scholarly journals Heavy Metal Adsorption and Release on Polystyrene Particles at Various Salinities

2021 ◽  
Vol 8 ◽  
Author(s):  
Beta Susanto Barus ◽  
Kai Chen ◽  
Minggang Cai ◽  
Rongmao Li ◽  
Huorong Chen ◽  
...  
Keyword(s):  
Heavy Metals ◽  
Heavy Metal ◽  
Adsorption Capacity ◽  
Release Rate ◽  
Heavy Metal Concentration ◽  
Aquatic Environments ◽  
Particle Sizes ◽  
Heavy Metal Adsorption ◽  
Heavy Metal Concentrations ◽  
Adsorption Capacities

Microplastics (MPs) and heavy metals are two major types of pollutants that interact with each other, but they are poorly understood. Polystyrene (PS) is one type of MPs that is often detected in aquatic environments. In this study, we examined the adsorption capacity and release rate of heavy metals with respect to different particle sizes of PS, heavy metals, initial heavy metal concentrations, and salinities. Virgin (new) PS with diameters of 20, 50, 130, and 250 μm was used in this study, and four heavy metals (lead, cadmium, copper, and zinc) were used. The results showed that larger PS particle sizes adsorbed more heavy metals even though it took longer to achieve equilibrium adsorption. An increase in heavy metal concentration caused the adsorption capacity (μg g–1) of PS particles to also increase, but the adsorption rate (%) decreased. Increased salinity of the heavy metal solution resulted in a slower adsorption time and a lower adsorption capacity and release rate from the surface of PS particles. Different heavy metals also had different adsorption capacities. Pb was consistently more highly adsorbed by MPs, followed by Cu, Zn, and Cd. Larger PS sizes released heavy metals faster than smaller PS sizes, and the amounts of heavy metals released were higher. The heavy metal with the highest release rate was Cd, followed by Pb, Cu, and Zn. Finally, our findings highlight the interactions between PS and heavy metals and strongly support that PS particles can act as vectors for heavy metals in aquatic systems.

Heavy metals accumulation in freshwater mussels (Lamellidens marginalis) as a biological monitor inhabiting in Dhanmondi Lake, Dhaka, Bangladesh.

2016 ◽  
Vol 5 (10) ◽  
pp. 4933
Author(s):  
Sabia Sultana ◽  
A. K. M. Nur Alam Siddiki ◽  
Md. Rokonujjaman ◽  
M. Niamul Naser ◽  
Abdus Salam ◽  
...  
Keyword(s):  
Heavy Metals ◽  
Heavy Metal ◽  
Soft Tissues ◽  
Freshwater Mussels ◽  
Heavy Metal Concentration ◽  
Heavy Metal Concentrations ◽  
Heavy Metals Accumulation ◽  
Manganese Zinc ◽  
Metals Accumulation ◽  
Test Level

The heavy metal concentration (e.g., Mn, Zn, Pb and Ni) were determined in soft tissues and shells of freshwater mussels (Lamellidens marginalis) at the various sites of Dhanmondi lake, Dhaka, Bangladesh between the period April, 2010 and March 2011. The heavy metal concentrations in shells and soft tissues of freshwater mussels were tended to vary significantly among sampling points and seasons in Dhanmondi Lake. Distribution of heavy metals in shell and soft tissue of Lamellidens marginalis followed the order Mn>Zn>Pb>Ni, respectively. According to the t-test, level of manganese, zinc and lead under investigation between shell and tissue showed statistically significant differences [Mn: t=-11.387; df=16; P=0.000; Zn: t=-2.590; df=16; P=0.020 and Pb: t=-2.8679; df=16; P=0.011].

scholarly journals Combined Influence of Low-Grade Metakaolins and Natural Zeolite on Compressive Strength and Heavy Metal Adsorption of Geopolymers

Minerals ◽  
2021 ◽  
Vol 11 (5) ◽  
pp. 486
Author(s):  
Alcina Johnson Sudagar ◽  
Slávka Andrejkovičová ◽  
Fernando Rocha ◽  
Carla Patinha ◽  
Maria R. Soares ◽  
...  
Keyword(s):  
Heavy Metals ◽  
Heavy Metal ◽  
Compressive Strength ◽  
Natural Zeolite ◽  
Metal Adsorption ◽  
Low Grade ◽  
Heavy Metal Adsorption ◽  
Adsorption Model ◽  
X Ray ◽  
Adsorption Capacities

