scholarly journals Corrosion Behaviour of Al-Si Cast Alloy Reinforced with Titanium diboride (TiB2) and Scandium (Sc)

2019 ◽  
Vol 3 (2) ◽  
pp. 1-8
Author(s):  
Keyword(s):  
Corrosion Resistance ◽  
Corrosion Rate ◽  
Grain Refinement ◽  
Titanium Diboride ◽  
Acidic Medium ◽  
Corrosion Behaviour ◽  
Cast Alloy ◽  
Resistance Rate ◽  
Acidic Solutions ◽  
Corrosion Rates

The aluminium-silicon (Al-Si) based on Metal Matrix Composites (MMCs) is widely used in lightweight constructions and transport applications requiring a combination of high strength and ductility. A grain refinement plays a crucial role in improving characteristics and properties of Al alloys. In this investigation, titanium diboride (TiB2) and scandium (Sc) inoculants were added to the Al-Si alloys for grain refinement of an alloy. In this investigation, the corrosion resistance rate of Al-Si cast alloy reinforced by TiB2 and Sc were measured by potentiostat (AUTOLAB) instrument. The aim of this research is to investigate the corrosion rate for Al-Si-TiB2-Sc composites that immersed in different concentration of acidic solutions. Besides, the immersion time of acidic solutions also was investigated. All the samples were prepared accordingly for ASTM standard by the composition of 6.0 wt% TiB2 and 0.6wt% Sc. All the samples undergo cold mounting technique for easy handling on corrosion tests. Then the samples were immersed in two different concentrations acidic medium solutions, which were 0.1.and 1.0 M hydrochloric acids (HCl). The corrosion rate also was investigated for immersion samples of 1.0 M HCl for 21 days. From the results obtained, added TiB2 and Sc onto Al-Si alloy gave the better properties in corrosion resistance. Corrosion rates to reduce when the samples were immersed in a lower concentration of acidic medium, 0.1 HCl. However, there are some significant on the result but it still following the corrosion rates trend. Thus, improvements to reinforcement content need to be done in further research to cover the lack of this corrosion rates trend.

scholarly journals An Investigation of corrosion of friction welded and post-weld heat-treated AA6061/SiC/graphite hybrid composites

2021 ◽  
Vol 61 (3) ◽  
pp. 456-464
Author(s):  
Jadamuni Senthilkumar ◽  
Pavan S. M. Kumar ◽  
Manickam Balasubramanian
Keyword(s):  
Corrosion Resistance ◽  
Corrosion Rate ◽  
Hybrid Composites ◽  
Corrosion Behaviour ◽  
High Strength ◽  
Corrosion Rates ◽  
Solution Treated ◽  
Heat Treated ◽  
Lower Corrosion Rate ◽  
Weld Heat

The aluminium-based hybrid metal matrix composites have noteworthy applications in sub-sea installations, structures of deep-sea crawlers, submarine parts, engine cylinders, drum brakes etc., as they possess high strength, corrosion resistance, chemical, and dimensional stability. In this investigation, the pitting corrosion behaviour of friction welded and post-weld heat-treated AA6061/SiC/graphite hybrid composites were analysed. The corrosion rates of AW (as welded), ST (Solution treated), STA (Solution treated and Aged), and AA (Artificially Aged) weld joints were experimentally determined. The corrosion behaviour has been discussed in light of microstructure. The experimental results revealed that the STA joints exhibited better corrosion resistance characteristics as compared to AW, AA, and ST joints. The corrosion rate was high for AW joints, followed by AA and ST joints, respectively. Taking into account the corrosion rates of AW and STA joints, the STA joints have a corrosion rate 34.6% lesser than that of AW joints. A comparison of AA and ST with STA joints reveals that the rate of corrosion for STA joints was 31.1% lesser than that of AA joints and 28.8% lesser than that of ST joints. A lower corrosion rate was observed for STA joints as compared to AA, AW, and ST joints.

