scholarly journals The Catalytic Activity of Biosynthesized Magnesium Oxide Nanoparticles (MgO-NPs) for Inhibiting the Growth of Pathogenic Microbes, Tanning Effluent Treatment, and Chromium Ion Removal

Catalysts ◽  
2021 ◽  
Vol 11 (7) ◽  
pp. 821
Author(s):  
Ebrahim Saied ◽  
Ahmed M. Eid ◽  
Saad El-Din Hassan ◽  
Salem S. Salem ◽  
Ahmed A. Radwan ◽  
...  
Keyword(s):  
Electron Microscopy ◽  
Magnesium Oxide ◽  
Oxygen Demand ◽  
Effluent Treatment ◽  
Oxide Nanoparticles ◽  
X Ray ◽  
Chromium Ion ◽  
Ion Removal ◽  
Magnesium Oxide Nanoparticles ◽  
Vis Spectroscopy

Magnesium oxide nanoparticles (MgO-NPs) were synthesized using the fungal strain Aspergillus terreus S1 to overcome the disadvantages of chemical and physical methods. The factors affecting the biosynthesis process were optimized as follows: concentration of Mg(NO3)2·6H2O precursor (3 mM), contact time (36 min), pH (8), and incubation temperature (35 °C). The characterization of biosynthesized MgO-NPs was accomplished using UV-vis spectroscopy, Fourier transform infrared (FT-IR) spectroscopy, transmission electron microscopy (TEM), scanning electron microscopy—energy dispersive X-ray (SEM-EDX), X-ray diffraction (XRD), and dynamic light scattering (DLS). Data confirmed the successful formation of crystallographic, spherical, well-dispersed MgO-NPs with a size range of 8.0–38.0 nm at a maximum surface plasmon resonance of 280 nm. The biological activities of biosynthesized MgO-NPs including antimicrobial activity, biotreatment of tanning effluent, and chromium ion removal were investigated. The highest growth inhibition of pathogenic Staphylococcus aureus, Bacillus subtilis, Pseudomonas aeruginosa, Escherichia coli, and Candida albicans was achieved at 200 μg mL–1 of MgO-NPs. The biosynthesized MgO-NPs exhibited high efficacy to decolorize the tanning effluent (96.8 ± 1.7% after 150 min at 1.0 µg mL–1) and greatly decrease chemical parameters including total suspended solids (TSS), total dissolved solids (TDS), biological oxygen demand (BOD), chemical oxygen demand (COD), and conductivity with percentages of 98.04, 98.3, 89.1, 97.2, and 97.7%, respectively. Further, the biosynthesized MgO-NPs showed a strong potential to remove chromium ions from the tanning effluent, from 835.3 mg L–1 to 21.0 mg L–1, with a removal percentage of 97.5%.

scholarly journals Biogenic synthesis of magnesium oxide nanoparticles using Manihot esculenta (Crantz) leaf extract

2019 ◽  
Vol 10 (1) ◽  
pp. 43-48 ◽  
Author(s):  
Enobong R. Essien ◽  
Violette N. Atasie ◽  
Anastecia O. Okeafor ◽  
Davies O. Nwude
Keyword(s):  
Electron Microscopy ◽  
Magnesium Oxide ◽  
Manihot Esculenta ◽  
Large Scale ◽  
Leaf Extract ◽  
Metal Oxide Nanoparticles ◽  
Oxide Nanoparticles ◽  
Manihot Esculenta Crantz ◽  
X Ray ◽  
Magnesium Oxide Nanoparticles

AbstractRecently, plant-mediated route or green approach for preparing metal and metal oxide nanoparticles has received enormous attention due to the ease of preparation and environmental friendliness when compared to physical and chemical methods. Plants contain phytochemicals which have been proposed as bio-reductants and capping agents for forming metal nanoparticles. Therefore, this study was aimed to prepare magnesium oxide nanoparticles (MgONPs) using aqueous extract of Manihot esculenta leaf. The leaf extract was first analyzed in a gas chromatograph–mass spectrometer (GC–MS) to examine the phytochemicals present. Then, the MgONPs formed were evaluated using UV–Visible (UV–Vis) spectrophotometry, scanning electron microscopy (SEM), energy-dispersive X-ray analysis (EDX), transmission electron microscopy (TEM), X-ray diffractometry (XRD) and Fourier transform infrared (FTIR) spectroscopy, to confirm the formation of MgONPs and to determine the morphology, elemental composition, shape and size, phase composition and nature of bonds present in the sample. Results revealed the formation of monodisperse, hexagonal shaped MgONPs of average size 36.7 nm having potentials for application in catalysis and as antimicrobial agent. Hence the process reported herein could be optimized for large-scale preparation of MgONPs.

