scholarly journals Effect of Ozone Treatment on the Properties of Oil Palm Empty Fruit Bunch Sulfonated Chemi-Mechanical Pulp

Forests ◽  
2021 ◽  
Vol 12 (8) ◽  
pp. 1085
Author(s):  
Xing Wan ◽  
Yang Ping ◽  
Jun Li

Oil palm empty fruit bunch (EFB) as an abundant waste material can be utilized for pulp production to alleviate the shortage of raw materials in the paper industry. Sulfonated chemi-mechanical pulp (SCMP) has great potential in paper making industry. However, its poor performance due to the high surface lignin content limits its application. In this study, we used EFB as raw material to produce SCMP and systematically studied the effect of ozone treatment on pulp properties. Results show that the surface structure and morphology of fibers exhibited distinct differences under different ozone dosage treatments. Compared to the control, the content of surface lignin of pulps was reduced by 2.56%, 4.64%, 13.24% and 25.24% when ozone consumption was 1, 3, 5 and 7 wt%, respectively. Meanwhile, the treated pulp had a lower drainability at the same refining energy level. Moreover, the physical and optical properties of handsheets were improved significantly after ozone treatment. Ozone treatment is a very efficient way to improve the performance of SCMP. Additionally, this method avoids complicated processes and chemical consumption. Therefore, as an effective, environmentally friendly and low-cost treatment method, ozone treatment can improve the performance of EFB SCMP and thus provide a high-quality pulp resource.

2020 ◽  
Vol 1 (2) ◽  
pp. 1-9

The pulp and paper industry is advanced rapidly since there are many types of raw materials containing cellulose fibres that could be used to produce different kinds of paper by different methods in the mills. In Malaysia, one of the abundant non-wood materials for pulp and paper production is empty fruit bunch (EFB) from the oil palm. The EFB is the main fibrous residue and natural fibre which has promising potential as an alternative to replace woody materials. This study provides insight into the use of EFB as an alternative non-wood fibre resource in pulp and paper making. The potential of oil palm EFB transformed into valuable fibre material was elaborated. In this review, detailed information on the properties of EFB for pulp and paper making process to identify the chemical composition and fibre morphology were discussed. Recent advanced applications including nanocellulose from EFB, polymeric hydrogel, and antimicrobial papers were discussed to demonstrate high commercialization for pulp and paper technology. The three-dimensional (3D) printing technique has been employed due to the high complexity of paper products. The future trends and challenges regarding the use of EFB in pulp and paper making were also reviewed. This study demonstrated that the EFB has met the demand of the market chains as a potential raw material in paper making and manufacturing.


Materials ◽  
2020 ◽  
Vol 13 (5) ◽  
pp. 1245 ◽  
Author(s):  
Farah Nadia Mohammad Padzil ◽  
Seng Hua Lee ◽  
Zuriyati Mohamed Asa’ari Ainun ◽  
Ching Hao Lee ◽  
Luqman Chuah Abdullah

Oil palm empty fruit bunch (OPEFB) is considered the cheapest natural fiber with good properties and exists abundantly in Malaysia. It has great potential as an alternative main raw material to substitute woody plants. On the other hand, the well-known polymeric hydrogel has gathered a lot of interest due to its three-dimensional (3D) cross-linked network with high porosity. However, some issues regarding its performance like poor interfacial connectivity and mechanical strength have been raised, hence nanocellulose has been introduced. In this review, the plantation of oil palm in Malaysia is discussed to show the potential of OPEFB as a nanocellulose material in hydrogel production. Nanocellulose can be categorized into three nano-structured celluloses, which differ in the processing method. The most popular nanocellulose hydrogel processing methods are included in this review. The 3D printing method is taking the lead in current hydrogel production due to its high complexity and the need for hygiene products. Some of the latest advanced applications are discussed to show the high commercialization potential of nanocellulose hydrogel products. The authors also considered the challenges and future direction of nanocellulose hydrogel. OPEFB has met the requirements of the marketplace and product value chains as nanocellulose raw materials in hydrogel applications.


