Methane Flux Estimation in MSW Open Dump Site by In-Situ Measurement and IPCC (DM and FOD) Model

2018 ◽  
Vol 4 (1-2) ◽  
Author(s):  
Rubina Chaudhary ◽  
Shukti Singh
Keyword(s):  
Field Data ◽  
Methane Flux ◽  
Methane Recovery ◽  
Intergovernmental Panel ◽  
Dump Site ◽  
Methane Generation ◽  
First Order ◽  
Flux Estimation ◽  
Ipcc Default

This paper deals with the use of different methods to predict methane generation on an open dump site. Methane recovery data obtained on site as part of a research program being carried out at the Devguradia dumpsite, Indore, is analyzed and used to obtain field methane emission in three seasons. Field data from Municipal solid waste (MSW) dump site are presented and discussed measured in-situ technique i.e. using close chamber methods. The Intergovernmental Panel on Climate Change (IPCC) Default Method (DM) and First order Decay (FOD) method is used to estimate methane generation. It is found that despite the assumptions and the simplicity of the adopted procedures, the values methane obtained are slightly varying to those measured in the field. The values obtained were 4.5, 2.9 and 0.35 Gg/y respectively.

Integrity Assurance of an Oil Transportation Pipeline in a Transformed Design Environment

2015 ◽  
Author(s):  
Amitabh Kumar ◽  
Brian McShane ◽  
Mark McQueen
Keyword(s):  
Field Data ◽  
Oil And Gas ◽  
High Reliability ◽  
Complex Loading ◽  
Calibration Method ◽  
Real Field ◽  
Design Environment ◽  
Data Feedback ◽  
Integrity Management

A large Oil and Gas pipeline gathering system is commonly used to transport processed oil and gas from an offshore platform to an onshore receiving facility. High reliability and integrity for continuous operation of these systems is crucial to ensure constant supply of hydrocarbon to the onshore processing facility and eventually to market. When such a system is exposed to a series of complex environmental loadings, it is often difficult to predict the response path, in-situ condition and therefore the system’s ability to withstand subsequent future loading scenarios. In order to continue to operate the pipeline after a significant environmental event, an overall approach needs to be developed to — (a) Understand the system loading and the associated integrity, (b) Develop a series of criteria staging the sequence of actions following an event that will verify the pipeline integrity and (c) Ensure that the integrity management solution is simple and easy to understand so that it can be implemented consistently. For a complex loading scenario, one of the main challenges is the ability to predict the controlling parameter(s) that drives the global integrity of these systems. In such scenarios, the presence of numerous parameters makes the technical modeling and prediction tasks arduous. To address such scenarios, first and foremost, it is crucial to understand the baseline environment data and other associated critical design input elements. If the “design environmental baseline” has transformed (due to large events e.g. storms etc.) from its original condition; it modifies the dynamics of the system. To address this problem, a thorough modeling and assessment of the in-situ condition is essential. Further, a robust calibration method is required to predict the future response path and therefore expected pipeline condition. The study further compares the planned integrity management solutions to the field data to validate the efficiency of the predicted scenarios. By the inclusion of real field-data feedback to the modeling method, balanced integrity solutions can be achieved and the ability to quantify the risks is made more practical and actionable.

Soil Persistence of Dinitramine

Weed Science ◽  
1980 ◽  
Vol 28 (6) ◽  
pp. 650-654 ◽  
Author(s):  
J. A. Poku ◽  
R. L. Zimdahl
Keyword(s):  
Mathematical Model ◽  
Soil Moisture ◽  
Field Data ◽  
Soil Moisture Content ◽  
Sandy Loam ◽  
Clay Loam ◽  
First Order ◽  
Soil Persistence ◽  
Herbicide Concentration ◽  
Increasing Temperature

The effects of soil temperature, moisture, and herbicide concentration on the rate of degradation of dinitramine (N4,N4-diethyl-α,α,α-trifluoro-3,5-dinitrotoluene-2,4-diamine) were measured in clay loam and sandy loam in the laboratory. In sandy loam, the rate of degradation increased with increasing temperature. In clay loam, the rate of degradation increased from 10 to 30 C and decreased at 40 C. Soil moisture content influenced the rate of degradation in the following order: 22>11>>2.2% (air-dry) for clay loam and 12.0 = 6.0>>0.5% (air-dry) for sandy loam. First-order half-lives ranged from 3.2 at 30 C to 47 weeks at 10 C in clay loam, and 2.3 at 40 C to 31 weeks at 10 C in sandy loam. Applications in 2 yr did not cause buildup of dinitramine in the field. A mathematical model was used in an attempt to correlate laboratory and field data.

