scholarly journals Fracture Properties Evaluation of Cellulose Nanocrystals Cement Paste

Materials ◽  
2020 ◽  
Vol 13 (11) ◽  
pp. 2507 ◽  
Author(s):  
SeyedAli Ghahari ◽  
Lateef N. Assi ◽  
Ali Alsalman ◽  
Kürşat E. Alyamaç
Keyword(s):  
Compressive Strength ◽  
Cement Paste ◽  
Cellulose Nanocrystals ◽  
Fracture Behavior ◽  
Building Materials ◽  
Weight Ratio ◽  
Cementitious Materials ◽  
Cellulose Nanocrystal ◽  
Hydration Properties ◽  
Fracture Properties

Due to the need for high-performance and sustainable building materials, the investigation of the determination of fracture toughness of cement paste using new and sustainable materials, such as cellulose nanocrystals (CNCs) is worthwhile. Contrary to other well-known nano-reinforcement particles, such as carbon nanotubes, CNCs are less toxic; therefore, they have less safety and environmental risks. Fracture behavior of cement paste has been studied intensively for a long time. However, the incorporation of new materials in the cement paste, such as cellulose nanocrystal materials (CNCs), has not been fully investigated. In this paper, the fracture behavior, compressive strength, and hydration properties of cement paste reinforced with cellulose nanocrystal particles were studied. At the age of 3, 7, and 28 days, a three-point bending moment test, and a calorimetry and thermogravimetric analysis, scanning electron microscopy (SEM), and energy dispersive x-ray spectroscopy (EDX) analysis were performed on the water-to-binder-weight ratio of 0.35 cement paste, containing 0.0%, 0.2%, and 1.0% volume cellulose nanocrystals. Results indicated that the fracture properties and compressive strength were improved for the sample containing 0.2% CNCs. Preliminary results indicate that CNCs can improve the fracture behavior of cementitious materials and can be considered as a renewable and sustainable material in construction.

scholarly journals Effects of Adding Neutralized Red Mud on the Hydration Properties of Cement Paste

Materials ◽  
2020 ◽  
Vol 13 (18) ◽  
pp. 4107
Author(s):  
Sukpyo Kang ◽  
Hyeju Kang ◽  
Byoungky Lee
Keyword(s):  
Compressive Strength ◽  
Cement Paste ◽  
Red Mud ◽  
Aluminum Industry ◽  
Construction Material ◽  
Calorific Value ◽  
Cementitious Materials ◽  
Heat Of Hydration ◽  
Hydration Properties ◽  
The Aluminum Industry

Red mud is a highly alkaline waste by-product of the aluminum industry. Although recycling of red mud is being actively researched, a feasible technological solution has not been found yet. In this study, we propose that neutralization of red mud alkalinity could assist in its use as a construction material. Neutralized red mud (LRM + S; pH 6–8) was prepared by adding sulfuric acid to liquefied red mud (LRM; pH 10–12). After adding LRM and LRM + S to cement paste, the heat of hydration, compressive strength, and hydration products were examined. The experiments revealed that the calorific value of the cement paste with LRM was low, and its peak was delayed, when compared with that of plain cement paste (referred to as Plain), whereas the calorific value of the cement paste with LRM + S was similar to that of Plain. At the age of 28 d, the compressive strength of the cement paste with 10% LRM + S was 99% whereas that with 20% LRM was only 55% of the strength of Plain. Thus, our results help to resolve the issue of strength degradation of cementitious materials observed upon the addition of red mud and enable its reuse as a construction material.

scholarly journals Effect of Ground Slag on Mechanical Properties of Concrete under Low Temperature

2021 ◽  
Vol 2109 (1) ◽  
pp. 012019
Author(s):  
Xuelian Yuan ◽  
Jie Hu
Keyword(s):  
Mechanical Properties ◽  
Fracture Toughness ◽  
Compressive Strength ◽  
Low Temperature ◽  
Cement Paste ◽  
High Volume ◽  
Hardened Cement ◽  
Micro Structure ◽  
Hardened Cement Paste ◽  
Fracture Properties

