Mixed esters of xanthogenic acids containing carbonyl, dithiocarbamine and thiocyane group and their research as additives improving tribological characteristics

2021 ◽  
Vol 04 (1) ◽  
pp. 60-64
Author(s):  
B.I. Musayeva ◽  
◽  
V.M. Farzaliyev ◽  
G.G. Ismayilova ◽  
N.N. Novotorzhina ◽  
...  
Keyword(s):  
Ir Spectroscopy ◽  
Functional Groups ◽  
Raw Materials ◽  
Environmentally Friendly ◽  
Monochloroacetic Acid ◽  
Tribological Characteristics ◽  
Sequential Reaction ◽  
Diethyl Dithiocarbamate ◽  
Sodium Diethyl Dithiocarbamate

On the basis of environmentally friendly raw materials of glycerol, by its interaction with monochloroacetic acid, 1,2,3-(trichloroacetyl)triglyceride was synthesized, which is used for further syntheses of xanthogenic acid derivatives containing a number of functional groups  dithiocarbamic, thiocyanic. The reaction of 1,2,3-(trichloroacetyl) triglyceride with potassium alkylxanthate in a ratio of 1:1 and 1:2 gave 1-butylxanthogenatoacetoxy-2,3-(dichloroacetoxy) propane and 1,3-di(alkylxanthogenatoacetoxy)-2-chloroacetoxypropane. Mixed esters of xanthogenic acid containing dithiocarbamic and thiocyanic groups were synthesized by the interaction of 1,2,3-(trichloroacetyl) triglyceride in the corresponding sequence, first with sodium diethyl dithiocarbamate, with potassium butylxanthate, as a result 1-butylxanthogenatoacetoxy-2-chloracetoxy-3-(diethyldithiocarbamatoacetoxy) propane. Sequential reaction of 1,2,3-(trichloroacetyl) triglyceride with potassium rhodanide with potassium butylxanthate gave 1-butylxanthogenatoacetoxy-2-chloroacetoxy-3-(thiocyanatoacetoxy)propane. The structure of the synthesized compounds has been proven by IR spectroscopy. The compounds have been tested as additives to improve the tribological characteristics of oils and have been shown to be effective.

scholarly journals Cycloaddition of Thiourea- and Guanidine-Substituted Furans to Dienophiles: A Comparison of the Environmentally-Friendly Methods

2020 ◽  
Vol 3 (1) ◽  
pp. 57
Author(s):  
Luka Barešić ◽  
Davor Margetić ◽  
Zoran Glasovac
Keyword(s):  
High Pressure ◽  
Functional Groups ◽  
Organic Synthesis ◽  
High Speed ◽  
Environmentally Friendly ◽  
Microwave Assisted ◽  
Pressure Synthesis ◽  
Ultrasound Assisted ◽  
Substituted Furans ◽  
Guanidine Moiety

The cycloaddition strategy was employed in order to obtain a 7-oxanorbornene framework substituted with a guanidine moiety or its precursor functional groups: protected amine or thiourea. In order to optimize the conditions for the cycloaddition, several environmentally-friendly methods—microwave assisted organic synthesis, high pressure synthesis, high speed vibrational milling, and ultrasound assisted synthesis—were employed. The outcomes of the cycloaddition reactions were interpreted in terms of endo/exo selectivity, the conversion of the reactants to the product, and the isolated yields. In general, our results indicated the HP and HSVM approaches as the methods of choice to give good yields and conversions.

scholarly journals The impact of functional groups of the surface of carbon materials on the efficiency of purification of extraction phosphoric acid from fluorine compounds

2019 ◽  
Vol 2 ◽  
pp. 11-18
Author(s):  
Smirnov N.N. ◽  
Konoval A.V. ◽  
Smirnova D.N. ◽  
Kochetkov S.P.
Keyword(s):  
Phosphoric Acid ◽  
Functional Groups ◽  
Carbon Materials ◽  
Raw Materials ◽  
Carbon Adsorbents ◽  
Joint Stock Company ◽  
Stock Company ◽  
Fluorine Compounds ◽  
The Impact ◽  
Extraction Phosphoric Acid

