scholarly journals Essential Oil Content of Baccharis crispa Spreng. Regulated by Water Stress and Seasonal Variation

2020 ◽  
Vol 2 (3) ◽  
pp. 458-470
Author(s):  
Maria Alejandra Moreno-Pizani ◽  
Franklin Javier Paredes-Trejo ◽  
Asdrubal Jesus Farias-Ramirez ◽  
Hugo Thaner dos Santos ◽  
Adna Prado Massarioli ◽  
...  
Keyword(s):  
Essential Oil ◽  
Oil Content ◽  
Seasonal Pattern ◽  
Irrigation Management ◽  
Principal Component ◽  
Hierarchical Cluster ◽  
Crop Productivity ◽  
Growing Seasons ◽  
Irrigation Regimes ◽  
Metabolite Profiles

Carqueja (Baccharis crispa Spreng.) has been primarily used as a medicinal plant around the world. Commercially, the essential oil content of carqueja leaves is the most valuable crop productivity variable. We evaluated the effect of irrigation management in different growing seasons on the essential oil content of carqueja leaves using gas chromatography coupled with mass spectrometry. The experiment was conducted in a greenhouse located in Southern Brazil, where the crop was cultivated for two years in different growing seasons under six irrigation regimes: 25%, 50%, 75%, 100%, 125%, and 150% of the reference crop evapotranspiration (T25, T50, T75, T100, T125, and T150, respectively). A seasonal pattern was observed in the number of metabolites of sesquiterpenes and phenolics in the essential oil extracted from the biomass; this outcome was correlated with irrigation regimes and air temperature. Principal component and hierarchical cluster analyses were used to discriminate the influence of abiotic conditions on secondary metabolite profiles. Spathulenol was the most abundant compound in the essential oils (95.43%) collected during the summer (December–March) season during the third harvest (H3) at T150. The essential oil content was 8.84% ± 0.05% and 10.52% ± 0.10% in summer and winter (June–September), respectively, with T100 at 45 and 46 days after planting.

scholarly journals Chemotypes of turmeric (Curcuma longa L.) essential oil from four different states of Brazil

2021 ◽  
pp. 1035-1042
Author(s):  
Franciele da Silva Quemel ◽  
Andira Pricila Dantas ◽  
Lincon Sanches ◽  
Ana Cláudia Graças Alves Viana ◽  
Eloísa Schneider Silva ◽  
...  
Keyword(s):  
Essential Oil ◽  
Chemical Constituents ◽  
Curcuma Longa ◽  
Principal Component ◽  
Chemical Compounds ◽  
Hierarchical Cluster ◽  
Main Compound ◽  
Group Iii ◽  
Group I ◽  
Chemical Class

Turmeric or curcuma (Curcuma longa L.) is a Zingiberaceae whose essential oil and coloring pigments obtained from the rhizome have been widely used in the food industry and medicine. This study aimed to extract and identify the chemical compounds found in C. longa essential oil from rhizomes collected in six different locations of Brazil. The oil extraction was carried out by hydrodistillation technique, using a Clevenger- type apparatus. The chemical constituents were identified by Gas Chromatography coupled to Mass Spectrometry (GC-MS). The principal component analysis (PCA) and the hierarchical cluster analysis (cluster)were done for the obtained data; and the composition of the studied accesses was verified. Three groups of chemotypes were obtained: group I was formed by the accesses of Campo Grande / Indígena-MS, Mara Rosa-GO, Campo Grande-MS and Perobal-PR, and had Ar-turmerone as its main compound; group II, formed by the access of Santa Tereza do Oeste-PR, presented α-costol and α-Phellandrene as the predominant compounds; and group III, the access of Holambra-SP, differed from the others regarding its essential oil chemical composition whose main agents were Curlone, Zingiberene, β-sesquiphellandrene, Humulene epoxide II, cis-α-trans-Bergamotol. The predominant chemical class in all accesses was hydrocarbon sesquiterpenes (Santa Tereza do Oeste-PR and Holambra-SP) and oxygenated sesquiterpenes (the others). This study evidenced the formation of three chemotypes

scholarly journals Seasonal Effect on the Chemical Composition, Insecticidal Properties and Other Biological Activities of Zanthoxylum leprieurii Guill. & Perr. Essential Oils

Foods ◽  
2020 ◽  
Vol 9 (5) ◽  
pp. 550 ◽  
Author(s):  
Evelyne Amenan Tanoh ◽  
Guy Blanchard Boué ◽  
Fatimata Nea ◽  
Manon Genva ◽  
Esse Leon Wognin ◽  
...  
Keyword(s):  
Chemical Composition ◽  
Essential Oil ◽  
Essential Oils ◽  
Biological Activities ◽  
Principal Component ◽  
Hierarchical Cluster ◽  
Wild Plant ◽  
Gas Chromatography Mass Spectrometry ◽  
Seasonal Effect ◽  
The Impact

