Mineral-geochemical characteristics Cu-U-Au-manifestations in the Kon Ra region of the Kon Tum province, Vietnam

2020 ◽  
Vol 63 (2) ◽  
pp. 73-85
Author(s):  
Minh Phuong Do ◽  
P. A. Ignatov ◽  
Thi Hong Phan ◽  
Duy Hung Nguyen ◽  
Duan Tran
Keyword(s):  
Mineral Composition ◽  
Absorption Spectrometry ◽  
Metamorphic Rocks ◽  
Multivariate Statistical ◽  
Ore Formation ◽  
Statistical Correlations ◽  
Icp Ms ◽  
Central Vietnam ◽  
The City ◽  
Geological Position

Background. Complex Au-Cu-U mineralization is found in the metamorphic rocks of central Vietnam in the zones of their contact with Triassic granite intrusions. It is localized in tectonic breccias and cataclasites, which affected Triassic granitoids and Precambrian metaskarn rocks. The greatest differentiation is observed for tectonically disturbed granites of the Hai Van complex and the metasomatically reworked zones of contacts of this complex with metacarbonate and metaultramafic rocks of the Kham Duc complex.Aim. To determine the mineral and elemental composition of complex occurrences of Cu, U and Au in Proterozoic rocks of the Kon Tum province of central Vietnam.Materials and methods. The work was based on the authors’ data obtained during fieldwork and analytical laboratory studies in the 2016–2019 period. The diagnostics of ore mineral composition was carried out using 60 polished sections. The chemical composition of ores was determined for 214 samples by ICP MS and for 374 samples by atomic absorption spectrometry at the Vietnamese Centre for Geological and Experimental Analysis in the city of Hanoi. The geochemical relationships of ore components were established by the method of multivariate statistical correlations.Results. The mineral composition includes pyrrhotite, pyrite, chalcopyrite, molybdenite, magnetite, martite, hematite, cubanite, marcasite, gold, xenotime, sphalerite, uraninite, chalcocite, covellite, goethite, malachite and limonite. According to the petrographic and petrochemical composition, the geological position and the data on isotopic age, the metamorphic formations of the Kham Duc complex can be considered as Neoproterozoic-Cambrian formations having experienced metamorphism in the Ordovician.Conclusion. A scheme of the sequence of mineral formation was outlined. ICP MS results of primary ores showed that, in addition to Cu, the formations under study contain concentrations of Co, Mo, U, Au, Zn, Ni, V, Y, La, and As. A positive correlation was found between Cu, U and Au. A model of hydrothermal ore formation was proposed.

scholarly journals Elemental analysis of coffee: a comparison of ICP-MS and AAS methods 

2014 ◽  
Vol 32 (No. 4) ◽  
pp. 354-359 ◽  
Author(s):  
M. Jarošová ◽  
D. Milde ◽  
M. Kuba
Keyword(s):  
Inductively Coupled Plasma ◽  
Microwave Digestion ◽  
Absorption Spectrometry ◽  
Mineral Nutrients ◽  
Multivariate Statistical Methods ◽  
Multivariate Statistical ◽  
Inductively Coupled ◽  
Icp Ms ◽  
Plasma Mass Spectrometry ◽  
Microwave Digestion System

We determined the mineral nutrients and toxic elements (Ca, Cu, Fe, Mg, Zn, Cd, Cr, Mn, Ni, and Pb) in five types of coffee by atomic absorption spectrometry and inductively coupled plasma mass spectrometry. The decomposition of the samples took place in a microwave digestion system with HNO<sub>3</sub> and H<sub>2</sub>O<sub>2</sub> reagents. Partial validation of the method was performed by using the certified reference material (NCS ZC 73014). Univariate and multivariate statistical methods were used to compare both the coffee samples and the techniques used. No significant differences were found between two used methods. Significant differences occurred between the coffee samples but only the application of multivariate statistics helps to distinguish among samples from different locations.