scholarly journals Effects of tungsten, chromium and zirconium on the corrosion behavior of ternary amorphous W–Cr–Zr alloys in 1 M NaOh solution

1970 ◽  
Vol 9 (9) ◽  
pp. 39-43
Author(s):  
Basu Ram Aryal ◽  
Jagadeesh Bhattarai
Keyword(s):  
Corrosion Resistance ◽  
Corrosion Rate ◽  
Open Circuit Potential ◽  
Open Circuit ◽  
Corrosion Rates ◽  
Corrosion Resistance Property ◽  
Naoh Solution ◽  
Order Of Magnitude ◽  
Sputter Deposited ◽  
Zr Alloys

Simultaneous additions of tungsten, chromium and zirconium in the chromium- and zirconium-enriched sputter-deposited binary W-xCr and W-yZr are effective to improve the corrosion resistance property of the ternary amorphous W- xCr-yZr alloys after immersion for 240 h in 1 M NaOH solution open to air at 25°C. The corrosion rates of all the examined sputter-deposited (10-57)W-(18-42)Cr-(25-73)Zr alloys is higher than those of alloy-constituting elements (that is, tungsten, chromium and zirconium) in aggressive 1 M NaOH solution open to air at 25°C. The corrosion rates of all the examined sputter−deposited W–xCr–yZr alloys containing 10-57 at% tungsten, 18-42 at% chromium and 25-73 at% zirconium were in the range of 1.5-2.5 × 10−3 mm/y or lower which are more than two orders of magnitude lower than that of sputter-deposited tungsten and even about one order of magnitude lower than those of the sputter-deposited zirconium in 1 M NaOH solution. Keywords: Ternary W–Cr–Zr alloys; Amorphous; Corrosion rate; Open circuit potential; 1 M NaOH. DOI: http://dx.doi.org/10.3126/sw.v9i9.5516 SW 2011; 9(9): 39-43

scholarly journals Effect of Grain Refinement on the Dynamic, Mechanical Properties, and Corrosion Behaviour of Al-Mg Alloy

Metals ◽  
2021 ◽  
Vol 11 (11) ◽  
pp. 1825
Author(s):  
Haitham M. Ahmed ◽  
Hussin A. M. Ahmed ◽  
Mohammed Hefni ◽  
Essam B. Moustafa
Keyword(s):  
Mechanical Properties ◽  
Grain Refinement ◽  
Corrosion Behaviour ◽  
Cast Alloy ◽  
Dynamic Properties ◽  
Damping Ratio ◽  
Xrd Analysis ◽  
Optical Microscope ◽  
Mg Alloy ◽  
Resonance Frequencies

In this investigation, aluminium Al-2.5% Mg cast alloy was modified by adding 0.5 Ti and 0.1 B wt % modifiers to investigate their impact on the dynamic behaviour, as well as the mechanical and microstructure properties. The dynamic properties were analysed experimentally using a free vibration impact test and predicted using finite element methods. This study used a high-resolution polarised optical microscope to analyse the microstructure of the studied alloys and X-ray Powder Diffraction (XRD) analysis to determine the developed phases. Microstructure and mechanical properties were mostly enhanced as a result of grain refining during solidification and through the metal segregation process. The microstructure analysis of the modified alloy showed a significant improvement in the grain refinement; hence, the grains were 10 times finer than the cast alloy. The modified Al-2.5% Mg/Ti-B alloy demonstrated reduced inter-granular corrosion (IGC) than the Al-2.5% Mg standard cast alloy. By incorporating Ti-B modifiers into the composition of the cast Al-Mg alloy, the ultimate tensile strength (UTS), strain (ε), and hardness values (HV) were increased by 30.5%, 100%, and 18.18%, respectively. The dynamic properties of the modified alloy showed an enhancement in the resonant (fn) and damping ratio (ζ) by 7% and 68%, respectively. The predicted resonance frequencies of the investigated alloys showed results close to the experimental dynamic tests.

scholarly journals The Corrosion Behavior of Sputter-Deposited Nanocrystalline W-Cr Alloys in Nacl and NaohaSolutions

