scholarly journals Experimental Study and Analysis on Degradation of Oily Sludge from Process Equipment by Continuous Hybrid Treatment

2018 ◽  
Vol 24 (7) ◽  
pp. 35
Author(s):  
Mohammad Fadhil Abid ◽  
Luma Hussein Mahmod ◽  
Samer Talib Breesam ◽  
Wasen Samie
Keyword(s):  
Oil Recovery ◽  
Operating Conditions ◽  
Solid Particles ◽  
Oil Refinery ◽  
Hybrid Process ◽  
Optimum Operating ◽  
Process Equipment ◽  
Oily Sludge ◽  
Efficient Treatment ◽  
Hybrid Treatment

It is well known that petroleum refineries are considered the largest generator of oily sludge which may cause serious threats to the environment if disposed of without treatment. Throughout the present research, it can be said that a hybrid process including ultrasonic treatment coupled with froth floatation has been shown as a green efficient treatment of oily sludge waste from the bottom of crude oil tanks in Al-Daura refinery and able to get high yield of base oil recovery which is 65% at the optimum operating conditions (treatment time = 30 min, ultrasonic wave amplitude = 60 micron, and (solvent: oily sludge) ratio = 4). Experimental results showed that 83% of the solvent used was recovered meanwhile the main water which was separated from solid particles was reused. Three types of sonic probes were used to compare effects of their amplitude created. Results revealed that beyond optimum ultrasound intensity, the treating time has an adverse effect on process efficiency. Results proved that usage 0.05% NaOH during the proposed hybrid process increased the oil recovery from 50 to 65%. The proposed hybrid treatment method could represent an environmentally friendly treatment of waste sludge produced from an oil refinery.  

Biosurfactants as demulsifying agents for oil recovery from oily sludge – performance evaluation

2013 ◽  
Vol 67 (12) ◽  
pp. 2875-2881 ◽  
Author(s):  
Evans M. N. Chirwa ◽  
Tshepo Mampholo ◽  
Oluwademilade Fayemiwo
Keyword(s):  
Oil Recovery ◽  
Sodium Dodecyl ◽  
Cost Effective ◽  
Solid Particles ◽  
Second Step ◽  
Oily Sludge ◽  
Waste Sludge ◽  
Complex Interactions ◽  
Oil Water ◽  
Living Organisms

The oil producing and petroleum refining industries dispose of a significant amount of oily sludge annually. The sludge typically contains a mixture of oil, water and solid particles in the form of complex slurry. The oil in the waste sludge is inextractible due to the complex composition and complex interactions in the sludge matrix. The sludge is disposed of on land or into surface water bodies thereby creating toxic conditions or depleting oxygen required by aquatic animals. In this study, a fumed silica mixture with hydrocarbons was used to facilitate stable emulsion (‘Pickering’ emulsion) of the oily sludge. The second step of controlled demulsification and separation of oil and sludge into layers was achieved using either a commercial surfactant (sodium dodecyl sulphate (SDS)) or a cost-effective biosurfactant from living organisms. The demulsification and separation of the oil layer using the commercial surfactant SDS was achieved within 4 hours after stopping mixing, which was much faster than the 10 days required to destabilise the emulsion using crude biosurfactants produced by a consortium of petrochemical tolerant bacteria. The recovery rate with bacteria could be improved by using a more purified biosurfactant without the cells.

scholarly journals Membrane Distillation Crystallization Hybrid Process for Zero Liquid Discharge in QAFCO Plant

2021 ◽  
Author(s):  
Mona Gulied ◽  
Sifani Zavahir ◽  
Tasneem Elmakki ◽  
Hazim Qiblawey ◽  
Bassim Hameed ◽  
...  
Keyword(s):  
Research Work ◽  
Membrane Distillation ◽  
Economic Feasibility ◽  
Operating Conditions ◽  
Hybrid Process ◽  
Optimum Operating ◽  
Low Grade ◽  
Water Recovery ◽  
Ongoing Research ◽  
Liquid Discharge