scholarly journals Moringa oleifera Leaf Extract-Mediated Green Synthesis of Nanostructured Alkaline Earth Oxide (MgO) and Its Physicochemical Properties

2021 ◽  
Vol 2021 ◽  
pp. 1-22
Author(s):  
Archana Venkatachalam ◽  
Joseph Prince Jesuraj ◽  
kalainathan Sivaperuman
Keyword(s):  
Magnesium Oxide ◽  
Leaf Extract ◽  
Moringa Oleifera ◽  
Oxide Nanoparticles ◽  
Stoichiometric Ratio ◽  
Face Centered Cubic ◽  
Promising Candidate ◽  
Mgo Nanoparticles ◽  
X Ray ◽  
Magnesium Oxide Nanoparticles

The magnesium oxide nanoparticles (MgO NPs) were prepared from Moringa oleifera leaf extract. Phytochemicals are derived from plant extract which are served as stabilizing and capping agents. This green route has been attracted owing to speed, reliable, and eco-friendly and cost-effective one. The synthesized magnesium oxide nanoparticles were taken into three different calcination temperatures (500, 600, and 700°C). The powder X-ray diffraction (PXRD) study shows a pure phase of face-centered cubic structure. Periclase MgO nanoparticles were prepared. The optical band gap of MgO nanoparticles is 4.5 eV, and its absorption in the UV region was observed by UV-visible spectroscopy (UV-Vis). Photoluminescence spectra have exhibited multicolor emissions were being at UV and visible region due to defect centers (F centers) of MgO nanoparticles. EDX (energy dispersive X-ray spectrum) has given the stoichiometric ratio of Mg and O. The functional groups have been studied by Fourier transformed infrared spectroscopy (FTIR), surface morphology transformation has been identified by scanning electron microscopy (SEM) studies, and VSM measurements have given the information of diamagnetic nature of MgO nanoparticles. H-R TEM micrographs have confirmed that particles were in nanorange matched with XRD report. Polycrystalline nature has been observed pattern information. TG-DSC characterization revealed phase transition and weight loss information. D-band and G-band of MgO nanoparticles are studied by micro-Raman analysis. Dielectric analysis has proven that MgO nanoparticles will be a promising candidate for linear dielectric ceramics, thermistor. The present resent studies have revealed that MgO powder will be an economical and promising candidate in superconductor, optoelectronic device, and energy storage applications.

scholarly journals Magnetic Field – Assisted Laser Ablation of Titanium Dioxide Nanoparticles in Water for Anti-Bacterial Applications

2021 ◽  
Author(s):  
Hasan H. Bahjat ◽  
R.A. Ismail ◽  
Ghassan M. Sulaiman ◽  
Majid S. Jabir
Keyword(s):  
Magnetic Field ◽  
Electron Microscopy ◽  
Laser Ablation ◽  
Titanium Oxide ◽  
Oxide Nanoparticles ◽  
Titanium Oxide Nanoparticles ◽  
X Ray ◽  
Vis Spectroscopy ◽  
The Magnetic Field ◽  
Scanning Electron

Abstract Titanium oxide nanoparticles (TiO2) were produced by pulsed Nd:YAG laser ablation in water under the effect of an external magnetic field. Various techniques such as X-ray diffraction (XRD), field emission scanning electron microscopy (FESEM), energy Dispersive x-ray (EDX), transmission electron microscopy (TEM), UV-Vis spectroscopy, and Raman spectroscopy were used to characterize the TiO2 nanoparticles. The XRD analysis of titanium oxide nanoparticles revealed that the synthesized nanoparticles were polycrystalline with mixed of tetragonal anatase and rutile TiO2. Scanning electron microscope shows the formation of spherical nanoparticles and the particles agglomeration decreases and the particle size from increases from 25nm to 35nm when the magnetic field applied. The optical energy gap of TiO2 nanoparticles decreased from 4.6eV to 3.4eV after using the magnetic field during the ablation. Raman studies show the existence of five vibration modes belong to TiO2. The antibacterial effect assay revealed a largest inhibition zone in S. aureus and E. coli, with a more potent effect for TiO2 NPs prepared by magnetic field when compared with that prepared without presence of magnetic field.

scholarly journals Structural and electrical studies on zinc added magnesium oxide nanoparticles

