The Effect of Additional Polyethylene Glycol (PEG) as Coating Fe3O4 for Magnetic Nanofluid Applications

Author(s):  
Ganesha Antarnusa ◽  
Yus Rama Denny ◽  
Andri Suherman ◽  
Indri Sari Utami ◽  
Asep Saefullah

Background & Objective: Magnetic nanofluid is a special class of nanofluid that exhibits both magnetic and fluid properties. The main purpose of using magnetic nanofluid as a heat transfer medium comes from the possibility of controlling the flow and the heat transfer process through an external magnetic field. This research aims at identifying the effect of adding polyethylene glycol (PEG) to magnetite (Fe3O4) nanoparticles for magnetic nanofluid applications. Method: The nanofluid were prepared by synthesizing Fe3O4 nanoparticles using the chemical precipitation method, and then dispersed in distilled water using a sonicator. Results: The result of XRD is that nanoparticles had inverse spinel structures and the smallest crystallite size is found in the Fe3O4@PEG-6000 samples. FE-SEM and TEM show that the addition of PEG can reduce the Fe3O4 agglomeration and the smallest particle size is found in the Fe3O4@PEG-6000 samples. The result of FT-IR shows that there is a surface modification of Fe3O4 nanoparticles and PEG polymer. The result of VSM shows the coercivity value is small so that the sample is superparamagnetic material. The addition of PEG increases the thermal conductivity of Fe3O4 nanoparticles. Conclusion: The addition of PEG makes particle size smaller, reduce the agglomeration and increases the thermal conductivity, so that it is potential for magnetic nanofluid applications.

Nanomaterials ◽  
2021 ◽  
Vol 11 (2) ◽  
pp. 341
Author(s):  
Tien Hiep Nguyen ◽  
Gopalu Karunakaran ◽  
Yu.V. Konyukhov ◽  
Nguyen Van Minh ◽  
D.Yu. Karpenkov ◽  
...  

This paper presents the synthesis of Fe–Co–Ni nanocomposites by chemical precipitation, followed by a reduction process. It was found that the influence of the chemical composition and reduction temperature greatly alters the phase formation, its structures, particle size distribution, and magnetic properties of Fe–Co–Ni nanocomposites. The initial hydroxides of Fe–Co–Ni combinations were prepared by the co-precipitation method from nitrate precursors and precipitated using alkali. The reduction process was carried out by hydrogen in the temperature range of 300–500 °C under isothermal conditions. The nanocomposites had metallic and intermetallic phases with different lattice parameter values due to the increase in Fe content. In this paper, we showed that the values of the magnetic parameters of nanocomposites can be controlled in the ranges of MS = 7.6–192.5 Am2/kg, Mr = 0.4–39.7 Am2/kg, Mr/Ms = 0.02–0.32, and HcM = 4.72–60.68 kA/m by regulating the composition and reduction temperature of the Fe–Co–Ni composites. Due to the reduction process, drastic variations in the magnetic features result from the intermetallic and metallic face formation. The variation in magnetic characteristics is guided by the reduction degree, particle size growth, and crystallinity enhancement. Moreover, the reduction of the surface spins fraction of the nanocomposites under their growth induced an increase in the saturation magnetization. This is the first report where the influence of Fe content on the Fe–Co–Ni ternary system phase content and magnetic properties was evaluated. The Fe–Co–Ni ternary nanocomposites obtained by co-precipitation, followed by the hydrogen reduction led to the formation of better magnetic materials for various magnetically coupled device applications.