2020 ◽  
Vol 25 (3) ◽  
Author(s):  
Nur Hidayah ◽  
Ikna Urwatul Wusko

Empty oil palm bunches are the largest solid waste produced from the palm oil industry processing. In processing 1 ton of fresh palm oil bunches, 230 Kg of empty palm oil bunches will be produced. Based on previous research, it is known that oil palm empty fruit bunches waste is proven to have a large amount of organic mass such as cellulose, hemicellulose, lignin. Organic content as mentioned is rich in benefits so that it can be used as raw material for making daily needs products ranging from food to complementary products such as household appliances, clothing and so on. For this reason, a study was conducted on the content of oil palm empty bunches originating from waste at PT. Kharisma Alam Persada. The characterization process was carried out using the SNI method 0128911992. From the research carried out it was found that the cellulose, hemicellulose and lignin content were 55.75%; 28.93% and 15.32% respectively. So that it is possible to be used as raw material for processing other products.


Author(s):  
Irina A. Chetvertneva ◽  
Oleg Kh. Karimov ◽  
Galina A. Teptereva ◽  
Natalia S. Tivas ◽  
Eldar M. Movsumzade ◽  
...  

The paper considers the main components and products of wood processing, agricultural waste, pulp and paper industry waste and qualifies them as sources of pentose-containing resource-renewable domestic raw materials. The article describes in detail the structural components of wood as a natural polymer, which contains aromatic and carbohydrate parts. It is noted that these poly-mers are promising as raw materials for the production of useful chemical products. The role of lignin, cellolose and hemicellulose in the design of mechanical and structural properties of wood is considered. The article considers the features of the sulfonation reactions of the lignin monomer unit depending on the pH of the medium: acidic, neutral and alkaline. There are three main reac-tions that occur simultaneously with lignin in the process of wood delignification during sulfite cooking, such as the sulfonation reaction, the hydrolytic destruction reaction, and the condensation reaction. It is shown that the lignin-hemicellulose matrix contains three types of interconnected mesh structures: the lignin itself; a network of covalent bonds of lignin with hemicelluloses, and a network whose structure is obtained due to the hydrogen bond and the forces of the physical inter-action of lignin and hemicelluloses. The features of chemical transformations of the monomeric aromatic link of lignosulfonate – phenylpropane unit in the processes of wood delignification, the main chemical reactions of wood raw material delignification under the conditions of sulfite and neutral-sulfite brews are shown. The method of quantitative determination of monosaccharides in the composition of the carbohydrate part is proposed.


2019 ◽  
Vol 48 (3) ◽  
pp. 547-557
Author(s):  
Hui-Jin Liu ◽  
Li Zhang ◽  
Yan-Nian Xu ◽  
Xiao-Ping Zhang ◽  
Xiao-Hong Li

The bark of Pteroceltis tatarinowii Maxim., an endemic tree in Ulmaceae, is the main raw material for manufacturing Xuan Paper which is widely used in calligraphy and painting field. The characteristics of P. tatarinowii bark is the main limiting factor for the quality of Xuan Paper specially the content of cellulose and lignin. The molecular basis related to cellulose and lignin synthesis in P. tatarinowii would be helpful to understand and seek higher quality raw materials for Xuan Paper. RNA-seq was utilized to reveal transcriptome differences in P. tatarinowii from three far isolated localities (AL, JX and XA) under different climate environments. A total of 290 million reads were generated for further analysis in three libraries. In total, 2,850, 2,038 and 1,986 DEGs were identified in XA, JX and AL, respectively. Compared with the sample from XA, there were 822 up-regulated and 1706 down-regulated in AL sample. AL sample has 611 up-regulated genes and 647 down-regulated genes in comparison with JX sample. Comparing XA and JX samples, 443 were up-regulated and 1,783 were down-regulated in XA. Three samples had similar GO enrichment patterns. There were 19 and 9 genes identified as CESA and CSL (E-value less than 1.0E-20), respectively. Although no significant expression differences were found in three samples, KOB1, GPI-anchored protein gene and CTL1 were differently expressed, and KOB1 and GPI-anchored protein gene were up-regulated in JX. A number of the unigenes (474) that were involved in ‘phenylpropanoid biosynthesis’, were mostly not differently expressed. Only a few genes annotated as PAL, 4CL, C4H and CAD were significantly different in expression. In AL, 3 CAD and 1 PAL were up-regulated, whereas 6 CAD, 3 4CL and 1 HCT were up-regulated in XA, and 1 PAL, 2 4CL, 2 C4H in JX. JX sample had the highest cellulose content and XA sample had the highest lignin content, which being consistent with the hierarchical cluster analysis of differently expressed genes. Differences in the expression of these genes might influence the cellulose and lignin content.