This study focused, for the first time, on the evaluation of the seasonal effect on the chemical composition and biological activities of essential oils hydrodistillated from leaves, trunk bark and fruits of Zanthoxylum leprieurii (Z. leprieurii), a traditional medicinal wild plant growing in Côte d’Ivoire. The essential oils were obtained by hydrodistillation from fresh organs of Z. leprieurii growing on the same site over several months using a Clevenger-type apparatus and analyzed by gas chromatography-mass spectrometry (GC/MS). Leaf essential oils were dominated by tridecan-2-one (9.00 ± 0.02–36.80 ± 0.06%), (E)-β-ocimene (1.30 ± 0.50–23.57 ± 0.47%), β-caryophyllene (7.00 ± 1.02–19.85 ± 0.48%), dendrolasin (1.79 ± 0.08–16.40 ± 0.85%) and undecan-2-one (1.20 ± 0.03–8.51 ± 0.35%). Fruit essential oils were rich in β-myrcene (16.40 ± 0.91–48.27 ± 0.26%), citronellol (1.90 ± 0.02–28.24 ± 0.10%) and geranial (5.30 ± 0.53–12.50 ± 0.47%). Tridecan-2-one (45.26 ± 0.96–78.80 ± 0.55%), β-caryophyllene (1.80 ± 0.23–13.20 ± 0.33%), α-humulene (4.30 ± 1.09–12.73 ± 1.41%) and tridecan-2-ol (2.23 ± 0.17–10.10 ± 0.61%) were identified as major components of trunk bark oils. Statistical analyses of essential oil compositions showed that the variability mainly comes from the organs. Indeed, principal component analysis (PCA) and hierarchical cluster analysis (HCA) allowed us to cluster the samples into three groups, each one consisting of one different Z. leprieurii organ, showing that essential oils hydrodistillated from the different organs do not display the same chemical composition. However, significant differences in essential oil compositions for the same organ were highlighted during the studied period, showing the impact of the seasonal effect on essential oil compositions. Biological activities of the produced essential oils were also investigated. Essential oils exhibited high insecticidal activities against Sitophilus granarius, as well as antioxidant, anti-inflammatory and moderate anti-plasmodial properties.

scholarly journals Seasonal and Antioxidant Evaluation of Essential Oil from Eugenia uniflora L., Curzerene-Rich, Thermally Produced in Situ

Biomolecules ◽  
2020 ◽  
Vol 10 (2) ◽  
pp. 328 ◽  
Author(s):  
Jamile S. da Costa ◽  
Adenilson S. Barroso ◽  
Rosa Helena V. Mourão ◽  
Joyce Kelly R. da Silva ◽  
José Guilherme S. Maia ◽  
...  
Keyword(s):  
Antioxidant Activity ◽  
Essential Oil ◽  
Biological Activities ◽  
Principal Component ◽  
Hierarchical Cluster ◽  
Oil Composition ◽  
Eugenia Uniflora ◽  
Average Value ◽  
Antibacterial And Antifungal Activities ◽  
Significant Difference

The essential oil of Eugenia uniflora has been attributed anti-depressive, antinociceptive, antileishmanial, larvicidal, antioxidant, antibacterial, and antifungal activities. It is known that the cultivation of this plant can be affected by seasonality, promoting alteration in the oil composition and its biological activities. This study aims to perform the annual evaluation of the curzerene-type oil of E. uniflora and determine its antioxidant activity. The oil yield from the dry season (1.4 ± 0.6%) did not differ statistically from that of the rainy season (1.8 ± 0.8%). Curzerene, an oxygenated sesquiterpene, was the principal constituent, and its percentage showed no significant difference between the two periods: dry (42.7% ± 6.1) and rainy (40.8 ± 5.9%). Principal component and hierarchical cluster analyses presented a high level of similarity between the monthly samples of the oils. Also, in the annual study, the yield and composition of the oils did not present a significant correlation with the climatic variables. The antioxidant activity of the oils showed inhibition of DPPH radicals with an average value of 55.0 ± 6.6%. The high curzerene content in the monthly oils of E. uniflora suggests their potential for use as a future phytotherapeutic alternative.

scholarly journals Rapid Screening of Mentha spicata Essential Oil and L-Menthol in Mentha piperita Essential Oil by ATR-FTIR Spectroscopy Coupled with Multivariate Analyses