1970 ◽  
Vol 25 ◽  
pp. 53-61
Author(s):  
Minu Basnet ◽  
Jagadeesh Bhattarai
Keyword(s):  
Corrosion Resistance ◽  
Corrosion Rate ◽  
Corrosion Behavior ◽  
Chromium Content ◽  
Open Circuit ◽  
Nacl Solution ◽  
Corrosion Rates ◽  
Naoh Solution ◽  
Order Of Magnitude ◽  
Sputter Deposited

The corrosion behavior of the sputter-deposited nanocrystalline W-Cr alloys wasstudied in 0.5 M NaCl and alkaline 1 M NaOH solutions at 25°C, open to air usingimmersion tests and electrochemical measurements. Chromium metal acts synergisticallywith tungsten in enhancing the corrosion resistance of the sputter-deposited W-Cr alloys soas to show higher corrosion resistance than those of alloy-constituting elements in both 0.5M NaCl and 1 M NaOH solutions. In particular, the nanocrystalline W-Cr alloys containing25-91 at% chromium showed about one order of magnitude lower corrosion rates (that is,about 1-2 × 10-3 mm.y-1) than those of tungsten and chromium metals even for prolongedimmersion in 0.5 M NaCl solution at 25°C. On the other hand, the corrosion rate of thesputter-deposited W-Cr alloys containing 25-75 at % chromium was decreased significantlywith increasing chromium content and showed lowest corrosion rates (that is, 1.5-2.0 × 10-3 mm.y-1) after immersed for prolonged immersion in 1 M NaOH solution. The corrosion ratesof these nanocrystalline W-(25-75)Cr alloys are nearly two orders of magnitude lower thanthat of tungsten and more than one order of magnitude lower corrosion rate than that ofsputter-deposited chromium metal in 1 M NaOH solution. The corrosion-resistant of all theexamined sputter-deposited W-Cr alloys in 0.5 M NaCl solution is higher than in alkaline 1M NaOH solution at 25°C. Open circuit potentials of all the examined W-Cr alloys areshifted to more noble direction with increasing the chromium content in the alloys afterimmersion for 72 h in both 0.5 M NaCl and 1 M NaOH solutions at 25°C, open to air.Keywords: Sputter deposition, nanocrystalline W-Cr alloys, corrosion test, electrochemicalmeasurement, NaCl and NaOH solutions.DOI:  10.3126/jncs.v25i0.3300Journal of Nepal Chemical Society Volume 25, 2010 pp 53-61

Microstructure and corrosion behaviour of precipitation hardened and thermo-mechanical treated high strength Al-12Zn-3Mg-2.5Cu alloy

2018 ◽  
Vol 65 (1) ◽  
pp. 79-86 ◽  
Author(s):  
V.V. Ravikumar ◽  
S. Kumaran
Keyword(s):  
Corrosion Resistance ◽  
Precipitation Hardening ◽  
Corrosion Behaviour ◽  
Cast Alloy ◽  
High Strength ◽  
Structural Features ◽  
Boundary Region ◽  
Nacl Solution ◽  
Content Type ◽  
Fine Grained Structure

Purpose The purpose of this paper is to study the corrosion behaviour of Al-12Zn-3Mg-2.5Cu alloy by cast, precipitation hardening and non-isothermal step rolling cum cold/cryo rolling (−80 and −196°C) in 3.5 per cent NaCl solution. Design/methodology/approach Aluminium alloy with high alloying concentration (Zn: 12 per cent, Mg: 3 per cent, Cu: 2.5 per cent) was prepared by squeeze casting method with controlled process parameters. The cast alloy was solution treated at 450°C for 24 h and aged at 120°C with varying time intervals. Initially, the alloy also underwent non-isothermal step rolling from 6 mm to 3 mm at 400-100°C at the step of 100ºC with 15% reduction in thickness. Non-isothermal rolled alloy (3 mm thickness) was the starting material for further rolling at three different temperatures, such as room temperature, −80 and −190°C with 85 per cent reduction. Microstructural evolution during precipitation and thermo-mechanical processing was studied with the help of optical microscopy and electron microscopy. A potentio-dynamic polarization study was performed to evaluate the corrosion behaviour of Al-12Zn-3Mg-2.5Cu alloy processed in different conditions in 3.5 per cent NaCl solution. Findings There is a distinct evidence that the alloy exhibits varying corrosion resistance by changing its structural features. In fact, the alloy with ultra-fine grained structure exhibits good corrosion resistance than that of alloy in cast. This is attributed to a greater grain boundary region with high dislocation density, and plastic strain adversely affects the corrosion resistance. Originality/value The results obtained by this investigation help in understanding the effect of precipitation hardening and non-isothermal step rolling cum cold/cryo rolling (−80 and −196°C) on corrosion behaviour.

