scholarly journals Investigation of Corrosion of A and E36 Naval Steels Using Potentiodynamic Polarization and Modified Prohesion Test

2021 ◽  
pp. ArticleID:21111
Author(s):  
Buruiana Daniela Laura ◽  
Keyword(s):  
Potentiodynamic Polarization ◽  
Naval Steels

scholarly journals Experimental, DFT and MD Assessments of Bark Extract of Tamarix aphylla as Corrosion Inhibitor for Carbon Steel Used in Desalination Plants

Molecules ◽  
2021 ◽  
Vol 26 (12) ◽  
pp. 3679
Author(s):  
Ismat H. Ali
Keyword(s):  
Corrosion Inhibitor ◽  
Potentiodynamic Polarization ◽  
Inhibition Efficiency ◽  
Electrochemical Impedance ◽  
Effect Of Temperature ◽  
Bark Extract ◽  
Plant Sample ◽  
Gravimetric Analysis ◽  
Sample Collection ◽  
Eis Measurements

This study aimed to examine the extract of barks of Tamarix aphylla as a corrosion inhibitor. The methodology briefly includes plant sample collection, extraction of the corrosion inhibitor, gravimetric analysis, plotting potentiodynamic polarization plots, electrochemical impedance spectroscopic measurements, optimization of conditions, and preparation of the inhibitor products. The results show that the values of inhibition efficiency (IE%) increased as the concentrations of the inhibitor increased, with a maximum achievable inhibition efficiency of 85.0%. Potentiodynamic polarization (PP) tests revealed that the extract acts as a dual-type inhibitor. The results obtained from electrochemical impedance spectroscopy (EIS) measurements indicate an increase in polarisation resistance, confirming the inhibitive capacity of the tested inhibitor. The adsorption of the inhibitor on the steel surface follows the Langmuir adsorption isotherm model and involves competitive physio-sorption and chemisorption mechanisms. The EIS technique was utilized to investigate the effect of temperature on corrosion inhibition within the 298–328 K temperature range. Results confirm that the inhibition efficiency (IE%) of the inhibitor decreased slightly as the temperature increased. Lastly, the thermodynamic parameters for the inhibitor were calculated.

scholarly journals Chemical, electrochemical, thermodynamic and adsorption study of EN8 dual-phase steel with ferrite-martensite structure in 0.5 M H2SO4 using pectin as inhibitor

2021 ◽  
Author(s):  
P. R. Prabhu ◽  
Pavan Hiremath ◽  
Deepa Prabhu ◽  
M. C. Gowrishankar ◽  
B. M. Gurumurthy
Keyword(s):  
Weight Loss ◽  
Adsorption Isotherm ◽  
Surface Analysis ◽  
Potentiodynamic Polarization ◽  
Dual Phase Steel ◽  
Inhibition Efficiency ◽  
Dual Phase ◽  
X Ray ◽  
Enthalpy And Entropy ◽  
Martensite Structure

AbstractThis paper presents the corrosion and inhibition behavior of heat-treated EN8 dual-phase steel with ferrite-martensite structure with pectin in 0.5 M sulphuric acid. The corrosion studies were performed using the weight loss method, electrochemical techniques such as potentiodynamic polarization measurements, and impedance spectroscopy. The study was done at different concentrations of pectin in the temperature range of 40 to 70 °C and immersion time of 1, 3, 5, and 7 h. The results showed that the inhibition performance of pectin has enhanced with an increase in pectin concentration and decreased with the temperature and time of exposure. From the weight loss study, highest inhibition efficiency of 76.43% was achieved at 5.0 g/L at 1 h of exposure at 40 °C. The maximum inhibition efficiency of 62% was obtained with 5.0 g/L of pectin at 40 °C by potentiodynamic polarization method. The energy, enthalpy, and entropy of activation and also thermodynamic parameters like free energy, enthalpy, and entropy of adsorption were assessed and discussed. Appropriate adsorption isotherm was fit to the obtained experimental outcomes and achieved Langmuir adsorption isotherm to be the best fit and obeyed physical adsorption. Surface analysis: scanning electron microscopy, X-ray diffraction techniques, atomic force microscopy, and energy dispersive X-ray were done with and without the addition of pectin. The metal surface appears to be uniform and smooth in the presence of pectin and adsorption was confirmed by surface analysis.