Abstract Through using cube resisting compression test, fracture properties and micro-structure, the mechanical properties of high volume ground slag concrete under low temperature are studied in this paper. The results show that low temperature can improve the compressive strength of high volume ground slag concrete. And strength increased with the decreased of temperature. Low temperature can also improve the fracture energy and fracture toughness. Not only can ground slag reduce the content of calcium hydroxide in hardened cement paste, but ground slag can improve the compactness of hardened cement paste, reduce porosity and improve the strength of the interface.

scholarly journals The Assessment of Strength of Cementitious Materials Impregnated Using Hydrophobic Agents Based on Near-Surface Hardness Measurements

Materials ◽  
2021 ◽  
Vol 14 (16) ◽  
pp. 4583
Author(s):  
Martyna Nieświec ◽  
Łukasz Sadowski
Keyword(s):  
Compressive Strength ◽  
Cement Paste ◽  
Concrete Structures ◽  
Surface Hardness ◽  
Cementitious Materials ◽  
Schmidt Hammer ◽  
Near Surface ◽  
Cement Ratio ◽  
Water Cement Ratio ◽  
The Impact

Recently, the surfaces of concrete structures are impregnated to protect them against the environment in order to increase their durability. It is still not known how the use of these agents affects the near-surface hardness of concrete. This is especially important for experts who use the near-surface hardness of concrete for estimating its compressive strength. The impregnation agents are colorless and, thus, without knowledge of their use, mistakes can be made when testing the surface hardness of concrete. This paper presents the results of investigations concerning the impact of impregnation on the subsurface hardness concrete measured using a Schmidt hammer. For this research, samples of cement paste with a water–cement ratio of 0.4 and 0.5 were used. The samples were impregnated with one, two, and three layers of two different agents. The first agent has been made based on silanes and siloxanes and the second agent has been made based on based on polymers. The obtained research results allow for the conclusion that impregnation affects the near-surface hardness of concrete. This research highlights the fact that a lack of knowledge about the applied impregnation of concrete when testing its near-surface hardness, which is then translated into its compressive strength, can lead to serious mistakes.

Effects of Microstructure on Fracture Behavior of Hardened Cement Paste

1994 ◽  
Vol 370 ◽  
Author(s):  
Asif Ahmed ◽  
Leslie Struble
Keyword(s):  
Mechanical Properties ◽  
Compressive Strength ◽  
Cement Paste ◽  
Fracture Behavior ◽  
Curing Temperature ◽  
Hardened Cement ◽  
Curing Time ◽  
Hardened Cement Paste ◽  
Fracture Parameters ◽  
Initial Hypothesis

AbstractMechanical properties of any material, including hardened cement paste, are assumed to be controlled by its microstructure. An attempt has been made here to establish a link between bulk fracture parameters of hardened cement paste and its microstructure. Paste microstructure has been varied by changing the initial w/c ratio, curing time and curing temperature, and by addition of chemicals to change the calcium hydroxide morphology. It has been found that, like compressive strength, fracture parameters depend directly on porosity. Contrary to our initial hypothesis, CH morphology was found to have no effect on the fracture parameters.

Effect of Composition of Cementitious Materials on Alkalinity of Pore Solution and Strength of Cement Paste

2013 ◽  
Vol 671-674 ◽  
pp. 1732-1735
Author(s):  
Xiao Lu Yuan ◽  
Shi Hua Zhou ◽  
Dong Mei Liu
Keyword(s):  
Compressive Strength ◽  
Cement Paste ◽  
Pore Solution ◽  
Ph Value ◽  
Cement Content ◽  
Cementitious Materials ◽  
Mineral Admixtures ◽  
Aluminate Cement

Alkalinity of the surroundings is the basis to study the MICP technology. Alkalinity of pore solution and strength of cement paste made of various cementitious materials were studied. Results show that the alkalinity of pore solution of cement paste decreased with the increase of sulpho-aluminate cement content. pH value of cement paste was about less than 10 when sulpho-aluminate cement content exceeded 75%. Incorporation of sulpho-aluminate cement decreased compressive strength of paste obviously; however, compressive strength of paste was improved when the addition of sulpho-aluminate cement was more than 75%. Addition of mineral admixtures reduced the alkalinity of pore solution of cement paste and increased its compressive strength. Compressive strength of specimens was decreased when the content of mineral admixtures increased.

