scholarly journals Biosorption of Hexavalent Chromium Metal Ions by Lentinula Edodes Biomass: Kinetic, Isothermal, and Thermodynamic Parameters

2021 ◽  
Vol 68 (3) ◽  
pp. 587-593
Author(s):  
Aslı Göçenoğlu Sarıkaya
Keyword(s):  
Thermodynamic Parameters ◽  
Hexavalent Chromium ◽  
Lentinula Edodes ◽  
Freundlich Isotherm ◽  
Chromium Concentration ◽  
Infrared Spectrometry ◽  
Order Kinetic ◽  
Biosorption Capacity ◽  
Kinetic And Thermodynamic Parameters ◽  
Biosorption Process

Lentinula edodes was investigated as a biosorbent for hexavalent chromium biosorption in this study. To examine the optimum conditions of biosorption, the pH of the hexavalent chromium solution, biosorbent dosage, temperature, contact time, and initial hexavalent chromium concentration were identified. Further, to clarify the biosorption mechanism process, the isothermal, kinetic, and thermodynamic parameters were determined. The functional groups and surface morphology of the biosorbent were identified using Fourier transform infrared spectrometry and scanning electron microscopy in the absence and presence of hexavalent chromium, respectively. Based on the results, the maximum biosorption capacity was determined as 194.57 mg g–1 under acidic conditions at 45 °C. From the kinetics studies, the biosorption process was observed to follow the Freundlich isotherm and pseudo-second-order kinetic models well. Thus, L. edodes as a biosorbent has potential usage for wastewater treatment owing to its effective biosorption capacity.

scholarly journals Removing of Hexavalent Chromium from Aqueous Solutions Using Dried Yogurt, and Studying Isotherm, Kinetic and Thermodynamic Parameters

2019 ◽  
Vol 16 (3) ◽  
pp. 0603
Author(s):  
Sultan Et al.
Keyword(s):  
Aqueous Solutions ◽  
Thermodynamic Parameters ◽  
Hexavalent Chromium ◽  
Treatment Time ◽  
Freundlich Isotherm ◽  
Second Order ◽  
Order Kinetic ◽  
Kinetic And Thermodynamic Parameters ◽  
Pseudo Second Order ◽  
Adsorbent Treatment

     In this study, Yogurt was dried and milled, then shaked with distilled water to remove the soluble materials, then again dried and milled. Batch experiments were carried out to remove hexavalent chromium from aqueous solutions. Different parameters were optimized such as amount of adsorbent, treatment time, pH and concentration of adsorbate. The concentrations of Cr6+ in solutions are determined by UV-Visible spectrophotometer.  Maximum percentage removal of Cr6+ was 82% at pH 2. Two equilibrium adsorption isotherms mechanisms are tested Langmuir and Freundlich, the results showed that the isotherm obeyed to Freundlich isotherm. Kinetic models were applied to the adsorption of Cr6+ ions on the adsorbents, pseudo-first-order, the pseudo second-order respectively. Results showed that pseudo second-order kinetic model was applicable to the experimental data well. The thermodynamic parameters such as ΔGº, ΔHº and ΔSº were calculated. ∆H°, ∆S° and ΔGº for this study were negative indicating that the process is exothermic, while negative values of ΔGº indicate spontaneous process.

scholarly journals Biosorption of Hexavalent Chromium from Aqueous Medium withOpuntiaBiomass

2014 ◽  
Vol 2014 ◽  
pp. 1-8 ◽  
Author(s):  
José A. Fernández-López ◽  
José M. Angosto ◽  
María D. Avilés
Keyword(s):  
Hexavalent Chromium ◽  
Low Cost ◽  
Isotherm Models ◽  
Order Kinetic ◽  
Biosorption Capacity ◽  
Biosorption Process ◽  
Equilibrium Data ◽  
Order Kinetic Model ◽  
Pseudo Second Order ◽  
Two Parameter

