scholarly journals The Pozzolanic Activity of the Sediment Treated by the Flash Calcination Method

2021 ◽  
Author(s):  
DUC CHINH CHU ◽  
Mouhamadou AMAR ◽  
Joelle KLEIB ◽  
Mahfoud BENZERZOUR ◽  
Damien BETRANCOURT ◽  
...  
Keyword(s):  
Compressive Strength ◽  
Isothermal Calorimetry ◽  
Pozzolanic Reactivity ◽  
Development Of Resistance ◽  
Physico Chemical ◽  
Flash Calcination ◽  
Alternative Materials ◽  
Different Temperatures ◽  
And Performance ◽  
Calcination Method

Abstract The dredged sediment has been positioned for years as alternative materials in the construction field. However, it is often necessary to apply a treatment to improve their reactivity and performance. This article aims to study the pozzolanic reactivity of fluvial sediment treated by flash calcination method at different temperatures 650 °C, 750 °C, and 800 °C. The physico-chemical, mineralogical, and environmental characteristics were studied for treated (flash-calcined sediment) and raw sediment. The pozzolanic reactivity of the flash-calcined sediments was estimated with Frattini’s test, isothermal calorimetry test, lime consumption analysis and compressive strength then compared to metakaolin which is considered as the reference. The results of the compressive strength of mortars show the detrimental effect of raw sediment on the development of resistance. Contrary to the raw sediment, the treatment of the sediments by flash calcination activates the pozzolanic reactivity of the clay phases and considerably improves the contribution of the sediments to the development of resistance and the porous structure. Moreover, the sediment calcined at 750 °C gives better properties than those obtained at 650 °C and 800 °C. The result demonstrates the feasibility of using calcined sediments as a pozzolanic mineral addition in a cementitious material.

scholarly journals The Apparent Activation Energy of a Novel Low-Calcium Silicate Hydraulic Binder

Materials ◽  
2021 ◽  
Vol 14 (18) ◽  
pp. 5347
Author(s):  
Mónica Antunes ◽  
Rodrigo Lino Santos ◽  
João Pereira ◽  
Ricardo Bayão Horta ◽  
Patrizia Paradiso ◽  
...  
Keyword(s):  
Activation Energy ◽  
Compressive Strength ◽  
Apparent Activation Energy ◽  
Isothermal Calorimetry ◽  
Hydration Product ◽  
Specific Rate ◽  
Initial Development ◽  
Low Calcium ◽  
Acceleration Period ◽  
Different Temperatures

In this work, the apparent activation energy (Ea) of a novel low-calcium binder was, for the first time, experimentally determined, using a calorimetric approach. Additionally, a correlation between the Ea, measured at the acceleration period with the C/S ratio of the hydration product is proposed. The Ea of the prepared pastes was determined through isothermal calorimetry tests by calculating the specific rate of reaction at different temperatures, using two different approaches. When comparing the Ea, at the acceleration period of this novel binder with the one published for alite and belite, we observed that its value is higher, which may be a result of a different hydration product formed with a distinct C/S ratio. Finally, to study the temperature effect on the compressive strength at early ages, a set of experiments with mortars was performed. The results showed that the longer the curing time at 35 °C, the higher the compressive strength after 2 days of hydration, which suggests a higher initial development of hydration products. This study also indicated that the novel binder has a higher sensitivity to temperature when compared with ordinary Portland cement (OPC).

scholarly journals Microstructural Modeling of Glass Cullet Reaction in Cementitious Systems

2018 ◽  
Author(s):  
Mohammadreza Mirzahosseini
Keyword(s):  
Cement Hydration ◽  
Isothermal Calorimetry ◽  
Experimental Studies ◽  
Glass Particle ◽  
Supplementary Cementitious Material ◽  
Microstructural Modeling ◽  
Pozzolanic Reactivity ◽  
And Performance ◽  
Main Components ◽  
Cementitious Systems

Finely ground glass has the potential for pozzolanic reactivity and can serve as a supplementary cementitious material (SCM). Glass reaction kinetics depends on both temperature and glass composition. Microstructural modeling is a helpful approach to get better understanding of cement hydration and microstructure development. Mechanical and performance properties of concrete are directly related to the development of concrete microstructure, which is the consequence of progress in cement hydration. This study initially provides a comprehensive background about cement hydration process and microstructural modeling of the hydration. It then utilizes results of experimental studies, i.e. isothermal calorimetry and thermogravimetric analysis, to find kinetics equation parameters called “Avrami Constants”. For the first time, these constants were found for three main components of cement, i.e. C3S, C2S, and C3A, and also for glass particles smaller than 25 µm. Although modeling of cement hydration and cementitious systems containing single glass particles showed promising results, simulations of combined glass types and sizes showed that more work on microstructural models is needed to properly model the reactivity of mixed glass particle systems.

