PEMANFAATAN ARANG AKTIF SABUT KELAPA SAWIT SEBAGAI ADSOBEN  ZAT WARNA SINTETIS REACTIVE RED-120 DAN DIRECT GREEN -26

The problem of environmental polution caused by waste of batik industry lately is increasing, so it needed a method to overcome that problem. The aim of this study was to determine the ability of activated charcoal from coconut fiber palm in adsorbing Reactive Red-120 and Direct Green-26 dyes in waste of batik along with determining the parameters of isotherms adsorption using UV-Vis Spectrophotometer analysis method. Variations of pH, contact time, adsorbent weight and temperature were carried out as variable to obtain optimum conditions of the adsorption process. The optimum of conditions for Reactive Red-120 occured at pH 3 and a contact time of 30 minutes, while Direct Green-26 occurred at pH 4 and a contact time of 40 minutes, with each adsorbent weight 150 mg and the temperature 30 °C. Adsorption isotherms determined by Freundlich and Langmuir models with maximum adsorption capacity (Qmax) were obtained for the Reactive Red-120 was 400 mg/g, while Direct Green-26 is 169 mg/g.

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Platinum (IV) Recovery from Waste Solutions by Adsorption onto Dibenzo-30-crown-10 Ether Immobilized on Amberlite XAD7 Resin–Factorial Design Analysis

Molecules ◽

10.3390/molecules25163692 ◽

2020 ◽

Vol 25 (16) ◽

pp. 3692

Author(s):

Oana Buriac ◽

Mihaela Ciopec ◽

Narcis Duţeanu ◽

Adina Negrea ◽

Petru Negrea ◽

...

Keyword(s):

Experimental Data ◽

Adsorption Capacity ◽

Thermodynamic Parameters ◽

Adsorption Isotherms ◽

Contact Time ◽

Adsorption Process ◽

Electrical Contacts ◽

Bet Surface Area ◽

Maximum Adsorption Capacity ◽

Order Kinetic

Platinum is a precious metal with many applications, such as: catalytic converters, laboratory equipment, electrical contacts and electrodes, digital thermometers, dentistry, and jewellery. Due to its broad usage, it is essential to recover it from waste solutions resulted out of different technological processes in which it is used. Over the years, several recovery techniques were developed, adsorption being one of the simplest, effective and economical method used for platinum recovery. In the present paper a new adsorbent material (XAD7-DB30C10) for Pt (IV) recovery was used. Produced adsorbent material was characterized by X-ray dispersion (EDX), scanning electron microscopy (SEM) analysis, Fourier Transform Infrared Spectroscopy and Brunauer-Emmett-Teller (BET) surface area analysis. Adsorption isotherms, kinetic models, thermodynamic parameters and adsorption mechanism are presented in this paper. Experimental data were fitted using three non-linear adsorption isotherms: Langmuir, Freundlich and Sips, being better fitted by Sips adsorption isotherm. Obtained kinetic data were correlated well with the pseudo-second-order kinetic model, indicating that the chemical sorption was the rate-limiting step. Thermodynamic parameters (ΔG°, ΔH°, ΔS°) showed that the adsorption process was endothermic and spontaneous. After adsorption, metallic platinum was recovered from the exhausted adsorbent material by thermal treatment. Adsorption process optimisation by design of experiments was also performed, using as input obtained experimental data, and taking into account that initial platinum concentration and contact time have a significant effect on the adsorption capacity. From the optimisation process, it has been found that the maximum adsorption capacity is obtained at the maximum variation domains of the factors. By optimizing the process, a maximum adsorption capacity of 15.03 mg g−1 was achieved at a contact time of 190 min, initial concentration of 141.06 mg L−1 and the temperature of 45 °C.

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Full Factorial Design for Gold Recovery from Industrial Solutions

Toxics ◽

10.3390/toxics9050111 ◽

2021 ◽

Vol 9 (5) ◽

pp. 111

Author(s):

Maria Mihăilescu ◽

Adina Negrea ◽

Mihaela Ciopec ◽

Petru Negrea ◽

Narcis Duțeanu ◽

...

