scholarly journals Reactivity and Pozzolanic Properties of Biomass Ashes Generated by Wheat and Soybean Straw Combustion

Materials ◽  
2021 ◽  
Vol 14 (4) ◽  
pp. 1004
Author(s):  
Slobodan Šupić ◽  
Mirjana Malešev ◽  
Vlastimir Radonjanin ◽  
Vesna Bulatović ◽  
Tiana Milović
Keyword(s):  
Chemical Activation ◽  
Cementitious Materials ◽  
Silica Content ◽  
Raw Material ◽  
Supplementary Cementitious Materials ◽  
Concrete Production ◽  
Soybean Straw ◽  
Reduction Of Co2 ◽  
Straw Ash ◽  
Biomass Ashes

A sustainable use of locally available wastes from agriculture as supplementary cementitious materials (SCMs) is an alternative solution for the prevention of excessive raw material usage, reduction of CO2 emission and cost-effective concrete production. This paper studies the reactivity of non-traditional waste SCMs: Wheat straw ash (WSA), mixture of wheat and soybean straw ash (WSSA) and soybean straw ash (SSA), which are abundant as agricultural by-products in Serbia. The chemical evaluation using XRF technique, thermal analysis (TGA/DSC), XRD and FTIR methods were performed along with physical properties tests to investigate the feasibility of utilizing biomass ashes as cement substitutes. The obtained results demonstrate a high pozzolanic activity of WSA, which is attributed to a high reactive silica content of the ash and its satisfactory level of fineness. A wider hump in XRD pattern of WSA compared to WSSA and SSA confirmed that it abounds in amorphous (reactive) phase. The insufficient activity index of soybean-based biomass ashes, characterized with a low silica content, was improved by additional grinding and/or blending with amorphous silica-rich material. This points out the mechanical activation, i.e., grinding procedure, and chemical activation, i.e., modification of the chemical composition, as techniques efficient at producing pozzolanic materials from biomass wastes. Tested biomass ashes are characterized with negligible leaching values of heavy metals, thereby satisfying eco-friendly principles of SCM utilization. The application of biomass ashes as SCMs leads to substantial cost savings, as well as benefits to the environment, such as lower consumption of cement, reduction of CO2 emissions during the production of cement and sustainable waste management.

scholarly journals Influence of Milling Techniques on the Performance of Wheat Straw Ash in Cement Composites

2020 ◽  
Vol 10 (10) ◽  
pp. 3511
Author(s):  
Abdul Qudoos ◽  
Ehsanullah Kakar ◽  
Atta ur Rehman ◽  
In Kyu Jeon ◽  
Hong Gi Kim
Keyword(s):  
Particle Size ◽  
Wheat Straw ◽  
Cementitious Materials ◽  
Supplementary Cementitious Materials ◽  
Hydration Reaction ◽  
Cement Composites ◽  
Cement Production ◽  
X Ray ◽  
Worldwide Production ◽  
Straw Ash

The worldwide production of cement is growing every year due to its increased use in the construction. Cement production is affiliated with an environmental concern as it contributes to the CO2 emissions. It is imperative to reduce the cement production by incorporating supplementary cementitious materials in the cement composites. In this research study, wheat straw ash (WSA) was used as an alternate of ordinary Portland cement. The ash was ground separately with a ball mill and a disintegrator mill as well as with a combination of both to enhance its pozzolanic efficiency. Mortar and paste specimens were made by substituting cement with WSA (20% by weight). Ash specimens were examined in terms of particle size distribution, X-ray diffraction, and X-ray fluorescence analyses. The performance of the ash specimens in cement composites was examined via compressive and flexural strengths, and ultrasonic pulse velocity (UPV) tests. Isothermal calorimetric, thermogravimetric analyses (TGA), mercury intrusion porosimetry (MIP), and scanning electron microscopy (SEM) were also employed on the specimens. The results revealed that the particle size of the wheat straw ash specimens significantly reduced and specific surface area enhanced when ground with a combination of both milling techniques. Cement composites made with this type of ash demonstrated improved mechanical and physical properties, accelerated hydration reaction at the early ages, reduce calcium hydroxide content at the later ages, and densified microstructure.