scholarly journals Novel pyrimidine-bichalcophene derivatives as corrosion inhibitors for copper in 1 M nitric acid solution

RSC Advances ◽  
2021 ◽  
Vol 11 (41) ◽  
pp. 25314-25333
Author(s):  
Mai A. Khaled ◽  
Mohamed A. Ismail ◽  
Ahmed. A. El-Hossiany ◽  
Abd El-Aziz S. Fouda
Keyword(s):  
Weight Loss ◽  
Electrochemical Impedance Spectroscopy ◽  
Nitric Acid ◽  
Impedance Spectroscopy ◽  
Acid Solution ◽  
Nitric Acid Solution ◽  
Potentiodynamic Polarization ◽  
Corrosion Inhibitors ◽  
Electrochemical Impedance ◽  
Pyrimidine Derivatives

This study targets the investigation of three pyrimidine derivatives (MA-1230, MA-1231, MA-1232) for the prevention of corrosion on copper in 1 M HNO3via weight loss (WL), potentiodynamic polarization (PDP), and electrochemical impedance spectroscopy (EIS) techniques.

Treatment of As(V) and As(III) by electrocoagulation using Al and Fe electrode

2009 ◽  
Vol 60 (5) ◽  
pp. 1341-1346 ◽  
Author(s):  
W. H. Kuan ◽  
C. Y. Hu ◽  
M. C. Chiang
Keyword(s):  
Passive Film ◽  
Potentiodynamic Polarization ◽  
Electrode Materials ◽  
Initial Period ◽  
Electrode System ◽  
Initial Solution ◽  
Alkaline Condition ◽  
Bipolar Electrode ◽  
Pitting Potential ◽  
Fe Hydroxide

A batch electrocoagulation (EC) process with bipolar electrode and potentiodynamic polarization tests with monopolar systems were investigated as methods to explore the effects of electrode materials and initial solution pH on the As(V) and As(III) removal. The results displayed that the system with Al electrode has higher reaction rate during the initial period from 0 to 25 minutes than that of Fe electrode for alkaline condition. The pH increased with the EC time because the As(V) and As(III) removal by either co-precipitation or adsorption resulted in that the OH positions in Al-hydroxide or Fe-hydroxide were substituted by As(V) and As(III). The pH in Fe electrode system elevate higher than that in Al electrode because the As(V) removal substitutes more OH position in Fe-hydroxide than that in Al-hydroxide. EC system with Fe electrode can successfully remove the As(III) but system with Al electrode cannot because As(III) can strongly bind to the surface of Fe-hydroxide with forming inner-sphere species but weakly adsorb to the Al-hydroxide surface with forming outer-sphere species. The acidic solution can destroy the deposited hydroxide passive film then allow the metallic ions liberate into the solution, therefore, the acidic initial solution can enhance the As(V) and As(III) removal. The over potential calculation and potentiodynamic polarization tests reveal that the Fe electrode systems possess higher over potential and pitting potential than that of Al electrode system due to the fast hydrolysis of and the occurrence of Fe-hydroxide passive film.

Electrochemical Investigation Cu Corrosion Behaviour of Electronic Circuit Board in Base Electrolyte

2014 ◽  
Vol 556-562 ◽  
pp. 141-144
Author(s):  
Zhi Hua Tao ◽  
Bin Leng ◽  
Chong Wang ◽  
Ding Jun Xiao ◽  
Ze Tan ◽  
...  
Keyword(s):  
Potentiodynamic Polarization ◽  
Electronic Circuit ◽  
Corrosion Behaviour ◽  
Chloride Ions ◽  
Circuit Board ◽  
Corrosion Mechanism ◽  
Base Electrolyte ◽  
Eis Measurements ◽  
Inhibition Performance ◽  
Cu Corrosion