Metakaolins (MKs) prepared from low-grade kaolins located in the Alvarães (A) and Barqueiros (B) regions of Portugal were used as the aluminosilicate source to compare their effect on the compressive strength and heavy metal adsorption of geopolymers. Natural zeolite, an inexpensive, efficient adsorbent, was used as an additive in formulations to enhance geopolymers’ adsorption capacities and reduce MK utilization’s environmental footprint. Geopolymers were synthesized with the replacement of MK by zeolite up to 75 wt.% (A25, B25—25% MK 75% zeolite; A50, B50—50% MK 50% zeolite; A75, B75—75% MK 25% zeolite; A100, B100—100% MK). The molar ratios of SiO2/Al2O3 and Na2O/Al2O3 were kept at 1 to reduce the sodium silicate and sodium hydroxide environmental impact. Geopolymers’ crystallography was identified using X-ray diffraction analysis. The surface morphology was observed by scanning electron microscopy to understand the effect of zeolite incorporation. Chemical analysis using X-ray fluorescence spectroscopy and energy dispersive X-ray spectroscopy yielded information about the geopolymers’ Si/Al ratio. Compressive strength values of geopolymers obtained after 1, 14, and 28 days of curing indicate high strengths of geopolymers with 100% MK (A100—15.4 MPa; B100—32.46 MPa). Therefore, zeolite did not aid in the improvement of the compressive strength of both MK-based geopolymers. The heavy metal (Cd2+, Cr3+, Cu2+, Pb2+, and Zn2+) adsorption tests exhibit relatively higher adsorption capacities of Barqueiros MK-based geopolymers for all the heavy metals except Cd2+. Moreover, zeolite positively influenced divalent cations’ adsorption on the geopolymers produced from Barqueiros MK as B75 exhibits the highest adsorption capacities, but such an influence is not observed for Alvarães MK-based geopolymers. The general trend of adsorption of the heavy metals of both MK-based geopolymers is Pb2+ > Cd2+ > Cu2+ > Zn2+ > Cr3+ when fitted by the Langmuir isotherm adsorption model. The MK and zeolite characteristics influence geopolymers’ structure, strength, and adsorption capacities.

scholarly journals The Effect of Heavy Metal Pollutants on Bioluminescence Intensity of Luminous Mushrooms (Nenothopanus sp)

2020 ◽  
Vol 21 (2) ◽  
pp. 98-109
Author(s):  
Witriani Marvinatur Ihsan ◽  
Ratnawulan Ratnawulan
Keyword(s):  
Heavy Metals ◽  
Heavy Metal ◽  
Heavy Metal Concentration ◽  
Maximum Intensity ◽  
Coastal Forest ◽  
Metal Pollutants ◽  
Heavy Metal Concentrations ◽  
Measurement Results ◽  
West Sumatra ◽  
Heavy Metal Pollutants

In the South Coastal Forest area, West Sumatra, a luminous mushroom with the species Neonothopanus Sp. This research was conducted with the aim of seeing the effect of heavy metals on the bioluminescence reaction of luminous mushrooms. Starting from the effect of heavy metal concentrations on the intensity and inhibition coefficient of luminous mushroom biolumination. From the measurement results, the maximum intensity value of luminous mushrooms is 499.6 au occurring at a wavelength of 505 nm. At a wavelength of 505 nm, visible light is produced in green. The results obtained are in accordance with observations, because the light emitted by the glowing mushroom is green. If the concentration of heavy metals is greater, the intensity of the bioluminescent fungus (Neonothopanus sp) will decrease. The type of heavy metal affects the intensity of the fungus biolumination. The greatest decrease in intensity occurred in copper (Cu) and iron (Fe), zinc (Zn) and lead (Pb). If the heavy metal concentration is greater, the inhibition coefficient will be smaller. The greatest inhibition coefficient due to the presence of heavy metals occurs in copper (Cu) then iron (Fe), zinc (Zn) and the smallest is lead (Pb).

scholarly journals Elemental Profile of Heavy Metals in Garden cress, Coriander, Lettuce and Spinach, Commonly Cultivated in Kahrizak, South of Tehran- Iran