scholarly journals Mineral Composition through Soil-Wine System of Portuguese Vineyards and Its Potential for Wine Traceability

Beverages ◽  
2018 ◽  
Vol 4 (4) ◽  
pp. 85 ◽  
Author(s):  
Sofia Catarino ◽  
Manuel Madeira ◽  
Fernando Monteiro ◽  
Ilda Caldeira ◽  
Raúl Bruno de Sousa ◽  
...  
Keyword(s):  
Elemental Composition ◽  
Mineral Composition ◽  
Quantitative Method ◽  
Geographical Origin ◽  
Geographic Origin ◽  
Multivariate Statistical ◽  
Icp Ms ◽  
Geological Formations ◽  
Composition Pattern ◽  
Grape Musts

The control of geographic origin is one of a highest priority issue regarding traceability and wine authenticity. The current study aimed to examine whether elemental composition can be used for the discrimination of wines according to geographical origin, taking into account the effects of soil, winemaking process, and year of production. The elemental composition of soils, grapes, musts, and wines from three DO (Designations of Origin) and for two vintage years was determined by using the ICP-MS semi-quantitative method, followed by multivariate statistical analysis. The elemental composition of soils varied according to geological formations, and for some elements, the variation due to soil provenance was also observed in musts and wines. Li, Mn, Sr and rare-earth elements (REE) allowed wine discrimination according to vineyard. Results evidenced the influence of winemaking processes and of vintage year on the wine’s elemental composition. The mineral composition pattern is transferred through the soil-wine system, and differences observed for soils are reflected in grape musts and wines, but not for all elements. Results suggest that winemaking processes and vintage year should be taken into account for the use of elemental composition as a tool for wine traceability. Therefore, understanding the evolution of mineral pattern composition from soil to wine, and how it is influenced by the climatic year, is indispensable for traceability purposes.

First Finding of the Orbicular Gabbroids in the Ukrainian Antarctic Station Area (Wilhelm Archipelago, West Antarctica)

2021 ◽  
Vol 43 (2) ◽  
pp. 40-48
Author(s):  
O.V. MYTROKHYN ◽  
V.G. BAKHMUTOV
Keyword(s):  
Mineral Composition ◽  
Small Area ◽  
Texture Features ◽  
West Antarctica ◽  
First Finding ◽  
Petrographic Feature ◽  
The Antarctic ◽  
Petrographic Description ◽  
Porphyritic Texture ◽  
Geological Position

A new occurrence of igneous rocks with an orbicular structure was discovered by the authors in West Antarctica. The place of finding is Hovgaard Island in the Wilhelm Archipelago located near the Graham Coast of the Antarctic Peninsula. Until now, not a single manifestation of these rare rocks was known in this region. Usually orbicular rocks are formed under the condition of local "coincidence" of many geological and petrogenetic factors. The study of the geological position, texture features and mineral composition of the orbicular rocks on Hovgaard Island was carried out in order to create their primary petrographic description. It was found that orbiculites are exposed in a small area, about 200 m2, in the field of amphibolized gabbroids and their intrusive breccias. The occurrence and textures of the orbiculites indicate that their crystallization occurred at the hypabyssal depth. Probably, this occurrence is a marginal facies of a small gabbroid intrusion, some parts of which are exposed on the adjacent coastal areas of Hovgaard Island. The studies performed have shown that the orbiculites of Hovgaard Island belong to the rarest petrographic representatives of these rocks namely orbicular gabbroids. In their petrographic feature, they differ markedly from the famous French napoleonites (corsites) exposed on the Corsica Island. The mineral composition of the orbicules is represented by calcium plagioclase (An88-97), hornblende (#Mg = 0.77-0.81), clinopyroxene (Wo48-50En43-47Fs5-8), spinel (Sp62-72Hrc14-20Mt12-17), actinolite, phlogopite, chlorite, magnetite and apatite. The interorbicular matrix has a gabbroid composition and a porphyritic texture. It differs from orbicules in somewhat less calcium plagioclase and less magnesian hornblende, as well as in the absence of spinel. In view of the rarity of orbicular gabbroids and the specificity of the described manifestation, it is proposed that the orbicular gabbro on Hovgaard Island be considered as a new petrographic variety of the gabbroid family. The name "hovgaardite" is recommended for the name of this variety of orbicular gabbro.