2019 ◽  
Vol 29 (4) ◽  
pp. 1466-1489 ◽  
Author(s):  
Mohammadhossein Hajiyan ◽  
Shohel Mahmud ◽  
Mohammad Biglarbegian ◽  
Hussein A. Abdullah ◽  
A. Chamkha

Purpose The purpose of this paper is to investigate the convective heat transfer of magnetic nanofluid (MNF) inside a square enclosure under uniform magnetic fields considering nonlinearity of magnetic field-dependent thermal conductivity. Design/methodology/approach The properties of the MNF (Fe3O4+kerosene) were described by polynomial functions of magnetic field-dependent thermal conductivity. The effect of the transverse magnetic field (0 < H < 105), Hartmann Number (0 < Ha < 60), Rayleigh number (10 <Ra <105) and the solid volume fraction (0 < φ < 4.7%) on the heat transfer performance inside the enclosed space was examined. Continuity, momentum and energy equations were solved using the finite element method. Findings The results show that the Nusselt number increases when the Rayleigh number increases. In contrast, the convective heat transfer rate decreases when the Hartmann number increases due to the strong magnetic field which suppresses the buoyancy force. Also, a significant improvement in the heat transfer rate is observed when the magnetic field is applied and φ = 4.7% (I = 11.90%, I = 16.73%, I = 10.07% and I = 12.70%). Research limitations/implications The present numerical study was carried out for a steady, laminar and two-dimensional flow inside the square enclosure. Also, properties of the MNF are assumed to be constant (except thermal conductivity) under magnetic field. Practical implications The results can be used in thermal storage and cooling of electronic devices such as lithium-ion batteries during charging and discharging processes. Originality/value The accuracy of results and heat transfer enhancement having magnetic field-field-dependent thermal conductivity are noticeable. The results can be used for different applications to improve the heat transfer rate and enhance the efficiency of a system.


BioResources ◽  
2020 ◽  
Vol 15 (2) ◽  
pp. 2645-2655
Author(s):  
Yuehua Zhu ◽  
Yaoli Zhang ◽  
Biao Pan

The thermal conductivity and the deformation of wood from the Taxodium hybrid ‘Zhongshanshan’ were studied in the process of heat transfer. The results showed that the average thermal conductivity of this wood was 0.1257 W/(m·K) under the condition of 12% wood moisture content and 30 °C heat transfer temperature. When the testing temperature exceeded 0 °C, the thermal conductivity increased linearly with both temperature and wood moisture content and was affected by the moisture content of the wood. During the heat transfer process, the deformation of features caused repeated swelling and shrinkage in the longitudinal, radial, and tangential directions. The dimensional change was greatly affected by the wood’s moisture content and was less affected by the temperature. These results are of great meaning for the study of the heat transfer process of Taxodium hybrid ‘Zhongshanshan’ wood. Furthermore, it provides a scientific basis for the heat preservation effect, drying treatment, and pyrolysis treatment of Taxodium hybrid ‘Zhongshanshan’ wood for use as a building material.


2021 ◽  
Author(s):  
Chase Ellsworth Christen

Solid particles are being considered in several high temperature thermal energy storage systems and as heat transfer media in concentrated solar power (CSP) plants. The downside of such an approach is the low overall heat transfer coefficients in shell-and-plate moving packed bed heat exchangers caused by the inherently low packed bed thermal conductivity values of the low-cost solid media. Choosing the right particle size distribution of currently available solid media can make a substantial difference in packed bed thermal conductivity, and thus, a substantial difference in the overall heat transfer coefficient of shell-and-plate moving packed bed heat exchangers. Current research exclusively focuses on continuous unimodal distributions of alumina particles. The drawback of this approach is that larger particle sizes require wider particle channels to meet flowability requirements. As a result, only small particle sizes with low packed bed thermal conductivities have been considered for the use in the falling-particle Gen3 CSP concepts. Here, binary particle mixtures, which are defined in this thesis as a mixture of two continuous unimodal particle distributions leading to a continuous bimodal particle distribution, are considered to increase packed bed thermal conductivity, decrease packed bed porosity, and improve moving packed bed heat exchanger performance. This is the first study related to CSP solid particle heat transfer that has considered the packed bed thermal conductivity and moving packed bed heat exchanger performance of bimodal particle size distributions at room and elevated temperatures. Considering binary particle mixtures that meet particle sifting segregation criteria, the overall heat transfer coefficient of shell-and-plate moving packed bed heat exchangers can be increased by 23% when compared to a monodisperse particle system. This work demonstrates that binary particle mixtures should be seriously considered to improve shell-and-plate moving packed bed heat exchangers.