The biosorption of hexavalent chromium from aqueous solutions byOpuntiacladodes and ectodermis from cactus fruits was investigated. Both types of biomass are considered low-cost, natural, and ecofriendly biosorbents. Batch experiments were carried out to determine Cr(VI) biosorption capacity and the efficiency of the biosorption process under different pH, initial Cr(VI) concentration, and sorbent dosage. The biosorption of Cr(VI) byOpuntiabiomass was highly pH dependent, favoring higher metal uptake at low pH. The higher biosorption capacity was exhibited at pH 2. The optimal conditions were obtained at a sorbent dosage of 1 g L−1and initial metal concentration of 10 mg L−1. Biosorption kinetic data were properly fitted with the pseudo-second-order kinetic model. The rate constant, the initial biosorption rate, and the equilibrium biosorption capacity were determined. The experimental equilibrium data obtained were analyzed using two-parameter isotherm models (Langmuir, Freundlich, and Temkin). The Langmuir maximum monolayer biosorption capacity (qmax) was 18.5 mg g−1for cladodes and 16.4 mg g−1for ectodermis. The results suggest thatOpuntiabiomass could be considered a promising low-cost biosorbent for the ecofriendly removal of Cr(VI) from aqueous systems.

scholarly journals Enhanced biosorption of Cr(VI) using cotton fibers coated with chitosan – role of ester bonds

2018 ◽  
Vol 78 (3) ◽  
pp. 476-486 ◽  
Author(s):  
Sergio I. Rojas ◽  
Diana C. Duarte ◽  
Sergio D. Mosquera ◽  
Felipe Salcedo ◽  
Juan P. Hinestroza ◽  
...  
Keyword(s):  
Hexavalent Chromium ◽  
Freundlich Isotherm ◽  
Kinetic Studies ◽  
Chitosan Solution ◽  
Cotton Fibers ◽  
Isotherm Models ◽  
Order Kinetic ◽  
Amino Groups ◽  
Removal Capacity

Abstract We report on the role of ester bonds in the enhanced removal of hexavalent chromium from water using cotton fibers coated with chitosan. Adsorption capacities up to five times higher than those of the unmodified fibers were observed when the cotton fibers were exposed to an NaOH, followed by citric acid (0.97 M), and a chitosan solution (2%). We found that the use of NaOH favors the formation of ester bonds over amide bonds on the surface of the cotton fibers. This increase in the surface density of ester bonds generates an increase in the amount of exposed amino groups from the chitosan, hence increasing the removal capacity of the modified fibers. Experimental results also reveal that the adsorption is induced by the electrostatic attraction between the protonated amino groups on the surface and the negatively charged chromium ions in the water. Adsorption isotherms and kinetic studies indicated that the adsorption process fits the Langmuir and the Freundlich isotherm models as well as the pseudo-first and pseudo-second order kinetic models. These results can open a new avenue for the manufacturing of fibers with enhanced removal capacities for hexavalent chromium.

scholarly journals Adsorption of Hexavalent Chromium from Aqueous Solution Using Chemically Activated Carbon Prepared from Locally Available Waste of Bamboo (Oxytenanthera abyssinica)

2014 ◽  
Vol 2014 ◽  
pp. 1-9 ◽  
Author(s):  
Tamirat Dula ◽  
Khalid Siraj ◽  
Shimeles Addisu Kitte
Keyword(s):  
Activated Carbon ◽  
Hexavalent Chromium ◽  
Freundlich Isotherm ◽  
Kinetic Studies ◽  
Batch Adsorption ◽  
Koh Activation ◽  
Order Kinetic ◽  
Oxytenanthera Abyssinica ◽  
Equilibrium Data ◽  
Order Kinetic Model

This study reports on the adsorption of Hexavalent Chromium from aqueous solutions using activated carbon prepared from bamboo (Oxytenanthera abyssinica) waste by KOH activation heating in an electrical furnace at 1073 K for 3 hrs. Batch adsorption experiments were also carried out as a function of pH, contact time, initial concentration of the adsorbate, adsorbent dosage, and temperature of the solution. Kinetic studies of the data showed that the adsorption follows the pseudo-second-order kinetic model. Thermodynamic parameters showed that adsorption on the surface of BWAC was feasible, spontaneous in nature, and exothermic between temperatures of 298 and 318 K. The equilibrium data better fitted the Freundlich isotherm model for studying the adsorption behavior of Hexavalent Chromium by BWAC. IR spectrum for loaded and unloaded BWAC was obtained using FT-IR spectrophotometer. Adsorption efficiency and capacity of Hexavalent Chromium were found to be 98.28% at pH 2 and 59.23 mg/g at 300 K.

