scholarly journals REMOVAL OF TERASIL BLUE DYE FROM SYNTHETIC WASTEWATER USING LOW COST AGRO-BASED ADSORBENTS

2019 ◽  
Vol 11 (2) ◽  
pp. 246-255 ◽  
Author(s):  
Hatem Asal Gzar ◽  
Noor Qassim Sabri

Natural materials that are readily available in large amounts in nature and easily accessible may be used as low cost additives. The aim of this study is to measure the susceptibility of these locally available materials, conocarpus plant, to improve the quality of wastewater discharged from textile industry.  In addition to conocarpus plant, carbonized conocarpus and activated carbon were used as adsorbents in order to make a comparison, and to test which one of the three types give the best efficiency for removing dye. The ability of adsorbents to adsorb dye was studied using batch system; studied parameters were effect of pH, dose of adsorbents, time, and agitation speed. The experimental results showed that the maximum removal efficiency of conocarpus was found to be 87.5% at 50 rpm mixing speed, pH value 3 , mixing time 120 min and the dose of adsorbent was 0.25 g.  The maximum removal efficiency for carbonized conocarpus was up to 98.7% at 150 rpm mixing speed, pH value 3 , mixing time was equal to 7 hours and the dose of sorbent was 1.25 g. For activated carbon the maximum removal efficiency was found to be 99% at mixing speed of 200 rpm, pH value 3 or 11, mixing time was equal to 7 hours and the dose of the sorbent was 1.25 g. The above removal efficiencies were obtained at temperature 20 °C.

2019 ◽  
Vol 11 (2) ◽  
pp. 229-245
Author(s):  
Hatem Asal Gzar ◽  
Noor Qassim Sabri

Natural materials that are readily available in large amounts in nature and easily accessible may be used as low cost additives. The aim of this study is to measure the susceptibility of these locally available materials, conocarpus plant, to improve the quality of wastewater discharged from textile industry. In addition to conocarpus- without chemically treated, conocarpus- chemically treated, carbonized conocarpus and activated carbon were used as adsorbents in order to make a comparison, and to test which one of the four types give the best efficiency for removing dye. The ability of adsorbents to adsorb dye was studied using continuous system; studied parameters were effect of flow rate, bed depth, and initial concentration. The experimental results showed that maximum removal efficiency of conocarpus - without chemically treated was found to be 90% after 75 min at flow rate 20 l/h, pH value 3 , bed depth 5cm and initial concentration 40 mg/l. The maximum removal efficiency for conocarpus- chemically treated was up to 83.75% after 15 min at flow rate 10 l/h, pH value 3, bed depth 10 cm and initial dye concentration 40 mg/l. The maximum removal efficiency for carbonized conocarpus was up to 99.67% after 15 min at flow rate 10 l/h, pH value 3, bed depth 10 cm and initial dye concentration 40 mg/l. For activated carbon the maximum removal efficiency was found to be 99.75% after 15 min at flow rate 10 l/h, pH value 3, bed depth 10cm and initial dye concentration 40 mg/l.


2017 ◽  
Vol 11 (12) ◽  
pp. 102 ◽  
Author(s):  
Muhammad Saleem ◽  
Mehmood Ali ◽  
Zia Siddiqi ◽  
Abdulrahman Saud Al Qahtani

Saudi Arabian desert tree Acacia (Vachellia Seyal) used to produce Activated Carbon (AC) by phosphoric acid mediated chemical activation at low temperature. Characterization of AC done based on proximate and detailed analysis including Moisture content, Total Ash content, pH value, Iodine number, Methylene blue number, pore volume and BET surface area. Results revealed that properties of produced activated carbon (PAC) are comparable to commercial activated carbon (CAC). Low ash content and hardness making it suitable for water and wastewater treatment. Cost of production found to be less than $0.5/kg. Both AC used to treat wastewater containing Methylene Blue (MB) dye. Initially the removal efficiency of CAC is higher than the PAC however, both AC reached to similar removal (95.3% for PAC and 98.2% for CAC) within one hour. Growing demand of AC in the country can be meet by producing low cost locally available waste materials Acacia seyal tree branches.


2018 ◽  
Vol 7 (4.19) ◽  
pp. 909 ◽  
Author(s):  
Saleem Ethaib ◽  
Iqbal K. Erabee ◽  
Ali A. Abdulsahib

The removal of textile-based cationic methylene blue (MB) dye from synthetic wastewater was investigated in batch model using low cost agro-based adsorbents named Kenaf core, and the activated carbon. A comparative analysis between these adsorbents was defined via pH, adsorbent dose and contact time on adsorption process, and morphological properties. In addition, isotherms adsorption studies were estimated for determination of the equilibrium adsorption capacity. The experimental observation showed that the optimum pH values for Kenaf core and the activated carbon were 6 and 4 respectively. Meanwhile the optimum adsorbent dosage values for Kenaf and the activated carbon were 1.5g for both. The results showed that a high adsorption efficiency for Kenaf core which was about 84% and 92 % for activated carbon. The correlation coefficients (𝑅2) for kenaf core were equal to 0.8789 and 89 for Langmuir and Freundlich isotherm, respectively. Meanwhile, the correlation coefficients (𝑅2) for activated carbon were equal were 0.8974 and 0.7643 for Langmuir and Freundlich isotherms, respectively. The results illustrated that the Kenaf core has a porous and an irregular surface area which make it a suitable adsorbent for dyes in the wastewater. 