2018 ◽  
Vol 3 (1) ◽  
pp. 32-37 ◽  
Author(s):  
Mohammad Kazem Souri ◽  
Neda Alipanahi ◽  
Mansoure Hatamian ◽  
Mohammad Ahmadi ◽  
Tsehaye Tesfamariam
Keyword(s):  
Heavy Metals ◽  
Heavy Metal ◽  
Leaf Tissue ◽  
Heavy Metal Concentration ◽  
Heavy Metal Accumulation ◽  
Vegetable Crops ◽  
Garden Cress ◽  
Metal Concentrations ◽  
Heavy Metal Concentrations

Abstract Heavy metal accumulation in vegetable tissues often poses a great risk for human health. In the present study, accumulation of heavy metal in green leafy vegetable crops of coriander, garden cress, lettuce and spinach were evaluated under waste water irrigation in fields located in Kahrizak, on the southern edge of the metropolitan city of Tehran, Iran. Atomic absorption spectrophotometery was used for determination of heavy metal concentrations in leaf tissue. The results showed that heavy metal concentrations in soil and irrigation water were significantly high than allowable levels. Analysis of plant leaf tissue showed that spinach and garden cress accumulated higher concentrations of heavy metals compared to coriander and lettuce plants. Central leaves of lettuce showed the lowest heavy metal concentration compared to outer leaves or leaves of other vegetable crops, and can be the safer product for fresh consumption. The results indicate that the vegetables produced in the region are not suitable for fresh consumption and the agricultural activities should change towards ornamental or industrial crops production.

scholarly journals Heavy Metal Concentration in Eight Fish Species from Epe Lagoon (Nigeria)

2019 ◽  
Vol 21 (1) ◽  
pp. 69-82
Author(s):  
Iyabode Olusola Taiwo ◽  
Olaniyi Alaba Olopade ◽  
Nathanael Akinsafe Bamidele
Keyword(s):  
Heavy Metals ◽  
Heavy Metal ◽  
Atomic Absorption ◽  
Metal Concentration ◽  
Fish Species ◽  
Heavy Metal Concentration ◽  
Atomic Absorption Spectrophotometry ◽  
Human Consumption ◽  
Heavy Metal Concentrations ◽  
Absorption Spectrophotometry

Abstract This research was undertaken to find out the levels of five heavy metals (Cu, Fe, Mn, Pb, and Zn) in the muscles of eight fish species from Epe Lagoon. The levels of heavy metals were determined by atomic absorption spectrophotometry after digestion of the samples using Kjldahl heating digester. The heavy metal concentrations among the fish species were statistically dissimilar (P < 0.5). The heavy metals of Pb, Fe, and Mn were above the FAO/WHO agreeable limits for human consumption.

Study on the adsorption of bacteria in ceramsite and their synergetic effect on adsorption of heavy metals

2013 ◽  
Vol 69 (2) ◽  
pp. 407-413 ◽  
Author(s):  
Shan Qiu ◽  
Fang Ma ◽  
Xu Huang ◽  
Shanwen Xu
Keyword(s):  
Electron Microscopy ◽  
Heavy Metals ◽  
Heavy Metal ◽  
Scanning Electron Microscopy ◽  
Adsorption Capacity ◽  
Synergetic Effect ◽  
Covalent Bond ◽  
Metal Adsorption ◽  
Heavy Metal Adsorption ◽  
Scanning Electron

In this paper, heavy metal adsorption by ceramsite with or without Bacillus subtilis (B. subtilis) immobilization was studied, and the synergetic effect of ceramsite and bacteria was discussed in detail. To investigate the roles of the micro-pore structure of ceramsite and bacteria in removing heavy metals, the amount of bacteria immobilized on the ceramsite was determined and the effect of pH was evaluated. It was found that the immobilization of B. subtilis on the ceramsite was attributed to the electrostatic attraction and covalent bond. The scanning electron microscopy results revealed that, with the presence of ceramsite, there was the conglutination of B. subtilis cells due to the cell outer membrane dissolving. In addition, the B. subtilis immobilized ceramsite showed a different adsorption capacity for different heavy metals, with the adsorption capacity ranking of La3+ &gt; Cu2+ &gt; Mg2+ &gt; Na+.

