Perbedaan Kadar Asam Lemak Bebas Pada Minyak Goreng Yang Mengalami Pemanasan Ulang Dengan Penambahan Bawang Merah (Allium Cepa) Dan Bawang Putih (Allium Sativum)

2018 ◽  
Vol 1 (2) ◽  
pp. 110
Author(s):  
Gervacia Jenny Ratnawati ◽  
Hendra Budi Sungkawa
Keyword(s):  
Fatty Acids ◽  
Free Fatty Acids ◽  
Unsaturated Fatty Acids ◽  
Saturated Fatty Acids ◽  
P Value ◽  
Cooking Oil ◽  
Frying Process ◽  
Used Cooking Oil ◽  
Study Results ◽  
Higher Temperature

Abstract: Cooking oil generally can be used for 3-4 times frying. If it used repeatedly, oil will be changed in color. When frying process, double bonds in unsaturated fatty acids will break and formed saturated fatty acids. A qualified oil was contained unsaturated fatty acid more than its saturated fatty acids. The use of oil many times will lead the oil double bond oxidized and form the peroxide group and cyclic monomer, such oil reported damage and harm our health. A higher temperature and a longer time of heating, saturated fatty acids level will be increased. Beside repeatedly frying, oil can be damaged by wrong storage for certain period, consequently triglyceride bond broke and form into glycerol and free fatty acids (FFA). Red onion and garlic contain high antioxidant. The benefits that make them become phenomenal in medical research is their potency in against cancer and other dangerous diseases. They also can be used as crucial antioxidant sources in the fight against free radicals in body. Based on study results showed that the average of free fatty acids (FFA) in used cooking oil that added by garlic was 5,29% and red onion was 5,22%. Statistical test gained by computerized data processing with t-test p value>0,05 so it can be concluded that Ha refused by meaning that there was not a difference between number of FFA in used cooking oil which added garlic and red onion. Abstrak: Minyak goreng biasanya bisa digunakan hingga 3 - 4 kali penggorengan. Jika digunakan berulang kali, minyak akan berubah warna. Saat penggorengan dilakukan, ikatan rangkap yang terdapat pada asam lemak tak jenuh akan putus membentuk asam lemak jenuh. Minyak yang baik adalah minyak yang mengandung asam lemak tak jenuh yang lebih banyak dibandingkan dengan kandungan asam lemak jenuhnya.  Penggunaan minyak berkali-kali akan membuat ikatan rangkap minyak teroksidasi membentuk gugus peroksida dan monomer siklik, minyak yang seperti ini dikatakan telah rusak dan berbahaya bagi kesehatan.  Suhu yang semakin tinggi dan semakin lama pemanasan, kadar asam lemak jenuh akan semakin naik. Selain karena penggorengan berkali-kali, minyak dapat menjadi rusak karena penyimpanan yang salah dalam jangka waktu tertentu sehingga ikatan  trigliserida pecah menjadi gliserol dan asam lemak bebas. Bawang merah dan bawang putih sangat tinggi akan kandungan antioksidannya. Manfaat bawang merah dan bawang putih yang membuatnya fenomenal di dunia medis adalah kemampuannya dalam memerangi kanker dan berbagai penyakit berbahaya. Ia juga dapat dijadikan sumber antioksidan yang sangat ampuh untuk memerangi radikal bebas di dalam tubuh. Berdasarkan hasil penelitian diperoleh kadar rata-rata kadar asam lemak bebas pada minyak goreng bekas yang ditambahkan bawang putih sebesar 5,29% dan bawang merah sebesar 5,22%. Hasil uji statistic diperoleh pengolahan data secara komputerisasi melalui uji-t  diperoleh nilai p > 0,05, sehingga dapat disimpulkan bahwa Ha ditolak yang artinya tidak terdapat perbedaan kadar bilangan asam lemak bebas pada minyak goreng bekas yang ditambahkan bawang putih dan bawang merah.

scholarly journals PERBEDAAN PENGARUH DIET TINGGI MINYAK SAWIT SEGAR DENGAN MINYAK JELANTAH TERHADAP LEMAK DAN TNF- α DARAH TIKUS

2015 ◽  
Vol 34 (1) ◽  
pp. 70
Author(s):  
Susila Sastri
Keyword(s):  
Fatty Acids ◽  
Total Cholesterol ◽  
Palm Oil ◽  
Unsaturated Fatty Acids ◽  
Saturated Fatty Acids ◽  
Blood Lipid ◽  
Blood Cholesterol ◽  
Cooking Oil ◽  
Used Cooking Oil ◽  
Tnf Α