Modified ferron assay for speciation characterization of hydrolyzed Al(III): a precise k value based judgment

2009 ◽  
Vol 59 (4) ◽  
pp. 823-832 ◽  
Author(s):  
Ye Changqing ◽  
Wang Dongsheng ◽  
Wu Xiaohong ◽  
Qu Jiuhui ◽  
John Gregory
Keyword(s):  
Kinetic Constant ◽  
Nonlinear Least Squares ◽  
Precise Determination ◽  
K Value ◽  
First Order ◽  
First Order Kinetics ◽  
Parallel Reactions

The speciation of Al-OH complexes in terms of Ala, Alb and Alc could be achieved by traditional ferron assay and Alb is generally considered as Al13, however, the inherent correlation between them remains an enigma. This paper presents a modified ferron assay to get precise determination of Al13 using nonlinear least squares analysis, and to clarify the correlation between Alb and Al13. Two parallel reactions conforming to pseudo-first-order kinetics can simulate the complicate reactions between polynuclear complexes and ferron successfully. Four types of experimental kinetic constant (k value) of Al-OH complexes can be observed by this method when investigating three typical aluminium solutions. Comparing with the results of 27Al NMR, the species with moderate kinetics around 0.001 s−1 can be confirmed to resemble to Al13 polycation. The other types of kinetics are also well-regulated in partially neutralized aluminium solutions with various OH/Al ratios (b values) in the range 0 ∼ 2.5. It would provide potential means to trace the in-situ formation of Al13 in dilute solutions such as coagulation with Al-based coagulants

In situ creep of frozen soil, Fenghuo Shan, Tibet Plateau, China

1995 ◽  
Vol 32 (3) ◽  
pp. 545-552 ◽  
Author(s):  
B. Wang ◽  
Hugh M. French
Keyword(s):  
Key Words ◽  
Power Flow ◽  
Field Data ◽  
Field Measurements ◽  
Frozen Soil ◽  
Tibet Plateau ◽  
Soil Creep ◽  
Extreme Variability ◽  
The Mean

Field measurements of frozen soil creep in the upper 3.0 m of permafrost indicate that creep occurs in both winter and summer. Between 1992 and 1993, the mean rate of creep ranged from 0.44 cm at 1.6 m depth to 0.16 cm at 2.8 m depth but there was extreme variability. Creep parameters n and A, as defined by the power flow law, were calculated from field data. Parameter n ranged between 1.96 and 2.29 and increased with depth, while A decreased with depth. Comparisons of creep rates for different permafrost environments suggest that ground temperature largely controls the magnitude of permafrost creep. Key words : permafrost, creep parameters, Tibet Plateau.

Inorganic mixed phase templated by a fatty acid monolayer at the air–water interface: the Mn and Mg case

2018 ◽  
Vol 20 (9) ◽  
pp. 6629-6637 ◽  
Author(s):  
Alae El Haitami ◽  
Michel Goldmann ◽  
Philippe Fontaine ◽  
Marie-Claude Fauré ◽  
Sophie Cantin
Keyword(s):  
Grazing Incidence ◽  
Water Interface ◽  
X Ray Diffraction ◽  
Inorganic Layer ◽  
X Ray ◽  
First Order ◽  
First Order Phase Transition ◽  
Air Water Interface ◽  
First Order Phase

A first-order phase transition with a peculiar feature is evidenced by means of in situ grazing incidence X-ray diffraction in the 2D organic phase-mediated nucleation of an inorganic layer.

Intergovernmental panel on climate change’s landfill methane protocol: Reviewing 20 years of application

2018 ◽  
Vol 36 (9) ◽  
pp. 827-840 ◽  
Author(s):  
Max J Krause
Keyword(s):  
Climate Change ◽  
Organic Carbon ◽  
Landfill Gas ◽  
Emission Inventories ◽  
Field Validation ◽  
Intergovernmental Panel ◽  
Site Specific ◽  
Methane Generation ◽  
National Estimates ◽  
Practical Tool

The Intergovernmental Panel on Climate Change (IPCC) protocol for predicting national methane emission inventories from landfills was published 22 years ago in the 1996 Revised Guidelines. There currently exists a broad dataset to review landfill parameters and reported values and their appropriateness in use and application in a range of site-specific, regional, and national estimates. Degradable organic carbon (DOC) content was found to range from 0.0105 to 0.65 g C/g waste, with an average of 0.166 g C/g waste. The fraction of DOC that would anaerobically degrade (DOC f) was reported to range from 50–83%, whereas higher and lower values have been experimentally determined for a variety of waste components, such as wood (0–50%) and food waste (50–75%). Where field validation occurred for the methane correction factor, values were substantially lower than defaults. The fraction of methane in anaerobic landfill gas ( F) default of 50% is almost universally applied and is appropriate for cellulosic wastes. The methane generation rate constant ( k) varied widely from 0.01 to 0.51 y−1, representing half-lives from 1 to 69 years. Methane oxidation (OX) default values of 0 and 10% may be valid, but values greater than 30% have been reported for porous covers at managed sites. The IPCC protocol is a practical tool with uncertainties and limitations that must be addressed when used for purposes other than developing inventories.

