scholarly journals PENGGUNAAN TZ SEBAGAI ANTI PRAKOAGULASI LATEKS PADA PROSES PEMBUATAN RSS DENGAN PENGGUMPAL ASAM FORMAT

2018 ◽  
Vol 37 (2) ◽  
pp. 119-128
Author(s):  
Henry Prastanto
Keyword(s):  

Ribbed Smoked Sheet (RSS) adalah salah satu produk karet mentah berupa lembaran yang diproses dari lateks kebun dengan disertai pengasapan. Amonia biasa digunakan sebagai pengawet lateks agar tidak terjadi prakoagulasi sebelum dibuat RSS. Amonia mempunyai sifat basa sehingga berdampak pada penggunaan bahan penggumpal asam format dalam jumlah yang lebih banyak. Pengurangan jumlah bahan penggumpal perlu diteliti lagi dengan menggunakan pengawet sekunder yang tidak menaikkan pH yaitu Tetramethyl thiuram disulfide – zinc oxide (TZ). Tujuan dari penelitian ini adalah untuk mengurangi penggunaan amonia dengan penambahan pengawet sekunder TZ. Efektifitas penggunaan pengawet sekunder dievaluasi dari keawetan lateks, konsumsi bahan penggumpal dan karakteristik air limbah yang dihasilkan. Percobaan pengawetan lateks dilakukan pada skala laboratorium dengan konsentrasi amonia 0,05% dan memvariasikan dosis TZ 0,01; 0,02; 0,03; 0,04; 0,05% v/v. Sebagai pembanding lateks diawetkan dengan amonia saja dengan konsentrasi 0,1%. Hasil penelitian menunjukkan, bahwa dosis pengawet ammonia 0,05% dikombinasikan dengan TZ 0,03% adalah dosis yang optimum. Pada konsentrasi tersebut, lateks mengalami prakoagulasi setelah 17 jam. Konsumsi penggumpal asam format berkurang 24,41%. Karakteristik limbah cair pengolahan RSS berpengawet TZ  0,03% + NH3 0,05% adalah : BOD turun 7,9%; COD turun 21,5%; TSS turun 18%; pH 5,2; N-amonia turun 34,5%; N-total turun 12,5%; dan logam Zn naik 120%.

Author(s):  
P. Sadhukhan ◽  
J. B. Zimmerman

Rubber stocks, specially tires, are composed of natural rubber and synthetic polymers and also of several compounding ingredients, such as carbon black, silica, zinc oxide etc. These are generally mixed and vulcanized with additional curing agents, mainly organic in nature, to achieve certain “designing properties” including wear, traction, rolling resistance and handling of tires. Considerable importance is, therefore, attached both by the manufacturers and their competitors to be able to extract, identify and characterize various types of fillers and pigments. Several analytical procedures have been in use to extract, preferentially, these fillers and pigments and subsequently identify and characterize them under a transmission electron microscope.Rubber stocks and tire sections are subjected to heat under nitrogen atmosphere to 550°C for one hour and then cooled under nitrogen to remove polymers, leaving behind carbon black, silica and zinc oxide and 650°C to eliminate carbon blacks, leaving only silica and zinc oxide.


Author(s):  
T. A. Emma ◽  
M. P. Singh

Optical quality zinc oxide films have been characterized using reflection electron diffraction (RED), replication electron microscopy (REM), scanning electron microscopy (SEM), and X-ray diffraction (XRD). Significant microstructural differences were observed between rf sputtered films and planar magnetron rf sputtered films. Piezoelectric materials have been attractive for applications to integrated optics since they provide an active medium for signal processing. Among the desirable physical characteristics of sputtered ZnO films used for this and related applications are a highly preferred crystallographic texture and relatively smooth surfaces. It has been found that these characteristics are very sensitive to the type and condition of the substrate and to the several sputtering parameters: target, rf power, gas composition and substrate temperature.


2009 ◽  
Vol 129 (11) ◽  
pp. 1981-1984
Author(s):  
Yuki Ueno ◽  
Takanori Aoki ◽  
Akio Suzuki ◽  
Tatsuhiko Matsushita ◽  
Masahiro Okuda

2015 ◽  
Vol 135 (6) ◽  
pp. 192-198 ◽  
Author(s):  
Shinnosuke Iwamatsu ◽  
Yutaka Abe ◽  
Toru Yahagi ◽  
Seiya Kobayashi ◽  
Kazushige Takechi ◽  
...  

2014 ◽  
Vol 29 (10) ◽  
pp. 1039
Author(s):  
TAN Man-Lin ◽  
WANG Yan-Tao ◽  
ZHANG Wei-Li ◽  
FU Dong-Ju ◽  
LI Dong-Shuang ◽  
...  

2002 ◽  
Vol 719 ◽  
Author(s):  
K. Thonke ◽  
N. Kerwien ◽  
A. Wysmolek ◽  
M. Potemski ◽  
A. Waag ◽  
...  

AbstractWe investigate by photoluminescence (PL) nominally undoped, commercially available Zinc Oxide substrates (from Eagle Picher) grown by seeded chemical vapor transport technique in order to identify residual donors and acceptors. In low temperature PL spectra the dominant emission comes from the decay of bound exciton lines at around 3.36 eV. Zeeman measurements allow the identification of the two strongest lines and some weaker lines in-between as donorrelated. From the associated two-electron satellite lines binding energies of the major donors of 48 meV and 55 meV, respectively, can be deduced.


2003 ◽  
Vol 763 ◽  
Author(s):  
H. W. Lee ◽  
Y. G. Wang ◽  
S. P. Lau ◽  
B. K. Tay

AbstractA detailed study of zinc oxide (ZnO) films prepared by filtered cathodic vacuum arc (FCVA) technique was carried out. To deposit the films, a pure zinc target was used and O2 was fed into the chamber. The electrical properties of both undoped and Al-doped ZnO films were studied. For preparing the Al-doped films, a Zn-Al alloy target with 5 wt % Al was used. The resistivity, Hall mobility and carrier concentration of the samples were measured. The lowest resistivity that can be achieved with undoped ZnO films was 3.4×10-3 Ωcm, and that for Al-doped films was 8×10-4 Ωcm. The carrier concentration was found to increase with Al doping.


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