The environmental problems of the production of extraction phosphoric acid and the effect of fluorine on the human body are discussed in the article. The creation of the industry of phosphoric fertilizers on the basis of processing of fluorine-containing phosphate raw materials and fluorine-containing compounds, the development of their application require the study of environmental consequences arising from this, because fluorine is characterized by high mobility in the biological cycle of metabolism. For the purification of phosphoric acid from fluorine was used carbon adsorbents such as active charcoal brand BAU, natural graphite deposits Kyshtymsky, P514 soot, charcoal. Experiments on the purification was carried out on non-evaporated half-hydrated extraction phosphoric acid which was produced by joint stock company «Apatit» in Cherepovets city in Russia. The following analyses were carried out: IR-Fourier spectrometry, research of acid–base properties of carbon materials by potentiometric titration, potentiometric method of fluorine determination in extraction phosphoric acid. It is mentioned that the carbon black P514 is the most efficient adsorbent for purification of extraction phosphoric acid. The total number of functional groups on its surface is 0.62 mmol/g, the degree of purification from fluorine compounds is 94.8%.

scholarly journals Potensi Minyak Kelapa Sawit Sebagai Bahan Baku Busa Pemadam Kebakaran Lahan Gambut di Indonesia: Suatu Tijauan Pustaka

2020 ◽  
Author(s):  
Purwo Subekti
Keyword(s):  
Palm Oil ◽  
Raw Materials ◽  
Value Added ◽  
Environmentally Friendly ◽  
Domestic Demand ◽  
Oil Products ◽  
Raw Material ◽  
Fire Extinguisher ◽  
Vegetable Raw Materials ◽  
Peat Fires

This researchs aims to to find out about the potential of palm oil as a raw material of foam firefighting peat fires in Indonesia.By using the method of literature approach to previous researchers, can be in the know that the vegetable raw materials with thepotential to be developed in Indonesia as a raw material of foam extinguishing peat fires is palm oil. In addition to theavailability of environmentally friendly palm oil is also guaranteed and sustained since 2015, Indonesia produced palm oil andits derivatives amounted to 32.5 million tons, to meet the domestic demand of 18.77% while exports amounted to 81.23%..Utilization of palm oil as a raw material foam fire extinguisher is one form of support to the Indonesian government in order toincrease the downstream and value-added palm oil products as well as reduce the level of risk of peat fires

An Environmentally Friendly Technology for Biomass Production Hydorchar from Renewable Resources

2013 ◽  
Vol 726-731 ◽  
pp. 634-637 ◽  
Author(s):  
Yan Qiu Lei ◽  
Hai Quan Su
Keyword(s):  
Activated Carbon ◽  
Reaction Time ◽  
Adsorption Capacity ◽  
Functional Groups ◽  
Biomass Production ◽  
Renewable Resources ◽  
Environmentally Friendly ◽  
Hydrothermal Carbonization ◽  
Removal Rates

A green and sustainable route for preparation of hydrochars from cornstalk by hydrothermal carbonization (200°C) was described. The morphology of the hydrochars changed with reaction time increased, the surface of the materials contained a large number of functional groups, showed higher adsorption capacity for Cr (VI) than activated carbon and the removal rates of Cr (VI) were 67% and 29% respectively (pH=1, 20°C).

Voltammetric Behavior of Arsenic(III) in the Presence of Sodium Diethyl Dithiocarbamate and Its Determination in Water and Highly Saline Samples by Adsorptive Stripping Voltammetry

2006 ◽  
Vol 18 (11) ◽  
pp. 1081-1089 ◽  
Author(s):  
Leandro M. de Carvalho ◽  
Paulo C. do Nascimento ◽  
Denise Bohrer ◽  
Eduardo J. Pilau ◽  
Raquel Stefanello ◽  
...  
Keyword(s):  
Stripping Voltammetry ◽  
Adsorptive Stripping Voltammetry ◽  
Diethyl Dithiocarbamate ◽  
Voltammetric Behavior ◽  
Sodium Diethyl Dithiocarbamate

CuI-Promoted [3+2] Cycloaddition/oxidation to construct Pyrrolo[2,1a]isoquinolino-quinones from naphthoquinone and tetrahydroisoquinoline

Synlett ◽  
2022 ◽  
Author(s):  
Zihua Yu ◽  
Xue Tang ◽  
Chenxi Huang ◽  
Yehan Shang ◽  
Yu-Jin Li ◽  
...  
Keyword(s):  
Raw Materials ◽  
Environmentally Friendly ◽  
One Pot

The copper-catalyzed three-component one-pot 1,3-dipole cycloaddition/oxidation has been developed to construct Pyrrolo[2,1-a]isoquinolinoquinone derivatives with environmentally friendly oxygen as the oxidant. The products Pyrrolo[2,1-a]isoquinolinoquinones were obtained from the naturally available raw materials tetrahydroisoquinoline, 1,4-naphthoquinone and benzaldehyde with medium yields.