Qatar fertilizer company (QAFCO) is one of the world’s largest single site producer of ammonia and urea with production capacity of 12,900 metric tons per day. Currently, QAFCO faces major challenges in terms of water streams management that is generated from many processes such as wastewater from Harbor-Bosch process and brine solution from multi-stage flash (MSF) desalination process. To protect the environment; QAFCO has been making an effort to minimize the disposal of all types of water disposed into the sea. Here, this project proposes to develop a viable and economically effective process that can reach zero-liquid discharge (ZLD) of all processed water or wastewater from QAFCO facilities. The best method for ZLD is membrane distillation crystallization (MDC) hybrid process that concentrates and minimizes the volume of wastewater/brine streams to form solid through crystallizer. Membrane distillation (MD) is a thermally driven membrane process. It applies low-grade energy to create a thermal gradient across a microporous hydrophobic to vaporize water in the feed stream and condense the permeated vapor in the cold side. This research work aims to evaluate the performance of MDC for ZLD using commercial/fabricated electrospun nanofiber membrane (ENM) PVDF –base membranes at different type water streams. A general observation, higher water vapor flux and water recovery were exhibited at higher feed conductivity at 70°C. Moreover, the fabricated hydrophobic PVDF ENMs results confirmed the formation of nanofiber at the membrane surface using scanning electron microscopy (SEM). In addition, the water contact angle values of PVDF ENMs were greater than 100° and have stable mechanical and chemical properties. The ongoing research work will conduct a comparison between the optimum PVDF ENMs and the commercial MD membranes in terms of water recovery, salt rejection%, fouling/scaling, amount of collected solid and energy consumption at optimum operating conditions in MDC. In addition, it will perform a techno- economic feasibility assessment of the MDC hybrid process.

scholarly journals Valorisation of used automotive lubrication oil

2019 ◽  
Author(s):  
◽  
Taegan Van Zyl
Keyword(s):  
South African ◽  
Impurity Content ◽  
Operating Conditions ◽  
Oil Refinery ◽  
Optimum Operating ◽  
Additive Package ◽  
Operating Variables ◽  
Lubrication Oil ◽  
Light Oil ◽  
Industrial Heating

This study has explored the production of Light Oil 10 (LO10) fuel from used automotive lubrication oil, thus providing a method for producing a cheaper alternative to diesel and paraffin for the South African industrial heating fuel market. Used automotive lubrication oil has different physical properties to that of the specified properties for Light Oil 10 fuel and therefore has to undergo processing that aligns the properties of the two. The low availability of Light Oil 10 fuel in the South African industrial heating market is driving companies such as a Durban based oil refinery to develop a continuous process that will produce Light Oil 10 fuels without the supplementation of paraffin. The supplementation has been done to retain customers but this resulted in the company selling Light Oil 10 fuel at a loss. Used automotive lubrication oil was of particular interest for use as the raw material for the new process as it is of low cost and is readily available. The viscosity (a measure of how easily a fluid flows at a particular temperature) of used lubrication oil was too high and needed to be reduced before it could qualify as Light Oil 10. The reduction of the viscosity of a fluid means that the ability of the fluid to flow at a particular temperature has improved. Additionally the additive package and the impurity content of the used automotive oil were too high. The additive package is added to mineral oil to give it the properties that new automotive lubrication oil requires; this package is still present in used automotive lubrication oil and is responsible for the high level of impurity content because it prevents impurities from agglomerating and dropping out of the oil. The new process was therefore required to be able to reduce the viscosity of used automotive lubrication oil and break the additive package. The required process and operating variables were developed / identified through literature review (qualitative) and the optimum operating variables were identified through experimentation (quantitative). A design of experiment was carried out using Design Expert software. This identified the matrix of runs that were required in identifying the optimum temperature, pressure and residence time for the ranges specified. The product from each of the runs was analysed in the Durban based oil refinery Research and Development lab. The results from the lab along with the corresponding run conditions were used to develop a model, and the model used to identify the optimum operating conditions. The research and experimentation took a total of two years to complete. The literature review found an existing refinery process, the drum type visbreaker to be the most suitable process for reducing the viscosity and breaking the additive package of used automotive lubrication oil. The drum type visbreaker holds oil in the drum for a period of time known as the residence time, at temperatures and pressures of 443oC and 15 bar respectively. These three variables are the critical operating variables in the visbreaking process. The high temperature breaks the large molecules into smaller molecules thereby reducing the viscosity via a process known as thermal cracking. This process also breaks down the additive package. The results from the experimental runs revealed that it is possible to produce Light Oil 10 from used automotive lubrication oil using the drum type visbreaker. The model produced through experimentation was found to be reliable and accurate within the range of variables investigated at predicting results for future runs. The model was also successfully used to identify the optimum operating conditions at which Light Oil 10 is produced from used automotive lubrication oil. The conditions were found to be 475oC, 15 bar and 60 minutes, confirmed by three confirmation runs. In conclusion this study has identified through literature and experimentation that thermal cracking via the free radical mechanism is the preferred process for producing Light Oil 10 from used automotive lubrication oil at liquid yields greater than 90%. An appropriate model was generated using the critical operating variables to predict future viscosity results. It was recommended that the Durban based oil refinery design and build a production scale pilot plant that includes all equipment and the feed heating coil (furnace used to heat feed to 475oC) that a full scale plant would have. This is because the run lengths due to coking (build up of hard carbon on the surfaces of heat exchange equipment) and functionality of the process need to be confirmed before the process can be deemed to be economically viable. Once this has been achieved a full scale production facility can be built.