Keyword(s):

Factorial Design ◽

Adsorption Capacity ◽

Contact Time ◽

Adsorption Process ◽

Design Method ◽

Precious Metals ◽

Gold Recovery ◽

Maximum Adsorption Capacity ◽

Gold Concentration ◽

Commercial Resin

Gold is one of the precious metals with multiple uses, whose deposits are much smaller than the global production needs. Therefore, extracting maximum gold quantities from industrial diluted solutions is a must. Am-L-GA is a new material, obtained by an Amberlite XAD7-type commercial resin, functionalized through saturation with L-glutamic acid, whose adsorption capacity has been proved to be higher than those of other materials utilized for gold adsorption. In this context, this article presents the results of a factorial design experiment for optimizing the gold recovery from residual solutions resulting from the electronics industry using Am-L-GA. Firstly, the material was characterized using atomic force microscopy (AFM), to emphasize the material’s characteristics, essential for the adsorption quality. Then, the study showed that among the parameters taken into account in the analysis (pH, temperature, initial gold concentration, and contact time), the initial gold concentration in the solution plays a determinant role in the removal process and the contact time has a slightly positive effect, whereas the pH and temperature do not influence the adsorption capacity. The maximum adsorption capacity of 29.27 mg/L was obtained by optimizing the adsorption process, with the control factors having the following values: contact time ~106 min, initial Au(III) concentration of ~164 mg/L, pH = 4, and temperature of 25 °C. It is highlighted that the factorial design method is an excellent instrument to determine the effects of different factors influencing the adsorption process. The method can be applied for any adsorption process if it is necessary to reduce the number of experiments, to diminish the resources or time consumption, or for expanding the investigation domain above the experimental limits.

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Modified/Unmodified Nanoparticle Adsorbents of Cellulose Origin With High Adsorptive Potential for Removal of Pb(II) From Aqueous Solution

European Scientific Journal ESJ ◽

10.19044/esj.2017.v13n27p425 ◽

2017 ◽

Vol 13 (27) ◽

pp. 425

Author(s):

Azeh Yakubu ◽

Gabriel Ademola Olatunji ◽

Folahan Amoo Adekola

Keyword(s):

Aqueous Solution ◽

Adsorption Capacity ◽

Contact Time ◽

Adsorption Process ◽

Correlation Coefficients ◽

Solution Temperature ◽

Isotherm Models ◽

Maximum Adsorption Capacity ◽

Kinetics Of Adsorption ◽

Kinetics Of

This investigation was conducted to evaluate the adsorption capacity of nanoparticles of cellulose origin. Nanoparticles were synthesized by acid hydrolysis of microcrystalline cellulose/cellulose acetate using 64% H3PO4 and characterized using FTIR, XRD, TGA-DTGA, BET and SEM analysis. Adsorption kinetics of Pb (II) ions in aqueous solution was investigated and the effect of initial concentration, pH, time, adsorbent dosage and solution temperature. The results showed that adsorption increased with increasing concentration with removal efficiencies of 60% and 92.99% for Azeh2 and Azeh10 respectively for initial lead concentration of 3 mg/g. The effects of contact time showed that adsorption maximum was attained within 24h of contact time. The maximum adsorption capacity and removal efficiency were achieved at pH6. Small dose of adsorbent had better performance. The kinetics of adsorption was best described by the pseudo-second-Order model while the adsorption mechanism was chemisorption and pore diffusion based on intra-particle diffusion model. The isotherm model was Freundlich. Though, all tested isotherm models relatively showed good correlation coefficients ranging from 0.969-1.000. The adsorption process was exothermic for Azeh-TDI, with a negative value of -12.812 X 103 KJ/mol. This indicates that the adsorption process for Pb by Azeh-TDI was spontaneous. Adsorption by Azeh2 was endothermic in nature.

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Study of Kinetics and Adsorption Isotherm of Methylene Blue Dye using Tannin Gel from Ceriops tagal

Jurnal Kimia Sains dan Aplikasi ◽

10.14710/jksa.23.10.370-376 ◽

2020 ◽

Vol 23 (10) ◽

pp. 370-376

Author(s):

Thamrin Azis ◽

La Ode Ahmad ◽

Keke Awaliyah ◽

Laode Abdul Kadir

Keyword(s):

Methylene Blue ◽

Adsorption Capacity ◽

Adsorption Kinetics ◽

Contact Time ◽

Adsorption Process ◽

Blue Dye ◽

Maximum Adsorption Capacity ◽

Methylene Blue Dye ◽

Ceriops Tagal ◽

Kinetics Of

Research on the equilibrium and adsorption kinetics of methylene blue dye using tannin gel from the Tingi tree (Ceriops tagal) has been carried out. This study aims to determine the capacity and adsorption kinetics of tannin gel against methylene blue dye. Several parameters, such as the effect of contact time, pH, and methylene blue dye concentration on adsorption, were also studied. Based on the research results, the optimum adsorption process is a contact time of 30 minutes and a pH of 7. The adsorption capacity increased to a concentration of 80 mg/L with a maximum adsorption capacity (qm) of 49.261 mg/g. The adsorption process follows the pseudo-second-order adsorption kinetics model and the Langmuir isotherm model.