Foods ◽  
2021 ◽  
Vol 10 (2) ◽  
pp. 202
Author(s):  
Osman Taylan ◽  
Nur Cebi ◽  
Osman Sagdic
Keyword(s):  
Essential Oil ◽  
Essential Oils ◽  
Ftir Spectroscopy ◽  
Principal Component ◽  
Hierarchical Cluster ◽  
Rapid Screening ◽  
Mentha Piperita ◽  
Least Squares Regression ◽  
Mentha Spicata ◽  
Quality Properties

Mentha piperita essential oil (EO) has high economic importance because of its wide usage area and health-beneficial properties. Besides health-beneficial properties, Mentha piperita EO has great importance in the flavor and food industries because of its unique sensory and quality properties. High-valued essential oils are prone to being adulterated with economic motivations. This kind of adulteration deteriorates the quality of authentic essential oil, injures the consumers, and causes negative effects on the whole supply chain from producer to the consumer. The current research used fast, economic, robust, reliable, and effective ATR-FTIR spectroscopy coupled chemometrics of hierarchical cluster analysis(HCA), principal component analysis (PCA), partial least squares regression (PLSR) and principal component regression (PCR) for monitoring of Mentha spicata EO and L-menthol adulteration in Mentha piperita EOs. Adulterant contents (Mentha spicata and L-menthol) were successfully calculated using PLSR and PCR models. Standard error of the cross-validation SECV values changed between 0.06 and 2.14. Additionally, bias and press values showed alteration between 0.06 and1.43 and 0.03 and 41.15, respectively. Authentic Mentha piperita was successfully distinguished from adulterated samples, Mentha spicata and L-menthol, by HCA and PCA analysis. The results showed that attenuated total reflectance-Fourier transform infrared (ATR-FTIR) spectroscopy, coupled with chemometrics could be effectively used for monitoring various adulterants in essential oils.

scholarly journals Triterpenoids and Other Non-Polar Compounds in Leaves of Wild and Cultivated Vaccinium Species

Plants ◽  
2021 ◽  
Vol 10 (1) ◽  
pp. 94
Author(s):  
Radka Vrancheva ◽  
Ivan Ivanov ◽  
Ivayla Dincheva ◽  
Ilian Badjakov ◽  
Atanas Pavlov
Keyword(s):  
High Performance ◽  
Natural Populations ◽  
Principal Component ◽  
Hierarchical Cluster ◽  
Polar Compounds ◽  
Vaccinium Corymbosum ◽  
Gas Chromatography Mass Spectrometry ◽  
Array Detector ◽  
Vaccinium Uliginosum ◽  
Metabolite Profiles

The purpose of the current study was to identify and quantify triterpenoids and other non-polar compounds in the leaves of three high bush blueberry cultivars (Vaccinium corymbosum L. var. Bluegold, var. Bluecrop and var. Elliott) and three natural populations of Vaccinium species (Vaccinium uliginosum L., Vaccinium myrtillus L. and Vaccinium vitis-idaea L.) by means of gas chromatography mass spectrometry (GC-MS) and high-performance liquid chromatography with diode array detector (HPLC-DAD). Metabolite profiles differed significantly among the Vaccinium species analyzed, as well as among the populations of the same species. The populations of V. vitis-idaea predominantly contained relative concentrations of phytosterols (varying between 10.48% of total ion current (TIC) and 22.29% of TIC) and almost twice the content of triterpenes (from 29.84% of TIC to 49.62% of TIC) of the other berry species investigated. The leaves of V. corymbosum varieties biosynthesized the highest relative amount of fatty acids, while the leaves of the populations of V. uliginosum had the highest relative concentrations of fatty alcohols. The results of principal component analysis (PCA) and hierarchical cluster analysis (HCA) showed that the diverse populations of each berry species analyzed differed from each other, most likely due to variations in the climatic and geographical conditions of their localities.

scholarly journals Assessment of phenotypic variability among EEA INTA Pergamino sunflower lines: Its relationship with the grain yield and oil content

OCL ◽  
2021 ◽  
Vol 28 ◽  
pp. 33
Author(s):  
Matías Domínguez ◽  
Stefanía Herrera ◽  
Julio Horacio González
Keyword(s):  
Grain Yield ◽  
Oil Content ◽  
Phenotypic Diversity ◽  
Phenotypic Variability ◽  
Morphological Variability ◽  
Principal Component ◽  
Hierarchical Cluster ◽  
Breeding Program ◽  
Depth Study ◽  
Selective Forces

