ca is found uniformly at the grain boundaries and that Mg is accommodated in the second-phase particles.The present investigation is concerned with identifying second-phase particles in different commercially-produced Al2O3 compacts and studying both their structure and composition. Preliminary results have been discussed previously. The investigation has dealt mainly with two different alumina compacts. One compact was prepared from an initial powder containing 0.25% MgO, a small amount of intentionally added Ni, and was prepared by hot pressing.

Effect of Low-Temperature Aging on Thermally-Induced Phase Transformation of NiTi Wire with a Wide Range of Grain Sizes

2021 ◽  
Vol 1042 ◽  
pp. 9-16
Author(s):  
Zhi Hao Zhao ◽  
Jian Ping Lin ◽  
Jun Ying Min ◽  
Yong Hou ◽  
Bo Sun
Keyword(s):  
Grain Size ◽  
Phase Transformation ◽  
Low Temperature ◽  
Thermally Induced ◽  
Grain Sizes ◽  
Average Grain Size ◽  
Wide Range ◽  
Low Temperature Aging ◽  
Niti Wires ◽  
Temperature Aging

Thermally-induced phase transformation (PT) is of significance and value to the application of NiTi alloy components. Low-temperature aging (LTA) treatment was used to alter PT characteristics of NiTi alloys avoiding undesirable grain growth. Effect of LTA on PT of NiTi wires with a wide range of grain sizes from 34 nm to 8021 nm was investigated in this study. As the average grain size varies from 34 to 217 nm, the temperature of the B2↔R transformation increase as a result of LTA, and the increasing effect is more obvious at a larger grain size. For NiTi alloys with average grain sizes ranging from 523 to 1106 nm, transformation sequence changes from B2↔B19' to B2↔R due to LTA. For the sample with an average grain size of 2190 nm, the B2↔B19' transformation is replaced by B2↔R←B19' after LTA. When the average grain size is larger than 2190 nm, transformation sequence changes from B2↔B19' to B2↔R↔B19' after LTA. Transmission emission microscope observations reveal that the above-mentioned PT behavior correlates with the coupled effect of grain size and precipitation. The precipitation of Ni4Ti3 in the grains with a size smaller than ~150 nm is inhibited after LTA, the temperature of B2→R of samples with average GS smaller than ~150 nm still is elevated due to the inhomogeneous grain size of NiTi wires.

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