Biosorption of Cu2+ by Anaerobic Granular Sludge

2014 ◽  
Vol 945-949 ◽  
pp. 3483-3488
Author(s):  
Bai Ren Yang ◽  
Dong Xue Liu ◽  
Xian Niu ◽  
Cheng Ding
Keyword(s):  
Freundlich Isotherm ◽  
Granular Sludge ◽  
Solution Temperature ◽  
Anaerobic Granular Sludge ◽  
Order Kinetic ◽  
Desorption Process ◽  
Biosorption Process ◽  
Order Kinetic Model ◽  
Pseudo Second Order ◽  
Isotherm Equations

In order to investigate the biosorption of Cu2+ by anaerobic granular sludge, the effect of equilibrium time, pH, sludge dosage, biosorption kinetics, biosorption thermodynamics and biosorption isotherms had been studied. Results showed that pseudo second-order kinetic model was useful to describe the biosorption process of Cu2+. Both Langmuir and Freundlich isotherm equations could well describe the desorption process at 15-55 °C. Thermodynamic studies showed that the biosorption process was spontaneous and endothermic in nature. When the solution temperature maintained at 35 °C, pH of 6~7, a good biosorption process could be obtained.

Comparative Study of Removal of Cadmium (II) and Chromium (III) Ions from Aqueous Solution Using Low-Cost Biosorbent

2014 ◽  
Vol 12 (1) ◽  
pp. 477-486 ◽  
Author(s):  
Abbas H. Sulaymon ◽  
Ahmed A. Mohammed ◽  
Tariq J. Al-Musawi
Keyword(s):  
Ph Value ◽  
Removal Rate ◽  
Low Cost ◽  
Order Kinetic ◽  
Cadmium Removal ◽  
Biosorption Capacity ◽  
Biosorption Process ◽  
Order Kinetic Model ◽  
Pseudo Second Order ◽  
Batch Biosorption

Abstract This study aims to evaluate the ability of abundant low-cost garden grass to remove cadmium and chromium ions from aqueous solutions. Batch biosorption studies were carried out to examine the biosorption capacity, pH value, temperature, agitation speed, and metal ions concentration. The biosorption process revealed that the garden grass was an effective biosorbent of cadmium and chromium. The maximum chromium and cadmium removal rate was 90 and 80% at pH 4, respectively. FTIR spectroscopy analysis showed that the hydroxyl, amine, and carboxyl groups were the major groups responsible for the biosorption process. The maximum biosorption capacity was 18.19 and 19.4 mg/g for cadmium and chromium, respectively. The biosorption isotherm data fitted well the Langmuir model. Kinetic data were adequately fitted by the pseudo-second-order kinetic model.

scholarly journals Utilization of anaerobic granular sludge for chromium (VI) removal from wastewater: optimization by response surface methodology

2017 ◽  
Vol 76 (5) ◽  
pp. 1112-1123
Author(s):  
Yifan Hu ◽  
Changzhu Yang ◽  
Jinfeng Dan ◽  
Wenhong Pu ◽  
Jiakuan Yang
Keyword(s):  
Photoelectron Spectroscopy ◽  
Freundlich Isotherm ◽  
Granular Sludge ◽  
Polynomial Equation ◽  
Anaerobic Granular Sludge ◽  
Order Kinetic ◽  
Chromium Vi ◽  
Biosorption Process ◽  
Initial Ph ◽  
The Impact

In this study, anaerobic granular sludge (AGS) was used as a novel adsorbent for hexavalent chromium (Cr (VI)) removal from aqueous solutions. Factor experiments were conducted to find out the effects of different variables on the biosorption process. Among these terms, the impact of three main independent variables (contact time, initial pH and AGS dosage) on the removal efficiency of Cr (VI) was modeled using a well-fitting polynomial equation (R2 = 0.9044), by conducting 20 batch experiments designed by a central composite. The experimental isotherm data were successfully described by the Freundlich isotherm and the pseudo-second-order kinetic model was more suitable for explaining the kinetics process of adsorption. The AGS can be disposed using 0.1 M NaOH with 96.4% desorption efficiency. The results of the analyses (X-ray photoelectron spectroscopy and Fourier transformed infrared spectroscopy) suggested that Cr (VI) adsorption most likely involved electrostatic adsorption, redox reaction and complexation.

scholarly journals Kinetics and Isotherm Studies on Adsorption of Hexavalent Chromium Using Activated Carbon from Water Hyacinth

2021 ◽  
Vol 15 (1) ◽  
pp. 1-8
Author(s):  
Angelica Macalalad ◽  
◽  
Quennie Rose Ebete ◽  
Dominic Gutierrez ◽  
Madelaine Ramos ◽  
...  
Keyword(s):  
Activated Carbon ◽  
Adsorption Capacity ◽  
Hexavalent Chromium ◽  
Water Hyacinth ◽  
Freundlich Isotherm ◽  
Second Order ◽  
Order Kinetic ◽  
Adsorbate Concentration ◽  
Order Kinetic Model ◽  
Pseudo Second Order

