scholarly journals ASDToolkit: A Novel MATLAB Processing Toolbox for ASD Field Spectroscopy Data

2020 ◽  
Author(s):  
Kathryn Elmer ◽  
Raymond Soffer ◽  
J. Pablo Arroyo-Mora ◽  
Margaret Kalacska
Keyword(s):  
Individual Characteristics ◽  
Atmospheric Conditions ◽  
Current Effort ◽  
Data Product ◽  
Field Spectroscopy ◽  
The Individual ◽  
Solar Position ◽  
Derived Data

Over the past 30 years, the use of field spectroscopy has risen in importance in remote sensing studies for the characterization of the surface reflectance of materials in situ within a broad range of applications. Potential uses range from measurements of individual targets of interest (e.g. vegetation, soils, validation targets etc.), to characterizing the contributions of different materials within larger spatially-mixed areas as would be representative of the spatial resolution captured by a sensor pixel (UAV to satellite scale). As such, it is essential that a complete and rigorous assessment of both the data-acquisition procedures, and the suitability of the derived data product be carried out. The measured energy from solar-reflected range spectroradiometers is influenced by the viewing and illumination geometries and the illumination conditions which vary due to changes in solar position and atmospheric conditions. By applying corrections, the estimated absolute reflectance (Rabs) of targets can be calculated. This property is independent of illumination intensity or conditions and is the metric commonly suggested to be used to compare spectra even when data are collected by different sensors or acquired under different conditions. By standardizing the process of estimated Rabs, as is provided in the described toolkit, consistency and repeatability in processing are ensured and the otherwise labor intensive and error-prone processing steps are streamlined. The resultant end data product (Rabs) represents our best current effort to generate consistent and comparable ground spectra which have been corrected for viewing and illumination geometries as well as other factors such as the individual characteristics of the reference panel used during acquisition.

scholarly journals ASDToolkit: A Novel MATLAB Processing Toolbox for ASD Field Spectroscopy Data

Data ◽  
2020 ◽  
Vol 5 (4) ◽  
pp. 96
Author(s):  
Kathryn Elmer ◽  
Raymond J. Soffer ◽  
J. Pablo Arroyo-Mora ◽  
Margaret Kalacska
Keyword(s):  
Individual Characteristics ◽  
Atmospheric Conditions ◽  
Data Product ◽  
Field Spectroscopy ◽  
The Individual ◽  
Solar Position ◽  
Derived Data ◽  
Processing Steps

Over the past 30 years, the use of field spectroscopy has risen in importance in remote sensing studies for the characterization of the surface reflectance of materials in situ within a broad range of applications. Potential uses range from measurements of individual targets of interest (e.g., vegetation, soils, validation targets) to characterizing the contributions of different materials within larger spatially mixed areas as would be representative of the spatial resolution captured by a sensor pixel (UAV to satellite scale). As such, it is essential that a complete and rigorous assessment of both the data acquisition procedures and the suitability of the derived data product be carried out. The measured energy from solar-reflective range spectroradiometers is influenced by the viewing and illumination geometries and the illumination conditions, which vary due to changes in solar position and atmospheric conditions. By applying corrections, the estimated absolute reflectance (Rabs) of targets can be calculated. This property is independent of illumination intensity or conditions, and is the metric commonly suggested to be used to compare spectra even when data are collected by different sensors or acquired under different conditions. By standardizing the process of estimated Rabs, as is provided in the described toolkit, consistency and repeatability in processing are ensured and the otherwise labor-intensive and error-prone processing steps are streamlined. The resultant end data product (Rabs) represents our current best effort to generate consistent and comparable ground spectra that have been corrected for viewing and illumination geometries as well as other factors such as the individual characteristics of the reference panel used during acquisition.