Suitability of Cordia millenii Ash Blended Cement in Concrete Production

2016 ◽  
Vol 22 ◽  
pp. 59-67 ◽  
Author(s):  
Olusola Emmanuel Babalola ◽  
Paul O. Awoyera
Keyword(s):  
Compressive Strength ◽  
Setting Time ◽  
Blended Cement ◽  
Cementitious Materials ◽  
Strength Properties ◽  
Supplementary Cementitious Materials ◽  
Sieve Analysis ◽  
Concrete Production ◽  
Alternative Materials ◽  
Concrete Control

Supplementary cementitious materials are most needed to enhance a sustainable development in poor communities. It is pertinent to investigate the suitability of such alternative materials for construction. The present study evaluates the strength characteristics of concrete made with varied proportion of Cordia millenii ash blended with Portland cement. Chemical composition of Cordia millenii and the setting time when blended with cement was determined. Other laboratory tests performed on Cordia millenii blended cement include: sieve analysis and specific gravity. Five replacement percentages of Cordia millenii (5%, 10%, 15%, and 20%) were blended with cement in concrete. Control specimens were also produced with only cement. Tests to determine the workability, air entrained, bulk density and compressive strength properties of the concrete were also conducted. Results obtained revealed that optimum Cordia millenii mix is 10%, which yielded the highest density and compressive strength in the concrete.

Application of Zeolite as a Partial Replacement of Cement in Concrete Production

2014 ◽  
Vol 621 ◽  
pp. 30-34
Author(s):  
Eva Vejmelková ◽  
Dana Koňáková ◽  
Monika Čáchová ◽  
Martin Keppert ◽  
Adam Hubáček ◽  
...  
Keyword(s):  
Portland Cement ◽  
Natural Zeolite ◽  
General Rule ◽  
Cementitious Materials ◽  
Supplementary Cementitious Materials ◽  
Partial Replacement ◽  
Large Variability ◽  
Substitution Level ◽  
Concrete Production ◽  
Zeolite Rock

Natural zeolite rocks are known to be able to act as Supplementary Cementitious Materials (SCM) in Portland cement based concrete. Generally SCMs are reacting with portlandite and providing binding hydration products just as Portland cement does. In this way an SCM can substitute certain amount of Portland cement in concrete and thus reduce the related energy consumption and CO2 generation. Due to a large variability of SCMs composition and properties there is not any general rule for an optimum Portland cement substitution level. In this paper, the influence of natural zeolite rock on selected mechanical, hygric and thermal properties of concrete is studied. Experimental results show that the analyzed zeolite is acting as a pozzolan but for higher amounts its application leads to an increase in concrete porosity which affects its properties in a significant way.

scholarly journals Effectiveness of agricultural wastes in soil stabilization.

2021 ◽  
Vol 10 (1) ◽  
pp. 14
Author(s):  
Deborah Dauda ◽  
Manju Dominic
Keyword(s):  
Waste Disposal ◽  
Soil Stabilization ◽  
Expansive Soils ◽  
Agricultural Waste ◽  
Cost Effective ◽  
Cementitious Materials ◽  
Agricultural Wastes ◽  
Supplementary Cementitious Materials ◽  
Concrete Production ◽  
The Cost