The aims of the present study were to assess the phenotypic diversity among 221 sunflower accessions of INTA Pergamino Sunflower Breeding Program, to obtain discriminant functions that allow the classification of new accessions in similar groups and to evaluate the relationship between genetic distance pairwise accessions and hybrid performance for grain yield and oil content. We used 19 quantitative descriptors to evaluate phenotypic and morphological variability. Principal Component Analysis (PCA) and Hierarchical Cluster Analysis (HCA) were used to evaluate simultaneously all the variables and to describe phenotypic variation patterns of the germplasm. The distribution of germplasm in the dendrogram did not follow a clear pattern with regard to the predefined groups. This study revealed the variability observed among the lines that form the INTA Pergamino breeding program despite the highly selective forces applied to obtain inbred lines that produce superior hybrids for the Argentinean sunflower area. This work demonstrates the need for more in-depth study of genetic variability to be used as a predictor of heterosis in sunflower.

scholarly journals Morphometric Traits and iPBS Based Molecular Characterizations of Walnut (Juglans regia L.) Genotypes

2021 ◽  
Author(s):  
İbrahim Başak ◽  
Göksel Özer ◽  
FERHAD MURADOGLU
Keyword(s):  
Juglans Regia ◽  
Principal Component ◽  
Hierarchical Cluster ◽  
Morphological Characters ◽  
Morphometric Traits ◽  
Breeding Programs ◽  
Growing Seasons ◽  
Main Components ◽  
Chemical Traits ◽  
High Level

Abstract In this study, walnut genotypes that selected during two growing seasons among thousands of seedlings were analyzed in terms of detailed morphometric, phenological, and chemical traits. A multivariate analysis was conducted with valuable traits for breeding and selection such as morphometric traits, chemical composition, and phenological characteristics. Also, genotypes were characterized by a retrotransposon-based iPBS marker system. The correlation analysis showed significant positive and negative correlations between agro-morphological characters. The principal component analysis explained 71.44% of the total variance into five main components. Principal component and hierarchical cluster analysis divided genotypes into three groups, whose subgroups were identified based on both agro-morphological characters and iPBS marker systems. A high level of polymorphism ratio was observed for tested markers. Mantel’s test demonstrated relatively low correlations between molecular and morphological treats (r=0.04). The genetic similarities among all individuals ranged from 0.39 (between 018 and 015 or 045 genotypes) to 0.98 (between 090 and 094 genotypes) with a mean similarity of 0.67. Remarkable phenotypic and molecular variations were observed among the genotypes. The features of some investigated genotypes were above the acceptable thresholds for walnut selection in breeding programs and our study indicated that iPBS markers can be beneficial in walnut breeding programs, allowing the evaluation of the genetic relationship between genotypes, helping to differentiate and select the best genotypes to improve agronomic properties.

scholarly journals Chemical and Enantioselective Analysis of the Essential Oils from Different Morphological Structures of Ocotea quixos (Lam.) Kosterm

Plants ◽  
2021 ◽  
Vol 10 (10) ◽  
pp. 2171
Author(s):  
Gianluca Gilardoni ◽  
Mayra Montalván ◽  
Marjorie Vélez ◽  
Omar Malagón
Keyword(s):  
Principal Component Analysis ◽  
Cluster Analysis ◽  
Essential Oil ◽  
Essential Oils ◽  
Hierarchical Cluster Analysis ◽  
Principal Component ◽  
Hierarchical Cluster ◽  
Methyl Cinnamate ◽  
Enantiomerically Pure ◽  
Enantioselective Analysis

The traditional Ecuadorian spice Ishpingo, characterized by a strong cinnamon-like aroma, is constituted by the dry cupules of Amazonian species Ocotea quixos. Nevertheless, bark and leaves also present aromatic properties and are sometimes used as substitutes. In the present study, the essential oils, distilled from these morphological structures, are comparatively analyzed for their chemical and enantiomeric compositions. A total of 88 components were identified with 2 orthogonal GC columns, whereas 79, corresponding to more than 94%, were also quantified with at least 1 column. Major compounds were (E)-methyl cinnamate in cupules (35.9–34.2%), (E)-cinnamaldehyde in bark (44.7–47.0%), and (E)-cinnamyl acetate (46.0–50.4%) in leaves. For what concerns the enantioselective analysis, 10 chiral terpenes and terpenoids were detected, of which 6 were present as enantiomeric pairs in at least 1 essential oil, the others being enantiomerically pure. Both quantitative and enantioselective analyses were submitted to Principal Component Analysis (PCA) and Hierarchical Cluster Analysis (HCA), where their results confirmed significative difference among the three products.

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