scholarly journals PENYISIHAN ION LOGAM MERKURI (Hg2+) MENGGUNAKAN ADSORBEN BERBAHAN BAKU LIMBAH PERTANIAN DAN GULMA TANAMAN

2017 ◽  
Vol 6 (1) ◽  
pp. 7-11 ◽  
Author(s):  
Miftahurrahmah ◽  
Suhendrayatna ◽  
Muhammad Zaki

This research was conducted to prepare adsorbents from agricultural and weeds waste biomass to remove Hg2+ metal ions from water phase. Water hyacinth biomass (agricultural waste) and rice husk (weed) was cleaned, dried in an oven dryer, and carbonized in a furnace at 500oC for 2 hours. Then, dried carbon was milled to get 100 mesh of size and was followed by activation using 0.5 N NaOH. The adsorption process was conducted by mix 1 gram of activated adsorbent on a 100 ml water containing 3 ppm Hg2+ metal ions at 100 rpm, pH 5, and 30oC. Hg2+ concentration in water phase were analyzed using AAS, Shimadzu AA-6300 for a specified time within a period of 20-100 minutes. This study shows that at the beginning process of adsorption, adsorbent from rice husk has ability to decrease 69.91% concentration of Hg2+ for 20 minutes, while adsorbent from water hyacinth reaches to 94.26%. The characterization results of FTIR spectra and SEM shows that adsorbent from water hyacinth was able to absorb more Hg2+ metal ions in a short time because it has a functional group that was able to bind heavy metals, and also has a random surface structure, compared with the adsorbent from rice husks that has less functional groups with uniform morphology structure

2014 ◽  
Vol 699 ◽  
pp. 221-226
Author(s):  
Nurul Hanim Razak ◽  
Md. Razali Ayob ◽  
M.A.M. Zainin ◽  
M.Z. Hilwa

Eggshells and rice husk, two types of notable agricultural waste were used as bioadsorbent to remove Methylene Blue dye (MBD) in aqueous solution. This study was to investigate the performance of these two bioadsorbents in removing MBD. The removal percentage, adsorption capacity, and porosity characterization were examined. The method applied was a physical filtration. UV-VIS Spectrophotometer was used to determine the efficiency of the bioadsorbents in MBD adsorption. The highest removal percentage at the most concentrated MBD were 51% and 98% for eggshells and rice husks respectively. Meanwhile the characterization of rice husks pore size and volume proves that higher adsorptivity towards dye compares to eggshells porosity. It was concluded that the eggshells and rice husks bioadsorbents was successful to treat industrial textile wastewater with rice husks as the most efficient bioadsorbent in removing MBD.


2015 ◽  
Vol 1113 ◽  
pp. 198-203 ◽  
Author(s):  
Farrah Zuhaira Ismail ◽  
Mohamad Nidzam Rahmat ◽  
Norishahaini M. Ishak

Noise has detrimental effects on human lives and it is a nuisance to the environment. As many of the available sound reduction materials in the current market are hazardous, there are demands for alternative sustainable materials to reduce the noise problem. Therefore, the aim of this research is to study the potential of using an agricultural waste as sound absorption panel. For the purpose of this study, the combination of two materials was under studied; rice husks and sugarcane baggase. There were two main objective of the research; first is to develop absorption panels from the combination of rice husks and sugarcane baggase at different percentage of mixture. Second objective is to identify the absorption rate of the panels. The study encompasses the fabrication of the sustainable sound panels using the rice husk and sugarcane fibre and bond using Phenol formaldehyde (PF). Five panels of sized 12 inch x 12 inch and 12 mm thick were fabricated. The absorption coefficient of the samples was done at the acoustic lab, Faculty of Engineering & Build Environment, Universiti Kebangsaan Malaysia (UKM), Bangi. The panels were tested using an impedance tube. The procedure of the test was carried out in accordance with ISO 10534-2:1998 standards. Based on the results, sample 1 gave the highest absorption coefficient compared to sample 2, 3, 4 and 5. It can be concluded that the acoustic panel made from a mixture of 100% rice husks had higher absorption co-efficient compared to the performance of the other samples given the fact that the characteristic of the rice husks which has air gap in every single piece of rice husk. The spongy properties of the sample 1 panel has created many void spaces which encouraged more sound absorption capability due to the porous surface of the panel. Sound absorption is very much affected by the availability of porosity level of the panel. Thus, further studies on other potential materials from waste should be conducted.Keywords. Noise, Agriculture waste, sound, absorption panels, absorption co-efficient


2020 ◽  
Vol 10 (1) ◽  
Author(s):  
Nazia Hossain ◽  
Sabzoi Nizamuddin ◽  
Gregory Griffin ◽  
Periasamy Selvakannan ◽  
Nabisab Mujawar Mubarak ◽  
...  