2020 ◽  
Vol 31 (3) ◽  
pp. 73-86
Author(s):  
Sumithraj Premkumar P. ◽  
Keyword(s):  
Magnesium Oxide ◽  
Oxide Nanoparticles ◽  
X Ray Diffraction ◽  
Mgo Nanoparticles ◽  
X Ray ◽  
Electrical Studies ◽  
Magnesium Oxide Nanoparticles ◽  
Different Temperatures ◽  
Crystalline Nature ◽  
Scanning Electron

Magnesium oxide (MgO, pure) and zinc added MgO nanoparticles were synthesised by a simple microwave assisted solvothermal method. The concentrations of impurity used in the present work were 0.25 M and 0.50 M. All samples were annealed at 400°C for 1 h to improve the ordering. The prepared pure and zinc added magnesium oxide nanoparticles were characterised by powder X-ray diffraction (PXRD), energy dispersive spectroscopy (EDS) and scanning electron microscopy (SEM). PXRD studies of pure and zinc added MgO nanoparticles showed that all samples belong to crystalline nature with cubic structure. The grain size of all samples were determined from the XRD results and it belongs to nano meter scale. The EDS confirmed the presence of zinc, magnesium and oxide elements in the respective prepared samples. The scanning electron microscope images confirmed that the prepared samples possess nanometer dimensions. The electrical properties such as AC conductivity, dielectric constant and dielectric loss were measured at different temperatures in the different frequency range by involving the impedance analyser of all the prepared samples.

scholarly journals Surfactant Free Synthesis of Magnesium Oxide Nanotubes by Simple Chemical Co-Precipitation Method

2020 ◽  
Vol 9 (4) ◽  
pp. 2504-2506
Keyword(s):  
Magnesium Oxide ◽  
Cost Effective ◽  
Precipitation Method ◽  
Diffraction Field ◽  
Oxide Nanoparticles ◽  
Outer Diameter ◽  
X Ray Diffraction ◽  
X Ray ◽  
Magnesium Oxide Nanoparticles ◽  
Co Precipitation

A simple cost effective preparation of Magnesium oxide nanoparticles in nanotube morphology is reported using Chemical co-precipitation method. As prepared magnesium oxide nanoparticles were characterized using UV-visible spectroscopy, X-ray Diffraction, Field Emission Scanning Electron Microscope and Energy dispersive X-ray spectroscopy. As prepared magnesium oxide nanoparticles were found in nanotube morphology whose inner and outer diameter were 31 nm and 78 nm. The band gap of as prepared nanotubes were found to be 5.37eV with maximum absorbance at 200 nm.

Nano Sized ZnO/MnO2/Gd2O3 Ternary Heterostructures for Enhanced Photocatalysis

2020 ◽  
Vol 5 (1) ◽  
pp. 36-46 ◽  
Author(s):  
Shubha Pranesh ◽  
Jayalakshmi Nagaraju
Keyword(s):  
Electron Microscopy ◽  
Methylene Blue ◽  
Visible Light ◽  
Effluent Treatment ◽  
Small Scale ◽  
Blue Dye ◽  
Aquatic Life ◽  
X Ray ◽  
Vis Spectroscopy ◽  
Wide Range

Background: The cost of effluent treatment is not affordable by small scale industries especially in developing countries. Hence the effluent is discharged without treatment into water bodies. The dyes do not degrade easily and possess a major concern to be addressed. The aquatic life is highly affected and also leads to bio magnification of the chemicals through the food chain. Objective: To synthesize a ternary hybrid structure for enhanced photocatalytic activity under visible light. It is intended to reduce toxicity caused by dyeing units. Methods: Synthesized nanomaterials are characterized and used as photocatlyst for the degradation of methylene blue. In degradation experiment known weight of catalyst was added to known volume of an aqueous solution of dye at various concentrations. The solutions are aerated in dark for about 30 min. At the time of irradiation of light, known aliquot of the aqueous mixture was collected at an interval of constant time each from the reaction solution. The catalyst in the mixture was separated by centrifuging the mixture and absorbance was measured. The % of degradation of the dye can be determined knowing initial and final dye concentration. Result: Heterostructures are characterized with analytical tools such as X-ray diffraction, Fourier transform infrared spectroscopy. Band gap of photocatlyst is calculated by application of UV-Vis spectroscopy. Morphology is seen using scanning electron microscopy and transmission electron microscopy. Distribution of constituent structures is observed with energy-dispersive X-ray (EDX) spectroscopy. The structures are used for photocatalytic degradation of methylene blue dye solution under UV and visible light irradiation. Heterostructures showed best performance under visible light. Conclusion: The ternary hybrid nanostructure ZnO-MnO2-Gd2O3 was effectively prepared by a simple solution combustion method. The ternary compound shows wide range of absorption by expanding absorption band both in UV and visible regions. Structures showed better catalytic property under visible light.