Coupled removal of organic compounds and heavy metals by titanate/carbon nanotube composites

2008 ◽  
Vol 58 (10) ◽  
pp. 1985-1992 ◽  
Author(s):  
Ruey-An Doong ◽  
Li-Fen Chiang
Keyword(s):  
Heavy Metals ◽  
Heavy Metal ◽  
Organic Compounds ◽  
Heavy Metal Adsorption ◽  
Hydrothermal Conditions ◽  
Surface Areas ◽  
Aspect Ratios ◽  
Adsorption Capacities ◽  
Nanotube Composites ◽  
Carbon Nanotube Composites

The objective of this study was to fabricate 1-dimensional (1-D) nanocomposite materials with high aspect ratios and specific surface areas for the coupled degradation of refractory organic compounds and heavy metals. The 1-D nanomaterials were composed of various ratios of carbon nanotubes (CNT) and titanate nanotubes (TNT) (CNT/TNT). Alkaline hydrothermal method was used to fabricate TNT under various hydrothermal conditions. The morphology changed from nanoparticles/nanosheets, nanotubes, nanowires and then to nanoribbon as the hydrothermal temperatures increased from 60 to 230°C. In addition, the CNT/TNT nanomaterials have a good capability toward heavy metal adsorption. The Langmuirian maximum adsorption capacities of nanomaterials were in the range 83–124 mg/g for Cu2 +  and 192–588 mg/g for Pb2 + , which is superior to that of CNT. The removal efficiency of Cu2 +  by CNT/TNT decreased when 40 mg/L MX5B was due to the complexation of MX5B with Cu2 + . Results obtained in this study clearly show the 1-D CNT/TNT nanomaterials are a promising nano-adsorbent for coupled removal of organic as well as heavy metal ions in solution.

scholarly journals Hubungan Logam Berat Pb terhadap Fraksi Sedimen dan Bahan Organik di Muara Sungai Tiram, Marunda, Jakarta Utara

2019 ◽  
Vol 8 (2) ◽  
pp. 61
Author(s):  
Indah Syahiddah Fitroh ◽  
Petrus Subardjo ◽  
Lilik Maslukah
Keyword(s):  
Heavy Metals ◽  
Heavy Metal ◽  
Grain Size ◽  
Organic Matter ◽  
Atomic Absorption ◽  
Size Fraction ◽  
Heavy Metal Concentration ◽  
Atomic Absorption Spectrophotometer ◽  
Metal Concentrations ◽  
Heavy Metal Concentrations

Kegiatan industri di Perairan Muara Sungai Tiram, Marunda, Jakarta Utara, akan berdampak terhadap konsentrasi logam berat di Perairan. Sedimen merupakan tempat akumulasinya logam tersebut dan pada suatu saat akan dapat menjadi sumber bagi kolom perairan diatasnya. Tujuan penelitian ini adalah untuk mengetahui konsentrasi logam berat pada sedimen dasar dan mengetahui korelasinya terhadap ukuran butir serta dan bahan organik. Analisa logam berat diawali dengan proses destruksi menggunakan aquaregia dan supernatannya di baca nilai absorbasninya menggunakan Atomic Absorption Spectrophotometer (AAS). Untuk melihat hubungan parameter logam berat terhadap ukuran butir dan bahan organik, menngunakan analisis korelasi Pearson. Berdasarkan penelitian tersebut diperoleh nilai konsentrasi logam berat dengan kisaran 20,19–55,68 ppm. Konsentrasi logam berat memiliki korelasi positif terhadap fraksi silt dan clay.  Distribusi logam berat di lokasi penelitian berasosiasi kuat terhadap fraksi ukuran butir halus dan bahan organik, melalui proses adsorpsi. The waters of the Muara Sungai Tiram, Marunda, North Jakarta, are areas that are surrounded by very dense industrial activities. The existence of these activities has an impact on the concentration of heavy metals in basic sediments in these waters. The purpose of this study was to determine the concentration of heavy metals in basic sediments and determine the correlation between the concentration of heavy metals with grain size on the base sediment in the liquid and the correlation between the concentration of heavy metals with organic matter. Analysis of heavy metal concentrations was carried out using the acid destruction method, then the concentration was read using the Atomic Absorption Spectrophotometer (AAS), and processed into a heavy metal concentration map using Arcgis 10.3. Based on these studies the value of heavy metal concentrations obtained in the range of 20.19 - 55.681 ppm. Heavy metal concentrations have a positive correlation with the mud and organic matter fractions with r values of 0.68 and 0.10, respectively. The distribution of heavy metals in this study is strongly associated with the fine grain size fraction and organic matter, through the adsorption process

scholarly journals Metal Concentration In Water, Sediment, and Green Alga Halimeda opuntia (Linnaeus) J.V. Lamouroux from Totok Bay and Blongko Waters, North Sulawesi