scholarly journals Spatial Connections between Microplastics and Heavy Metal Pollution within Floodplain Soils

2022 ◽  
Vol 12 (2) ◽  
pp. 595
Author(s):  
Collin J. Weber ◽  
Jens Hahn ◽  
Christian Opp
Keyword(s):  
Heavy Metals ◽  
Heavy Metal ◽  
Wide Distribution ◽  
Soil Material ◽  
Statistical Correlations ◽  
Floodplain Soils ◽  
Icp Ms ◽  
Metal Contents ◽  
Sediment Layers ◽  
Deposition Conditions

Soils contain an increasing number of different pollutants, which are often released into the environment by human activity. Among the “new” potential pollutants are plastics and microplastics. “Recognized” pollutants such as heavy metals, of geogenic and anthropogenic origin, now meet purely anthropogenic contaminants such as plastic particles. Those can meet especially in floodplain landscapes and floodplain soils, because of their function as a temporary sink for sediments, nutrients, and pollutants. Based on a geospatial sampling approach, we analyzed the soil properties and heavy metal contents (ICP-MS) in soil material and macroplastic particles, and calculated total plastic concentrations (Ptot) from preliminary studies. Those data were used to investigate spatial connections between both groups of pollutants. Our results from the example of the Lahn river catchment show a low-to-moderate contamination of the floodplain soils with heavy metals and a wide distribution of plastic contents up to a depth of two meters. Furthermore, we were able to document heavy metal contents in macroplastic particles. Spatial and statistical correlations between both pollutants were found. Those correlations are mainly expressed by a comparable variability in concentrations across the catchment and in a common accumulation in topsoil and upper soil or sediment layers (0–50 cm). The results indicate comparable deposition conditions of both pollutants in the floodplain system.

scholarly journals Main parameters influencing the plastic behavior of clays used for traditional ceramics production

2021 ◽  
Author(s):  
Hicham El Boudour El Idrissi
Keyword(s):  
Mineral Composition ◽  
Ceramic Industry ◽  
Raw Material ◽  
Plastic Behavior ◽  
Different Types ◽  
The Impact ◽  
The City ◽  
Traditional Ceramics ◽  
Clayey Materials ◽  
Clay Mineral Composition

This paper investigates the main parameters influencing the plastic behavior of clays used for traditional ceramics production. For this, twenty-six clayey pastes were selected from twelve traditional ceramic plants around the city of Marrakech (Morocco). According to the lithology, six different types of materials are used as raw material in the ceramic industry of this region. Emphasis is placed on the impact of the characteristics of these clayey materials upon the plastic behavior of these clays. The pastes were characterized through their consistency using the Atterberg limits. It has been concluded that the gain size, the mineralogical and the clay mineral composition and content, the effect of diagenesis and the presence of talc-pyrophyllite association play the most important role in the control of the plasticity behavior.

scholarly journals Arsenic quantification techniques and ISO/IEC 17025 accreditation in Brazil

2019 ◽  
Vol 6 (14) ◽  
pp. 803-817
Author(s):  
Jefferson Luiz Antunes Santos ◽  
Jader Galba Busato ◽  
Rodrigo de Almeida Heringer ◽  
Juscimar da Silva ◽  
Leonardo Barros Dobbss
Keyword(s):  
Atomic Absorption Spectrometry ◽  
Atomic Absorption ◽  
Inductively Coupled Plasma ◽  
Hydride Generation ◽  
Absorption Spectrometry ◽  
Emission Spectrometry ◽  
Icp Oes ◽  
Analytical Technique ◽  
Inductively Coupled ◽  
Icp Ms

