scholarly journals Effects of relative humidity on ethanol vapour releases from hydrophilic filmbased sachet in active food packaging

Food Research ◽  
2021 ◽  
Vol 5 (5) ◽  
pp. 89-94
Author(s):  
H. Kampawong ◽  
W. Utto ◽  
R. Pruthtikul
Keyword(s):  
Relative Humidity ◽  
Water Vapour ◽  
Food Packaging ◽  
Ethylene Vinyl Acetate ◽  
Exponential Model ◽  
Ethanol Vapour ◽  
Vapour Concentration ◽  
Active Food Packaging ◽  
Microbial Proliferation ◽  
Concentration Levels

Active food package incorporating an ethanol vapour-controlled release sachet has been known for its efficacies to delay microbial proliferation in fresh fruit and vegetable. High humidity inside the package could be utilized as a stimulus for conditional releases as a means to stabilize the sachet prior to being used. The present research was undertaken to investigate the effects of relative humidity on ethanol vapour release from the hydrophilic film-based sachet. The prototype 4-side sealed sachets were made of either ethylene vinyl acetate (EVA) or laminated film comprising EVA and Nylon/PE (designated as ENP). A gas chromatogram equipped with a flame-ionized detector (FID-GC) was employed to analyze ethanol vapour concentration levels released from both sachet types and accumulated in headspaces of sealed glass beakers having different relative humidity (RH) levels. For a given RH level, the concentrations in the headspaces containing the ENPbased sachets were lower than those containing the EVA-based sachets. Delays of ethanol vapour release up to 24 h were observed in the ENP-based sachet system, whilst these did not occur among EVA-based sachets. Both sachets could release ethanol vapour with faster rates and subsequently higher concentrations accumulated at the very high relative humidity level (90-99% RH), compared to lower RH levels (60-89% RH). However, the release rates and concentration levels accumulated in 60-75% RH were not different from those in 80-89% RH. Extents of water vapour uptake by films were relatively small when the films were kept at the lower RH levels, but these became exponentially increased when the RH levels were ≥90%RH. Experimental data on water vapour uptakes were well predicted by an exponential model (R2 0.92-0.99; and root mean square of errors (RMSE) 0.004-0.054). Overall, experiment findings indicate that the ENP film caused delayed ethanol vapour releases from the sachet. The relative humidity levels had significant effects on the releases from hydrophilic film-based sachets

scholarly journals Effect of Cellulose Nanocrystals and Lignin Nanoparticles on Mechanical, Antioxidant and Water Vapour Barrier Properties of Glutaraldehyde Crosslinked PVA Films

Polymers ◽  
2020 ◽  
Vol 12 (6) ◽  
pp. 1364 ◽  
Author(s):  
Weijun Yang ◽  
Guochuang Qi ◽  
José Maria Kenny ◽  
Debora Puglia ◽  
Piming Ma
Keyword(s):  
Water Vapour ◽  
Cellulose Nanocrystals ◽  
Food Packaging ◽  
Radical Scavenging Activity ◽  
Radical Scavenging ◽  
Primary Objective ◽  
Nanocomposite Films ◽  
Shielding Effect ◽  
Strong Interactions ◽  
Active Food Packaging

In this work, PVA nanocomposite films containing cellulose nanocrystals (CNC) and different amounts of lignin nanoparticles (LNP), prepared via a facile solvent cast method, were crosslinked by adding glutaraldehyde (GD). The primary objective was to investigate the effects of crosslinker and bio-based nanofillers loading on thermal, mechanical, antioxidant and water barrier behaviour of PVA nanocomposite films for active food packaging. Thermogravimetric analysis showed improved thermal stability, due to the strong interactions between LNP, CNC and PVA in the presence of GD, while Wide-angle X-ray diffraction results confirmed a negative effect on crystallinity, due to enhanced crosslinking interactions between the nanofillers and PVA matrix. Meanwhile, the tensile strength of PVA-2CNC-1LNP increased from 26 for neat PVA to 35.4 MPa, without sacrificing the ductility, which could be explained by a sacrificial hydrogen bond reinforcing mechanism induced by spherical-like LNP. UV irradiation shielding effect was detected for LNP containing PVA films, also migrating ingredients from PVA nanocomposite films induced radical scavenging activity (RSA) in the produced films in presence of LNP. Furthermore, PVA-CNC-LNP films crosslinked by GD showed marked barrier ability to water vapour.

