Investigation of Wide Bandgap Semiconductors for Thermoelectric Applications

2013 ◽  
Vol 1490 ◽  
pp. 161-166 ◽  
Author(s):  
B. Kucukgok ◽  
Q. He ◽  
A. Carlson ◽  
A. G. Melton ◽  
I. T. Ferguson ◽  
...  

ABSTRACTThermoelectric materials with stable mechanical and chemical properties at high temperature are required for power generation applications. For example, gas temperatures up to 1000°C are normally present in the waste stream of industrial processes and this can be used for electricity generation. There are few semiconductor materials that can operate effectively at these high temperatures. One solution may be the use of wide bandgap materials, and in particular GaN-based materials, which may offer a traditional semiconductor solution for high temperatures thermoelectric power generation. In particular, the ability to both grow GaN-based materials and fabricate them into devices is well understood if their thermoelectric properties are favorable. To investigate the possibility of using III-Nitride and its alloys for thermoelectric applications, we synthesized and characterized room temperature thermoelectric properties of metal organic chemical vapor deposition grown GaN and InGaN with different carrier concentrations and indium compositions. The promising value of Seebeck coefficients and power factors of Si-doped GaN and InGaN indicated that these materials are suitable for thermoelectric applications.

2018 ◽  
Vol 12 (2) ◽  
pp. 175-178
Author(s):  
Shinichi Shikata ◽  

To achieve a 50% worldwide reduction of CO2by the middle of this century, development of energy saving power device technology using wide bandgap materials is urgently needed. Diamond is receiving increasing attention as a next generation material for wide bandgap semiconductors owing to its extreme characteristics. Research studies investigating large wafers, low resistivity, and low dislocation have accelerated. This study targets the use of wafers for power electronics applications, and the required machining technologies for diamond, including wafer shaping, slicing, and surface finishing, are introduced.


2020 ◽  
Vol 161 ◽  
pp. 01107
Author(s):  
A V Solomnikova ◽  
V. A. Lukashkin ◽  
O V Derevianko

To improve the performance characteristics of power and high-frequency electronics, wide bandgap semiconductors are now widely used. This paper presents consideration of features arising during exploration of electronic characteristics of wide bandgap materials. We use the admittance spectroscopy method for analyzing free carrier concentration and boron-impurity activation energy in semiconductor diamond. The special aspect that should be taken into account while studying wide bandgap materials is incomplete ionization of impurity. In this work we adjust the experimental conditions, basing on the previous experience, in particular reduce signal/noise ratio and reckon with heat capacity of the samples and substrate. As a result we obtained high quality conductance spectra and activation energy of boron impurity in low-doped diamond.


2010 ◽  
Vol 97 (11) ◽  
pp. 112105 ◽  
Author(s):  
Hua Tong ◽  
Jing Zhang ◽  
Guangyu Liu ◽  
Juan A. Herbsommer ◽  
G. S. Huang ◽  
...  

2006 ◽  
Vol 16 (02) ◽  
pp. 515-543
Author(s):  
MATTHEW H. KANE ◽  
MARTIN STRASSBURG ◽  
WILLIAM E. FENWICK ◽  
ALI ASGHAR ◽  
IAN T. FERGUSON

Wide-bandgap dilute magnetic semiconductors (DMS), such as transition-metal doped ZnO and GaN , have gained attention for use in spintronic devices because of predictions and experimental reports of room temperature ferromagnetism which may enable their use in spintronic devices. However, there has been some debate over the source of ferromagnetism in these materials. This paper focuses on the high quality growth of wide bandgap DMS, and the characterization of Zn 1-x Mn x O produced by melt-growth techniques and Ga 1-x Mn x N grown by metal organic chemical vapor deposition (MOCVD). High resolution X-ray diffraction results revealed no second phases in either the ZnO crystals or the GaN films. Undoped as-grown, bulk crystals of Zn 1-x Mn x O and Zn 1-x Co x O crystals are shown to be paramagnetic at all temperatures. In contrast, the Ga 1-x Mn x N films showed ferromagnetic behavior at room temperature under optimum growth conditions. Experimental identification of the Mn ion charge state and the presence of bands in the bandgap of GaN are investigated by optical spectroscopy and electron spin paramagnetic resonance (EPR). It is shown that the broadening of states in the Mn 3d shell scaled with Mn concentration, and that optical transitions due to this band correlated with the strong ferromagnetism in these samples. However, this band disappeared with an increase in free electron concentration provided by either annealing or doping. Raman studies of Ga 1-x Mn x N revealed two predominant Mn -related modes featured with increasing concentration, a broad disorder related structure at 300cm-1 and a sharper peak at 669cm-1 This works show that the development of practical ferromagnetic wide bandgap DMS materials for spintronic applications will require both the lattice site introduction of Mn as well as careful control of the background defect concentration to optimize these materials.


2009 ◽  
Vol 1166 ◽  
Author(s):  
Harald Böttner

AbstractA survey of state of the art of the development of high temperature materials is presented and will be discussed in comparison to the situation in the 1990th. An attempt will be made to assess the state of the art of the materials thermoelectric properties, their technical level, and possible potential for standardized device technology. Also a first assessment based on current commodity prices for some important thermoelectric compounds will be made. As a roundup advantages and drawbacks for some classical and upcoming compounds will be given. The main challenges, which will have to be overcome to finally enable thermoelectric power generation as a recycling technology of “nomadic” energy, will be summarized. As a result, thermoelectrics should play an important role in the field of green energies.