Variation in highly repetitive DNA composition of heterochromatin in rye studied by fluorescence in situ hybridization

Genome ◽  
1995 ◽  
Vol 38 (6) ◽  
pp. 1061-1069 ◽  
Author(s):  
A. Cuadrado ◽  
N. Jouve ◽  
C. Ceoloni
Keyword(s):  
In Situ Hybridization ◽  
Fluorescence In Situ Hybridization ◽  
Repetitive Dna ◽  
Dna Sequences ◽  
5S Rdna ◽  
Individual Identification ◽  
Highly Repetitive Dna ◽  
The Individual

The molecular characterization of heterochromatin in six lines of rye has been performed using fluorescence in situ hybridization (FISH). The highly repetitive rye DNA sequences pSc 119.2, pSc74, and pSc34, and the probes pTa71 and pSc794 containing the 25S–5.8S–18S rDNA (NOR) and the 5S rDNA multigene families, respectively, were used. This allowed the individual identification of all seven rye chromosomes and most chromosome arms in all lines. All varieties showed similar but not identical patterns. A standard in situ hybridization map was constructed following the nomenclature system recommended for C-bands. All FISH sites observed appeared to correspond well with C-band locations, but not all C-banding sites coincided with hybridization sites of the repetitive DNA probes used. Quantitative and qualitative differences between different varieties were found for in situ hybridization response at corresponding sites. Variation between plants and even between homologous chromosomes of the same plant was found in open-pollinated lines. In inbred lines, the in situ pattern of the homologues was practically identical and no variation between plants was detected. The observed quantitative and qualitative differences are consistent with a corresponding variation for C-bands detected both within and between cultivars.Key words: fluorescence in situ hybridization, repetitive DNA, rye, Secale cereale, polymorphism.

Characterization of the Human Junctional Epithelial Cells Directly Attached to the Tooth (DAT Cells)in Periodontal Disease

1994 ◽  
Vol 73 (12) ◽  
pp. 1818-1823 ◽  
Author(s):  
D.O. Overman ◽  
J.I. Salonen
Keyword(s):  
Periodontal Disease ◽  
Tooth Surface ◽  
Junctional Epithelium ◽  
Transmission Electron ◽  
The Individual ◽  
Pocket Formation ◽  
Resistant Structure ◽  
Proliferative Ability

This study examined the directly attached cells (DAT cells) of the human junctional epithelium from teeth extracted for advanced periodontal disease. The monolayer nature of the DAT cells remaining on the tooth surface after extraction offers a unique opportunity to study their morphology and activity in situ. We collected DAT cells and examined them by transmission electron microscopy and by autoradiography of cells labeled with 3H-thymidine. Our morphological results suggest that degenerative changes associated with pocket formation affect individual cells rather than regions of the DAT cell population at one time. The epithelial attachment apparatus (EAA) appeared to be the most resistant structure persisting on the tooth surface during the degeneration of the individual DAT cells. The new technique developed for two-dimensional observation of the sheet of DAT cells labeled in situ on the tooth surface in culture showed that the attached cells, even in periodontal disease, exhibit proliferative ability, suggesting a regenerative role for the DAT cells.

Synchrotron Characterization of Texture and Stress Evolution in Ag Films

2007 ◽  
Vol 1027 ◽  
Author(s):  
Aaron Vodnick ◽  
Michael Lawrence ◽  
Bethany Little ◽  
Derek Worden ◽  
Shefford Baker
Keyword(s):  
Real Time ◽  
Driving Forces ◽  
Texture Evolution ◽  
High Energy ◽  
Fiber Texture ◽  
X Ray Diffraction ◽  
Synchrotron Source ◽  
The Individual