AbstrakMasyarakat akhir-akhir ini cenderung memilih minyak sawit sebagai bahan penggoreng, hal ini mungkin karena harganya lebih murah dan mudah didapat dibandingkan minyak lain. Pemakain MS oleh masyarakat biasanya untuk bahan penggoreng bahan makanan. Minyak sawit mengandung asam lemak jenuh dan asam lemak tidak jenuh yang hampir seimbang, asam lemak jenuh meningkatkan lemak darah dan asam lemak tidak jenuh dikatakan dapat menurunkan lemak darah. Asam lemak tidak jenuh disisi lain mudah dioksidasi dengan pemanasan. Penelitian ini bertujuan melihat perbedaan pengaruh diet tinggi minyak sawit segar dan jelantah minyak sawit terhadap lemak darah dan TNF-α.Sudah dilakukan pemberian diet tinggi minyak sawit (50%) pada tikus Wistar selama 8 minggu secara adlibitum. Pengukuran kadar kolesterol total, HDL-kol dan trigliserida melalui serum darah dengan alat spectrophotometer dan pemeriksaan TNF-α darah dengan cara ELISA.Hasil penelitian menunjukkan terdapat peninggian kadar lemak (trigliserida dan kolesterol total) dan TNF-α darah bermakna (p<0,05) pada tikus diet tinggi minyak sawit segar ataupun minyak jelantah bila dibandingkan dengan kontrol namun peninggian lemak dan TNF-α oleh minyak jelantah lebih tinggi bermakna bila dibandingkan dengan minyak sawit segar. Kadar kolesterol darah tikus DMS lebih rendah dari kelompok kontrol positif.Kesimpulan; diet tinggi minyak sawit segar dan minyak jelantah pada tikus dapat meningkatkan kadar kolesterol total, trigliserida dan TNF-α secara bermakna dibandingkan kontrol, sedangkan peningkatan oleh minyak jelantah lebih tinggi bermakna dari minyak sawit segar.Kata kunci : diet tinggi minyak sawit, lemak darah, TNF-αAbstractSociety these days tend to prefer palm oil as raw roaster, this is probably because the price is cheap and easily available than other oils. MS usage by the community generally to material food fryer. Palm oil contains saturated fatty acids and unsaturated fatty acids are nearly balanced, saturated fatty acids increase blood fats and unsaturated fatty acid is said to lower blood fats. Unsaturated fatty acids on the other hand easily oxidized by heating. This study aims to look atARTIKEL PENELITIAN71differences in the influence of a diet high in fresh palm oil and palm oil used cooking oil on blood lipid and TNF-α. Already done giving a diet high in palm oil (50%) in Wistar rats for 8 weeks in adlibitum. Measurement of total cholesterol, HDL-Chol and triglycerides through the blood serum with a spectrophotometer and checking blood TNF-α by ELISA. The results showed there were elevated levels of fats (triglycerides and total cholesterol) and blood TNF-α significantly (p <0.05) in mice a diet high in fresh palm oil or used cooking oil when compared with controls but the elevation of fat and TNF-α by used cooking oil significantly higher when compared with fresh palm oil. DMS rat blood cholesterol levels lower than the positive control group. Conclusion: a diet high in fresh palm oil and used cooking oil in rats can increase total cholesterol, triglycerides and TNF-α significantly compared to controls, whereas the used cooking oil increased by significantly higher than fresh palm oil.Key words : high diet palm oil, blood lipid, TNF-α

scholarly journals THE EFFECTIVENESS OF KESUM LEAVES (polygonum minus) IN REDUCING OF FREE FATTY ACIDS IN USED COOKING OIL

2021 ◽  
Vol 7 (2) ◽  
pp. 167
Author(s):  
Gervacia Jenny Ratnawaty ◽  
Ratih Indrawati
Keyword(s):  
Fatty Acids ◽  
Fatty Acid ◽  
Free Fatty Acids ◽  
Total Sample ◽  
P Value ◽  
Cooking Oil ◽  
Used Cooking Oil ◽  
Regression Test ◽  
Quasi Experimental ◽  
Polygonum Minus