2015 ◽  
Vol 64 (4) ◽  
pp. 047202
Author(s):  
Wang Bao-Zhu ◽  
Zhang Xiu-Qing ◽  
Zhang Ao-Di ◽  
Zhou Xiao-Ran ◽  
Bahadir Kucukgok ◽  
...  

2021 ◽  
Vol 59 (7) ◽  
pp. 505-513
Author(s):  
Zahid Hussain ◽  
Hye-Won Yang ◽  
Byung-Sang Choi

A three-dimensionally interconnected hexagonal boron nitride (3Di-hBN) networked Cu-Ni (3DihBN-Cu-Ni) composite was successfully synthesized in situ using a simple two-step process which involved the compaction of mixed Cu-Ni powders (70 wt.% Cu and 30 wt.% Ni) into a disc followed by metal-organic chemical vapor deposition (MOCVD) at 1000 oC. During MOCVD, the Cu-Ni alloy grains acted as a template for the growth of hexagonal boron nitride (hBN) while decaborane and ammonia were used as precursors for boron and nitrogen, respectively. Boron and nitrogen atoms diffused into the Cu-Ni solution during the MOCVD process and precipitated out along the Cu-Ni interfaces upon cooling, resulting in the formation of the 3Di hBN-Cu-Ni composite. Energy-dispersive spectroscopic analysis confirmed the presence of boron and nitrogen atoms at the interfaces of Cu-Ni alloy grains. Optical microscopy examination indicated that there was a minimum amount of bulk hBN at a certain compaction pressure (280 MPa) and sintering time (30 min). Scanning electron microscopy and transmission electron microscopy revealed that an interconnected network of hBN layers surrounding the Cu-Ni grains developed in the 3Di-hBN-Cu-Ni composite. This 3Di-hBN network is expected to enhance the mechanical, thermal, and chemical properties of the 3Di-hBN-Cu-Ni composite. Moreover, the foam-like 3Di-hBN extracted from 3Di-hBN-Cu-Ni composite could have further applications in the fields of biomedicine and energy storage.


Author(s):  
E. McGlynn ◽  
M.O. Henry ◽  
J.-P. Mosnier

This article describes the growth, characterization and applications of zinc oxide (ZnO) wide-bandgap semiconductor nanostructures. It first introduces the reader to the basic physics and materials science of ZnO, with particular emphasis on the crystalline structure, electronic structure, optical properties and materials properties of ZnO wide-bandgap semiconductors. It then considers some of the commonly used growth methods for ZnO nanostructures, including vapor-phase transport, chemical vapor deposition, molecular beam epitaxy, pulsed-laser deposition, sputtering and chemical solution methods. It also presents the results of characterization of ZnO nanostructures before concluding with a discussion of some promising areas of application of ZnO nanostructures, such as field emission applications; electrical, optical/photonic applications; and applications in sensing, energy production, photochemistry, biology and engineering.


2011 ◽  
Vol 324 ◽  
pp. 46-51 ◽  
Author(s):  
Dominique Tournier ◽  
Pierre Brosselard ◽  
Christophe Raynaud ◽  
Mihai Lazar ◽  
Herve Morel ◽  
...  

Progress in semiconductor technologies have been so consequent these last years that theoretical limits of silicon, speci cally in the eld of high power, high voltage and high temperature have been achieved. At the same time, research on other semiconductors, and es- pecially wide bandgap semiconductors have allowed to fabricate various power devices reliable and performant enough to design high eciency level converters in order to match applications requirements. Among these wide bandgap materials, SiC is the most advanced from a techno- logical point of view: Schottky diodes are already commercially available since 2001, JFET and MOSFET will be versy soon. SiC-based switches Inverter eciency bene ts have been quite established. Considering GaN alternative technology, its driving force was mostly blue led for optical drive or lighting. Although the GaN developments mainly focused for the last decade on optoelectronics and radio frequency, their properties were recently explored to design devices suitable for high power and high eciency applications. As inferred from various studies, due to their superior material properties, diamond and GaN should be even better than SiC, silicon (or SOI) being already closed to its theoretical limits. Even if the diamond maturity is still far away from GaN and SiC, laboratory results are encouraging speci cally for very high voltage devices. Apart from packaging considerations, SiC, GaN and Diamond o ers a great margin of progress. The new power devices o er high voltage and low on-resistance that enable important reduction in energy consumption in nal applications. Applications for wide bandgap materials are the direction of high voltage but also high temperature. As for silicon technology, WBG-ICs are under development to take full bene ts of power and drive integration for high temperature applications.


Science ◽  
2021 ◽  
pp. eabi8668
Author(s):  
Bingchao Qin ◽  
Dongyang Wang ◽  
Xixi Liu ◽  
Yongxin Qin ◽  
Jin-Feng Dong ◽  
...  

Thermoelectric materials transfer heat and electrical energy, being useful for power generation or cooling applications. Many of these materials have narrow bandgaps, especially for cooling applications where this property has been seen as particularly important for enhancing the thermoelectric properties. We developed SnSe crystals with a wide bandgap Eg ~ 33 kBT with attractive thermoelectric properties through Pb alloying. The momentum and energy multiband alignment promoted by Pb alloying resulted in an ultra-high power factor ~75 μWcm–1K–2 at 300 K, and a ZTave ~ 1.90. We show that a 31-pair thermoelectric device can produce a power generation efficiency ~4.4% and a cooling ΔTmax ~ 45.7 K. These results demonstrate that wide bandgap compounds can be used for thermoelectric cooling applications.


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