AbstractReal-time in-situ synchrotron x-ray diffraction measurements were performed at the Cornell High Energy Synchrotron Source to characterize both the texture evolution and stresses within the individual texture components of Ag films during recrystallization. As deposited films had a nearly perfect (111) fiber texture. During isothermal anneals, stress and texture were characterized in real-time as the texture evolved into a strong (001) fiber. An Avrami analysis of the evolving texture fractions yielded very different activation energies for films on different barrier layers, suggesting different governing mechanisms were responsible for secondary grain growth. The strains were used to test a common model for texture prediction that assumes the same strain within each texture component. It was found that secondary (001) grains were able to grow primarily strain free. Selection for this strain energy minimizing orientation occurred during the nucleation process during which texture interactions play an important role. By using these real time measurements, we are able to show that driving forces for texture transformations in metal films may not be as simple previously described.

scholarly journals Synthesis and Characterization of 12CaO·7Al2O3 Slags: The Effects of Impurities and Atmospheres on the Phase Relations

2020 ◽  
Vol 51 (6) ◽  
pp. 2689-2710
Author(s):  
Fabian Imanasa Azof ◽  
Kai Tang ◽  
Jinglin You ◽  
Jafar Safarian
Keyword(s):  
Room Temperature ◽  
Intermediate Phase ◽  
Atmospheric Conditions ◽  
X Ray Diffraction ◽  
Alumina Crucible ◽  
Electron Probe Micro Analyzer ◽  
Low Concentrations ◽  
A Minor

AbstractSynthesis of crystalline slags of 12CaO·7Al2O3 phase from the corresponding melt compositions in different atmospheric conditions and different purities is investigated. Observations using a thermogravimetry coupled with differential thermal analysis showed that the dehydration of a zeolitic 12CaO·7Al2O3 phase occur at 770 °C to 1390 °C before it congruently melts at 1450 °C. The X-ray diffraction pattern of the slag showed that a single 12CaO·7Al2O3 phase is produced from a mixture, which has small SiO2 impurity with a 49:51 mass ratio of CaO to Al2O3. A scanning electron microscope and electron probe micro-analyzer showed that a minor Ca-Al-Si-O-containing phase is in equilibrium with a grain-less 12CaO·7Al2O3 phase. Moreover, 12CaO·7Al2O3 is unstable at room temperature when the high-purity molten slag is solidified under oxidizing conditions contained in an alumina crucible. On the other hand, a high-temperature in-situ Raman spectroscopy of a slag that was made of a higher purity CaO-Al2O3 mixture showed that 5CaO·3Al2O3 phase is an unstable/intermediate phase in the the CaO-Al2O3 system, which is decomposed to 12CaO·7Al2O3 above 1100 °C upon heating in oxidizing conditions. It was found that 5CaO·3Al2O3 is present at room temperature when the 12CaO·7Al2O3 dissociates to a mixture of 5CaO·3Al2O3, 3CaO·Al2O3, and CaO·Al2O3 phases during the cooling of the slag at 1180 °C ± 20 °C in reducing atmosphere. It is proposed that low concentrations of Si stabilize 12CaO·7Al2O3 (mayenite), in which Si is a solid solution in its lattice, which is named Si-mayenite. Regarding the calculated CaO-Al2O3-SiO2 diagram in this study, this phase may contain a maximum of 4.7 wt pct SiO2, which depends on the total SiO2 in the system and the Ca/Al ratio.

scholarly journals Cyanoarylporphyrazines with High Viscosity Sensitivity: A Step towards Dosimetry-Assisted Photodynamic Cancer Treatment

Molecules ◽  
2021 ◽  
Vol 26 (19) ◽  
pp. 5816
Author(s):  
Irina V. Balalaeva ◽  
Tatiana A. Mishchenko ◽  
Victoria D. Turubanova ◽  
Nina N. Peskova ◽  
Natalia Y. Shilyagina ◽  
...  
Keyword(s):  
Photophysical Properties ◽  
High Viscosity ◽  
Individual Characteristics ◽  
Fluorescence Lifetime Imaging ◽  
Detailed Characterization ◽  
Lifetime Imaging ◽  
Anticancer Treatment ◽  
Viscosity Sensors ◽  
The Individual