Enzyme- and Relative Humidity-Responsive Antimicrobial Fibers for Active Food Packaging

2021 ◽  
Author(s):  
Zeynep Aytac ◽  
Jie Xu ◽  
Suresh Kumar Raman Pillai ◽  
Brian D. Eitzer ◽  
Tao Xu ◽  
...  
Keyword(s):  
Relative Humidity ◽  
Food Packaging ◽  
Active Food Packaging

scholarly journals Development of Inclusion Complexes With Relative Humidity Responsive Capacity as Novel Antifungal Agents for Active Food Packaging

2022 ◽  
Vol 8 ◽  
Author(s):  
Cristina Muñoz-Shugulí ◽  
Francisco Rodríguez-Mercado ◽  
Carolina Mascayano ◽  
Andrea Herrera ◽  
Julio E. Bruna ◽  
...  
Keyword(s):  
Gas Chromatography ◽  
Relative Humidity ◽  
Inclusion Complexes ◽  
Water Sorption ◽  
Food Packaging ◽  
Antifungal Agents ◽  
Entrapment Efficiency ◽  
Packaging Materials ◽  
Food Packaging Materials ◽  
Active Food Packaging

Background: Allyl isothiocyanate is an excellent antimicrobial compound that has been applied in the development of active food packaging materials in the last years. However, the high volatility of this compound could prevent a lasting effect over time. In order to avoid this problem, cyclodextrin inclusion complexes have been proposed as an alternative, being beta-cyclodextrin (β-CD) as the main candidate. In addition, β-CD could act as a relative humidity-responsive nanoparticle. In this regard, the aim of this study was to develop inclusion complexes based on β-CD and AITC as relative humidity-responsive agents, which can be used in the design of active food packaging materials.Methods: Two different β-CD:AITC inclusion complexes (2:1 and 1:1 molar ratios) were obtained by the co-precipitation method. Entrapment efficiency was determined by gas chromatography, while inclusion complexes were characterized through thermal, structural, and physicochemical techniques. Antifungal capacity of inclusion complexes was determined in a headspace system. Furthermore, the AITC release from inclusion complexes to headspace at different percentages of relative humidity was evaluated by gas chromatography, and this behavior was related with molecular dynamic studies.Key Findings and Conclusions: The entrapment efficiency of inclusion complexes was over to 60%. Two coexisting structures were proposed for inclusion complexes through spectroscopic analyses and molecular dynamic simulation. The water sorption capacity of inclusion complexes depended on relative humidity, and they exhibited a strong fungicide activity against Botrytis cinerea. Furthermore, the AITC release to headspace occurred in three stages, which were related with changes in β-CD conformational structure by water sorption and the presence of the different coexisting structures. In addition, a strong influence of relative humidity on AITC release was evidenced. These findings demonstrate that β-CD:AITC inclusion complexes could be used as potential antifungal agents for the design of food packaging materials, whose activity would be able to respond to relative humidity changes.

scholarly journals Chitosan-Zinc Oxide Composite for Active Food Packaging Applications

2018 ◽  
Vol 7 (4.30) ◽  
pp. 253 ◽  
Author(s):  
S.R. Abdul Razak ◽  
H. Basri
Keyword(s):  
Contact Angle ◽  
Zinc Oxide ◽  
Water Vapour ◽  
Food Packaging ◽  
Transmission Rate ◽  
Chitosan Film ◽  
Zno Films ◽  
One Pot ◽  
Vapour Permeability ◽  
Active Food Packaging

Chitosan-zinc oxide (C-ZnO) films were prepared by a simple one pot procedure. In order to investigate the property of C-ZnO films, two composite films were prepared by varying the loading of ZnO and compared with pure chitosan film (C). The films were characterized by various techniques such as FTIR, DSC, tensile, contact angle and water vapour permeability. FTIR analysis showed changes in hydrogen bonds band at 3351 cm-1 compared to pure chitosan film. The incorporation of ZnO in chitosan films increased the contact angle by 30.5% in C-ZnO1.0 film while water vapour transmission rate decreased by 7.8% compared to C film. From the tensile test, C-ZnO0.5 and C-ZnO1.0 films were found to be much superior by 1.5 times and 2.5 times respectively compared to bare chitosan film. Larger inhibition ring (by 47%) was exhibited by C-ZnO1.0 as compared to C-ZnO0.5 when tested against S.aureus. From the results, it is displayed that the incorporation of zinc oxide to chitosan improve their properties which also shown the potential to become a candidate for food active packaging.