2019 ◽  
Vol 7 (1) ◽  
pp. 233
Author(s):  
. Nasprianto ◽  
Desy M.H. Mantiri ◽  
Grevo S Gerung
Keyword(s):  
Heavy Metals ◽  
Heavy Metal ◽  
Metal Concentration ◽  
Green Alga ◽  
Marine Algae ◽  
Heavy Metal Concentration ◽  
Low Concentration ◽  
Heavy Metal Concentrations ◽  
North Sulawesi ◽  
Water And Sediment

Heavy metals in the water and sediment, in spite of low concentration, will not degrade and even can be absorbed  and biologically accumulated by marine algae. This study was aimed to analyze the heavy metal concentrations in the seawater, sediment, and  Halimeda opuntia in Totok Bay and Blongko waters. Samples were analyzed using  APHA method  and USEPA method in Water Laboratory Nusantara (WLN). Results showed that the heavy metal concentration in Totok Bay waters was  <0.0001 ppm for Cadmium (Cd),  <0.001 ppm for lead (Pb),  <0.005 ppm for Zinc (Zn), and  <0.00005 ppm for mercury (Hg), respectively, while Blongko waters had Cd concentration of <0.0001 ppm, Pb  <0.001 ppm, Zn <0,005 ppm, Hg <0.00005 ppm. Heavy metal concentration in the sediment of Totok Bay was 4.71 ppm for Cd, 10.7 ppm for lead, 58 ppm for Zn, and 2.68 ppm for Hg, respectively, while in Blongko, the heavy metal concentration was 0,03 ppm for Cd,  0.4 ppm for Pb,  <1 ppm for Zn, and <0.05 ppm for Hg, respectively. The heavy metal concentration in H. opuntia of  Totok Bay was 0.18 ppm for Cd,  2.2 ppm for Pb, 5.10 ppm for Zn, 0.74 ppm for Hg, while H. opuntia of Blongko contained 0.02 ppm of Cd,  0.2 ppm of lead,  <0.5 ppm of  Zn, and  0.009 ppm of Hg, respectively.Keywords : Cadmium (Cd); Lead (Pb); Zink (Zn); Mercury (Hg); Halimeda opuntia; Totok Bay; Blongko waters.ABSTRAKLogam berat dalam perairan dan sedimen meskipun memiliki kadar yang relatif rendah namun tidak akan mengalami degradasi bahkan dapat diabsorbsi dan terakumulasi secara biologis oleh alga laut. Tujuan penelitian adalah menganalisis kandungan logam berat dalam air laut, sedimen dan Halimeda opuntia di perairan Teluk Totok dan Perairan Blongko. Analisis sampel mengacu metode APHA, (2012) dan USEPA, (2005) yang dianalisis di Water Laboratory Nusantara (WLN). Hasil analisis konsentrasi logam berat dalam air laut di perairan Teluk Totok yaitu kadmium (Cd) <0,0001 ppm, timbal (Pb) <0,001 ppm, seng (Zn) <0,005 ppm dan merkuri (Hg) <0,00005 ppm sedangkan dari perairan Blongko yaitu konsentrasi kadmium (Cd) <0,0001 ppm, timbal (Pb) <0,001 ppm, seng (Zn) <0,005 ppm dan merkuri (Hg) <0,00005 ppm. Konsentrasi logam berat pada sedimen di perairan Teluk Totok yaitu kadmium (Cd) 4,71 ppm, timbal (Pb) 10,7 ppm, seng (Zn) 58 ppm dan merkuri (Hg) 2,68 ppm dan perairan Blongko dengan konsentrasi kadmium (Cd) 0,03 ppm, timbal (Pb) 0,4 ppm, seng (Zn) <1 ppm dan merkuri (Hg) <0,05 ppm. Sedangkan konsentrasi logam berat pada H. opuntia di perairan Teluk Totok dengan konsentrasi kadmium (Cd) 0,18 ppm, timbal (Pb) 2,2 ppm, seng (Zn) 5,10 ppm dan merkuri (Hg) 0,74 ppm dan perairan Blongko dengan konsentrasi kadmium (Cd) 0,02 ppm, timbal (Pb) 0,2, seng (Zn) <0,5 ppm dan merkuri (Hg) 0,009 ppm.Kata-kata kunci : Kadmium (Cd); Timbal (Pb); Seng (Zn); Merkuri (Hg); Halimeda opuntia; Teluk Totok; Perairan Blongko.