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Adsorption of Basic and Acidic Dyes onto Agricultural Wastes

International Letters of Chemistry Physics and Astronomy ◽

10.18052/www.scipress.com/ilcpa.70.12 ◽

2016 ◽

Vol 70 ◽

pp. 12-26 ◽

Cited By ~ 1

Author(s):

Nnaemeka John Okorocha ◽

J. Josphine Okoji ◽

Charles Osuji

Keyword(s):

Adsorption Capacity ◽

Contact Time ◽

Adsorption Process ◽

Aqueous Media ◽

Batch Adsorption ◽

Maximum Adsorption Capacity ◽

Thermodynamic Quantities ◽

Order Kinetic ◽

Dyes Adsorption ◽

Adsorbent Dose

The potential of almond leaves powder, (ALP) for the removal of Crystal violet (CV) and Congo red (CR) dyes from aqueous solution was investigated. The adsorbent (ALP) was characterized by FTIR and SEM analysis. Batch adsorption studies were conducted and various parameters such as contact time, adsorbent dosage, initial dye concentration, pH and temperature were studied to observe their effects in the dyes adsorption process. The optimum conditions for the adsorption of CV and CR dyes onto the adsorbent (ALP) was found to be: contact time (100mins), pH (10.0), temperature (343K) for an initial CV dye concentration of 50mg/L using adsorbent dose of 1.0g and contact time (100mins), pH (2.0), temperature (333K) for an initial CR dye concentration of 50mg/L using adsorbent dose 1.0g respectively. The experimental equilibrium adsorption data fitted best and well to the Freundlich isotherm model for both CV and CR dyes adsorption. The maximum adsorption capacity of ALP was found to be 22.96mg/g and 7.77mg/g for the adsorption of CV and CR dyes respectively. The kinetic data conformed to the pseudo-second-order kinetic model. Thermodynamic quantities such as Gibbs free energy (ΔG0), enthalpy (ΔH0) and entropy (ΔS0) were evaluated and the negative values of ΔG0obtained for both dyes indicate the spontaneous nature of the adsorption process while the positive values of ΔH0and ΔS0obtained indicated the endothermic nature and increased randomness during the adsorption process respectively for the adsorption of CV and CR onto ALP. Based on the results obtained such as good adsorption capacity, rapid kinetics, and its low cost, ALP appears to be a promising adsorbent material for the removal of CV and CR dye stuff from aqueous media.

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Use of Bioballs as an Adsorbent for the Removal of Copper

Journal of the chemical society of pakistan ◽

10.52568/000565 ◽

2021 ◽

Vol 43 (2) ◽

pp. 114-114

Author(s):

Hakan elebi Hakan elebi

Keyword(s):

Heavy Metals ◽

Adsorption Capacity ◽

Adsorption Process ◽

Batch Process ◽

Practical Method ◽

High Density ◽

Maximum Adsorption Capacity ◽

Optimum Conditions ◽

Fixed Amount ◽

High Level

Nowadays, heavy metals, which are among the various hazardous pollutants, are present at a high level of density in the receiving environments. Among heavy metals, especially copper is mainly present in wastewater due to the industrial activities. Adsorption is the most practical method to prevent this pollution, and in recent years, researchers have been involved in researching both adsorption and cost-efficient, accessible, easy-to-apply environmentally friendly adsorbents. In this study, the adsorption capacity of high density bioballs having a potential adsorbent characteristic was investigated. Accordingly, different pH values (2.0 – 6.0) and the contact times (1 -150 minutes) of a solution on the adsorption process was evaluated under a constant agitating speed (150 rpm), a constant temperature (25and#176;C) and a fixed amount of adsorbent (2.0 g). Experimental data on the pH and contact times obtained were evaluated using different isotherm and kinetic models in a batch process. The optimum conditions for the adsorption process were determined as follows: adsorbent dose = 2 g/L, pH = 6.23 and contact time = 45 minute. The maximum copper refining efficiency of a high density bioball was calculated to be approximately 78% under the optimum conditions determined. The maximum adsorption capacity based on the Langmuir isotherm is 5.60 mg/g, and the adsorption of the copper element onto the high-density bioball is defined by a pseudo-second-order kinetics. The process was found to be applicable, spontaneous, and endothermic according to thermodynamic parameters. As a result, it has been noted that high density bioballs used as a biofilm material may be an alternative adsorbent for copper and the other heavy metals.