Despite the significant relevance of photodynamic therapy (PDT) as an efficient strategy for primary and adjuvant anticancer treatment, several challenges compromise its efficiency. In order to develop an “ideal photosensitizer” and the requirements applied to photosensitizers for PDT, there is still a need for new photodynamic agents with improved photophysical and photobiological properties. In this study, we performed a detailed characterization of two tetracyanotetra(aryl)porphyrazine dyes with 4-biphenyl (pz II) and 4-diethylaminophenyl (pz IV) groups in the periphery of the porphyrazine macrocycle. Photophysical properties, namely, fluorescence quantum yield and lifetime of both photosensitizers, demonstrate extremely high dependence on the viscosity of the environment, which enables them to be used as viscosity sensors. PzII and pz IV easily enter cancer cells and efficiently induce cell death under light irradiation. Using fluorescence lifetime imaging microscopy, we demonstrated the possibility of assessing local intracellular viscosity and visualizing viscosity changes driven by PDT treatment with the compounds. Thus, pz II and pz IV combine the features of potent photodynamic agents and viscosity sensors. These data suggest that the unique properties of the compounds provide a tool for PDT dosimetry and tailoring the PDT treatment regimen to the individual characteristics of each patient.

scholarly journals Characterization of soluble bromide measurements and a case study of BrO observations during ARCTAS

2011 ◽  
Vol 11 (9) ◽  
pp. 26999-27030 ◽  
Author(s):  
J. Liao ◽  
L. G. Huey ◽  
E. Scheuer ◽  
J. E. Dibb ◽  
R. E. Stickel ◽  
...  
Keyword(s):  
Detection Efficiency ◽  
Hydrogen Bromide ◽  
The Arctic ◽  
Ionization Mass ◽  
Atmospheric Conditions ◽  
Vertical Column ◽  
Bromine Oxide ◽  
Mist Chamber

Abstract. A focus of the Arctic Research of the Composition of the Troposphere from Aircraft and Satellites (ARCTAS) mission was examination of bromine photochemistry in the spring time, high latitude troposphere based on aircraft and satellite measurements of BrO and related species. The NASA DC-8 aircraft utilized a chemical ionization mass spectrometry (CIMS) instrument to measure BrO and a mist chamber (MC) to measure soluble bromide. We have determined that the MC detection efficiency to molecular bromine (Br2), hypobromous acid (HOBr), bromine oxide (BrO), and hydrogen bromide (HBr) as soluble bromide (Br−) was 0.9±0.1, 1.06±0.30, 0.4±0.1, and 0.95±0.1, respectively. These efficiency factors were used to estimate soluble bromide levels along the DC-8 flight track of 17 April 2008 from photochemical calculations constrained to in situ BrO measured by CIMS. During this flight, the highest levels of soluble bromide and BrO were observed and atmospheric conditions were ideal for the space-borne observation of BrO. The good agreement (R2 = 0.76; slope = 0.98; intercept = −3.5 pptv) between modeled and observed soluble bromide, when BrO was above detection limit (>2 pptv) under unpolluted conditions (NO < 100 pptv), indicates that the CIMS BrO measurements were consistent with the MC soluble bromide. Tropospheric BrO vertical column densities (BROTROPVCD) derived from CIMS BrO observations compare well with BROTROPVCD from OMI on 17 April 2008.

scholarly journals Sociodemographic Characteristics and Stress of People from Spain Confined by COVID-19

2020 ◽  
Vol 10 (4) ◽  
pp. 1095-1105
Author(s):  
Susana Rodríguez ◽  
Antonio Valle ◽  
Isabel Piñeiro ◽  
Carolina Rodríguez-Llorente ◽  
Estefanía Guerrero ◽  
...  
Keyword(s):  
Individual Characteristics ◽  
Significant Information ◽  
Daily Lives ◽  
Stress Control ◽  
Stress Scale ◽  
Low Incomes ◽  
Confinement Stress ◽  
The Individual ◽  
Working Situation