2012 ◽  
Vol 550-553 ◽  
pp. 3253-3257
Author(s):  
Xian Qi Sun ◽  
Chuan Shan Zhao ◽  
Hui Rong Yang

Hand towel is one kind of disposable tissue paper which has characteristic of soaking up water quickly and lower cost. It becomes increasingly popularity in families, at work, and public places. There are many kinds of raw materials to produce hand towel according to its level. Some researches showed that bleached chemical pulp could be partially used to the production of hand towel and some other household paper. In this study, some kinds of raw material which be used to produce hand towel were analyzed and trying to looking for new one. Poplar Extruding Mechanical Pulp (EMP) had characteristics of long fiber, high level of strength and brightness. Different ratio of poplar EMP and certain Bleached Kraft Pulp were tested to make hand towel. The effects of poplar EMP on whiteness, tensile strength, bulkiness, absorbability were discussed. The results showed that characteristic targets of hand towel made from poplar EMP and Bleached Kraft Pulp met the quality requirements of GBT22455-2009 and satisfied the high-end hand towel. The new hand towel had lower cost, higher stiffness and higher bulkiness. It was feasible from the technique and economy point.


2013 ◽  
Vol 2013 ◽  
pp. 1-8 ◽  
Author(s):  
Satriani Aga Pasma ◽  
Rusli Daik ◽  
Mohamad Yusof Maskat ◽  
Osman Hassan

Oil palm empty fruit bunch fiber (OPEFB) is a lignocellulosic waste from palm oil mills. It contains mainly cellulose from which glucose can be derived to serve as raw materials for valuable chemicals such as succinic acid. A three-level Box-Behnken design combined with the canonical and ridge analysis was employed to optimize the process parameters for glucose production from OPEFB cellulose using enzymatic hydrolysis. Organosolv pretreatment was used to extract cellulose from OPEFB using ethanol and water as the solvents. The extracted cellulose was characterized by thermogravimetric analysis, FTIR spectroscopy, and field emission scanning electron microscopy. Hydrolysis parameters including amount of enzyme, amount of cellulose, and reaction time were investigated. The experimental results were fitted with a second-order polynomial equation by a multiple regression analysis and found that more than 97% of the variations could be predicted by the models. Using the ridge analysis, the optimal conditions reaction time found for the production of glucose was 76 hours and 30 min, whereas the optimum amount of enzyme and cellulose was 0.5 mL and 0.9 g, respectively. Under these optimal conditions, the corresponding response value predicted for glucose concentration was 169.34 g/L, which was confirmed by validation experiments.


1993 ◽  
Author(s):  
Israel Finkelstain ◽  
Steven Buccola ◽  
Ziv Bar-Shira

In recent years there has been a growing concern over the performance of Israel and U.S. agricultural marketing organizations. In Israel, poor performance of some marketing institutions has led to radical reforms. Examples are the two leading export industries - citrus and flowers. In the U.S., growth of local market power is eliminating competitive row product prices which served as the basis for farmer cooperative payment plans. This research studies, theoretically, several aspects of the above problem and develops empirical methods to assess their relative importance. The theoretical part deals with two related aspects of the operation of processing and marketing firms. The first is the technological structure of these firms. To this end, we formalize a detailed theory that describes the production process itself and the firm's decision. The model accounts for multiple products and product characteristics. The usefulness of the theory for measurement of productivity and pricing of raw material is demonstrated. The second aspect of the processing and marketing firm that we study is unique to the agricultural sector, where many such firms are cooperatives. In such cooperative an efficient and fair mechanism for purchasing raw materials from members is crucial to successful performances of the firm. We focus on: 1) pricing of raw materials. 2) comparison of employment of quota and price regimes by the cooperative to regulate the quantities, supplied by members. We take into consideration that the cooperative management is subject to pressure from member farmers. 3) Tier pricing for raw materials in order to ensure efficiency and zero profits at the cooperative level. This problem is examined in both closed and open cooperatives. The empirical part focuses in: 1) the development of methodologies for estimating demand for differentiated products; 2) assessing farmers response to component pricing; 3) measurement of potential and actual exploitation of market power by an agricultural marketing firm. The usefulness of the developed methodologies are demonstrated by several application to agricultural sub-sectors, including: U.S. dairy industry, Oregon wine industry, Israeli Cotton industry and Israeli Citrus industry.


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