This study aims to determine the effect of adding kesum leaves (polygonum minus) to used cooking oil on reducing levels of free fatty acids. This type of research is quasi experimental. The population in this study is used cooking oil and the sample used is used cooking oil that has been added with the leaves of kesum with 5 treatments and replicated 5 times so that the total sample is 25.From the results, it was found that the average reduction in free fatty acid levels in used cooking oil before adding the leaves of kesum was 7,12%, which had added kesum leaves as much as 20 grams of 6.93%, 40 grams of 5.36%, 60 gr at 3.93%, 80 gr at 3.26% and 100 gr at 1.62%. The results of the analysis using linear regression test, it is known that the addition of 20 grams and 40 grams of p-value is 0.026 and 0.021 (p <0.05), respectively, so Ha is accepted, that is, there is a relationship between the effectiveness of leaves of kesum (polygonum minus) in reducing levels of fatty acid numbers. free of used cooking oil, namely the addition of 20 and 40 grams. Whereas in the addition of 60, 80 and 100 grams of kesum leaves there was no relationship that was shown with a p value> 0.05.

New Lubricant from Used Cooking Oil: Cyclic Ketal of Ethyl 9,10-Dihydroxyoctadecanoate

2017 ◽  
Vol 901 ◽  
pp. 135-141 ◽  
Author(s):  
Yehezkiel Steven Kurniawan ◽  
Muslih Anwar ◽  
Tutik Dwi Wahyuningsih
Keyword(s):  
Fatty Acids ◽  
Free Fatty Acids ◽  
Viscosity Index ◽  
Acid Number ◽  
Base Number ◽  
Sonochemical Method ◽  
Total Acid ◽  
Cooking Oil ◽  
Used Cooking Oil ◽  
Total Base

A new ketal cyclic from ethyl 9,10-dihydroxyoctadecanoate with acetone had been synthesized by reflux and sonochemical method. The synthesis was performed via several steps of reaction, i.e.: transesterification, hydrolysis, oxidation with 1% KMnO4 in basic condition, esterification, and ketalization. The structures of the products were confirmed by FTIR, GC-MS, 1H- and 13C-NMR spectrometers. Direct transesterification of used cooking oil produced a mixture of ethyl ester in 82.94% yield meanwhile hydrolysis of this mixture gave free fatty acids mixture in 88.46% yield. Hydroxylation reaction of free fatty acids mixture yielded a white powder of 9,10-dihydroxyoctadecanoic acid in 46.52% yield. Esterification of 9,10-dihydroxyoctadecanoic acid and ethanol catalyzed by sulfuric acid with reflux condition for 4 hours and sonochemical method, respectively yielded 90% and 93.8% of ethyl 9,10-dihydroxystearate. In the other side, the utilization of KSF montmorillonite as catalyst conducted with reflux gave 52% in yield of ester. Furthermore, the use of acetone in 45 minutes sonochemical method with montmorillonite KSF catalyst gave cyclic ketal (ethyl 8-(2,2-dimethyl-5-octyl-1,3-dioxolan-4-yl)octanoate) as a yellow viscous liquid in 53.30% yield. From physicochemical properties –density, kinematic viscosity, viscosity index, total acid number, total base number and iodine value- gave the conclusion that this novel compound is potential biolubricant candidates to be developed.

scholarly journals DECREASE IN FREE FATTY ACID CONTENT AND COLOR AT USED COOKING OIL WITH ACTIVATED CARBON OF REEDS (Imperata cylindrica L. Raeusch)

1970 ◽  
pp. 87-94
Author(s):  
Samsuar Samsuar
Keyword(s):  
Fatty Acids ◽  
Activated Carbon ◽  
Fatty Acid ◽  
Free Fatty Acid ◽  
Free Fatty Acids ◽  
Fatty Acid Content ◽  
Optimum Concentration ◽  
Imperata Cylindrica ◽  
Cooking Oil ◽  
Used Cooking Oil

Cooking oil is one of the foods that are needed by the community in daily life. The use of cooking oil continuously at high temperatures, produces cooking oil that is no longer feasible to use. Therefore, it’s necessary to purify used cooking oil so that it can be reused for non-foood purposes such as making soap or biodiesel fuel. This purification process is utilie the activated carbon of reeds (Imperata cylindrica L. Raeusch) as an adsorbent to reduce the levels of free fatty acids and colors in used cooking oil. Free fatty acid content test using acid base titration method and color change using Uv-Vis spectrofotometry method. This study aims to determine the optimum concentration of reeds activated carbon as an adsorbent in reducing the levels of free fatty acids and colors in used cooking oil, which consists of the concentration of reeds activated carbon which is a consentration of 2,5; 5; 7,5; 10; dan 12,5%. The results of variance analysis showed the optimum concentration of reeds activated carbon to reduce the levels of free fatty acids and colors absorbance in used cooking oil at a concentration of 7,5%. The percentage of decreasing levels of free fatty acids gorengan and pecel lele are 78.57% and 78.85%. Decrease in absorbance of gorengan color from 1,792% to 0,384% and the pecel lele color absorbance from 2,521 to 0,515. Keywords : Activated Carbon,Color, Free Fatty Acid, Reeds, and Used Cooking Oil.

