scholarly journals Perovskites based Nano Heterojunctions for Photocatalytic Pollutant Removal

2021 ◽  
pp. 208-252
Author(s):  
S. Kumar
Keyword(s):  
Hydrogen Generation ◽  
Sol Gel ◽  
Ceramic Powder ◽  
Pollutant Removal ◽  
High Symmetry ◽  
Future Perspectives ◽  
Inorganic Pollutant ◽  
Materials Used ◽  
New Generation ◽  
Low Symmetry

The development of new generation photocatalytic materials used for the betterment of human as well as environment. Perovskites and perovskites related nano-hetero-junction shows great interest for photocatalytic organic and inorganic pollutant removal. This chapter discusses its crystalline structures varying from cubic (high symmetry) to triclinic (very low symmetry). Various methods have been utilized for synthesis of perovskites such as sol-gel, hydrothermal, vapor deposition methods, solid-state reaction routs from oxide and high pressure technique. The first technique is used for the synthesis of perovskite is ceramic route in which the mixture of oxide was treated at high temperature and processed later by ceramic powder method. Various photocatalyst such as nitrides, sulphides, phosphides, oxide and mixed oxide are employed for photocatalytic water splitting or hydrogen generation. Future perspectives of perovskite-related photocatalyst are included in this chapter.

The usefulness of high index low symmetry zone axes for holz line analysis

1987 ◽  
Vol 45 ◽  
pp. 384-385
Author(s):  
C. M. Sung ◽  
D. B. Williams
Keyword(s):  
Lattice Parameter ◽  
High Order ◽  
Zone Axis ◽  
High Index ◽  
High Symmetry ◽  
Second Phases ◽  
Line Patterns ◽  
Low Symmetry ◽  
Line Analysis

Researchers have tended to use high symmetry zone axes (e.g. <111> <114>) for High Order Laue Zone (HOLZ) line analysis since Jones et al reported the origin of HOLZ lines and described some of their applications. But it is not always easy to find HOLZ lines from a specific high symmetry zone axis during microscope operation, especially from second phases on a scale of tens of nanometers. Therefore it would be very convenient if we can use HOLZ lines from low symmetry zone axes and simulate these patterns in order to measure lattice parameter changes through HOLZ line shifts. HOLZ patterns of high index low symmetry zone axes are shown in Fig. 1, which were obtained from pure Al at -186°C using a double tilt cooling holder. Their corresponding simulated HOLZ line patterns are shown along with ten other low symmetry orientations in Fig. 2. The simulations were based upon kinematical diffraction conditions.

Materials for bullet core

2020 ◽  
Vol 2020 (10) ◽  
pp. 8-21
Author(s):  
A. G. Kolmakov ◽  
◽  
I. O. Bannykh ◽  
V. I. Antipov ◽  
L. V. Vinogradov ◽  
...  
Keyword(s):  
High Speed ◽  
Bending Strength ◽  
Low Alloy Steels ◽  
Hard Alloys ◽  
Small Arms ◽  
Alloy Steels ◽  
Materials Used ◽  
Basic Ideas ◽  
New Generation ◽  
Natural Composite

he basic ideas about the process of introducing cores into protective barriers and the most common core patterns and their location in conventional and sub-caliber small arms bullets are discussed. The materials used for manufacture of cores are analyzed. It is concluded that for mass bullets of increased armor penetration the most rational choice can be considered the use of high-carbon low-alloy steels of a new generation with a natural composite structure and hardness of up to 70 HRC. For specialized armor-piercing bullets, cores made from promising economically-alloyed high-speed steels characterized by a high complex of «hardness—bending strength» are better alternative than ones made of hard alloys or tungsten alloys.

scholarly journals Nanoengineering in biomedicine: Current development and future perspectives

2020 ◽  
Vol 9 (1) ◽  
pp. 700-715 ◽  
Author(s):  
Wei Jian ◽  
David Hui ◽  
Denvid Lau
Keyword(s):  
Molecular Dynamics ◽  
Research And Development ◽  
Molecular Dynamics Simulations ◽  
Material Properties ◽  
Biomedical Applications ◽  
Metallic Materials ◽  
Future Perspectives ◽  
Current Development ◽  
Materials Used ◽  
Dynamics Simulations

AbstractRecent advances in biomedicine largely rely on the development in nanoengineering. As the access to unique properties in biomaterials is not readily available from traditional techniques, the nanoengineering becomes an effective approach for research and development, by which the performance as well as the functionalities of biomaterials has been greatly improved and enriched. This review focuses on the main materials used in biomedicine, including metallic materials, polymers, and nanocomposites, as well as the major applications of nanoengineering in developing biomedical treatments and techniques. Research that provides an in-depth understanding of material properties and efficient enhancement of material performance using molecular dynamics simulations from the nanoengineering perspective are discussed. The advanced techniques which facilitate nanoengineering in biomedical applications are also presented to inspire further improvement in the future. Furthermore, the potential challenges of nanoengineering in biomedicine are evaluated by summarizing concerned issues and possible solutions.