scholarly journals Effect of Sr and Ti Addition on the Corrosion Behaviour of Al-7Si-0.3Mg Alloy

2017 ◽  
Vol 17 (2) ◽  
pp. 125-130 ◽  
Author(s):  
M. Uludağ ◽  
M. Kocabaş ◽  
D. Dışpınar ◽  
R. Çetin ◽  
N. Cansever
Keyword(s):  
Mechanical Properties ◽  
Corrosion Resistance ◽  
Corrosion Rate ◽  
Potentiodynamic Polarization ◽  
Corrosion Test ◽  
Corrosion Behaviour ◽  
Tensile Tests ◽  
Nacl Solution ◽  
Cyclic Potentiodynamic Polarization ◽  
Ti Addition

AbstractIn the present study, the corrosion behaviour of A356 (Al-7Si-0.3Mg) alloy in 3.5% NaCl solution has been evaluated using cyclic/potentiodynamic polarization tests. The alloy was provided in the unmodified form and it was then modified with AlTi5B1 for grain refinement and with AlSr15 for Si modifications. These modifications yield to better mechanical properties. Tensile tests were performed. In addition, bifilm index and SDAS values were calculated and microstructure of the samples was investigated. As a result of the corrosion test, the Ecorr values for all conditions were determined approximately equal, and the samples were pitted rapidly. The degassing of the melt decreased the bifilm index (i.e. higher melt quality) and thereby the corrosion resistance was increased. The lowest corrosion rate was founded at degassing and as-received condition (3.9x10-3mm/year). However, additive elements do not show the effect which degassing process shows.

The Corrosion Resistance of the Mg-Al-Ca-Sr Sand Casting Magnesium Alloys

2012 ◽  
Vol 326-328 ◽  
pp. 255-260 ◽  
Author(s):  
Andrzej Kiełbus ◽  
Tomasz Rzychoń ◽  
Joanna Michalska ◽  
Michal Stopyra
Keyword(s):  
Corrosion Resistance ◽  
Corrosion Rate ◽  
Magnesium Alloys ◽  
Room Temperature ◽  
Immersion Test ◽  
Corrosion Layer ◽  
Sand Casting ◽  
Nacl Solution ◽  
Effective Barrier ◽  
Corrosion Rates

In this paper, the corrosion resistance of two sand-casting creep resistant magnesium alloys Mg-9Al-1.5Ca-0.3Sr and Mg-9Al-2.2Ca-0.8Sr in the salt environment has been investigated. Specimens of each alloy has been immersed in 3.5% NaCl solution at room temperature and successively taken out after 1, 2, 4, 5 and 9 days. After immersion test, the microstructure and the appearances of the corroded structure were examined. The corrosion rates of both investigated alloys increased lineally with increasing the exposure time in both solutions. Mg-9Al-1.5Ca-0.3Sr alloy exhibits the higher corrosion rate during the immersion test than Mg-9Al-2.2Ca-0.8Sr. The corrosion layer of both alloys consists of MgO, MgOH and phases containing Cl, Na, Al and Ca. The increase of Ca content in the Mg-9Al-2.2Ca-0.8Sr alloy improved the corrosion resistance due to the formation of the reticular (Mg,Al)2Ca phase, which acted as an effective barrier against corrosion.