scholarly journals Pemanfaatan Kunyit (Curcuma domestica Val) Untuk Memurnikan Minyak Jelantah

2018 ◽  
Vol 7 (1) ◽  
pp. 41
Author(s):  
Muhammad Silmi Hi Abubakar ◽  
Siti Nuryanti ◽  
Suherman Suherman
Keyword(s):  
Fatty Acids ◽  
Moisture Content ◽  
Free Fatty Acids ◽  
Quality Parameters ◽  
Test Results ◽  
Cooking Oil ◽  
Used Cooking Oil ◽  
Before And After

Study on the purification and quality test of used cooking oil with turmeric has been done. This study aims to determine the quality of cooking oil after purified turmeric. The quality parameters of oil studied were the moisture content, free fatty acids (FFA), and peroxide. The methods used for determination of these parameters were gravimetry for moisture content, acid-base titration for free fatty acids, and iodometric for peroxide. The test results for water from 0.6% to 0.4% free fatty acid from 1.2% to 0.2%, and peroxide levels before and after purification were successively from and 6 meq/g to 4 meq/g, respectively. Only free fatty acids of all three parameters met the requirement of SNI.

Rancidity of Used Cooking Oil and Heavy Metal Analyses on Selected Street-Vended Foods

10.17158/224 ◽  
2012 ◽  
Vol 18 (1) ◽  
Author(s):  
Annabelle A. Callano
Keyword(s):  
Fatty Acids ◽  
Heavy Metal ◽  
Free Fatty Acids ◽  
Peroxide Value ◽  
Heavy Metal Contamination ◽  
Prolonged Exposure ◽  
Oxidation Stability ◽  
Food Poisoning ◽  
Cooking Oil ◽  
Used Cooking Oil

Intake of unsafe food causes many acute and life-long diseases, ranging from diarrheal diseases to various forms of cancer. Thus, it is imperative that safety issues on food adulteration and heavy metals contamination be evaluated for the benefits of the consuming public. Consequently, oxidation stability and heavy metal analyses on used cooking oil and four selected street-vended foods from three different sampling sites were done. Analyses of test parameters were performed using standard methods and procedures. Overall results of the analyses with three trials each showed that peroxide value, free fatty acids, cadmium (Cd) and lead (Pb) did not conform to the allowable levels set for the food products. The peroxide value was three to eight times higher than the limit of 10meq/kg since it ranges from 33.33 - 86.67meq/kg whereas Cd and Pb showed concentration of 0.60 – 1.57 ppm and 30.00-35.00 ppm, respectively. On the other hand, percent free fatty acids (%FFA) ranges from 0.72 to 0.93% on used cooking oil while selected street-vended foods FFA status were recorded at the range of 1.49 to 2.92%. The results clearly indicate oxidative rancidity due to repetitive use of cooking oil and heavy metal contamination on the test samples which were found to be significantly higher than the maximum limits. This could mean that prolonged exposure to these street vended foods is detrimental to human health. The high level of POV, Cd and Pb of these products can significantly pose food poisoning, foodborne disease, neurotoxicity and even cancer.

scholarly journals Identification of Organic Constituents in Cooking Oil by Adding Turmeric as a Potential Antioxidant Agent

2020 ◽  
Vol 11 (2) ◽  
pp. 8904-8914
Keyword(s):  
Fatty Acids ◽  
Oleic Acid ◽  
Fatty Acid ◽  
Palmitic Acid ◽  
Unsaturated Fatty Acid ◽  
Unsaturated Fatty Acids ◽  
Saturated Fatty Acids ◽  
Fatty Acid Content ◽  
Cooking Oil ◽  
Turmeric Extract