This study responds to the need to explore the individual characteristics that may help us to understand the levels of stress involved in the significant COVID-19-related restrictions to people’s daily lives. In order to understand levels of stress and stress control during the COVID-19 confinement, 1269 people from Spain (17.5% men) aged between 18 and 70 completed the Perceived Stress Scale (PSS-14). The results indicated that people aged under 40, and especially those under 25, women, and those on low incomes reported higher rates of confinement stress. The nature of where people live, and their working situation during confinement also contributed to people’s stress response, although with lower levels of impact. In this context, our study suggests that the levels of stress in those who combine remote working with in situ working were lower than those who had other working conditions. Our study contributes significant information to understanding the effects of confinement, and its results may be used to inform intervention tools and programs.

A Review of Orientation-Microstructure-Property Relationships for PZT / Metal or Metal-Oxide Layered Heterostructures

1994 ◽  
Vol 341 ◽  
Author(s):  
Orlando Auciello ◽  
H. N. Al Shareef ◽  
K. D. Gifford ◽  
D. J. Lichtenwalner ◽  
R. Dat ◽  
...  
Keyword(s):  
Metal Oxide ◽  
Bottom Electrode ◽  
Ion Beam ◽  
Sol Gel ◽  
Atmospheric Conditions ◽  
Microstructure And Properties ◽  
Electrode Interface ◽  
Ferroelectric Memories

AbstractStudies performed by our group on orientation-microstructure-property relationships of Pb(ZrxTil1-x)O3 (PZT) / metal or metal-oxide layered heterostructure are reviewed. The work discussed is related to the synthesis and characterization of ferroelectric PZT and conductive Pt, RuO2, and Lao.5Sr0.5CoO3 layers and their integration into heterostructure capacitors suitable for non-volatile memories. The main objective of our research was to determine the influence of deposition techniques and their related parameters and layer processing on the orientation, microstructure, and properties of PZT-based capacitors, with the goal of controlling electrical properties such as polarization fatigue, retention, and imprint effects, in order to produce commercial non-volatile ferroelectric memories. The work discussed relates to the synthesis of films by ion beam sputter-deposition (IBSD), and pulsed laser ablation deposition (PLAD), where the heterostructures are grown in-situ without exposing the interfaces to uncontrollable atmospheric conditions. Comparisons are presented between orientation and microstructural characteristics and properties of PZT heterostructure capacitors produced by IBSD and PLAD and those synthesized by the sol-gel technique. The work reviewed indicates that substrate and template layers (at the ferroelectric/bottom electrode interface) and/or bottom electrode material type contribute to the control of orientation and/or microstructure, and properties of PZT-based capacitors.

The Use of Advanced Analytical Techniques for Characterization of the Chemical, Physical, and Crystallographic Nature of a Surface

1973 ◽  
Vol 31 ◽  
pp. 132-133 ◽  
Author(s):  
R. E. Herfert
Keyword(s):  
Surface Characterization ◽  
Analytical Techniques ◽  
X Ray Diffraction ◽  
Depth Of Penetration ◽  
X Ray ◽  
The Past ◽  
Transmission Electron ◽  
Scanning Electron

Studies of the nature of a surface, either metallic or nonmetallic, in the past, have been limited to the instrumentation available for these measurements. In the past, optical microscopy, replica transmission electron microscopy, electron or X-ray diffraction and optical or X-ray spectroscopy have provided the means of surface characterization. Actually, some of these techniques are not purely surface; the depth of penetration may be a few thousands of an inch. Within the last five years, instrumentation has been made available which now makes it practical for use to study the outer few 100A of layers and characterize it completely from a chemical, physical, and crystallographic standpoint. The scanning electron microscope (SEM) provides a means of viewing the surface of a material in situ to magnifications as high as 250,000X.

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