scholarly journals Heavy Metals in Air Emission and Assessment of Human Toxicity Footprint

2021 ◽  
Vol 43 (9) ◽  
pp. 614-622
Author(s):  
Junbeum Kim
Keyword(s):  
Heavy Metals ◽  
Heavy Metal ◽  
Life Cycle ◽  
Metal Concentration ◽  
Heavy Metal Concentration ◽  
Human Toxicity ◽  
Concentration Data ◽  
City Governments ◽  
Heavy Metal Concentrations ◽  
Metropolitan City

Objective : The purpose of this study is to propose the concept of the human toxicity (human cancer and non-cancer) footprint (µg 1,4 DCB (Dichlorobenzene) eqv./m3) using heavy metal concentration data in the air in Provincial and Metropolitan City governments. In addition, the final goal is to assess and compare the human carcinogenic toxicity footprint in Provincial and Metropolitan City Governments from 1991 to 2019.Method : To calculate the human carcinogenic toxicity footprint using heavy metal concentration in Provincial and Metropolitan City Governments, the ReCiPe 2016 life cycle impact assessment method in life cycle assessment (LCA) was used. For the human carcinogenic toxicity footprint calculation, the heavy metal concentration data in Provincial and Metropolitan City Governments are multiplied by the characterization factors of each heavy metal such as Pb, Cd, Cr, Ni, and As (Cu, Mn, Fe, Al, Ca, and Mg are not included in the air monitoring data) data (µg/m3). The unit of human carcinogenic toxicity footprint is shown in µg 1,4 DCB eqv. value.Results and Discussion : The results show that the heavy metal concentrations in Provincial and Metropolitan City governments were decreased significantly from 1991 to 2019. In the case of Pb, Incheon was decreased by about 2,124% (from 0.427 µg/m3 to 0.0192 µg/m3), and Busan was decreased by about 1,250% (from 0.2471 µg/m3 to 0.0183 µg/m3). In addition, in Cd’s case, Gwangju decreased by about 1,550% (from 0.0033 µg/m3 to 0.0002 µg/m3), and Incheon was decreased by about 1,071% (from 0.0082 µg/m3 to 0.0007 µg/m3). The results of human carcinogenic toxicity footprint in 1991 (early stage), 2005 (middle-stage), and 2019 (current) show that the average of human carcinogenic toxicity footprint was 8,478 µg 1,4 DCB eqv. in 1991, 5,545 µg 1,4 DCB eqv. in 2005 (about 53% decreased from 1991), and 1,997 µg 1,4 DCB eqv. in 2019 (about 178% decreased from 2005). In 2019, the human carcinogenic toxicity footprint results showed that Gyeongbuk had the highest value of 5,184 µg 1,4 DCB eqv. followed by Busan 3,929 µg 1,4 DCB eqv., Gyeongi 3,305 µg 1,4 DCB eqv., Seoul 2,184 µg 1,4 DCB eqv., Gwangwon 2,011 µg 1,4 DCB eqv. One of the reasons for the highest human carcinogenic toxicity footprint is the concentration of Cr and As, which have very high characterization factors.Conclusions : In this study, the human carcinogenic toxicity footprint using a heavy metal concentration in Provincial and Metropolitan City governments was proposed and calculated. Even though the heavy metal concentrations were decreasing, the number of measuring stations should be increased in each Provincial and Metropolitan City Government to improve the data quality and reduce the human carcinogenic toxicity impact by heavy metals.

Sign in / Sign up

Export Citation Format

Share Document