Abstract The recent implication of circular economy in Australia spurred the demand for waste material utilization for value-added product generations on a commercial scale. Therefore, this experimental study emphasized on agricultural waste biomass, rice husk (RH) as potential feedstock to produce valuable products. Rice husk biochar (RB) was obtained at temperature: 180 °C, pressure: 70 bar, reaction time: 20 min with water via hydrothermal carbonization (HTC), and the obtained biochar yield was 57.9%. Enhancement of zeta potential value from − 30.1 to − 10.6 mV in RB presented the higher suspension stability, and improvement of surface area and porosity in RB demonstrated the wastewater adsorption capacity. Along with that, an increase of crystallinity in RB, 60.5%, also indicates the enhancement of the catalytic performance of the material significantly more favorable to improve the adsorption efficiency of transitional compounds. In contrast, an increase of the atomic O/C ratio in RB, 0.51 delineated high breakdown of the cellulosic component, which is favorable for biofuel purpose. 13.98% SiO2 reduction in RB confirmed ash content minimization and better quality of fuel properties. Therefore, the rice husk biochar through HTC can be considered a suitable material for further application to treat wastewater and generate bioenergy.


2020 ◽  
Vol 6 (11) ◽  
pp. 3080-3090
Author(s):  
Chengbo Zhan ◽  
Priyanka R. Sharma ◽  
Hongrui He ◽  
Sunil K. Sharma ◽  
Alexis McCauley-Pearl ◽  
...  

Nanocellulose scaffolds derived from rice husks could efficiently remove heavy metal ions from contaminated water.


Author(s):  
Subhasish Majee ◽  
Gopinath Halder ◽  
R. N. Krishnaraj ◽  
Tamal Mandal

The present study focused on the utilization of solid wastes viz. wet blue leather of leather industry, rice husk ash from rice mills, and water hyacinth in addition to a commercial steamed bone meal for the invention of nutrient-enriched organic fertilizer. To produce NPK organic fertilizer, chromium-free wet blue leather (WBL) as nitrogen source was amalgamated with rice husk ash, water hyacinth, and commercial steamed bone meal as a potassium and phosphorus source. The efficiency of such developed organic fertilizer designated as type I was tested as a nutrients source on the marigold plant. Ammonia analysis of fertilizer applied soil samples revealed that the content of liberated free ammonia in the soil fertilized with organic fertilizer was 44.80 %, 20.70 %, and 10.35% higher than the natural soil, chemically fertilized soil and fertilized with vermicompost respectively. Application of developed organic fertilizer and vermicompost designated as type II on marigold plant resulted in significant growth which are comparable to those obtained with commercial Chemical fertilizer. The plant growth increased by chemical fertilizer, Type I fertilizer, and Type II fertilizer in terms of plant height 26.5 %, 20 %, 22.7% and leaf size 21.2 %, 15.4 %, 17.3 % respectively which are observed to be higher than the growth of the control plant.


Author(s):  
Muhammad Irfan ◽  
Amir Shafeeq ◽  
Tahir Saleem Nasir ◽  
Farzana Bashir ◽  
Tausif Ahmad ◽  
...  

Removal of heavy metal ions (HMI) from water streams is desirable due to their toxic and carcinogenic effects. Therefore, this study was conducted to prepare a low cost adsorbent in the form of non-activated carbon (NAC) and activated carbon (AC) using rice husk, a local bio-waste material. Activation of material was performed by base leaching, chemical activation using ZnCl2, followed by acid washing. The initial and final concentrations of HMI in water were measured using Atomic Absorption Spectroscopy. Volatile matter, ash, moisture and surface area of the prepared material were measured using ASTM methods E 897- 88 R04, E 830 - 87 R04, E 949 - 88 R04 and D 1050 - 1 respectively. An enhancement factor was used to evaluate the activating effect of the adsorbent. Maximum % age removal of HMI was measured as 69.0, 64.0, 62.0 and 56% for Ni, Cd, Zn and Pb respectively using NAC. However, by using AC, a significant increase in the %age removal efficiency of HMI was observed and measured as 99.0, 95.5, 93.0 and 89% for Ni, Cd, Zn and Pb respectively. The results showed that AC derived from waste biomass is a simple, ecological and cost-effective approach to remove bulk of metal ions from water and wastewater.  