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Langmuir and Freundlich isotherm equation test on the adsorption process of Cu (II) metal ions by cassava peel waste (Manihot esculenta crantz)

Journal of Physics Conference Series ◽

10.1088/1742-6596/2126/1/012022 ◽

2021 ◽

Vol 2126 (1) ◽

pp. 012022

Author(s):

S Nuryanti ◽

Suherman ◽

S Rahmawati ◽

M Amalia ◽

T Santoso ◽

...

Keyword(s):

Activated Carbon ◽

Adsorption Capacity ◽

Manihot Esculenta ◽

Contact Time ◽

Adsorption Process ◽

Freundlich Isotherm ◽

Maximum Adsorption Capacity ◽

Manihot Esculenta Crantz ◽

Isotherm Equations ◽

Cassava Peel

Abstract This Study aims to determine the adsorption process of Cu (II) metal by cassava peel waste (Manihot esculenta crantz) meeting the Langmuir equation and Freundlich. Research method cassava peel made into activated carbon, then determine the mass, pH and optimum contact time. Then the determination of the maximum adsorption capacity was carried out by testing with the Langmuir isotherm and Freundlich isotherm equations. The results showed that the best conditions (optimal conditions) were obtained with the addition of 0.5 grams of active carbs from cassava peels. The percentage of Cu ion adsorption in these conditions was 97.72%, at pH 6 and a contact time of 60 minutes and the absorption capacity was 98.49%. The maximum adsorption capacity of cassava peel activated carbon to Cu(II) ions at the optimum condition was determined based on the Langmuir and Freundlich isotherm equations. The results obtained were-51.813 mg/g and 26,792 mg/g, respectively.

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MODEL ISOTERM FREUNDLICH DAN LANGMUIR OLEH ADSORBEN ARANG AKTIF BAMBU ANDONG (G. verticillata (Wild) Munro) DAN BAMBU ATER (G. atter (Hassk) Kurz ex Munro)

Jurnal Sains Natural ◽

10.31938/jsn.v2i1.31 ◽

2017 ◽

Vol 2 (1) ◽

pp. 17 ◽

Cited By ~ 1

Author(s):

Murtihapsari Murtihapsari ◽

Bertha Mangallo ◽

Dini Dwi Handyani

Keyword(s):

Adsorption Capacity ◽

Activated Charcoal ◽

Langmuir Isotherm ◽

Physical Adsorption ◽

Regression Coefficients ◽

Maximum Adsorption Capacity ◽

Optimum Conditions ◽

Isotherm Equation ◽

Freundlich Isotherms ◽

Langmuir Isotherm Equation

Freundlich and Langmuir Isotherms Model by Active Chorcoal Adsorbent Bamboo Andong (G. verticillata (Wild) Munro) and Bamboo Ater (G. atter (Hassk) Kurz ex Munro) Diazinon insecticide adsorption by two types of adsorbent, namely activated charcoal bamboo andong (G. verticillata (Wild) Munro) and bamboo ater (G. atter (Hassk) Kurzex Munro) at optimum conditions determined the maximum adsorption capacity of both types of adsorbent. Data analysison the effect of concentration on the adsorption capacity was used Langmuir and Freundlich isotherms equation. It was obtained. That the curve of adsorption isotherms of the Langmuir isotherm better modeled with linear regression coefficients were relatively more approach 1 is R2 = 0,996 for both types of adsorbents. Langmuir isotherm equation obtained from adsorpsi maximum capacity of activated charcoal bamboo andong (G. verticillata (Wild) Munro) of 4.630 mg/g (1,433.10-5 mol/g) with K = 0,332 (Kmol/L)-1 and Eads at -2,750 kJ/mol, while the activated charcoal bamboo ater (G. atter (Hassk) Kurzex Munro) produce the maximum adsorption capacity of 1,786 mg/g (5,868.10-6 mol/g) with K = 0,202 (Kmol/L)-1 and Eads = -3,898 kJ/mol, so the adsorption of both types of adsorbents indicated experiencing a physical adsorption (physisorption / fisisorpsi).Keyword: G. verticillata (Wild) Munro, G. atter (Hassk) Kurz ex Munro, Adsorption, Diazinon, actived charcoal ABSTRAK Adsorpsi insektisida diazinon oleh dua jenis adsorben, yaitu arang aktif bambu andong (G. verticillata (Wild) Munro) dan bambu ater (G. atter (Hassk) Kurz ex Munro) pada kondisi optimum bertujuan untuk menentukan kapasitas adsorpsi maksimum dari kedua jenis adsorben. Analisis data pengaruh konsentrasi terhadap kapasitas adsorpsi digunakan persamaan isoterm Langmuir dan Freundlich. Berdasarkan data yang diperoleh, kurva isoterm adsorpsi lebih mengikuti model isoterm Langmuir dengan koefisien regresi linier yang relatif lebih mendekati 1 yaitu R2 = 0,996 untuk kedua jenis adsorben. Dari persamaan isoterm Langmuir diperoleh kapasitas adsorpsi maksimum arang aktif bambu andong (G. verticillata (Wild) Munro) sebesar 4,630 mg/g (1,433.10-5 mol/g) dengan K = 0,332 (Kmol/L)-1 dan Eads sebesar -2,750 kJ/mol, sedangkan arang aktif bambu ater (G. atter (Hassk) Kurz ex Munro) menghasilkan kapasitas adsorpsi maksimum sebesar 1,786 mg/g (5,868.10-6 mol/g) dengan K = 0,202 (Kmol/L)-1 dan Eads = -3,898 kJ/mol, sehingga adsorpsi kedua jenis adsorben diindikasikan mengalami adsorpsi secara fisik (physisorption/ fisisorpsi).Kata kunci : G. verticillata (Wild) Munro, G. atter (Hassk) Kurz ex Munro Adsorpsi, Diazinon, Arang aktif

