On-site sodium metal production with electrolysis by offshore wind or solar cell power generation for hydrogen generation

2009 ◽  
Vol 1216 ◽  
Author(s):  
Masataka Murahara ◽  
Kazuichi Seki ◽  
Yuji Sato ◽  
Etsuo Fujiwara
Keyword(s):  
Power Generation ◽  
Solar Cell ◽  
Sodium Hydroxide ◽  
Hydrogen Generation ◽  
Raw Material ◽  
Offshore Wind ◽  
Hydrogen Storage Material ◽  
Metal Production ◽  
Sodium Metal ◽  
By Products

AbstractSodium metal reacts with water explosively to generate hydrogen. Therefore, sodium metal can have an important role as a hydrogen storage material. Seawater contains water most and sodium second. Seawater is electrolyzed by offshore wind or solar cell power generation to produce sodium; which is transported to a thermoelectric power plant on land and then is reacted with water to produce hydrogen for electric power generation. Sodium hydroxide, a by-product, is used as a raw material for soda industries. In the sodium production process, many by-products such as fresh water, magnesium, sodium hydroxide, hydrochloric acid, and sulfuric acid are produced. Thus, sodium metal is an economical, renewable, and sustainable fuel that discharges neither CO2 nor radioactivity.

Salt as Alternative Energy Material to Fossil Fuel

2013 ◽  
Vol 1492 ◽  
pp. 189-194
Author(s):  
Masataka Murahara ◽  
Yuji Sato ◽  
Toshio Okawara
Keyword(s):  
Power Generation ◽  
Sodium Hydroxide ◽  
Alternative Energy ◽  
Salt Lake ◽  
Economic Effect ◽  
Raw Material ◽  
Molten Salt Electrolysis ◽  
Sodium Metal ◽  
Energy Material ◽  
Production Of Hydrogen

ABSTRACTSalt is the raw material of sodium metal, which reacts with water to produce hydrogen for power generation. Sodium metal is solid matter and its specific gravity is low; therefore, it can be stored or transported for long at room temperature and under atmospheric pressure as oil and coal can. Sodium metal is produced with molten-salt electrolysis from sea salt, lake salt or rock salt, and securely kept immersed in kerosene for preventing it from reacting with air or moisture when transported to a consumer place; where it reacts violently with water to generate a large amount of hydrogen instantly. And sodium hydroxide, which is a reaction residue obtained after the production of hydrogen, is supplied as it is as the raw material of soda industries. Moreover, fresh water, sulfuric acid, hydrochloric acid, sodium hydroxide, and magnesium are generated as by-products in the processes of manufacturing sodium metal and generating hydrogen. Sodium metal can be an alternative energy material for hydrogen combustion power generation, having a far-reaching economic effect.

Sodium Hydride as Alternative Energy Having Hydrogen Absorption and Hydrogen Generation Functions and Hydrogen Fuel Cycle

2011 ◽  
Vol 1311 ◽  
Author(s):  
Masataka Murahara ◽  
Toshio Ohkawara
Keyword(s):  
Power Generation ◽  
Alternative Energy ◽  
Hydrogen Generation ◽  
Fuel Cycle ◽  
Raw Materials ◽  
Sodium Hydride ◽  
Hydrogen Fuel ◽  
Long Distance ◽  
Molten Salt Electrolysis ◽  
Sodium Metal

ABSTRACTHydrogen was converted to such a material as coal or oil with a low specific gravity so that it could be stored for a longer period and transported for a long distance at room temperature and under atmospheric pressure; which is sodium metal or sodium hydride. Sodium metal is produced with molten-salt electrolysis from seawater by wind power and transported to a thermoelectric power station in the consumption place for hydrogen-fueled combustion power generation. Sodium hydroxide, a waste, is re-electrolyzed to produce sodium for hydrogen generation; which constructs a hydrogen fuel cycle. This hydrogen fuel cycle is a clean, environmentally friendly recycle system that never requires repeated supply of raw materials in the same manner as the nuclear fuel cycle. Sodium or sodium hydride is an alternative energy.