The eleetronic material, or even the whole equipments may be destroyed by very slight corrosion, so it is important to study the corrosion mechanism and corrosion protections. The Cyproconazole as a Cu corrosion inhibitor for Electronic Circuit Board in the base electrolyte (containing 70 ppm chloride ions, 0.54 mol/L H2SO4and 0.8 mol/L CuSO4) was investigated using polarization curves and AC impedance. The results showed that the inhibition performance of the Cyproconazole depended on the concentration of the inhibitor and the highest inhibition efficiency of the Cyproconazole reached 99.9% at 1×10-3mol/L in the base electrolyte. The results obtained from EIS measurements are in good agreement with that obtained from potentiodynamic polarization. Potentiodynamic polarization studies clearly revealed that Cyproconazole adsorption acted essentially as the mixed-type inhibitor.

Microstructure and Phase Analyses on the Corrosion of SAC305 Solder in NaСl Solution

2018 ◽  
Vol 273 ◽  
pp. 91-94 ◽  
Author(s):  
Nurwahida Mohd Zaini ◽  
Mukridz Md Mohtar ◽  
Ahmad Azmin Mohamad ◽  
Muhammad Firdaus Mohd Nazeri
Keyword(s):  
Corrosion Product ◽  
Potentiodynamic Polarization ◽  
Structural Changes ◽  
Corrosion Performance ◽  
Sac305 Solder ◽  
Characterization Methods

Utilization of Sn-3.0Ag-0.5Cu to replace toxic lead-based solder was only feasible if the corrosion performance of this solder was assured. To obtain this information, potentiodynamic polarization was implement in 3.5 wt. % NaCl. The morphological and structural changes were investigated via crucial characterization methods (SEM and XRD). Collective evidences verified that the needle-like corrosion product confirmed to be made ofSnO, SnO2and SnCl-and responsible to passivation behavior of this solder.

Degradation Behaviour of Metallic Biomaterials for Degradable Stents

2006 ◽  
Vol 15-17 ◽  
pp. 113-118 ◽  
Author(s):  
Hendra Hermawan ◽  
Maryam Moravej ◽  
Dominique Dubé ◽  
Michel Fiset ◽  
D. Mantovani
Keyword(s):  
Potentiodynamic Polarization ◽  
Degradation Rate ◽  
Corrosion Behaviour ◽  
Dynamic Test ◽  
Potential Candidate ◽  
Human Coronary Artery ◽  
Ion Release ◽  
Degradation Behaviour ◽  
Static Immersion

The short-term need of scaffolding function of stent and the prevention of potential longterm complication of permanently implanted stent have directed to the original idea of biodegradable stent. Selecting and developing materials showing appropriate mechanical and degradation properties are key steps for the development of this new class of medical devices. Therefore, the study of their in vitro degradation behaviour is mandatory for the selection of potential candidate materials suited in vivo. In this work, the degradation behaviour of current studied biodegradable metals including three magnesium alloys (Mg, AM60B and AZ91D), pure iron and Fe-35Mn was investigated. The tests were performed in a simulated blood plasma solution at 37±0.1 oC, using three different methods; potentiodynamic polarization, static immersion, and dynamic test in a test-bench which mimics the flow condition in human coronary artery. Degradation rate was determined as ion release rate measured by using atomic adsorption spectroscopy (AAS) and also estimated from weight loss and corrosion current. Surface morphology and chemical composition of corroded specimens were analyzed by using SEM/EDS. The three degradation methods provide consistent results in corrosion tendency, where Mg showed the highest corrosion rate followed by AZ91D, AM60B, Fe-35Mn and iron. Potentiodynamic polarization gives a rapid estimation of corrosion behaviour and rate. Static immersion test shows the effect of time on the degradation rate and behaviour. Dynamic test provides the closest approach to the environment after stent implantation and its results show the effect of the flow on the materials degradation. In conclusion, the three investigated methods can be applied for screening, selecting and validating materials for degradable stent application before going further to in vivo assessments.

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