2014 ◽  
Vol 2014 ◽  
pp. 1-10 ◽  
Author(s):  
Ying Zhang ◽  
Jiaying Zhao ◽  
Zhao Jiang ◽  
Dexin Shan ◽  
Yan Lu

Rice husk ash (RHA), an agricultural waste, was used as biosorbent for the removal of Iron(II) and Manganese(II) ions from aqueous solutions. The structural and morphological characteristics of RHA and its elemental compositions before and after adsorption of Fe(II) and Mn(II) were determined by scanning electron microscopic (SEM) and X-ray fluorescence (XRF) analyses. Batch experiments were carried out to determine the influence of initial pH, contact time, adsorbent dosage, and initial concentration on the removal of Fe(II) and Mn(II) ions. Langmuir, Freundlich, and Dubinin-Radushkevich (D-R) models were applied to describe the biosorption isotherm of the metal ions by RHA. The correlation coefficient (R2) of Langmuir and Freundlich isotherm models equals 0.995 and 0.901 for Fe(II), 0.9862 and 0.8924 for Mn(II), respectively, so the Langmuir model fitted the equilibrium data better than the Freundlich isotherm model. The mean free energy values evaluated from the D-R model indicated that the biosorption of Fe(II) and Mn(II) onto RHA was physical in nature. Experimental data also showed that the biosorption processes of both metal ions complied with the pseudo-second-order kinetics.


2018 ◽  
Vol 156 ◽  
pp. 05020 ◽  
Author(s):  
Bastian Arifin ◽  
Sri Aprilia ◽  
Pocut Nurul Alam ◽  
Farid Mulana ◽  
Amri Amin ◽  
...  

The current development of the packaging industry is increasing as well as the dependence of non-renewable oil-based materials encouraging researchers to look for alternative polymeric strengthening materials from biomass. Especially used from agricultural waste because it is cheap and widely available in nature and it can be renewed. In this study, agriculture waste used were rice husk and rice husks ash that prepared as organic nanofillers for the development of polymer nanocomposites. XRF analysis showed that rice husk ash has the highest silica (SiO2) content of 89. 835%, while rice husk has SiO2 contents of 82.540%. From XRD analysis on 2 theta there is a crystalline silica region at 22° and this analysis shows the sample is amorphous. FTIR analysis showed Si-H at peak 2339 cm−1 in rice husk and 2129 cm−1 for rice husk ash.


2012 ◽  
Vol 15 (1) ◽  
pp. 57 ◽  
Author(s):  
K.K. Kudaybergenov ◽  
E.K. Ongarbayev ◽  
Z.A. Mansurov

Agricultural byproducts or residues are widely produced in Kazakhstan and their utilization as a sorbent material for petroleum spill can be developed as low cost, high tech environmental technology. Rice husk, an agricultural waste, was used as petroleum sorbent material. The present study examines the sorption capacity of thermally treated rice husk for different petroleum products. Results showed that the petroleum sorption capacity of this material prepared at 700 ºC was 15 g/g for heavy crude petroleum. The material obtained by thermal treatment of rice husk has very good buoyancy characteristics, high petroleum sorption capacity and high hydrophobicity. The effects of heating temperature, contact time and petroleum density on the petroleum sorption capacity of thermally treated rice husks were further studied on the basis of phase composition, microstructure and morphology using X-ray diffraction analysis, FTIR spectrometry, optical digital microscopy and scanning electron microscopy (SEM). The results of the SEM and optical microscopy studies strongly indicate that thermal treatment is a suitable method to improve structure of husk particles regarding porosity compared to virgin samples. The research provides the basis for development of a new environmental material with optimal characteristics, providing efficient sorption of petroleum and petroleum products from aqueous medium.


2012 ◽  
Vol 727-728 ◽  
pp. 1502-1507 ◽  
Author(s):  
Izabelle Marie Trindade Bezerra ◽  
Suélen Silva Figueiredo ◽  
João Batista Queiroz de Carvalho ◽  
Gelmires Araújo Neves ◽  
Jozilene de Souza ◽  
...  

The use of agricultural waste has become a necessity due to the high environmental cost derived from its improper disposal in nature. In this scenario, rice husks, as well as the ash produced by burning, became worrying in certain regions of the country due to the large volume produced annually [.


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