Investigation of the different particle size dust releases from rigid filter candles during pulse-jet cleaning

2021 ◽  
pp. 095440622110179
Author(s):  
Xin Luan ◽  
Zhongli Ji ◽  
Longfei Liu ◽  
Ruifeng Wang
Keyword(s):  
Particle Size ◽  
Critical Role ◽  
Operating Conditions ◽  
Solid Particles ◽  
Dust Particles ◽  
Cleaning Efficiency ◽  
Term Operation ◽  
Cleaning Performance ◽  
Experimental Apparatus ◽  
Pulse Jet

Rigid filters made of ceramic or metal are widely used to remove solid particles from hot gases at temperature above 260 °C in the petrochemical and coal industries. Pulse-jet cleaning of fine dust from rigid filter candles plays a critical role in the long-term operation of these filters. In this study, an experimental apparatus was fabricated to investigate the behavior of a 2050 mm filter candle, which included monitoring the variation of pressure dynamic characteristics over time and observing the release of dust layers that allowed an analysis of the cleaning performance of ISO 12103-1 test dusts with different particle size distributions. These results showed the release behavior of these dusts could be divided into five stages: radial expansion, axial crack, flaky release, irregular disruption and secondary deposition. The cleaning performance of smaller sized dust particles was less efficient as compared with larger sized dust particles under the same operating conditions primarily because large, flaky-shaped dust aggregates formed during the first three stages were easily broken into smaller, dispersed fragments during irregular disruption that forced more particles back to the filter surface during secondary deposition. Also, a “low-pressure and long-pulse width” cleaning method improved the cleaning efficiency of the A1 ultrafine test dust from 81.4% to 95.9%.

scholarly journals Enzymatic Transesterification of Waste Frying Oil from Local Restaurants in East Colombia Using a Combined Lipase System

2020 ◽  
Vol 10 (10) ◽  
pp. 3566
Author(s):  
Mary Angélica Ferreira Vela ◽  
Juan C. Acevedo-Páez ◽  
Nestor Urbina-Suárez ◽  
Yeily Adriana Rangel Basto ◽  
Ángel Darío González-Delgado
Keyword(s):  
Reaction Time ◽  
Methyl Esters ◽  
Enzyme Concentration ◽  
Operating Conditions ◽  
Frying Oil ◽  
Biodiesel Production ◽  
Optimum Operating ◽  
Waste Frying Oil ◽  
Production Chain ◽  
Enzymatic Transesterification