Untersuchungen zum Diffusionswiderstand von Holzwerkstoffen | Diffusion resistance of timber materials

2005 ◽  
Vol 156 (3-4) ◽  
pp. 100-103
Author(s):  
Rudolf Popper ◽  
Peter Niemz ◽  
Gerhild Eberle
Keyword(s):  
Relative Humidity ◽  
Water Vapour ◽  
Middle Lamella ◽  
Solid Wood ◽  
Diffusion Resistance ◽  
Water Vapour Diffusion ◽  
Wood Panels ◽  
Vapour Diffusion ◽  
Wet Climate ◽  
Panel Thickness

The water vapour diffusion resistance of timber materials were tested in a wet climate (relative humidity ranging from 100%to 65% at 20 °C) and in a dry climate (relative humidity ranging from 0% to 65% and from 0% to 35% at 20 °c) with variation by relative humidity and vapour pressure gradient. The diffusion resistance of multilayer solid wood panels lies under or within the range of the solid wood (spruce), tending even to a lower range. This can be attributed to the loosely inserted middle lamella of the used solid wood panels, which were not correctly glued by the manufacturer. The diffusion resistance of the solid wood panels increases with decreasing moisture content and decreasing panel thickness, as well as with increasing water vapour gradient from 818 to 1520 Pa. There were clear differences between the tested timber materials. The diffusion resistance of particle composites is strongly dependent on the specific gravity. Due to laminar particles OSBs(Oriented Strand Boards) have a larger diffusion resistance than chipboards. The water vapour diffusion resistance of OSBs lies within the range of plywood.

scholarly journals Low-Density Polyethylene Films Carrying ferula asafoetida Extract for Active Food Packaging: Thermal, Mechanical, Optical, Barrier, and Antifungal Properties

2020 ◽  
Vol 2020 ◽  
pp. 1-15
Author(s):  
Razieh Niazmand ◽  
Bibi Marzieh Razavizadeh ◽  
Farzaneh Sabbagh
Keyword(s):  
Polymer Matrix ◽  
Food Packaging ◽  
Barrier Properties ◽  
Low Density Polyethylene ◽  
Low Density ◽  
Optical Barrier ◽  
Leaf Extracts ◽  
Polyethylene Films ◽  
Active Food Packaging ◽  
Ferula Asafoetida

The physical, thermal, mechanical, optical, microstructural, and barrier properties of low-density polyethylene films (LDPE) containing ferula asafoetida leaf and gum extracts were investigated. Results showed a reduction in elasticity and tensile strength with increasing extract concentration in the polymer matrix. The melting temperature and enthalpy increased with increasing concentration of extracts. The films containing extracts had lower L∗ and a∗ and higher b∗ indices. The films containing leaf extract had more barrier potential to UV than the gum extracts. The oxygen permeability in films containing 5% of leaf and gum extracts increased by 2.3 and 2.1 times, respectively. The morphology of the active films was similar to bubble swollen islands, which was more pronounced at higher concentrations of gum and leaf extracts. FTIR results confirmed some chemical interactions of ferula extracts with the polymer matrix. At the end of day 14th, the growth rate of Aspergillus niger and Saccharomyces cerevisea in the presence of the PE-Gum-5 reduced more than PE-Leaf-5 (3.7 and 2.4 logarithmic cycles, respectively) compared to the first day. Our findings showed that active LDPE films have desire thermo-mechanical and barrier properties for food packaging.

scholarly journals Incorporation of Poly(Itaconic Acid) with Quaternized Thiazole Groups on Gelatin-Based Films for Antimicrobial-Active Food Packaging

Polymers ◽  
2021 ◽  
Vol 13 (2) ◽  
pp. 200
Author(s):  
Celeste Cottet ◽  
Andrés G. Salvay ◽  
Mercedes A. Peltzer ◽  
Marta Fernández-García
Keyword(s):  
Antimicrobial Activity ◽  
Itaconic Acid ◽  
Food Packaging ◽  
Crosslinking Agent ◽  
Radical Scavenging ◽  
Proton Nuclear Magnetic Resonance ◽  
Esterification Reaction ◽  
Alkylation Reaction ◽  
Vapor Permeability ◽  
Active Food Packaging