Many ways have been sought to improve soils, especially expansive soils which have been problematic to structures and pavements built over them and soil stabilization seems to be one of the effective ways. But soil stabilization in itself is not cost-effective hence the introduction of agricultural wastes being researched on and seen as a cheaper means to be used as stabilizing agents which helps in minimizing the cost of soil stabilization, thereby reducing the problem of waste disposal. Agricultural wastes like Rice Husk Ash, Bagasse Ash, Sugarcane Straw Ash, Saw Dust Ash, Coconut Husk Ash, Millet Husk Ash, Corn Cob Ash, Locust Bean Pod Ash, Cassava Peel Ash and Bamboo Leaf Ash have been experimented with in stabilizing soils and as well, serving as supplementary cementitious materials for cement in concrete production. The strengths of the soils and the concrete stabilized with these wastes were seen to improve significantly and their effectiveness was estimated based on an average optimum value. Agricultural waste processing Industries can be set up to help in the massive production of these natural stabilizers which would lessen the cost of soil stabilization using cement and chemicals and also generally reduce problems that are associated with waste disposal, helping in waste management.  Keywords—expansive soils, soil stabilization, agricultural wastes

scholarly journals Performance of Beting Bamboo (Gigantochloa Levis) as Partial Replacement for Coarse Aggregate in Concrete

2021 ◽  
Vol 920 (1) ◽  
pp. 012014
Author(s):  
R M K Tahara ◽  
M H Hasnan ◽  
N Z N Azizan
Keyword(s):  
Coarse Aggregate ◽  
Construction Materials ◽  
Environmental Issues ◽  
Cementitious Materials ◽  
Natural Fibre ◽  
Supplementary Cementitious Materials ◽  
Partial Replacement ◽  
Concrete Mixtures ◽  
Concrete Production ◽  
Alternative Materials

Abstract Conventional construction materials are considered as exploitation to natural resources. Thus, numerous alternative materials using natural or waste materials are proposed for concrete production as a response for greener, renewable and biodegradable environments with regard to sustainability. Natural fibre such as bamboo has been rapidly proposed for many applications especially for concrete production in construction. In order to tackle the environmental issues and focusing on sustainability, natural fibre of Beting bamboo is proposed for partial replacement used as supplementary cementitious materials. Current study investigates the partial replacement of coarse aggregate with Beting bamboo in concrete mixtures. The outcome of the study discovers that through the mix design, replacing 5% by weight of Beting bamboo is an ideal % to achieve concrete mixture for structural and nonstructural application. However, with the increase % of Beting bamboo for partial replacement, the strength of the concrete gradually decreased.

The Influence of Partial Substitution of Raw Materials with Heavy Ash on the Main Properties of Portland Cements

2018 ◽  
Vol 69 (4) ◽  
pp. 860-863 ◽  
Author(s):  
Carmen Oproiu ◽  
Georgeta Voicu ◽  
Adrian Ionut Nicoara ◽  
Alina Ioana Badanoiu
Keyword(s):  
Raw Materials ◽  
Bottom Ash ◽  
Cementitious Materials ◽  
Cement Industry ◽  
Raw Material ◽  
Supplementary Cementitious Materials ◽  
Partial Substitution ◽  
X Ray Diffraction ◽  
Binder Ratio ◽  
Water To Binder Ratio

The use of wastes in cement industry have impact both from economic and environmental point of views. Wastes can be used in clinker manufacture (to substitute raw materials or as alternative fuel) as well as supplementary cementitious materials in cement. This paper presents results regarding the use of heavy ash (bottom ash) as component of raw mix used for the clinker manufacture. Two types of cements were obtained by the milling of clinker produced with/without heavy ash (HA) as component of raw mix and gypsum (2%). The compressive strengths of these cements was assessed on plastic mortars (water:binder = 1:2 ratio and binder:aggregate = 1:3 ratio), cast in prismatic moulds (14x14x160 mm3), hardened different periods of time comprised between 1 to 28 days. The hydration and hardening processes which occur in the cementitious systems with/without waste content were assessed on pastes with water to binder ratio of 0.5, hardened for 1 up to 90 days. X-ray diffraction (XRD) and complex thermal analysis (DTA-TG) were used for pastes� characterization. The composition of clinker was assessed by XRD and microstructure by scanning electron microscopy (SEM). The results obtained in the framework of this research do not show any important difference between the clinkers� characteristics produced with alternative raw material (heavy ash) as compared with the ones produced with natural raw materials. Also, the properties of cements produced of these clinkers are similar.