Sodium Metal Production for Energy Storage from Warm Seawater Discharged at Nuclear Power Plant

2015 ◽  
Vol 1739 ◽  
Author(s):  
Masataka Murahara ◽  
Yuji Sato
Keyword(s):  
Power Plant ◽  
Nuclear Power Plant ◽  
Nuclear Power ◽  
Raw Material ◽  
Electric Power Station ◽  
Power Station ◽  
Metal Production ◽  
Molten Salt Electrolysis ◽  
Sodium Metal ◽  
Surplus Power

ABSTRACTThe storage and transportation barriers of hydrogen are cleared by sodium metal “Source of Hydrogen” produced from warm seawater discharged at the nuclear power plant. The warm seawater is electrolyzed to produce sodium hydroxide; which is then subjected to molten-salt electrolysis by surplus power of the plant to produce sodium metal “a hydrogen generator”. The seawater contains salt most after fresh water; which is the raw material of sodium metal and is never drained. The sodium metal is transported to the electric power station in a consumption place, where a large amount of hydrogen is generated immediately by adding water on the sodium metal for power generation. Salt, the raw material of sodium metal, is in the sea over the world, and it is not necessary to worry about the maldistribution and exhaustion.

Environmental benefits of magnesium hydroxide-based peroxide bleaching of mechanical pulp – mill results

TAPPI Journal ◽  
2013 ◽  
Vol 12 (6) ◽  
pp. 9-15 ◽  
Author(s):  
TOMI HIETANEN ◽  
JUHA TAMPER ◽  
KAJ BACKFOLK
Keyword(s):  
Sodium Hydroxide ◽  
Magnesium Hydroxide ◽  
Oxygen Demand ◽  
Pulp Mill ◽  
Transition Metal Ions ◽  
Environmental Benefits ◽  
Raw Material ◽  
Paper Machine ◽  
High Brightness ◽  
Peroxide Bleaching

The use of a new, technical, high-purity magnesium hydroxide-based peroxide bleaching additive was evaluated in full mill-scale trial runs on two target brightness levels. Trial runs were conducted at a Finnish paper mill using Norwegian spruce (Picea abies) as the raw material in a conventional pressurized groundwood process, which includes a high-consistency peroxide bleaching stage. On high brightness grades, the use of sodium-based additives cause high environmental load from the peroxide bleaching stage. One proposed solution to this is to replace all or part of the sodium hydroxide with a weaker alkali, such as magnesium hydroxide. The replacement of traditional bleaching additives was carried out stepwise, ranging from 0% to 100%. Sodium silicate was dosed in proportion to sodium hydroxide, but with a minimum dose of 0.5% by weight on dry pulp. The environmental effluent load from bleaching of both low and high brightness pulps was significantly reduced. We observed a 35% to 48% reduction in total organic carbon (TOC), 37% to 40% reduction in chemical oxygen demand (COD), and 34% to 60% reduction in biological oxygen demand (BOD7) in the bleaching effluent. At the same time, the target brightness was attained with all replacement ratios. No interference from transition metal ions in the process was observed. The paper quality and paper machine runnability remained good during the trial. These benefits, in addition to the possibility of increasing production capacity, encourage the implementation of the magnesium hydroxide-based bleaching concept.

scholarly journals Life Cycle Cost of Electricity Production: A Comparative Study of Coal-Fired, Biomass, and Wind Power in China

Energies ◽  
2021 ◽  
Vol 14 (12) ◽  
pp. 3463
Author(s):  
Xueliang Yuan ◽  
Leping Chen ◽  
Xuerou Sheng ◽  
Mengyue Liu ◽  
Yue Xu ◽  
...  
Keyword(s):  
Power Generation ◽  
Life Cycle ◽  
Wind Power ◽  
Life Cycle Cost ◽  
Raw Material ◽  
Electricity Production ◽  
Maintenance Cost ◽  
External Cost ◽  
Levelized Cost Of Electricity ◽  
Cost Of Electricity

Economic cost is decisive for the development of different power generation. Life cycle cost (LCC) is a useful tool in calculating the cost at all life stages of electricity generation. This study improves the levelized cost of electricity (LCOE) model as the LCC calculation methods from three aspects, including considering the quantification of external cost, expanding the compositions of internal cost, and discounting power generation. The improved LCOE model is applied to three representative kinds of power generation, namely, coal-fired, biomass, and wind power in China, in the base year 2015. The external cost is quantified based on the ReCiPe model and an economic value conversion factor system. Results show that the internal cost of coal-fired, biomass, and wind power are 0.049, 0.098, and 0.081 USD/kWh, separately. With the quantification of external cost, the LCCs of the three are 0.275, 0.249, and 0.081 USD/kWh, respectively. Sensitivity analysis is conducted on the discount rate and five cost factors, namely, the capital cost, raw material cost, operational and maintenance cost (O&M cost), other annual costs, and external costs. The results provide a quantitative reference for decision makings of electricity production and consumption.

