scholarly journals Conductive Electrospun Nanofiber Mats

Materials ◽  
2019 ◽  
Vol 13 (1) ◽  
pp. 152 ◽  
Author(s):  
Tomasz Blachowicz ◽  
Andrea Ehrmann

Conductive nanofiber mats can be used in a broad variety of applications, such as electromagnetic shielding, sensors, multifunctional textile surfaces, organic photovoltaics, or biomedicine. While nanofibers or nanofiber from pure or blended polymers can in many cases unambiguously be prepared by electrospinning, creating conductive nanofibers is often more challenging. Integration of conductive nano-fillers often needs a calcination step to evaporate the non-conductive polymer matrix which is necessary for the electrospinning process, while conductive polymers have often relatively low molecular weights and are hard to dissolve in common solvents, both factors impeding spinning them solely and making a spinning agent necessary. On the other hand, conductive coatings may disturb the desired porous structure and possibly cause problems with biocompatibility or other necessary properties of the original nanofiber mats. Here we give an overview of the most recent developments in the growing field of conductive electrospun nanofiber mats, based on electrospinning blends of spinning agents with conductive polymers or nanoparticles, alternatively applying conductive coatings, and the possible applications of such conductive electrospun nanofiber mats.

Polymers ◽  
2019 ◽  
Vol 11 (2) ◽  
pp. 206 ◽  
Author(s):  
Sher Lee ◽  
Chi-Jung Chang

Conductive polymers have been widely investigated in various applications. Several conductive polymers, such as polyaniline (PANI), polypyrrole (PPy), poly(3,4-ethylenedioxythiophene) (PEDOT)), and polythiophene (PTh) have been loaded with various semiconductor nanomaterials to prepare the composite photocatalysts. However, a critical review of conductive polymer-based composite photocatalysts has not been available yet. Therefore, in this review, we summarized the applications of conductive polymers in the preparation of composite photocatalysts for photocatalytic degradation of hazardous chemicals, antibacterial, and photocatalytic hydrogen production. Various materials were systematically surveyed to illustrate their preparation methods, morphologies, and photocatalytic performances. The synergic effect between conductive polymers and semiconductor nanomaterials were observed for a lot of composite photocatalysts. The band structures of the composite photocatalysts can be analyzed to explain the mechanism of their enhanced photocatalytic activity. The incorporation of conductive polymers can result in significantly improved visible-light driven photocatalytic activity by enhancing the separation of photoexcited charge carriers, extending the light absorption range, increasing the adsorption of reactants, inhibiting photo-corrosion, and reducing the formation of large aggregates. This review provides a systematic concept about how conductive polymers can improve the performance of composite photocatalysts.


Materials ◽  
2018 ◽  
Vol 11 (9) ◽  
pp. 1604 ◽  
Author(s):  
Irén Juhász Junger ◽  
Daria Wehlage ◽  
Robin Böttjer ◽  
Timo Grothe ◽  
László Juhász ◽  
...  

Textile-based dye-sensitized solar cells (DSSCs) can be created by building the necessary layers on a textile fabric or around fibers which are afterwards used to prepare a textile layer, typically by weaving. Another approach is using electrospun nanofiber mats as one or more layers. In this work, electrospun polyacrylonitrile (PAN) nanofiber mats coated by a conductive polymer poly(3,4-ethylenedioxythiopene) polystyrene sulfonate (PEDOT:PSS) were used to produce the counter electrodes for half-textile DSSCs. The obtained efficiencies were comparable with the efficiencies of pure glass-based DSSCs and significantly higher than the efficiencies of DSSCs with cotton based counter electrodes. The efficiency could be further increased by increasing the number of PEDOT:PSS layers on the counter electrode. Additionally, the effect of the post treatment of the conductive layers by HCl, acetic acid, or dimethyl sulfoxide (DMSO) on the DSSC efficiencies was investigated. Only the treatment by HCl resulted in a slight improvement of the energy-conversion efficiency.


Polymer ◽  
2009 ◽  
Vol 50 (18) ◽  
pp. 4389-4396 ◽  
Author(s):  
Nasser A.M. Barakat ◽  
Muzafar A. Kanjwal ◽  
Faheem A. Sheikh ◽  
Hak Yong Kim

2020 ◽  
Vol 15 ◽  
pp. 155892501989968 ◽  
Author(s):  
Tomasz Blachowicz ◽  
Andrea Ehrmann

Especially for the potential use as sensors, but also in all other applications in which an interaction with the environment occurs, nanofibrous materials are advantageous due to their large specific surface area. An interesting material for electrospinning is the semiconductor zinc oxide (ZnO) which is often used in photoelectric or sensory applications. Nanofibers containing ZnO can be produced, for example, by electrospinning polyvinylpyrrolidone/zinc nitrate from a dimethylformamide/ethanol solution, followed by calcination to remove the organic phase. Alternatively, the polymer/semiconductor blended nanofibers can be used which are often less brittle, but on the other hand offer less contact between ZnO and the environment. Finally, decorating a nanofiber mat with ZnO offers another possibility to prepare nanofibers with ZnO surface. Possible applications of electrospun ZnO nanofibers or nanofiber mats include gas sensing, microwave absorption, photocatalytic degradation or enhancement of supercapacitor electrodes. This short review gives an overview of the most recent electrospinning and after-treatment techniques to create pure and blended ZnO nanofibers and presents the broad variety of possible applications of this well-known semiconductor with some still surprising properties.