Vegetable oils – raw materials for producing biodiesel

2021 ◽  
Vol 80 (2) ◽  
pp. 286-292
Author(s):  
T. Mamilov ◽  
◽  
G.S. Aitkaliyeva ◽  
A.B. Ismailova ◽  
M.A. Yelubay ◽  
...  
Keyword(s):  
Functional Groups ◽  
Vegetable Oils ◽  
Raw Materials ◽  
Chemical Properties ◽  
Biodiesel Fuel ◽  
Physical And Chemical Properties ◽  
Sunflower Oils ◽  
Transesterification Method ◽  
Physical And Chemical ◽  
And Chemical Properties

This paper presents the results of a study of the physical and chemical properties of samples of vegetable oils (sunflower, rapeseed, olive). It has been shown that the viscosity of oils varies from 41.4 to 61.7 cSt at a temperature of 40 ° C for olive and sunflower oils, respectively. The acid numbers of the oil samples were also determined, it was found that the lowest indicator is characteristic of sunflower oil. Pour points of oils also range from -3 to -16 ° C for olive and sunflower oils, respectively. Using the method of IR spectroscopy, functional groups in the composition of samples of vegetable oils were studied and it was shown that the composition of oils contains carbonyl and hydroxyl functional groups, indicating the presence of carboxylic acids. Based on studies of the physical and chemical properties of vegetable oils, it was found that sunflower, olive and rapeseed oils can serve as raw materials for the synthesis of biofuels based on them, since they contain free fatty acids. To obtain biodiesel fuel based on vegetable oils, it is planned to use the transesterification method in the presence of various catalysts (alkaline, acidic, and complex).

NEW APPROACH TO AGRICULTURAL PRODUCTION: PLANT PROBIOTICS

2021 ◽  
Vol 0 (15) ◽  
pp. 0-0
Author(s):  
Hatice ÖĞÜTCÜ
Keyword(s):  
Root Zone ◽  
Raw Materials ◽  
Agricultural Practices ◽  
Environmentally Friendly ◽  
Plant Production ◽  
World Population ◽  
Production Plant ◽  
Plant Tolerance ◽  
The World

With the increase in the world population every year, the need for plant and animal foods has increased. In order to meet these needs, the amount of fertilizers (with chemical content) used to increase productivity in agriculture has increased and has become a threat to the soil and the environment. In order to minimize the harms of chemical fertilizers and to preserve the fertility of the soil, new environmentally friendly applications have been researched. In this context, studies on "Plant Probiotics", which are one of the effective applications both in protecting the quality of the soil and increasing the yield in plant production, especially on local isolates and formulations to be prepared from them, have gained momentum. Plant probiotics are a group of microorganisms or microorganisms that can improve soil health, plant growth, and plant tolerance or immunity to various abiotic and biotic stresses, thanks to their potential role in enhanced nutrient acquisition and/or biocontrol activities by colonizing the root zone of plants, called the rhizosphere. As a result of inoculation of plants with strains of these bacteria, which have very different properties (nitrogen binding, phosphate solubilizing, biocontrol agent, stress resistance, phytohormone synthesis), it directly affects the growth and development of the roots and shoots of the plant, increasing the biomass, as well as contributing to the increase of the yield and quality of the product. In this context, the preparation and use of biofertilizer formulations of local plant probiotic bacteria, which will be obtained from their natural areas, has become very important in rational agricultural practices in recent years and intensive researches are carried out. With the use of the aforementioned plant probiotic formulations, environmentally friendly green production will be made by contributing to the production of both foodstuffs and feed raw materials in order to ensure the continuity of the world population. As a result, the protection of the ecosystem will be ensured by preventing environmental pollution, which is the problem of the whole world.

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