SURFACE-CHARGE-ENABLED PHOTOLYTIC HYDROGEN GENERATION IN V2O5·H2O/Au NANOCONJUGATES

MRS Advances ◽  
2016 ◽  
Vol 1 (46) ◽  
pp. 3121-3126
Author(s):  
Sunith Varghese ◽  
Charuksha Walgama ◽  
Mark Wilkins ◽  
Sadagopan Krishnan ◽  
Kaan Kalkan
Keyword(s):  
Surface Charge ◽  
Hydrogen Generation ◽  
Hydrogen Reduction ◽  
Energy Levels ◽  
Sol Gel ◽  
Band Edge ◽  
Conduction Band Edge ◽  
Current Voltage ◽  
Negative Surface ◽  
Negative Surface Charge

ABSTRACTThe present work investigates sol-gel synthesized vanadium oxyhydrate (V2O5·H2O) nanowires decorated with Au nanoparticles as potential photolytic H2 generators. As determined by UV photoelectron and optical spectroscopies, the conduction band edge of V2O5·H2O lies 0.6 eV below standard H+ reduction potential, implying no H2 can be generated. On the contrary, as measured by gas chromatography, our nanoconjugates yield reproducible light-to-hydrogen conversion efficiency of 5.3%, for the first hour of photolysis under 470 nm excitation. To explain the observed hydrogen reduction, we have hypothesized the vanadia electron energy levels are raised by some negative surface charge. With the objective of validating this hypothesis, we have performed cyclic current-voltage measurements. The derived conduction and valence band edge energies are not only consistent with the optical band gaps, but also validate the hypothesized energy increase by 1.6 eV, respectively. The negative surface charge is also corroborated by the ζ-potential. Based on the measured pH of 2.4, we attribute the negative surface charge to Lewis acid nature of the nanowires, establishing dative bonding with OH−. The present work establishes the importance of surface charge in photoelectrochemical reactions, where it can be instrumental and enabling in photolytic fuel production.

Fabrication and Characterization of Sol-Gel Derived PZT/WO3 Ceramics

2008 ◽  
Vol 55-57 ◽  
pp. 369-372 ◽  
Author(s):  
T. Sreesattabud ◽  
Anucha Watcharapasorn ◽  
Sukanda Jiansirisomboon
Keyword(s):  
Lead Zirconate Titanate ◽  
Sol Gel ◽  
Rhombohedral Phase ◽  
Lead Zirconate ◽  
X Ray Diffraction ◽  
Calcination Process ◽  
Materials Used ◽  
Phase Characterization ◽  
Gel Processing

Lead zirconate titanate/tungsten oxide (PZT/WO3) ceramics were prepared from the powders synthesized by a modified triol sol-gel processing method. In this study, the starting materials used for synthesis of PZT-sol were zirconium (IV) propoxide, titanium (IV) isopropxide, lead (II) acetate trihydrate and 1,1,1,- tris (hydroxymethyl) ethane. To prepare PZT/xWO3 powders (where x = 0, 0.5, 1 and 3 wt%), nano-sized WO3 was ultrasonically dispersed and mixed with the PZT sol, dried and calcined at 600°C for 4 h. X-ray diffraction results indicated that fully crystallized powders were obtained. Phase characterization suggested that at high WO3 concentration, the reaction between PZT and WO3 occurred during the calcination process. To prepare PZT/xWO3 ceramics, the powders were pressed and sintered at 1100°C for 6 h. Phase characterization by XRD indicated that the content of WO3 significantly affected tetragonal-to-rhombohedral phase transition. Microstructure of thermally etched samples showed that increasing the content of WO3 decreased grain size of the ceramics.