2021 ◽  
Author(s):  
Yannan Lu ◽  
Ruqing Lu ◽  
Xiaochun Hang ◽  
David James Young

Poly(3,4-ethylenedioxythiophene):poly(styrenesulfonate) (PEDOT:PSS) is a promising, biocompatible conductive polymer for bio-integrated electronics with health-care applications. However, the intrinsic biocompatibility of PEDOT: PSS is potentially jeopardized by post-treatment additives such as ionic...


2021 ◽  
Vol 11 (15) ◽  
pp. 6929
Author(s):  
Ewin Tanzli ◽  
Andrea Ehrmann

In biotechnology, the field of cell cultivation is highly relevant. Cultivated cells can be used, for example, for the development of biopharmaceuticals and in tissue engineering. Commonly, mammalian cells are grown in bioreactors, T-flasks, well plates, etc., without a specific substrate. Nanofibrous mats, however, have been reported to promote cell growth, adhesion, and proliferation. Here, we give an overview of the different attempts at cultivating mammalian cells on electrospun nanofiber mats for biotechnological and biomedical purposes. Starting with a brief overview of the different electrospinning methods, resulting in random or defined fiber orientations in the nanofiber mats, we describe the typical materials used in cell growth applications in biotechnology and tissue engineering. The influence of using different surface morphologies and polymers or polymer blends on the possible application of such nanofiber mats for tissue engineering and other biotechnological applications is discussed. Polymer blends, in particular, can often be used to reach the required combination of mechanical and biological properties, making such nanofiber mats highly suitable for tissue engineering and other biotechnological or biomedical cell growth applications.


2021 ◽  
pp. 152808372199746
Author(s):  
Tittaya Thairin ◽  
Patcharaporn Wutticharoenmongkol

Herein, ciprofloxacin (CIP)-loaded alginate/poly (vinyl alcohol)/gelatin (SPG) (CIP–SPG) nanofiber mats were successfully fabricated by electrospinning. The average fiber diameters of the mats before and after crosslinking were in the range of 190–260 and 385–484 nm, respectively. The chemical integrity of CIP remained intact after encapsulation into the mats. The degree of weight loss and water swelling decreased with an increase in the gelatin content of the electrospun nanofiber mats. A release study was carried out by total immersion and diffusion methods using phosphate buffer as a release medium. Burst release of CIP was observed in case of the total immersion method, while a more sustained release was observed in case of the diffusion method. The maximum amounts of CIP released during total immersion and diffusion were in the range of 70–90% and 72–85%, respectively. For both the total immersion and diffusion methods, the released amounts of CIP decreased and the release slowed down with an increase in the gelatin content; this result is consistent with the weight loss and water swelling values. The Young’s modulus increased, while the tensile strength and strain at break decreased with an increase in the gelatin content. The CIP–SPG nanofiber mats were slightly toxic to L929 mouse fibroblasts as evaluated by indirect cytotoxicity assay. The electrospun CIP–SPG nanofiber mats exhibited excellent antimicrobial activity against Staphylococcus aureus and Escherichia coli. These results reveal that the electrospun CIP–SPG nanofiber mats are potentially promising materials for wound healing applications.


2013 ◽  
Vol 10 (12) ◽  
pp. 4509-4526 ◽  
Author(s):  
S. Khansari ◽  
S. Duzyer ◽  
S. Sinha-Ray ◽  
A. Hockenberger ◽  
A. L. Yarin ◽  
...  

2016 ◽  
Vol 47 (8) ◽  
pp. 2228-2252 ◽  
Author(s):  
Subhankar Maity ◽  
Arobindo Chatterjee

This article reviews the preparation, development and characteristics of conductive polymer-based electro-conductive textile composites for electromagnetic interference shielding. Modification of ordinary textile materials in the form of electro-conductive composites makes them suitable for this purpose. Various metallic and non-metallic electro-conductive textiles have been explored here as the material for electromagnetic shielding. Different approaches of preparing textile electromagnetic shield have been described here. Recent advancements of application of conductive polymers in the field of textile electromagnetic shielding are described. Conductive polymer-coated textile materials showed superior electrical property as electromagnetic shield. Different methods of applications of conductive polymers onto textile surface are described here with their relative merits and demerits. Different conductive polymer-coated woven and nonwoven fabrics prepared by various researchers for electromagnetic shielding are taken into account. The effects of different process parameters of polymer processing on electromagnetic shielding are described.


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