The importance of arsenic (As) quantification in environmental compartments is due to its risks to ecosystems and public health. There are reports of high concentrations of this metalloid in Brazil and technological differences between states are observed. The objective of this work was to present and discuss current scenarios of accreditation and compare the limit of quantification (LOQ) of As by analytical technique in Brazil. Data from accredited laboratories were collected on Inmetro website and in state metrological networks and then grouped and analyzed by state, matrix and analytical technique. There are large discrepancies between the number of laboratories per state and a good correlation with gross domestic product (GDP). Almost all laboratories have a LOQ less than the environmental limits. The observed list of techniques sorted from lowest to highest LOQ values is: for liquid samples ICP MS (inductively coupled plasma mass spectrometry), ET AAS (electrothermal atomic absorption spectrometry), HG AAS (hydride generation combined with atomic absorption spectrometry) or HG ICP OES (hydride generation combined with inductively coupled plasma optical emission spectrometry) and UV VIS (visible ultraviolet spectroscopy); for solids samples HG ICP OES, ICP MS, HG AAS, ET AAS and FAAS (flame atomic absorption spectrometry); and for bioindicators ICP MS, HG ICP OES. Analysis of As species is accredited in only one laboratory, but does not include all species.

Finding of artisanal uses of elemental mercury in the city of Murcia in medieval times

2021 ◽  
Author(s):  
José María Esbrí ◽  
Luis Mansilla-Plaza ◽  
María Jesús Sanchez-Gonzalez ◽  
Pablo Higueras
Keyword(s):  
Atomic Absorption ◽  
Elemental Mercury ◽  
Absorption Spectrometry ◽  
Speciation Analysis ◽  
Outer Wall ◽  
High Concentration ◽  
Entire Area ◽  
High Concentrations ◽  
Under Construction ◽  
The City

&lt;p&gt;Mercury (Hg) was used in gilding techniques since ancient times. This metal gilding technique consisted of applying an amalgam of Au and Hg to the surface of a metallic object and then removing the Hg to achieve adhesion of the Au to the support. The traditional preparation of amalgam was a mixture of Au with Hg (in a ratio of 1/8). After this preparation, the mixture usually was ground in a mortar, heated, and then cooled by pouring it into water. The paste was applied to the areas to be browned and then the piece was subjected to mild temperatures so that the Hg evaporated, leaving a thin layer of Au on the surface of the object.&lt;/p&gt;&lt;p&gt;The origin of this work is the discovery of an evident quantity of liquid Hg on a site under construction, near the old wall of the city of Murcia, at a level identified as from medieval times. To elucidate the origin of this Hg, a sampling of medieval materials has been carried out throughout the site, including both the area with liquid Hg, the entire area what appears to be the work room and the adjacent rooms. The sampling has been carried out using an Ejkelkamp sampler at various depths. These soil samples were analysed by Energy Dispersion X-Ray Fluorescence using a PanAlytical device. Total Hg and Hg speciation data were obtained by Atomic Absorption Spectrometry using a Lumex equipment. In addition to this, a gaseous mercury monitoring has been carried out using a portable atomic absorption equipment to search Hg sources and gaseous Hg dispersion in the atmosphere of the studied site. Results of the survey has shown an evident and intense soil Hg pollution in a small area of 2x2 m. This affected area was located near the outer wall of the medieval building and was very restricted, which suggests that it was a storage place for liquid Hg for later use in other areas. The degassing of these recently uncovered materials produced a significant dispersion of the Hg gas throughout the enclosure. In addition to this, samples of medieval materials have shown very high concentrations of Hg in the vicinity of the contaminated area, and high concentrations in the rest of the enclosure. Speciation analysis have shown that the Hg in this part of the enclosure is in the form of metacinnabar and Hg bound to humic acids, which suggests the presence of an atmosphere with extremely high concentration of gaseous Hg in medieval times that was later deposited in the soil, being fixed to its organic phase. Multielemental analysis has shown additional high concentrations of Pb, Cu and Sn, suggesting that the artisanal works in the enclosure involved these elements too. While waiting for more specific archaeology works that can corroborate it, the origin of this Hg in the area could be the storage for the realization of gilding work on metals with this element.&lt;/p&gt;&lt;p&gt;This work was funded by the company &amp;#8220;Obras y Proyectos Soyma&amp;#8221;.&lt;/p&gt;

