Automatic Isotherm Derivation From Field Data for Oilfield Scale-Inhibitor Squeeze Treatments

SPE Journal ◽  
2013 ◽  
Vol 18 (03) ◽  
pp. 563-574 ◽  
Author(s):  
Oscar Vazquez ◽  
David Corne ◽  
Eric James Mackay ◽  
Myles Martin Jordan

Summary Oilfield scale formation represents a significant flow-assurance challenge to the oil and gas industry, because of increasing water production worldwide and higher oil prices. Scale-inhibitor (SI) squeeze treatment is the most widespread method to combat downhole scaling. To predict SI squeeze treatments accurately for further optimization, it is necessary to simulate the SI retention in the formation, which may be described by a pseudoadsorption isotherm. Although these are often derived from coreflood experiments, sometimes they are not appropriate for modeling well treatments because the core tests on which they are based cannot fully represent field-scale processes. In practice, the parameters of an analytic form of the isotherm equation are modified by trial and error by an experienced practitioner until a match is obtained between the prediction and the return profile of the first treatment in the field. The main purpose of this paper is to present a stochastic hill-climbing algorithm for automatic isotherm derivation. The performance of the algorithm was evaluated by use of data from three field cases. Two success criteria were defined: the ability to match a single historical treatment and the ability to predict subsequent successive treatments. To test for the second criterion, a candidate isotherm was derived from the first treatment in a well that was treated with the same chemical package on consecutive occasions, and then the predictions by use of the suggested solution were compared with the observed SI concentration-return profiles from the subsequent treatments. In all the calculations, the performances of both the isotherms suggested by the hill-climbing algorithm and the isotherms derived by trial and error were compared. The results demonstrate that the hill-climbing algorithm is an effective technique for deriving an isotherm for a single treatment, although predictions for successive treatments worsened slightly with each treatment.

Author(s):  
Ully Zakyatul Husna ◽  
Khaled Abdalla Elraies ◽  
Juhairi Aris B. M. Shuhili ◽  
Ahmed Abdulla Elryes

AbstractScale formation is one of the major issues in the petroleum industry. The development of these scale layers could result in production losses and equipment instability because of pipeline blockage, energy leakage, corrosion acceleration and severe accidents which will impact the safety of the production process. The utilization of chemical scale inhibitors (SIs) is considered an economical and successful route for the scale prevention. Two main components of the chemical SIs are phosphonate and polymer. Many of the phosphorous compounds are toxic and very expensive. Besides, portions of the phosphonate compounds are thermally less stable than polymeric scale inhibitors in a harsh environment of high temperature and high pressure (HTHP). This is considered as an issue as a good scale inhibitor should be able to be applied under wide range of temperature and pressure. Therefore, the continuous development in petroleum production imposes the need to develop a novel phosphorus-free scale inhibitor. Meanwhile, polymers have been broadly applied as a scale inhibitor in oil and gas fields because of their enhanced thermal stability and improved environmental compatibility. Polymeric scale inhibitors also show better dispersing efficiency. Today, the biopolymers have pulled in a tremendous consideration from the industry to replace the utilization of synthetic polymer due to their interesting qualities such as their lightness, strong mechanical properties, and appealing functionality. Biopolymers are insensitive toward brine salinity yet are vulnerable to biological degradation. Specifically, these polymers present enormous potential for environmental application because of their biodegradability, chemical adaptability and reactivity, biocompatibility, and nontoxicity. Recently, several new eco-friendly scale inhibitors have been reported in the literature. Hence, this paper provides a review of the utilization of biopolymer as scale inhibitor in the application of oil and gas industry under laboratory approach or field trial application. The types of scales, chemical scale inhibitors (SIs) and biopolymers are likewise reviewed here. The presented work in this paper is expected to enhance the fundamental understanding of scale formation, as well as contribute to the development process of biopolymer scale inhibitors.


2014 ◽  
Author(s):  
Y.. Zhang ◽  
J.K.. K. Daniels ◽  
J.. Hardy-Fidoe ◽  
C.. Durnell ◽  
M. E. Broussard ◽  
...  