Author(s):  
P. E. Phelan ◽  
J. R. Pacheco

In this paper, a numerical scheme based on the immersed boundary method is used to study the motion of nano-sized particles subjected to Brownian motion and heat transfer. Our objective is to use this numerical technique as a tool to better understand the effect that Brownian forces have on the overall heat transfer process. The conventional approach to perform Brownian dynamic simulations is based on the use of a random force in the particle motion such that the fluctuation-dissipation theorem is satisfied. Our preliminary computational results suggest an increase in the thermal conductivity of the bulk fluid. Results are presented for several particles in a two-dimensional space.


2020 ◽  
Vol 274 ◽  
pp. 128043
Author(s):  
Shahir Hussain ◽  
Md. Mottahir Alam ◽  
Mohd Imran ◽  
Nasser Zouli ◽  
Abdul Aziz ◽  
...  

2018 ◽  
Vol 251 ◽  
pp. 02048 ◽  
Author(s):  
Ian Ofrikhter ◽  
Alexander Zaharov ◽  
Andrey Ponomaryov ◽  
Natalia Likhacheva

In this paper, a new model is presented for calculating the thermal conductivity of soils, and the main provisions for the derivation of analytical formulas are given. The presented model allows taking into account the density, moisture content and temperature of the soil base. The technique presented in the paper makes it possible to dispense with laborious experiments to estimate the thermal conductivity of the soil. The method of analytical calculation is step by step presented in the paper. Two variants of using the method are proposed: 1) Less accurate method, for preliminary evaluation, without the need to take probe and conduct experiments. 2) More accurate method, with at least one experiment with a disturbed or undisturbed sample. The results of comparison of calculated values of thermal conductivity and experimental data are presented.


2013 ◽  
Vol 32 (5) ◽  
pp. 511-515 ◽  
Author(s):  
Xiao Guo Cao ◽  
Jia Wang ◽  
Qi Bai Wu ◽  
Hai Yan Zhang

AbstractYb:YAG transparent ceramic nano-powder was prepared by chemical co-precipitation method, with ammonium bicarbonate as the precipitant and polyethylene glycol as surfactant. The addition of polyethylene glycol can reduce the agglomeration and particle size of the prepared Yb:YAG powder. The morphology, thermal stability and phase structure of Yb:YAG nano-powder were charactered by scanning electron microscopy (SEM), thermogravimetry and differential thermal analysis (TG-DTA), X-ray diffraction (XRD), and Fourier transform infrared spectroscopy. The results show that well-crystallized nano-powder was obtained by calcining the precursors at 900 °C for 3 h. The average particle size of Yb:YAG powder is about 100–200 nm. When the volume amount of polyethylene glycol is 2.0%, well-dispersed Yb:YAG powder with spherical particles of 100 nm diameter was obtained.


2021 ◽  
Author(s):  
Ruifeng CAO ◽  
Taotao WANG ◽  
Yuxuan ZHANG ◽  
Hui WANG

Improved heat transfer in composites consisting of guar gel matrix and randomly distributed glass microspheres is extensively studied to predict the effective thermal conductivity of composites using the finite element method. In the study, the proper and probabilistic three-dimensional random distribution of microspheres in the continuous matrix is automatically generated by a simple and efficient random sequential adsorption algorithm which is developed by considering the correlation of three factors including particle size, number of particles, and particle volume fraction controlling the geometric configuration of random packing. Then the dependences of the effective thermal conductivity of composite materials on some important factors are investigated numerically, including the particle volume fraction, the particle spatial distribution, the number of particles, the nonuniformity of particle size, the particle dispersion morphology and the thermal conductivity contrast between particle and matrix. The related numerical results are compared with theoretical predictions and available experimental results to assess the validity of the numerical model. These results can provide good guidance for the design of advanced microsphere reinforced composite materials.


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