scholarly journals Agricultural Solid Waste as Source of Supplementary Cementitious Materials in Developing Countries

Materials ◽  
2019 ◽  
Vol 12 (7) ◽  
pp. 1112 ◽  
Author(s):  
Suvash Chandra Paul ◽  
Peter Mbewe ◽  
Sih Kong ◽  
Branko Šavija
Keyword(s):  
Developing Countries ◽  
Cementitious Materials ◽  
Agricultural Wastes ◽  
Cement Industry ◽  
Supplementary Cementitious Materials ◽  
Engineering Properties ◽  
Partial Replacement ◽  
Cement Production ◽  
Cement Replacement ◽  
Concrete Production

Concrete production utilizes cement as its major ingredient. Cement production is an important consumer of natural resources and energy. Furthermore, the cement industry is a significant CO2 producer. To reduce the environmental impact of concrete production, supplementary cementitious materials such as fly ash, blast furnace slag, and silica fume are commonly used as (partial) cement replacement materials. However, these materials are industrial by-products and their availability is expected to decrease in the future due to, e.g., closing of coal power plants. In addition, these materials are not available everywhere, for example, in developing countries. In these countries, industrial and agricultural wastes with pozzolanic behavior offer opportunities for use in concrete production. This paper summarizes the engineering properties of concrete produced using widespread agricultural wastes such as palm oil fuel ash, rice husk ash, sugarcane bagasse ash, and bamboo leaf ash. Research on cement replacement containing agricultural wastes has shown that there is great potential for their utilization as partial replacement for cement and aggregates in concrete production. When properly designed, concretes containing these wastes have similar or slightly better mechanical and durability properties compared to ordinary Portland cement (OPC) concrete. Thus, successful use of these wastes in concrete offers novel sustainable materials and contributes to greener construction as it reduces the amount of waste, while also minimizing the use of virgin raw materials for cement production. This paper will help the concrete industry choose relevant waste products and their optimum content for concrete production. Furthermore, this study identifies research gaps which may help researchers in further studying concrete based on agricultural waste materials.

scholarly journals Harvest residues ash as a pozzolanic additive for engineering applications: A review and the catalogue

2021 ◽  
Vol 64 (1) ◽  
pp. 1-18
Author(s):  
Slobodan Šupić ◽  
Mirjana Malešev ◽  
Vlastimir Radonjanin
Keyword(s):  
Fossil Fuels ◽  
Experimental Studies ◽  
Cementitious Materials ◽  
Silica Content ◽  
Supplementary Cementitious Materials ◽  
Engineering Applications ◽  
Biomass Waste ◽  
Harvest Residues ◽  
Greenhouse Gasses ◽  
Cementitious Systems

Biomass ashes originating from wood and harvest residues combustion may be considered as one of the prospective environmentally friendly candidates for supplementary cementitious materials (SCM) production. In the region of Vojvodina province, biomass waste is becoming increasingly important as ''green'' fuel, thus allowing the reduction of the environmental impact of waste disposal, lowering the expensive fossil fuels application and its subsequent greenhouse gasses emission. In the light of the above, the present paper surveys the experimental studies of harvest residues ash (HRA) as a pozzolanic additive for engineering applications. Thus far conducted research on the HRA possible application in cementitious systems, worldwide and in the studied region, has been summarized and the benefits of such approaches outlined. Finally, locally available types of wheat straw, soya straw, sunflower husk, silo waste, oil rapeseed - based ashes were collected, characterized both physically and chemically, evaluated and presented through catalogue. The reactivity results, depending on the amorphous silica content and the achieved level of fineness, are very promising in terms of the potential reuse of these ashes in cementing systems.

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