Author(s):  
Irshad. S. Shaikh

Textile industry is one of the major industries in the world that provide employment with no required special skills and play a major role in the economy of many countries. The textile industry utilizes various chemicals and large amount of water during the production process. Colour is the major pollutants present in the effluent from various textile industries. These are highly toxic to living things and have hazardous effect on their health. Thus removal of colour using natural flocculant is a major step towards the protection of natural resources. Coagulation-flocculation is the most widely used method and is applicable for the removal of the colour even at low concentrations. This paper represents the results of investigations carried out for the removal of colour along with SS, DS, TS and COD from waste water by using natural flocculant i.e. Cactus, Aloevera, and combination of Cactus & Aloevera. The colour removal efficiency of flocculant was investigated by batch wise coagulation flocculation method. The effect of various important parameters on the % removal of colour was studied to find the optimum condition for the maximum removal of colour. The parameters like pH, coagulant dose, flocculant dose, coagulant mixing time, coagulant mixing speed, flocculant mixing time, flocculant mixing speed, setting time & concentration of waste water were investigated. These parameters for Cactus were found to be 12, 10 ml/L, 20 ml/L, 2 min, 140 rpm, 15 min, 70 rpm, 6 min, 300 ml/L respectively, for Aloevera were Journal of Water Resource Engineering & Pollution Studies Volume 5 Issue 1 found to be 11.5, 10 ml/L, 100 ml/L, 2 min, 140 rpm, 15 min, 30 rpm, 1 min, 300 ml/L respectively and simultaneously for combination of Cactus & Aloevera were found to be 12, 10 ml/L, 10% + 80% (Cactus + Aloevera dose) ml/L, 2 min, 140 rpm, 25 min, 50 rpm, 10 min, 300 ml/L respectively. These natural flocculants gives maximum colour removal efficiency in the range 85-100%. The colour removal efficiency was found in between 85-100% for all parameters. All the result was validated on the basis of mathematical analysis. All the graphs were fitted to various trend lines out of which polynomial third order curve is best fit to experimental work as the coefficient of correlation (R2 value) is closer to unity.


2021 ◽  
Vol 16 (1) ◽  
Author(s):  
Xiao Li Ma ◽  
Guang Tao Fei ◽  
Shao Hui Xu

Abstract In this study, polyaniline (PANI) is prepared by means of chemical oxidization polymerization and directly loaded on the modified fiber ball (m-FB) to obtain macroscale polyaniline/modified fiber ball (PANI/m-FB) composite, and then its removal ability of Cr(VI) is investigated. The effects of different parameters such as contact time, pH value and initial concentration on Cr(VI) removal efficiency are discussed. The experimental results illustrate that the favorable pH value is 5.0 and the maximum removal capacity is measured to be 293.13 mg g−1. Besides, PANI/m-FB composites can be regenerated and reused after being treated with strong acid. The kinetic study indicates that the adsorption procedure is mainly controlled by chemical adsorption. More importantly, the macroscale of composites can avoid secondary pollution efficiently. Benefiting from the low cost, easy preparation in large scale, environmentally friendly, excellent recycling performance as well as high removal ability, PANI/m-FB composites exhibit a potential possibility to remove Cr(VI) from industrial waste water. Graphic Abstract The polyaniline (PANI) was coated on modified fiber ball (m-FB) to remove Cr(VI) in waste water, and this kind of PANI/m-FB composites can avoid secondary pollution efficiently due to its macrostructure. Furthermore, the removal capacity can reach to 291.13 mg/g and can be multiple reused.


2013 ◽  
Vol 65 (1) ◽  
Author(s):  
Norzita Ngadi ◽  
Chin Chiek Ee ◽  
Nor Aida Yusoff

Dyes contain carcinogenic materials which can cause serious hazards to aquatic life and the users of water. Textile industry is the main source of dye wastewater which results in environmental pollution. Many studies have been conducted to investigate the use of low cost adsorbent as an alternative technique for the adsorption of dye. The objective of this study is to determine the potential of eggshell powder as an adsorbent for methylene blue removal and find out the best operating conditions for the color adsorption at laboratory scale. The adsorption of cationic methylene blue from aqueous solution onto the eggshell powder was carried out by varying the operating parameters which were contact time, pH, dosage of eggshell powder and temperature in order to study their effect in adsorption capacity of eggshell powder. The results obtained showed that the best operating condition for removal of methylene blue was at pH 10 (78.98 %) and temperature 50°C (47.37 %) by using 2 g of eggshell powder (57.03 %) with 30 minutes equilibrium time (41.36 %). The kinetic studies indicated that pseudo-second-order model best described the adsorption process.