Preliminary field data of selected deep-rooted vegetation effects on the slope-vegetation-atmosphere interaction: results from an in-situ test 

2021 ◽  
Author(s):  
Vito Tagarelli ◽  
Federica Cotecchia ◽  
Osvaldo Bottiglieri
Keyword(s):  
Soil Water ◽  
Pore Water ◽  
Field Data ◽  
Test Site ◽  
Grass Species ◽  
In Situ Test ◽  
South Eastern ◽  
Atmosphere Interaction ◽  
The Stability

<p>The soil-vegetation-atmosphere interaction is becoming more and more the subject of intense scientific research, motivated by the wish of using smart vegetation implants as sustainable mitigation measure for erosive phenomena and slope instability processes. <br>The use of novel naturalistic interventions making use of vegetation has been already proven to be successful in the reduction of erosion along sloping grounds, or in increasing the stability of the shallow covers of slopes, whereas the success of vegetation as slope stabilization measure still needs to be scientifically proven for slopes location of deep landslides, whose current activity is climate-induced, as frequent in the south-eastern Apennines. Recently, though, peculiar natural perennial grass species, which develop deep root systems, have been found to grow in the semi-arid climate characterizing the south-eastern Apennines and to determine a strong transpirative flow. Therefore, their peculiar leaf architecture, their crop density, combined with their perennial status and transpiration capacity, make such grass species suitable for the reduction of the net infiltration rates, equal to the difference between the rainfall rate and the sum of the runoff plus the evapotranspiration rate. As such, the grass species here of reference have been selected as vegetation measure intended to determine a reduction of the piezometric levels in the slope down to large depths, in order to increase the stability of deep landslide bodies. <br>At this stage, only preliminary field data representing the interaction of clayey soils with the above cited vegetation species are available. These have been logged within a full scale in-situ test site, where the deep-rooted crop spices have been seeded and farmed. The test site (approximatively 2000 m<sup>2</sup>) has been set up in the toe area of the climate-induced Pisciolo landslide, in the eastern sector of the Southern Apennines.<br>The impact of the vegetation on the hydro-mechanical state of the soil is examined in terms of the spatial and temporal variation of the soil water content, suction an pore water pressure from ground level down to depth, both within the vegetated test site and outside it, where only spare wild vegetation occur, in order to assess the effects of the implant of the selected vegetation. The soil water contents, suctions and pore water pressures have been also analyzed taking into account of the climatic actions, monitored by means of a meteorological station. </p>

scholarly journals An Electrochemical Process Comparison of As(III) in Simulated Groundwater at Low Voltage in Mixed and Divided Electrolytic Cells

Water ◽  
2020 ◽  
Vol 12 (4) ◽  
pp. 1126 ◽  
Author(s):  
Yanyan Qin ◽  
Yanping Cui ◽  
Lidan Lei ◽  
Ya Gao ◽  
Zhengwei Zhou ◽  
...  
Keyword(s):  
Low Voltage ◽  
Electrochemical Process ◽  
First Order ◽  
Electrolytic Cells ◽  
Process Comparison ◽  
First Order Kinetics ◽  
Simulated Groundwater ◽  
High Arsenic ◽  
High Arsenic Groundwater

A relatively low voltage can be favor of e- transfer and peroxide generation from dominant 2e--reduction of O2 on carbon materials as cathode, with low energy loss. In this study the conversion of As(III) in simulated high arsenic groundwater at low voltage was compared in a mixed and a anode–cathode separated electrolytic system. With applied voltages (the potential difference between cathode and anode) from 0.1 V to 0.8 V, As(III) was found to be efficiently converted to As(V) in the mixed electrolytic cells and in separated anodic cells. The complete oxidation of As(III) to As(V) at 0.1–0.8 V was also achieved on graphite in divided cathodic cells which could be long-running. The As(III) conversion process in mixed electrolytic cells, anodic cells and cathodic cells all conformed to the pseudo first-order kinetics equation. The energy consumed by As(III) conversion was decreased as the applied voltage declined. Low voltage electrolysis is of great significance for saving energy consumption and improving the current efficiency and can be applied to in-situ electrochemical pre-oxidation for As(III) in high arsenic groundwater.

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