Abstract Control of inorganic scale deposition within the near well bore area under both natural depletion and injection water support has been a challenge to the oil industry for a number of decades. The application of scale inhibitor squeeze treatments to production wells to control the onset of inorganic scale within the near-wellbore and production tubing has been a common practice within the onshore and offshore oil and gas industry for over 30 years. The development of subsea fields require scale inhibitor squeeze treatments with extended squeeze lifetimes while limited number of flowlines to the host facility has increased the difficulty in obtaining and evaluating individual well water samples from which residual scale inhibitor concentrations are derived. Traditional analytical techniques, while robust and widely accepted, do not provide differentiation between scale inhibitors that belong to the same chemical family (i.e.: two or more phosphonates or two or more polymers). The individual analysis of phosphonate scale inhibitors in co-mingled flow backs from subsea wells is a particularly challenging application for analytical techniques in the industry. Advances in separation and mass detection techniques, however, provide new options to accurately measure the concentration of scale inhibitors in these fluids to very low detection limits. This paper will describe the analytical development of these new techniques and discuss its implication to the optimization of scale squeeze treatments in subsea, deepwater developments.


2014 ◽  
Author(s):  
N.. Ghorbani ◽  
M. C. Wilson ◽  
N.. Kapur ◽  
N.. Fleming ◽  
A.. Neville

Abstract A new potential application of nanotechnology for mineral scale prevention in the oil and gas industry is presented. In current squeeze treatments, in which scale inhibitors are squeezed into wells to adsorb or precipitate onto rock surfaces for later release, a large proportion of the injected inhibitor does not adsorb and is therefore returned very quickly from the reservoir upon well re-start. Here it is demonstrated that nano-particles have the potential to enhance squeeze lifetime by greatly increasing the adsorption of inhibitors within the formation. An extensive literature review is presented, exploring the potential for using nano-scale materials in squeeze treatments. One of the observations from scale inhibitor squeezes into sandstone reservoirs is the apparent lack of suitable surfaces available for adsorption. The main constituent of sandstones, quartz, has a very low ability to adsorb inhibitor (1 mg/l). Given this, research using nanotechnology was targeted towards enhancing the available sites for scale inhibitor adsorption within the near wellbore. Specifically, research was undertaken to examine the potential benefits of using carbon nanotubes in a process called Nanotechnology Assisted Squeeze Treatment (NAST). The process involves carbon nanotubes adsorbing and permanently modifying the near wellbore with scale inhibitors subsequently adsorbing onto the nanotubes. This process was observed to be significantly higher than a non-modified near wellbore surface, with a maximum adsorption of more than 85 and 160mg/g onto the nanotubes in solution of distilled water (DW) and CaCl2 in DW; respectively, compared to 1 mg/g directly onto the rock. Coreflood tests comparing the NAST procedure with a simplified standard coreflood show the potential for improvement of the squeeze lifetime.


2020 ◽  
Vol 78 (7) ◽  
pp. 861-868
Author(s):  
Casper Wassink ◽  
Marc Grenier ◽  
Oliver Roy ◽  
Neil Pearson

2004 ◽  
pp. 51-69 ◽  
Author(s):  
E. Sharipova ◽  
I. Tcherkashin

Federal tax revenues from the main sectors of the Russian economy after the 1998 crisis are examined in the article. Authors present the structure of revenues from these sectors by main taxes for 1999-2003 and prospects for 2004. Emphasis is given to an increasing dependence of budget on revenues from oil and gas industries. The share of proceeds from these sectors has reached 1/3 of total federal revenues. To explain this fact world oil prices dynamics and changes in tax legislation in Russia are considered. Empirical results show strong dependence of budget revenues on oil prices. The analysis of changes in tax legislation in oil and gas industry shows that the government has managed to redistribute resource rent in favor of the state.


2011 ◽  
pp. 19-33
Author(s):  
A. Oleinik

The article deals with the issues of political and economic power as well as their constellation on the market. The theory of public choice and the theory of public contract are confronted with an approach centered on the power triad. If structured in the power triad, interactions among states representatives, businesses with structural advantages and businesses without structural advantages allow capturing administrative rents. The political power of the ruling elites coexists with economic power of certain members of the business community. The situation in the oil and gas industry, the retail trade and the road construction and operation industry in Russia illustrates key moments in the proposed analysis.


2019 ◽  
Vol 16 (6) ◽  
pp. 50-59
Author(s):  
O. P. Trubitsina ◽  
V. N. Bashkin

The article is devoted to the consideration of geopolitical challenges for the analysis of geoenvironmental risks (GERs) in the hydrocarbon development of the Arctic territory. Geopolitical risks (GPRs), like GERs, can be transformed into opposite external environment factors of oil and gas industry facilities in the form of additional opportunities or threats, which the authors identify in detail for each type of risk. This is necessary for further development of methodological base of expert methods for GER management in the context of the implementational proposed two-stage model of the GER analysis taking to account GPR for the improvement of effectiveness making decisions to ensure optimal operation of the facility oil and gas industry and minimize the impact on the environment in the geopolitical conditions of the Arctic.The authors declare no conflict of interest


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