The present study is focused on the use of activated carbon derived from water hyacinth (WH-AC) as adsorbent for the removal of Cr(VI) from aqueous solution. The optimized WH-AC was found to be mesoporous and considered as granular. The surface area of 11.564 m2/g was found to have a good adsorption capacity. The adsorption data of the optimized WH-AC followed a pseudo-second order kinetics and the Freundlich isotherm model. Based on the correlation coefficient obtained from pseudo-second-order kinetic model, the R2 values were all above 0.99, which is closer to unity of one (1) indicating that it followed a chemisorption process. The adsorption capacity of WH-AC increased from 1.98 to 4.68 mg/g when adsorbate concentration increased from 20 to 50 mg/l. The overall study proved that the adsorption by activated carbon derived from water hyacinth can be an alternative and efficient technique in hexavalent chromium removal.

scholarly journals Isotherms, thermodynamic and mechanism studies of removal of low concentration uranium (VI) by Aspergillus niger

2017 ◽  
Vol 75 (12) ◽  
pp. 2727-2736 ◽  
Author(s):  
Xiaoyu Wang ◽  
Tieshan Wang ◽  
Xinyan Zheng ◽  
Yanghao Shen ◽  
Xia Lu
Keyword(s):  
Aspergillus Niger ◽  
Biomass Concentration ◽  
Freundlich Isotherm ◽  
Nano Particles ◽  
Infrared Spectrometry ◽  
Low Concentration ◽  
Spectrometry Analysis ◽  
Biosorption Process ◽  
Uranium Ions ◽  
Radioactive Wastewater

In order to develop an effective and economical method for removing low concentration radioactive wastewater of uranium, the biomass of ‘CMCC(F)-98003’ Aspergillus niger was investigated in a batch system. The maximum uranium adsorption capacity of 12.5 mg g−1 was obtained at the initial uranium concentration of 0.75 mg L−1. The biosorption data on a biomass concentration of 0.029 g L−1 fitted well to the Freundlich isotherm with a correlation coefficient (R2) of 0.987. The calculated thermodynamic parameters showed that the biosorption of uranium ions was endothermic (ΔH° < 0). The results of scanning electron microscope and Fourier transform infrared spectrometry analysis revealed that nano-particles of uranium precipitation were formed on the cell surfaces after biosorption, and the functional groups of –CH, N-H, –COOH, P = O and the carbohydrates and alcohols were involved in the biosorption process between A. niger and uranium ions.

Comparative study on batch equilibrium biosorption of Cd(II), Pb(II) and Zn(II) using plantain (Musa paradisiaca) flower: kinetics, isotherm, and thermodynamics

2019 ◽  
Author(s):  
Chem Int
Keyword(s):  
Metal Ions ◽  
Metal Ion ◽  
Freundlich Isotherm ◽  
Sorption Process ◽  
Ion Concentration ◽  
Isotherm Model ◽  
Order Kinetic ◽  
Sorption Data ◽  
Musa Paradisiaca ◽  
Biosorption Process

The potential of plantain (Musa paradisiaca) flower to remove Cd(II), Pb(II) and Zn(II) from aqueous solutions has been investigated under different process parameters like pH, contact time, biomass dose and initial metal ion concentration. The optimum pH for the biosorption of each of the metal ions is pH 6. The kinetic data obtained were subjected to four kinetic models, among which the pseudo-second order kinetic model was found to be the best model that describes the biosorption of each of the metal ions. The equilibrium sorption data were fitted into Langmuir, Freundlich, Temkin and D-R isotherms. In each case, the Freundlich isotherm model gave the best fit giving the sorption intensity (n) values of 1.17, 0.91 and 0.90 which indicate favourable sorption of Cd(II), Pb(II) and Zn(II), respectively. The heat of the sorption process was estimated from Temkin Isotherm model and the mean free energy was estimated from D-R isotherm model to be 312.81Jmol-1, 223.61Jmol-1 and 316.55Jmol-1 for Cd(II), Pb(II) and Zn(II), respectively. Thermodynamically, the biosorption of each of the metal ions is endothermic and the order of spontaneity of the biosorption process being Cd(II) > Zn(II) > Pb(II). Similarly, positive change in entropy was observed for each, the order of disorderliness is Cd(II) > Zn(II) = Pb(II).

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