scholarly journals Polyphenols From Vitis vinifera Lambrusco By-Products (Leaves From Pruning): Extraction Parameters Evaluation Through Design of Experiment

2019 ◽  
Vol 14 (7) ◽  
pp. 1934578X1986290 ◽  
Author(s):  
Massimo Tacchini ◽  
Ilaria Burlini ◽  
Immacolata Maresca ◽  
Alessandro Grandini ◽  
Tatiana Bernardi ◽  
...  
Keyword(s):  
Vitis Vinifera ◽  
Antioxidant Capacity ◽  
Design Of Experiment ◽  
Extraction Yield ◽  
Wine Industry ◽  
Raw Material ◽  
Extraction Time ◽  
Total Phenolic ◽  
Vitis Vinifera L ◽  
By Products

Vitis vinifera L. leaves from pruning are by-products of the wine industry and represent an important source of secondary raw material, thanks to their polyphenols content. Optimization of the extraction processes is a key factor for their valorization, and Design of Experiment (DOE) could be a tool to obtain the most performing extract in terms of polyphenols quality/quantity and bioactivity. Vitis vinifera Lambrusco leaves were subjected to ultrasound-assisted extractions guided by a 23 factorial design. Three independent parameters (% solvent, time of extraction, and solvent:solid ratio) were considered to evaluate the extraction process by analyzing the extraction yield, the total phenolic content (Folin-Ciocalteu assay), and the antioxidant capacity (DPPH assay). Moreover, the content of the main molecules was identified and quantified by reversed-phase high-performance liquid chromatography coupled with diode array detection and mass spectrometry. The DOE highlighted the best extraction conditions that showed slight changes considering the different evaluating parameters. The highest extraction yield was obtained by extraction with 100% water, 60 minutes of extraction time, and 30:1 solvent:solid ratio, but it was neither the richest in polyphenols nor antioxidant capacity. The latter 2 characteristics were associated with the extraction performed using 50% ethanol, 35 minutes of extraction time, and a 20:1 solvent:solid ratio. That extract also exhibited the highest quantity of flavonols.

Sedimentary Clays as Geopolymer Precursor

2018 ◽  
Vol 39 ◽  
pp. 97-111
Author(s):  
F. Mostefa ◽  
Nasr Eddine Bouhamou ◽  
H.A. Mesbah ◽  
Salima Aggoun ◽  
D. Mekhatria
Keyword(s):  
Sodium Hydroxide ◽  
Mineralogical Composition ◽  
Cementitious Materials ◽  
Raw Material ◽  
X Ray Diffraction ◽  
Calcination Time ◽  
Calorimetric Analysis ◽  
X Ray ◽  
Before And After ◽  
Mechanical Performances

This work aims to study the feasibility of making a geopolymer cement based on dredged sediments, from the Fergoug dam (Algeria) and to evaluate their construction potential particularly interesting in the field of special cementitious materials. These sediments due to their mineralogical composition as aluminosilicates; are materials that can be used after heat treatment. Sedimentary clays were characterized before and after calcination by X-ray diffraction, ATG / ATD, spectroscopy (FTIR) and XRF analysis. The calcination was carried out on the raw material sieved at 80 μm for a temperature of 750 ° C, for 3.4 and 5 hours. The reactivity of the calcined products was measured using isothermal calorimetric analysis (DSC) on pastes prepared by mixing an alkaline solution of sodium hydroxide (NaOH) 8 M in an amount allowing to have a Na / Al ratio close to 1 (1: 1). Also, cubic mortar samples were prepared with a ratio L / S: 0.8, sealed and cured for 24 hours at 60 ° C and then at room temperature until the day they were submited to mechanical testing. to check the extent of geopolymerization. The results obtained allowed to optimize the calcination time of 5 hours for a better reactivity of these sediments, and a concentration of 8M of sodium hydroxide and more suitable to have the best mechanical performances.

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