scholarly journals Disparities in the Concentrations of Essential/Toxic Elements in the Blood and Scalp Hair of Lymphoma Patients and Healthy Subjects

2019 ◽  
Vol 9 (1) ◽  
Author(s):  
Muhammad Abdul Qayyum ◽  
Munir H. Shah
Keyword(s):  
Toxic Elements ◽  
Cell Lymphoma ◽  
Scalp Hair ◽  
B Cell Lymphoma ◽  
Absorption Spectrometry ◽  
Correlation Study ◽  
Mixed Cellularity ◽  
Multivariate Statistical ◽  
Different Types ◽  
Nodular Sclerosing

Abstract Lymphoma is one of the fastest growing malignancies worldwide and imbalance in the concentrations of trace elements can play a significant role in the onset and progression of the disease. Selected essential and toxic elements (Fe, Zn, Cu, Mn, Ni, Cr, Cd and Pb) were analysed in the blood & scalp hair of lymphoma patients (n = 59 & 58, respectively) and controls (n = 61 & 60, respectively) by atomic absorption spectrometry. On the average, Ni, Cr, Cu and Cd revealed significantly higher contents in the blood and scalp hair of the patients than the controls (p < 0.05). The correlation study showed significantly diverse relationships among the elements in blood & scalp hair of the two donor groups. Variations in the elemental levels with different types of lymphoma (non-Hodgkin and Hodgkin) were also evaluated. Disparities in the elemental concentrations were also investigated for various types of non-Hodgkin (diffuse large B-cell lymphoma, follicular lymphoma and peripheral T-cell lymphoma) and Hodgkin lymphoma (mixed cellularity, nodular lymphocyte predominant and nodular sclerosing), as well as for different stages (I, II, III & IV) of the cancer. Multivariate statistical analysis showed considerably divergent associations of the elements in the patients and controls. The study indicated profound alteration of the elemental levels in the patients; it may be implicated in elemental-induced disorders including lymphoma.

scholarly journals Changes in the Building Stock of Da Nang between 2015 and 2017

Data ◽  
2020 ◽  
Vol 5 (2) ◽  
pp. 42 ◽  
Author(s):  
Andreas Braun ◽  
Gebhard Warth ◽  
Felix Bachofer ◽  
Tram Thi Quynh Bui ◽  
Hao Tran ◽  
...  
Keyword(s):  
Spatial Patterns ◽  
Satellite Image ◽  
Visual Interpretation ◽  
City Center ◽  
Building Stock ◽  
Hexagonal Grid ◽  
Personal Rights ◽  
Central Vietnam ◽  
The City ◽  
New Buildings

This descriptor introduces a novel dataset, which contains the number and types of buildings in the city of Da Nang in Central Vietnam. The buildings were classified into nine distinct types and initially extracted from a satellite image of the year 2015. Secondly, changes were identified based on a visual interpretation of an image of the year 2017, so that new buildings, demolished buildings and building upgrades can be quantitatively analyzed. The data was aggregated by administrative wards and a hexagonal grid with a diameter of 250 m to protect personal rights and to avoid the misuse of a single building’s information. The dataset shows an increase of 19,391 buildings between October 2015 and August 2017, with a variety of interesting spatial patterns. The center of the city is mostly dominated by building changes and upgrades, while most of the new buildings were constructed within a distance of five to six kilometers from the city center.

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