Hydration Properties of Steel Slag under Different Curing Temperatures

2014 ◽  
Vol 507 ◽  
pp. 295-299 ◽  
Author(s):  
Bo Zhang ◽  
Jin Hu ◽  
Meng Yuan Li
Keyword(s):  
Compressive Strength ◽  
Pore Structure ◽  
Water Content ◽  
Cement Paste ◽  
Steel Slag ◽  
Pore Distribution ◽  
Curing Temperature ◽  
Hydration Properties ◽  
Evaporable Water ◽  
Temperature Conditions

The non-evaporable water content, compressive strength, and pore distribution of steel slag paste cured under different curing temperature conditions were investigated in this paper. The non-evaporable water content of steel slag paste at early ages is obviously larger at higher curing temperature. At the age of 28 days, the non-evaporable water content of steel slag paste at normal curing temperature is close to that at high curing temperature, but the compressive strength of steel slag paste at normal curing temperature is much lower than that at high curing temperature. The pore structure of steel slag paste is much coarser than that of cement paste under the same conditions.

scholarly journals Feasibility Tests on Concrete with Very-High-Volume Supplementary Cementitious Materials

2014 ◽  
Vol 2014 ◽  
pp. 1-11
Author(s):  
Keun-Hyeok Yang ◽  
Yong-Su Jeon
Keyword(s):  
Compressive Strength ◽  
Weight Ratio ◽  
High Volume ◽  
Cementitious Materials ◽  
Positive Influence ◽  
Supplementary Cementitious Materials ◽  
Early Age ◽  
Freezing And Thawing ◽  
Strength And Durability ◽  
Very High

The objective of this study is to examine the compressive strength and durability of very high-volume SCM concrete. The prepared 36 concrete specimens were classified into two groups according to their designed 28-day compressive strength. For the high-volume SCM, the FA level was fixed at a weight ratio of 0.4 and the GGBS level varied between the weight ratio of 0.3 and 0.5, which resulted in 70–90% replacement of OPC. To enhance the compressive strength of very high-volume SCM concrete at an early age, the unit water content was controlled to be less than 150 kg/m3, and a specially modified polycarboxylate-based water-reducing agent was added. Test results showed that as SCM ratio (RSCM) increased, the strength gain ratio at an early age relative to the 28-day strength tended to decrease, whereas that at a long-term age increased up toRSCMof 0.8, beyond which it decreased. In addition, the beneficial effect of SCMs on the freezing-and-thawing and chloride resistances of the concrete decreased atRSCMof 0.9. Hence, it is recommended thatRSCMneeds to be restricted to less than 0.8–0.85 in order to obtain a consistent positive influence on the compressive strength and durability of SCM concrete.

scholarly journals Hydration Properties of Cement with Liquefied Red Mud Neutralized by Nitric Acid

Materials ◽  
2021 ◽  
Vol 14 (10) ◽  
pp. 2641
Author(s):  
Sukpyo Kang ◽  
Hyeju Kang ◽  
Byoungky Lee
Keyword(s):  
Compressive Strength ◽  
Nitric Acid ◽  
Cement Paste ◽  
Red Mud ◽  
Positive Impact ◽  
Low Cost ◽  
Construction Material ◽  
Construction Materials ◽  
Aluminum Production ◽  
Hydration Properties