Poly(itaconic acid) (PIA) was synthesized via conventional radical polymerization. Then, functionalization of PIA was carried out by an esterification reaction with the heterocyclic groups of 1,3-thiazole and posterior quaternization by N-alkylation reaction with iodomethane. The modifications were confirmed by Fourier transform infrared (FTIR) and proton nuclear magnetic resonance (1H-NMR), as well as ζ-potential measurements. Their antimicrobial activity was tested against different Gram-negative and Gram-positive bacteria. After characterization, the resulting polymers were incorporated into gelatin with oxidized starch and glycerol as film adjuvants, and dopamine as crosslinking agent, to develop antimicrobial-active films. The addition of quaternized polymers not only improved the mechanical properties of gelatin formulations, but also decreased the solution absorption capacity during the swelling process. However, the incorporation of synthesized polymers increased the deformation at break values and the water vapor permeability of films. The antioxidant capacity of films was confirmed by radical scavenging ability and, additionally, those films exhibited antimicrobial activity. Therefore, these films can be considered as good candidates for active packaging, ensuring a constant concentration of the active compound on the surface of the food, increasing products’ shelf-life and reducing the environmental impact generated by plastics of petrochemical origin.

scholarly journals Tannic-Acid-Cross-Linked and TiO2-Nanoparticle-Reinforced Chitosan-Based Nanocomposite Film

Polymers ◽  
2021 ◽  
Vol 13 (2) ◽  
pp. 228
Author(s):  
Swarup Roy ◽  
Lindong Zhai ◽  
Hyun Chan Kim ◽  
Duc Hoa Pham ◽  
Hussein Alrobei ◽  
...  
Keyword(s):  
Mechanical Properties ◽  
Tannic Acid ◽  
Nanocomposite Film ◽  
Food Packaging ◽  
Titanium Dioxide Nanoparticles ◽  
Casting Technique ◽  
Active Food Packaging ◽  
Reinforcing Agent ◽  
Solution Casting Technique ◽  
Cross Linker

A chitosan-based nanocomposite film with tannic acid (TA) as a cross-linker and titanium dioxide nanoparticles (TiO2) as a reinforcing agent was developed with a solution casting technique. TA and TiO2 are biocompatible with chitosan, and this paper studied the synergistic effect of the cross-linker and the reinforcing agent. The addition of TA enhanced the ultraviolet blocking and mechanical properties of the chitosan-based nanocomposite film. The reinforcement of TiO2 in chitosan/TA further improved the nanocomposite film’s mechanical properties compared to the neat chitosan or chitosan/TA film. The thermal stability of the chitosan-based nanocomposite film was slightly enhanced, whereas the swelling ratio decreased. Interestingly, its water vapor barrier property was also significantly increased. The developed chitosan-based nanocomposite film showed potent antioxidant activity, and it is promising for active food packaging.

scholarly journals Recent Developments in Seafood Packaging Technologies

Foods ◽  
2021 ◽  
Vol 10 (5) ◽  
pp. 940
Author(s):  
Michael G. Kontominas ◽  
Anastasia V. Badeka ◽  
Ioanna S. Kosma ◽  
Cosmas I. Nathanailides
Keyword(s):  
Shelf Life ◽  
Food Packaging ◽  
Modified Atmosphere Packaging ◽  
High Water ◽  
Edible Films ◽  
Nitrogenous Compounds ◽  
Quality Properties ◽  
Unsaturated Lipids ◽  
Active Food Packaging ◽  
Seafood Products

Seafood products are highly perishable, owing to their high water activity, close to neutral pH, and high content of unsaturated lipids and non-protein nitrogenous compounds. Thus, such products require immediate processing and/or packaging to retain their safety and quality. At the same time, consumers prefer fresh, minimally processed seafood products that maintain their initial quality properties. The present article aims to review the literature over the past decade on: (i) innovative, individual packaging technologies applied to extend the shelf life of fish and fishery products, (ii) the most common combinations of the above technologies applied as multiple hurdles to maximize the shelf life of seafood products, and (iii) the respective food packaging legislation. Packaging technologies covered include: Modified atmosphere packaging; vacuum packaging; vacuum skin packaging; active food packaging, including oxygen scavengers; carbon dioxide emitters; moisture regulators; antioxidant and antimicrobial packaging; intelligent packaging, including freshness indicators; time–temperature indicators and leakage indicators; retort pouch processing and edible films; coatings/biodegradable packaging, used individually or in combination for maximum preservation potential.

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