The search for innovation and biotechnological strategies in the biodiesel production chain have become a topic of interest for scientific community owing the importance of renewable energy sources. This work aimed to implement an enzymatic transesterification process to obtain biodiesel from waste frying oil (WFO). The transesterification was performed by varying reaction times (8 h, 12 h and 16 h), enzyme concentrations of lipase XX 25 split (14%, 16% and 18%), pH of reaction media (6, 7 and 8) and reaction temperature (35, 38 and 40 °C) with a fixed alcohol–oil molar ratio of 3:1. The optimum operating conditions were selected to quantify the amount of fatty acid methyl esters (FAMEs) generated. The highest biodiesel production was reached with an enzyme concentration of 14%, reaction time of 8 h, pH of 7 and temperature of 38 °C. It was estimated a FAMEs production of 42.86% for the selected experiment; however, best physicochemical characteristics of biodiesel were achieved with an enzyme concentration of 16% and reaction time of 8 h. Results suggested that enzymatic transesterification process was favorable because the amount of methyl esters obtained was similar to the content of fatty acids in the WFO.

Optimum operating conditions for chiral separations in liquid chromatography

The Analyst ◽  
1999 ◽  
Vol 124 (5) ◽  
pp. 713-719 ◽  
Author(s):  
R. P. W. Scott ◽  
Thomas E. Beesley
Keyword(s):  
Liquid Chromatography ◽  
Chiral Separations ◽  
Operating Conditions ◽  
Optimum Operating

scholarly journals Evaluation of wet air oxidation variables for removal of organophosphorus pesticide malathion using Box-Behnken design

2016 ◽  
Vol 75 (3) ◽  
pp. 619-628 ◽  
Author(s):  
Melike Isgoren ◽  
Erhan Gengec ◽  
Sevil Veli
Keyword(s):  
Removal Efficiency ◽  
Applied Pressure ◽  
Organophosphorus Pesticide ◽  
Operating Conditions ◽  
Quadratic Model ◽  
Air Oxidation ◽  
Wet Air Oxidation ◽  
Reaction Conditions ◽  
Efficient Treatment ◽  
Optimum Reaction

This paper deals with finding optimum reaction conditions for wet air oxidation (WAO) of malathion aqueous solution, by Response Surface Methodology. Reaction conditions, which affect the removal efficiencies most during the non-catalytic WAO system, are: temperature (60–120 °C), applied pressure (20–40 bar), the pH value (3–7), and reaction time (0–120 min). Those were chosen as independent parameters of the model. The interactions between parameters were evaluated by Box-Behnken and the quadratic model fitted very well with the experimental data (29 runs). A higher value of R2 and adjusted R2 (>0.91) demonstrated that the model could explain the results successfully. As a result, optimum removal efficiency (97.8%) was obtained at pH 5, 20 bars of pressure, 116 °C, and 96 min. These results showed that Box–Behnken is a suitable design to optimize operating conditions and removal efficiency for non-catalytic WAO process. The EC20 value of raw wastewater was measured as 35.40% for malathion (20 mg/L). After the treatment, no toxicity was observed at the optimum reaction conditions. The results show that the WAO is an efficient treatment system for malathion degradation and has the ability of converting malathion to the non-toxic forms.

Performance Analysis of a Variable Speed-Ratio Metal V-Belt Drive

1988 ◽  
Vol 110 (4) ◽  
pp. 472-481 ◽  
Author(s):  
D. C. Sun
Keyword(s):  
Operating Conditions ◽  
Computational Scheme ◽  
Optimum Operating ◽  
Speed Ratio ◽  
Belt Drive ◽  
Variable Speed ◽  
Change Effect ◽  
Multiple Band ◽  
Ratio Change ◽  
Metal Block

A model of the metal V-belt drive (MBD), considering its detailed multiple-band and metal-block structure, and the ratio-change effect during its operation, is constructed and analyzed. A computational scheme is devised that adapts the analysis to the computation of the MBD’s performance for any specified drive-schedule. General performance characteristics of the MBD and an example illustrating its response to a given drive-schedule are presented. The use of the analysis and the computational scheme in the design of the MBD and in finding the optimum operating conditions is discussed.

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