An increasing amount of red mud (RM) is being generated globally due to the growth in aluminum production. To avoid RM pollution, low-cost methods for effectively recycling RM are being investigated. We propose a method for recycling RM as a construction material. Liquefied RM (LRM) was neutralized by nitric acid and added to cement paste, and the hydration heat, compressive strength, and hydration products were investigated. The cement paste with neutralized LRM had a higher compressive strength than that of plain cement paste and cement paste with LRM without neutralization at 1 day of aging; this indicates that nitric acid neutralization increases the early-age strength. Furthermore, the cement paste with 10% neutralized LRM showed 28 days-compressive strength and hydration heating curves similar to the plain mixture, indicating the positive impact of LRM neutralization on the strength. It was noted that a greater quantity of portlandite was produced earlier in cement paste with neutralized LRM than in that without. Therefore, the proposed method of using RM as a concrete additive has the potential to reduce the cost and environmental impact of both construction materials and RM waste management.

scholarly journals Hydration–Strength–Workability–Durability of Binary, Ternary, and Quaternary Composite Pastes

Materials ◽  
2021 ◽  
Vol 15 (1) ◽  
pp. 204
Author(s):  
Yi Han ◽  
Seokhoon Oh ◽  
Xiao-Yong Wang ◽  
Run-Sheng Lin
Keyword(s):  
Compressive Strength ◽  
Cement Paste ◽  
Carbon Emissions ◽  
Cementitious Materials ◽  
Heat Of Hydration ◽  
Surface Resistivity ◽  
Cement Industry ◽  
Supplementary Cementitious Materials ◽  
Limestone Powder ◽  
Alternative Materials

At present, reducing carbon emissions is an urgent problem that needs to be solved in the cement industry. This study used three mineral admixtures materials: limestone powder (0–10%), metakaolin (0–15%), and fly ash (0–30%). Binary, ternary, and quaternary pastes were prepared, and the specimens’ workability, compressive strength, ultrasonic pulse speed, surface resistivity, and the heat of hydration were studied; X-ray diffraction and attenuated total reflection Fourier transform infrared tests were conducted. In addition, the influence of supplementary cementitious materials on the compressive strength and durability of the blended paste and the sustainable development of the quaternary-blended paste was analyzed. The experimental results are summarized as follows: (1) metakaolin can reduce the workability of cement paste; (2) the addition of alternative materials can promote cement hydration and help improve long-term compressive strength; (3) surface resistivity tests show that adding alternative materials can increase the value of surface resistivity; (4) the quaternary-blended paste can greatly reduce the accumulated heat of hydration; (5) increasing the amount of supplementary cementitious materials can effectively reduce carbon emissions compared with pure cement paste. In summary, the quaternary-blended paste has great advantages in terms of durability and sustainability and has good development prospects.

scholarly journals An Experimental Study of the Effects of Low-Calcium Fly Ash on Type II Concrete

Ceramics ◽  
2021 ◽  
Vol 4 (4) ◽  
pp. 600-617
Author(s):  
Kong Fah Tee ◽  
Sayedali Mostofizadeh
Keyword(s):  
Compressive Strength ◽  
Fly Ash ◽  
Weight Ratio ◽  
High Strength ◽  
Cementitious Materials ◽  
Alkaline Solutions ◽  
Curing Period ◽  
Low Calcium ◽  
Permeation Properties

In this study, the compressive strength and the permeation properties of fly ash-based Geopolymer were experimentally investigated. Type 2 Portland cement (T2PC) was partially or entirely replaced with 0, 10, 20, 30, 50, 70, and 100% of fly ash (FA). The laboratory tests were conducted for compressive strength at 7, 28, and 90 days, and permeation properties such as water absorption at 7 and 28 days. The main goal was to produce eco-friendly concrete with high strength and low permeability through blending cementitious materials including low Calcium (Ca) (T2PC and FA) for protecting concrete against sulphate attacks and other chemically destructive compounds in the environment. This study focused on the effectiveness of the curing period, combinations of chemical activators by varying the molarity of alkaline solutions between 4.16 and 12.96 M and keeping the sodium silicate (SS) to sodium hydroxide (SH) by the weight ratio of 2.5. Lab observations from this study demonstrated that the compressive strength was enhanced with the increment in fly ash content at all ages, with optimum being at 20% as the replacement of T2PC.

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