The objective of this study to compare the fatty acids composition in cooking oil from repeated frying without added turmeric extract and added. The research design is testing the composition of fatty acids in repeated cooking oil using two types of treatment, namely cooking oil from frying without adding turmeric extract and cooking oil from frying with 0.03% turmeric extract added with 10 times frying repeat because it is suspected that repeated frying will increase the composition of fatty acids in cooking oil. The analysis of fatty acids was conducted using gas chromatography. Based on these results that the fatty acid components were produced of saturated fatty acids, namely lauric acid, myristic acid, palmitic acid, and stearic acid, whereas unsaturated fatty acids also detected such as elaidic acid, oleic acid, linoleic acid, cis-11-eicosadienoic acid, linolenic acid, and cis-11,14-eicosadienoic acid. The highest saturated fatty acid content in cooking oil before frying is palmitic acid (30.88%), whereas unsaturated fatty acid was oleic acid (35.86%). The highest content of saturated fatty acids in cooking oil has been added turmeric extract before frying is palmitic acid (28.5%), while unsaturated fatty acid of oleic acid was 32.97%.

scholarly journals ARANG AMPAS TEBU UNTUK MENURUNKAN KADAR ASAM LEMAK BEBAS MINYAK GORENG BEKAS

2018 ◽  
pp. 189-193
Author(s):  
P Purwati ◽  
Tri Harningsih
Keyword(s):  
Fatty Acids ◽  
Fatty Acid ◽  
Free Fatty Acid ◽  
Free Fatty Acids ◽  
Fatty Acid Content ◽  
Cooking Oil ◽  
Used Oil ◽  
Used Cooking Oil ◽  
Lower Free Fatty Acid

ABSTRAK Minyak digunakan secara berulangkali mengakibatkan penurunan kualitas minyak. Salah satunya adalah peningkatan asam lemak bebasnya. Limbah ampas tebu yang diubah ke dalam bentuk arang digunakan menurunkan asam lemak bebas pada minyak goreng bekas. Penambahan arang ampas tebu dengan variasi massa dapat menurunkan asam lemak bebas. Asam lemak bebas minyak bekas sebelum ditambah dengan arang ampas tebu adalah 0,62 %. Angka tersebut mengalami penurunan setelah penambahan variasi massa ampas tebu dimulai dengan 2,5 gram; 5,0 gram; 7,5 gram; 10,0 gram dan 12,5 gram. Hasil asam lemak bebas berturut-turut 0,61%; 0,55%; 0,48%; 0,45%; 0,43%. Kondisi optimum dari massa arang ampas tebu sebesar 12,5 gram. Prosentase penurunan asam lemak bebas sebesar 30,41 % dengan kadar asam lemak bebas dari sebelum dilakukan adsorbsi sebanyak 0,61% menjadi 0,43%.   Kata kunci: arang ampas tebu, asam lemak bebas, minyak goreng bekas       ABSTRACT Oils used repeatedly will result in a decrease in the quality of oil. One of which is the increase in free fatty acids. The waste bagasse which is converted into charcoal form used to lower free fatty acid in used oil casting. The addition of charcoal of bagasse with variation of mass can decrease free fatty acid. The fatty acid free of used oil before it is added with sugarcane bagasse is 0,62%. The number decreases after the addition of variation of bagasse mass begins with 2,5 grams; 5,0 grams; 7,5 grams; 10,0 grams and 12; 5 grams. Free fatty acids result are 0,61%; 0,55%; 0,48%; 0,45%; 0; 43% respectively. The optimum condition from the mass of charcoal of bagasse is 12,5 grams. Percentage of free fatty acid decrease of 30,41% with free fatty acid content from before adsorbs 0,61% to 0,43%.   Keywords: charcoal of bagasse, free fatty acids, used cooking oil

scholarly journals Penurunan Bilangan Peroksida Dan Asam Lemak Bebas Pada Minyak Jelantah Menggunakan Serbuk Mahkota Dewa

2020 ◽  
Vol 2 (2) ◽  
pp. 83-87
Author(s):  
Mutiara Putri Utami Susanto ◽  
Kenny Kencanawati ◽  
Dwi Tia Septiani ◽  
Sani Nurahayu
Keyword(s):  
Fatty Acids ◽  
Fatty Acid ◽  
Free Fatty Acid ◽  
Free Fatty Acids ◽  
Fatty Acid Analysis ◽  
Peroxide Number ◽  
Cooking Oil ◽  
Used Cooking Oil ◽  
Stirring Time

The study used mahkota dewa as adsorben to decrease of the peroxide number and free fatty acids on the used cooking oil with immersion variations for 2 days dan 3 days and also concentration variations of mahkota dewa 5 % w/v, 10 % w/v, and 20 % w/v. The results of the peroxide analysis test still exceed the required number of SNI namely 10 meq O2/kg and the results of the free fatty acid analysis test in the sample with immersion and stirring time for 2 days and 3 days the concentration of  mahkota dewa 20 % w/v has met the SNI, which is 1.04 % and 0.91%.

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