2021 ◽  
Vol 900 (1) ◽  
pp. 012003
Author(s):  
M Balintova ◽  
Z Kovacova ◽  
S Demcak ◽  
Y Chernysh ◽  
N Junakova

Abstract Removal of heavy metals from the environment is important for living beings. The present work investigates the applicability of the natural and MnO2 - coated zeolite as sorbent for the removal of copper from synthetic solutions. Batch experiments were carried out to identify the influence of initial pH and concentration in the process of adsorption. A maximum removal efficiency of Cu(II) was observed in 10 mg/L for natural (95.6%) and modified (96.4%) zeolite, where the values was almost identical, but at concentration of 500 mg/L was the removal efficiency of modified zeolite three times higher. Based on the correlation factors R2, the Langmuir isotherms better describe the decontamination process than Freundlich. The optimum pH value was set at 5.0.


2019 ◽  
Vol 79 (5) ◽  
pp. 895-904 ◽  
Author(s):  
Priyanka Jamwal ◽  
Daniel Phillips ◽  
Kim Karlsrud

Abstract In the present study, three low-cost filter aggregate materials were tested and compared for organic matter and fecal coliform (FC) removal at the laboratory scale. Setups were subjected to synthetic wastewater at two hydraulic loading rates (HLR), i.e. 4 cm/day and 40 cm/day. The hydraulic retention time (HRT) at the two HLRs varied from 4 days to 12 h, respectively. The result obtained shows that the biochemical oxygen demand (BOD5) removal efficiency of aggregate materials decreased with the increase in HLR. Both at high and low HLR, the terracotta aggregate material exhibited maximum BOD5 loading removal and without significant difference for the case of FC removal efficiency for all the three aggregate materials. At higher HLR, cell debris and biofilm loss from the aggregate material contributed to the chemical oxygen demand (COD) levels in the treated water. The terracotta aggregate material provided best organic matter removal at both HLRs. The study demonstrates the potential of incorporating inexpensive and readily available local materials into decentralized, frugal green infrastructure interventions capable of lowering the quantum of harmful biological contaminants in open storm water channels in rapidly urbanizing cities of developing countries, and that the terracotta aggregate material provided best organic removal at both HLRs.


Water ◽  
2019 ◽  
Vol 11 (4) ◽  
pp. 781 ◽  
Author(s):  
Wang ◽  
Zhang ◽  
Lv

The removal efficiency and mechanism of Cr(VI) removal from aqueous solution on semi-decomposed maize straw biochars pyrolyzed at 300 to 600 °C were investigated. The removal of Cr(VI) by the biochars decreased with pyrolysis temperature increasing from 300 to 600 °C, and the maximum removal capacity of Cr(VI) for maize straw biochar pyrolyzed at 300 °C was 91 mg/g at pH 2.0. The percentage removal of Cr(VI) rapidly decreased with pH increasing from 2.0 to 8.0, with the maximum (>99.9%) at pH 2.0. The variation of Cr(VI) and Cr(III) concentrations in the solution after reaction showed that Cr(VI) concentration decreased while Cr(III) increased and the equilibrium was reached after 48 h, while the redox potential after reaction decreased due to Cr(VI) reduction. X-ray photoelectron spectroscopy (XPS) semi-quantitative analysis showed that Cr(III) accounted for 75.7% of the total Cr bound to maize straw biochar, which indicated reductive adsorption was responsible for Cr(VI) removal by the biochars. Cr(VI) was firstly adsorbed onto the positively charged biochar surface and reduced to Cr(III) by electrons provided by oxygen-containing functional groups (e.g., C=O), and subsequently part of the converted Cr(III) remained on the biochar surface and the rest released into solution. Fourier transform infrared (FTIR) data indicated the participation of C=O, Si–O, –CH2 and –CH3 groups in Cr(VI) removal by the biochars. This study showed that maize straw biochar pyrolyzed at 300 °C for 2 h was one low-cost and efficient adsorbent for Cr(VI) removal from aqueous solution.


2012 ◽  
Vol 60 (2) ◽  
pp. 185-189 ◽  
Author(s):  
Mohammad Arifur Rahman ◽  
S. M. Ruhul Amin ◽  
A. M. Shafiqul Alam

The possible utilization of rice husk activated carbon as an adsorbent for the removal of methylene blue dye from aqueous solutions has been investigated. In this study, activated carbons, prepared from low-cost rice husk by sulfuric acid and zinc chloride activation, were used as the adsorbent for the removal of methylene blue, a basic dye, from aqueous solutions. Effects of various experimental parameters, such as adsorbent dosage and particle size, initial dye concentration, pH and flow rate were investigated in column process. The maximum uptakes of methylene blue by activated rice husk carbon at optimized conditions (particle sizes: 140 ?m; Flow rate: 1.4 mL/min; pH: 10.0; initial volume of methylene blue: 50 mL and initial concentration of methylene blue: 4.0 mg/L etc.) were found to 97.15%. The results indicate that activated carbon of rice husk could be employed as low-cost alternatives to commercial activated carbon in waste water treatment for the removal of basic dyes. This low cost and effective removal method may provide a promising solution for the removal of crystal violet dye from wastewater.DOI: http://dx.doi.org/10.3329/dujs.v60i2.11491 Dhaka Univ. J. Sci. 60(2): 185-189, 2012 (July)


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