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Adsorben Magnetit Terlapis Dimerkaptosilika untuk Adsorpsi Anion Logam [AuCl4]- dan [Cr2O7]-

Jurnal Riset Kimia ◽

10.25077/jrk.v11i2.353 ◽

2020 ◽

Vol 11 (2) ◽

pp. 113-120

Author(s):

Ngatijo Ngatijo ◽

Diah Riski Gusti ◽

Abdurrazaq Habib Fadhilah ◽

Resilta Khairunnisah

Keyword(s):

Adsorption Capacity ◽

Contact Time ◽

Adsorption Process ◽

Adsorption Efficiency ◽

Optimum Conditions ◽

Metal Anion ◽

Metal Anions

Adsorbent magnetite-dimercapto-silica (Fe3O4 - DMS) is a synthesis of magnetite with 2,3-dimercapto-1-propanol which has been applied to adsorb anions [AuCl4] - and [Cr2O7]-2. The adsorption process of metal anion [AuCl4]- at pH 5 with a contact time of 100 minutes was found optimum results at an adsorption capacity of 77.58 mg/g and an adsorption efficiency value of 96.975%. While the optimum conditions of metal anion [Cr2O7]-2 after the adsorption process at pH 4 with a contact time of 90 minutes was found an adsorption capacity of 85.0426 mg/g and an adsorption efficiency value of 85.0426%. The adsorption efficiency of metal anions [AuCl4]- is higher than the adsorption efficiency of metal anions [Cr2O7] -2

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Pengaruh Konsentrasi Aktivator Asam Fosfat (H3PO4) pada Pembuatan Karbon Aktif dari Sabut Kelapa terhadap Adsorpsi Logam Kromium

EKUILIBRIUM Journal of Chemical Engineering ◽

10.20961/equilibrium.v5i1.53572 ◽

2021 ◽

Vol 5 (1) ◽

pp. 45

Author(s):

Hamida Ishmatu Sholikhah ◽

Hartika Rahma Putri ◽

Inayati Inayati

Keyword(s):

Optimum Condition ◽

Phosphoric Acid ◽

Adsorption Capacity ◽

Contact Time ◽

Potassium Chromate ◽

Maximum Adsorption Capacity ◽

Activator Concentration ◽

Coconut Fiber ◽

Chromium Adsorption ◽

As Adsorption

Chromium is one of the hazardous heavy metal contained in the industrial wastewater. It can be reduced by various methods, such as adsorption. The purpose of this study was initialized an activated carbon from coconut fiber by various phosphoric acid (H3PO4) activator concentration (0,1M; 0,5M; 1M; 1,5M; 2M) and variation of contact time (30; 60; 90; 120; 150; 180 minutes) to obtain optimum adsorption capacity of chromium. Analysis of the activated coconut fiber carbon by SAA obtained a surface area of 53,39 m2/g. The potassium chromate (K2CrO4) solution was adsorbed by the adsorbent and then analyzed by a UV-VIS Spectrophotometer to measure the chromium content. This study proved that chromium adsorption by activated coconut fiber carbon was increased by the time until reaching optimum condition. Enhancement of adsorption capacity was directly proportional as the more concentrated phosphoric acid activator. Maximum adsorption capacity obtained was 3,464 mg/g and the optimum condition was at contact time of 150 minutes with the phosphoric acid activator concentration of 2M.

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