scholarly journals Phytoassisted synthesis of magnesium oxide nanoparticles from Pterocarpus marsupium rox.b heartwood extract and its biomedical applications

2021 ◽  
Vol 19 (1) ◽  
Author(s):  
Manne Anupama Ammulu ◽  
K. Vinay Viswanath ◽  
Ajay Kumar Giduturi ◽  
Praveen Kumar Vemuri ◽  
Ushakiranmayi Mangamuri ◽  
...  
Keyword(s):  
Magnesium Oxide ◽  
Cost Effective ◽  
Oxide Nanoparticles ◽  
X Ray Diffraction ◽  
Pterocarpus Marsupium ◽  
X Ray ◽  
Magnesium Oxide Nanoparticles ◽  
Cost Effective Method ◽  
Ft Ir ◽  
Crystalline Nature

Abstract Background Unlike chemical techniques, the combination of metal oxide nanoparticles utilizing plant concentrate is a promising choice. The purpose of this work was to synthesize magnesium oxide nanoparticles (MgO-NPs) utilizing heartwood aqueous extract of Pterocarpus marsupium. The heartwood extract of Pterocarpus marsupium is rich in polyphenolic compounds and flavonoids that can be used as a green source for large-scale, simple, and eco-friendly production of MgO-NPs. The phytoassisted synthesis of MgO is characterized by UV-Visible spectroscopy, X-ray diffraction (XRD), dynamic light scattering (DLS), Fourier transform infrared spectroscopy (FT-IR), scanning electron microscopy (SEM) with EDS (energy dispersive X-ray spectroscopy), and transmission electron microscopy (TEM). Results The formation of MgO-NPs is confirmed by a visual color change from colorless to dark brown and they displayed a wavelength of 310 nm in UV-Spectrophotometry analysis. The crystalline nature of the obtained biosynthesized nanoparticles are revealed by X-ray diffraction analysis. SEM results revealed the synthesized magnesium oxide nanoparticles formed by this cost-effective method are spherically shaped with an average size of < 20 nm. The presence of magnesium and oxygen were confirmed by the EDS data. TEM analysis proved the spherical shape of the nanoparticles with average particle size of 13.28 nm and SAED analysis confirms the crystalline nature of MgO-NPs. FT-IR investigation confirms the existence of the active compounds required to stabilize the magnesium oxide nanoparticles with hydroxyl and carboxyl and phenolic groups that act as reducing, stabilizing, and capping agent. All the nanoparticles vary in particle sizes between 15 and 25 nm and obtained a polydispersity index value of 0.248. The zeta-potential was measured and found to be − 2.9 mV. Further, MgO-NPs were tested for antibacterial action against Staphylococcus aureus (Gram-positive bacteria) and Escherichia coli (Gram-negative bacteria) by minimum inhibitory concentration technique were found to be potent against both the bacteria. The blended nanoparticles showed good antioxidant activity examined by the DPPH radical scavenging method, showed good anti-diabetic activity determined by alpha-amylase inhibitory activity, and displayed strong anti-inflammatory activity evaluated by the albumin denaturation method. Conclusions The investigation reports the eco-friendly, cost-effective method for synthesizing magnesium oxide nanoparticles from Pterocarpus marsupium Rox.b heartwood extract with biomedical applications. Graphical abstract

Antibacterial activity of magnesium oxide nanoparticles prepared by Calcination method

2019 ◽  
Vol 10 (03) ◽  
Author(s):  
Elaf Ayad Kadhem ◽  
Miaad Hamzah Zghair ◽  
Sarah , Hussam H. Tizkam, Shoeb Alahmad Salih Mahdi ◽  
Hussam H. Tizkam ◽  
Shoeb Alahmad
Keyword(s):  
Antibacterial Activity ◽  
Magnesium Oxide ◽  
Diffusion Method ◽  
Oxide Nanoparticles ◽  
Gram Negative Bacteria ◽  
Gram Positive ◽  
Gram Negative ◽  
Gram Positive Bacteria ◽  
Magnesium Oxide Nanoparticles ◽  
Agar Disc

magnesium oxide nanoparticles (MgO NPs) were prepared by simple wet chemical method using different calcination temperatures. The prepared NPs were characterized by Electrostatic Discharge (ESD), Scanning Electron Microscope (SEM) and X-ray Diffraction (XRD). It demonstrates sharp intensive peak with the increase of crystallinty and increase of the size with varying morphologies with respect to increase of calcination temperature. Antibacterial studies were done on gram negative bacteria (E.coli) and gram positive bacteria (S.aureus) by agar disc diffusion method. The zones of inhibitions were found larger for gram positive bacteria than gram negative bacteria, this mean, antibacterial MgO NPs activity more active on gram positive bacteria than gram negative bacteria because of the structural differences. It was found that antibacterial activity of MgO NPs was found it has directly proportional with their concentration.