Corrosion Behaviour of Structural Ceramics in Supercritical Water

2006 ◽  
Vol 45 ◽  
pp. 173-177 ◽  
Author(s):  
Masahiro Nagae ◽  
Tetsuo Yoshio ◽  
Kohei Oda
Keyword(s):  
Corrosion Resistance ◽  
Corrosion Rate ◽  
Corrosion Behavior ◽  
Supercritical Water ◽  
Intergranular Corrosion ◽  
Corrosion Behaviour ◽  
Impurity Content ◽  
Amorphous Layer ◽  
Structural Ceramics ◽  
Alumina Ceramics

The corrosion behavior of Si3N4, SiC, mullite, alumina and sapphire was investigated in supercritical water at 450 °C and 45MPa for 2 to 50h. Corrosion resistance for the ceramics was as follows in the order; Si3N4 < SiC < mullite < alumina < sapphire. Pitting corrosion with formation of amorphous layer and intergranular corrosion due to dissolution of additives were observed in PLS-Si3N4 and PLS-SiC, respectively. The corrosion behavior of mullite was characterized by dissolution of SiO2 and formation of boehmite residue layer. High purity alumina ceramics showed the highest corrosion resistance in the ceramics. Intergranular corrosion proceeded in the alumina ceramics and its corrosion rate was strongly dependent on the impurity content.

Corrosion Behaviour of Duplex Treated EN 42CrMo4 Steel by Gas Nitriding and TiAlN PAPVD Deposition

2016 ◽  
Vol 1138 ◽  
pp. 159-164
Author(s):  
Ramona Monica Buzdugan ◽  
Mircea Dan ◽  
Iosif Hulka ◽  
Monica Dome ◽  
Anamaria Feier ◽  
...  
Keyword(s):  
Corrosion Resistance ◽  
Corrosion Rate ◽  
Linear Polarization ◽  
Corrosion Behaviour ◽  
Nacl Solution ◽  
Gas Nitriding ◽  
Duplex Treatment ◽  
42Crmo4 Steel

A Duplex treatment consisting in gas nitriding followed by PAPAVD deposition of TiAlN has been proposed as a solution for improving the corrosion behaviour of EN 42CrMo4 steel. The corrosion resistance in 3.5% NaCl solution was evaluated by linear polarization. It was found that the Duplex treated samples exhibited better corrosion resistance and that the corrosion rate decreased significantly from 0.069 mm an-1 (untreated samples) to 0.008 mm an -1 (Duplex treated).

scholarly journals The Influence of Hot Forming on the Microstructure and Corrosion Behaviour of AZ31B Magnesium Alloys

2018 ◽  
Vol 3 (2) ◽  
pp. 150
Author(s):  
Juliawati Alias ◽  
Nurul Shuhada Shuhada Mohamed ◽  
Mahadzir Ishak ◽  
Xiorong Zhou ◽  
George E Thompson
Keyword(s):  
Corrosion Rate ◽  
Magnesium Alloys ◽  
Corrosion Behaviour ◽  
Cast Alloy ◽  
Intermetallic Particle ◽  
Dendritic Structure ◽  
Grain Structure ◽  
Hot Forming ◽  
Forming Process ◽  
Twin Roll Cast

The influence of the hot forming process of AZ31B wrought and twin roll cast (TRC) magnesium alloy sheets on the microstructure and corrosion behaviour have been evaluated. The corrosion behaviour was investigated by hydrogen evolution experiments in chloride-containing solution. Filiform-like corrosion was predominant attack to the AZ31 magnesium alloys, as observed by in-situ corrosion observation. The intermetallic particle existence and grain structure significantly influenced the corrosion rate. The dendritic structure of the as-cast TRC alloy was severely attacked, revealing that the as-cast alloy was highly susceptible to corrosion. The presence of twins in wrought alloy was found to act as a corrosion barrier, while the increase in grain size showed the high corrosion rate of the alloy.

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