Progress and Prospects in Translating Nanobiotechnology in Medical Theranostics

2020 ◽  
Vol 16 (5) ◽  
pp. 685-707 ◽  
Author(s):  
Amna Batool ◽  
Farid Menaa ◽  
Bushra Uzair ◽  
Barkat Ali Khan ◽  
Bouzid Menaa
Keyword(s):  
Biological Properties ◽  
Chemical Characteristics ◽  
Intrinsic Properties ◽  
The Past ◽  
Profound Influence ◽  
Functionalized Nanomaterials ◽  
Physico Chemical ◽  
Properties Of Materials ◽  
Targeted Drug ◽  
And Performance

: The pace at which nanotheranostic technology for human disease is evolving has accelerated exponentially over the past five years. Nanotechnology is committed to utilizing the intrinsic properties of materials and structures at submicroscopic-scale measures. Indeed, there is generally a profound influence of reducing physical dimensions of particulates and devices on their physico-chemical characteristics, biological properties, and performance. The exploration of nature’s components to work effectively as nanoscaffolds or nanodevices represents a tremendous and growing interest in medicine for various applications (e.g., biosensing, tunable control and targeted drug release, tissue engineering). Several nanotheranostic approaches (i.e., diagnostic plus therapeutic using nanoscale) conferring unique features are constantly progressing and overcoming all the limitations of conventional medicines including specificity, efficacy, solubility, sensitivity, biodegradability, biocompatibility, stability, interactions at subcellular levels. : This review introduces two major aspects of nanotechnology as an innovative and challenging theranostic strategy or solution: (i) the most intriguing (bare and functionalized) nanomaterials with their respective advantages and drawbacks; (ii) the current and promising multifunctional “smart” nanodevices.

scholarly journals Fire Resistance Behaviour of Geopolymer Concrete:An Overview

Buildings ◽  
2021 ◽  
Vol 11 (3) ◽  
pp. 82
Author(s):  
Salmabanu Luhar ◽  
Demetris Nicolaides ◽  
Ismail Luhar
Keyword(s):  
Compressive Strength ◽  
Thermal Resistance ◽  
Building Materials ◽  
Elevated Temperatures ◽  
Construction Materials ◽  
Flexural Behavior ◽  
Thermal Shrinkage ◽  
Physico Chemical ◽  
The Impact ◽  
Loss Of Strength

Even though, an innovative inorganic family of geopolymer concretes are eye-catching potential building materials, it is quite essential to comprehend the fire and thermal resistance of these structural materials at a very high temperature and also when experiencing fire with a view to make certain not only the safety and security of lives and properties but also to establish them as more sustainable edifice materials for future. The experimental and field observations of degree of cracking, spalling and loss of strength within the geopolymer concretes subsequent to exposure at elevated temperature and incidences of occurrences of disastrous fires extend an indication of their resistance against such severely catastrophic conditions. The impact of heat and fire on mechanical attributes viz., mechanical-compressive strength, flexural behavior, elastic modulus; durability—thermal shrinkage; chemical stability; the impact of thermal creep on compressive strength; and microstructure properties—XRD, FTIR, NMR, SEM as well as physico-chemical modifications of geopolymer composites subsequent to their exposures at elevated temperatures is reviewed in depth. The present scientific state-of-the-art review manuscript aimed to assess the fire and thermal resistance of geopolymer concrete along with its thermo-chemistry at a towering temperature in order to introduce this novel, most modern, user and eco-benign construction materials as potentially promising, sustainable, durable, thermal and fire-resistant building materials promoting their optimal and apposite applications for construction and infrastructure industries.

Self-Toughness Porous Sodium Titanate Bioceramics Prepared via In Situ Grown Na2Ti6O13 Rods

2017 ◽  
Vol 727 ◽  
pp. 806-814 ◽  
Author(s):  
Xiao Wei Ma ◽  
Jian Xing Shen ◽  
Ke Chang Zhang ◽  
Ling Kai Kong ◽  
Jia Le Sun ◽  
...  
Keyword(s):  
Fracture Toughness ◽  
Compressive Strength ◽  
Sodium Titanate ◽  
The Novel ◽  
Ceramic Samples ◽  
Porous Bioceramic ◽  
Different Temperatures ◽  
Growth Method ◽  
Titanate Ceramics

Here in, we report the porous bioceramic with Na2Ti6O13 rods prepared by in‒situ growth method. The samples were prepared using cold uniaxial pressing (40 MPa) technique and further sintered at different temperatures. The structure and morphology were characterized by XRD and SEM. The porosity, compressive strength and fracture toughness were also investigated. The bone-like apatite deposition ability of the fabricated ceramic samples was evaluated by Kokubo simulated body fluid (SBF) soaking method. The results indicated that the Na2Ti6O13 rods with about 1‒3 μm in diameter are uniformly distributed in the self‒toughness porous sodium titanate ceramics (SPSTC). The SPSTC with a porosity of 61.10±1.12 % exhibits good compressive strength (43.36±2.43 MPa) and fracture toughness (3.47±0.21 MPa·m1/2). The results indicate that the novel SPSTC scaffolds are promising for bone tissue engineering applications.