Applications of ZnO and MgO Nanoparticles in Reducing Zinc Pollution Level in Rubber Manufacturing Processes: A Review

2020 ◽  
Vol 6 (2) ◽  
pp. 103-107 ◽  
Author(s):  
Seyyed Mohammad Javadi
Keyword(s):  
Zinc Oxide ◽  
Fatty Acid ◽  
Magnesium Oxide ◽  
Environmental Effects ◽  
Pollution Level ◽  
Oxide Nanoparticles ◽  
Mgo Nanoparticles ◽  
Magnesium Oxide Nanoparticles ◽  
Council Directive ◽  
Zno Particles

Background: Rubber vulcanization is a consolidated chemical process to enhance the mechanical properties of the polymeric material by sulfur crosslinking of the polymer chains, such as rubber. Vulcanization Activators are important rubber processing additives that activate sulfur cure and improve the efficiency of sulfur-based cure systems. The most common activator is zinc fatty acid ester that is often formed in-situ by the reaction of fatty acid with zinc oxide. Although zinc is one of the less harmful heavy metals, according to European Council Directive 2004/73/EC, the reduction of zinc level in the environment has become an important task because of its toxic effect on aquatic organisms. : The current study reviews the research achievements in the field of reducing the consumption of micronutrients of ZnO particles based on the use of nanoparticles instead of them in the polymer industry. Among the proposed methods, due to the less environmental effects of magnesium oxide, the use of MgO nanoparticles instead of zinc oxide has also achieved good results. Objective: The aim of this paper is considering suggested different methods on the reduction of using ZnO particles in related industries, the use of ZnO nanoparticles has had better results than its particles. In addition, due to the less environmental effects of magnesium oxide, magnesium oxide nanoparticles can be used instead of micronutrients of zinc oxide. Overall, the results of various investigations show that reducing the diameter of the zinc oxide particles reduces the amount required for curing the rubber and thus reduces its toxic effects. Also, the use of magnesium oxide nanoparticles instead of zinc oxide in different concentrations is investigated.

scholarly journals Phytosynthetic Fabrication of Lanthanum Ion-Doped Nickel Oxide Nanoparticles Using Sesbania grandiflora Leaf Extract and Their Anti-Microbial Properties

Crystals ◽  
2021 ◽  
Vol 11 (2) ◽  
pp. 124
Author(s):  
Srihasam Saiganesh ◽  
Thyagarajan Krishnan ◽  
Golla Narasimha ◽  
Hesham S. Almoallim ◽  
Sulaiman Ali Alhari ◽  
...  
Keyword(s):  
Electron Microscopy ◽  
Optical Properties ◽  
Rare Earth ◽  
Nickel Oxide ◽  
Photoelectron Spectroscopy ◽  
Metal Oxide Nanoparticles ◽  
Oxide Nanoparticles ◽  
Nio Nanoparticles ◽  
X Ray ◽  
Sesbania Grandiflora

Over the past few years, the photogenic fabrication of metal oxide nanoparticles has attracted considerable attention, owing to the simple, eco-friendly, and non-toxic procedure. Herein, we fabricated NiO nanoparticles and altered their optical properties by doping with a rare earth element (lanthanum) using Sesbania grandiflora broth for antibacterial applications. The doping of lanthanum with NiO was systematically studied. The optical properties of the prepared nanomaterials were investigated through UV-Vis diffuse reflectance spectra (UV-DRS) analysis, and their structures were studied using X-ray diffraction analysis. The morphological features of the prepared nanomaterials were examined by scanning electron microscopy and transmission electron microscopy, their elemental structure was analyzed by energy-dispersive X-ray spectral analysis, and their oxidation states were analyzed by X-ray photoelectron spectroscopy. Furthermore, the antibacterial action of NiO and La-doped NiO nanoparticles was studied by the zone of inhibition method for Gram-negative and Gram-positive bacterial strains such as Escherichia coli and Bacillus sublitis. It was evident from the obtained results that the optimized compound NiOLa-04 performed better than the other prepared compounds. To the best of our knowledge, this is the first report on the phytosynthetic fabrication of rare-earth ion Lanthanum (La3+)-doped Nickel Oxide (NiO) nanoparticles and their anti-microbial studies.

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