An X-ray diffraction study of AgNbO3 and comparison with NaNbO3

1999 ◽  
Vol 14 (4) ◽  
pp. 253-257 ◽  
Author(s):  
C. N. W. Darlington
Keyword(s):  
Diffraction Pattern ◽  
Figure Of Merit ◽  
Parent Phase ◽  
Incident Beam ◽  
Large Error ◽  
High Symmetry ◽  
X Ray Diffraction ◽  
Beam Focusing ◽  
Low Symmetry

The powder diffraction pattern of the perovskite AgNbO3 has been measured using CuKα1 radiation with an incident beam focusing monochromator to eliminate the Kα2 component. Indexing the pattern shows that the multipartite cell is 2×2×4 times that of the pseudocubic subcell. Comparison is made with the diffraction pattern of NaNbO3, which has a similar multipartite unit cell. There are strong similarities, but close inspection shows that the structures are not isomorphous. The paper concludes with a discussion of the figure of merit FN for pseudosymmetric structures. It is suggested that two figures of merit be reported. The first should be the standard one using either all measured reflections or just the first 30. The proposed second figure of merit does not include any superlattice reflections. These superlattice reflections tend to be very weak, resulting in a low completeness factor and relatively large error in the measurement of their position. This effect produces an unrealistically low value of the standard figure of merit. By including only “main” reflections, i.e., those reflections that are common to both the low-symmetry and high-symmetry parent phase (if it exists), a much better estimate of the quality of the fitting of the measured diffraction pattern is obtained.

scholarly journals Nucleus-independent chemical shift profiles along the intrinsic distortion path for Jahn-Teller active molecules. Study on cyclopentadienyl radical and cobaltocene

2015 ◽  
Vol 80 (7) ◽  
pp. 877-888 ◽  
Author(s):  
Ljubica Andjelkovic ◽  
Marko Peric ◽  
Matija Zlatar ◽  
Maja Gruden-Pavlovic
Keyword(s):  
Density Functional ◽  
Chemical Shifts ◽  
High Symmetry ◽  
Functional Theory ◽  
Aromatic Character ◽  
Nucleus Independent Chemical Shift ◽  
Jahn Teller ◽  
Cyclopentadienyl Radical ◽  
Cyclopentadienyl Anion ◽  
Low Symmetry

The aromatic/antiaromatic behavior of the cyclopentadienyl anion (Cp-), bis(?5-cyclopentadienyl)iron(II) (Fe(Cp)2), as well as of the Jahn-Teller (JT) active cyclopentadienyl radical (Cp?) and bis(?5-cyclopentadienyl)cobalt(II) (Co(Cp)2) has been investigated using Density Functional Theory (DFT) calculations of the Nuclear Independent Chemical Shifts (NICS). According to the NICS values, pentagon ring in Fe(Cp)2 is more aromatic than isolated Cp-. The NICS parameters have been scanned along the Intrinsic Distortion Path (IDP) for Cp? and Co(Cp)2 showing antiaromaticity, which decreases with increasing deviation from high symmetry D5h to low symmetry (LS) C2v. Changes in the NICS values along the IDP revealed that Co(Cp)2 in the LS nuclear arrangement has aromatic character, in contrast to the case of Cp?

scholarly journals Supporting Infrastructure and Acceptability Issues for Materials Used in New Generation Vehicles

10.2172/6657 ◽  
1999 ◽  
Author(s):  
S. Das ◽  
T.R. Curlee ◽  
D.W. Jones ◽  
P.E. Leiby ◽  
J.D. Rubin ◽  
...  
Keyword(s):  
Materials Used ◽  
New Generation

scholarly journals Peculiar features of silicate materials curing

2018 ◽  
Vol 196 ◽  
pp. 04013
Author(s):  
Yulia Sidorenko ◽  
Alexander Guryanov ◽  
Vyacheslav Kozlov
Keyword(s):  
Technology Development ◽  
High Surface ◽  
Sol Gel ◽  
Practical Implementation ◽  
Modern Material ◽  
Individual Housing ◽  
Adhesive Ability ◽  
New Generation ◽  
The Given ◽  
Silicate Materials

The papers on contact-condensing (non-autoclave) curing of silicate materials point at the expediency of technology development. Non-autoclave silicate products of M 100 … 300 grades can be used in low-rise and individual housing construction. The complexity of practical implementation of the technology associated with the processes occurring in the field of highly dispersed phases requires research on micro capsulation of hydro silicate binder, in particular, the maintenance of its properties in technological redistribution. High surface energy of newgrowth causes particle clustering. It is desirable to obtain aggregates characterized by the lowest energy of their total intercrystallite interaction. Main mechanism of directed structure formation at the boundaries of the sections of the given binder is ultradisperse particles with a high adsorption capacity and adhesive ability, the main purpose of which is to strengthen the contact zone. The novelty of the proposed solutions lies in the fact that contact formation zone is presented as a multilayer system having different rheological characteristics. The study and description of contact-condensing processes occurring in unstable hydrosilicate systems as well as the sol-gel technologies are the important aspects in the foundations development of modern material science, the creation of materials and new generation products.

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