scholarly journals Response of Recycled Brick Aggregate Concrete to High Temperatures

2019 ◽  
Vol 8 (10) ◽  
pp. 224-227
Keyword(s):  
Mechanical Properties ◽  
Air Pollution ◽  
Compressive Strength ◽  
Construction Industry ◽  
Fire Performance ◽  
Demolition Waste ◽  
Aggregate Concrete ◽  
Different Temperatures ◽  
Better Than ◽  
Made In

The abundant availability of demolition waste from construction industry is leading towards a significant problem of disposal, land and air pollution. The natural aggregate resources are also depleting due to development of construction activities. An attempt is made in this study to convert this waste into wealth by substituting the recycled brick from demolition waste to granite aggregate in production of the concrete. The granite aggregate (GA) is replaced with recycled brick aggregate (RBA) by 25% of its weight to produce M15 and M20 grades of concrete. The granite aggregate concrete (GAC) and recycled brick aggregate concrete (RBAC) were subjected to different temperatures between 100 to 1000oC for a duration of 3 hours and the mechanical properties such as compressive strength and flexural strength were examined to assess its fire performance. The response of RBAC is better than GAC at each temperature. The study revealed that the residual strength increases with the increase in grade of concrete at all temperatures.

scholarly journals Characterization and Performance of Mechanical Properties of GGBS Based Geo Polymer Mortars

2019 ◽  
Vol 8 (4) ◽  
pp. 8336-8342
Keyword(s):  
Mechanical Properties ◽  
Compressive Strength ◽  
Fly Ash ◽  
Sodium Hydroxide ◽  
Construction Industry ◽  
Research Paper ◽  
Setting Times ◽  
And Performance ◽  
Creep And Shrinkage

From decades it has been recognized that Geopolymer will considerably replace the role of cement in the construction industry. In general, Geopolymer exhibits the property of the peak compressive strength, minimal creep and shrinkage. In this current research paper, Geopolymer mortar is prepared by using GGBS and Fly ash. The mix proportions are of (100-60)%GGBS with Fly ash by 10% replacement. The alkali activators Na0H and Na2Sio3 are used in the study for two different molarities of 4&8. The ratio to Sodium silicates to sodium hydroxide is maintained from 1.5, 2, 2.5 & 3 were used. Mortars are prepared and studied the effect of molarities of alkali activators in their setting times and strengths

scholarly journals Influence of Reduced Water Cement Ratio on Behaviour of Concrete Having Plastic Aggregate

2018 ◽  
Vol 4 (12) ◽  
pp. 2971 ◽  
Author(s):  
Saad Tayyab ◽  
Asad Ullah ◽  
Kamal Shah ◽  
Faial Mehmood ◽  
Akhtar Gul
Keyword(s):  
Compressive Strength ◽  
Coarse Aggregate ◽  
Stress Strain ◽  
Cement Ratio ◽  
Coarse Aggregates ◽  
Alternative Materials ◽  
Super Plasticizer ◽  
Strain Relationship ◽  
Natural Aggregates ◽  
Reduced Water

The production and use of plastic bottles is increasing tremendously with passing time. These plastic bottles become a problem when they are disposed as they are non-biodegradable. This means that the waste plastic, when dumped, does not decompose naturally and stays in the environment affecting the ecological system. The use of alternative aggregates like Plastic Coarse Aggregate (PCA) is a natural step in solving part of reduction of natural aggregates as well as to solve the issue discussed above. The researchers are trying from half a century to investigate the alternative materials to be replaced in concrete mixture in place of either aggregate or cement.  In this research, the concrete made from plastic waste as coarse aggregates were investigated for compressive strength and Stress-strain relationship. Plastic coarse aggregate have been replaced in place of natural coarse aggregate by different percentages with w/c 0.5, 0.4 and 0.3. The percentage replacement of plastic aggregate in place of mineral coarse aggregate was 25%, 30%, 35% and 40 %. Using Super-plasticizer Chemrite 520-BAS. OPC-53 grade cement was used. Total of forty five Cylinders were prepared based on different combination of Percentage of Plastic aggregate replaced and W/C as discussed above and checked for compressive strength and stress-strain relationship. The compressive strength increases by about 19.25% due to the decrease in W/C from 0.5 to 0.3 for plastic percentage addition of 40%.

Sign in / Sign up

Export Citation Format

Share Document