scholarly journals Oxidic 2D Materials

Materials ◽  
2021 ◽  
Vol 14 (18) ◽  
pp. 5213
Author(s):  
Oliver Dubnack ◽  
Frank A. Müller

The possibility of producing stable thin films, only a few atomic layers thick, from a variety of materials beyond graphene has led to two-dimensional (2D) materials being studied intensively in recent years. By reducing the layer thickness and approaching the crystallographic monolayer limit, a variety of unexpected and technologically relevant property phenomena were observed, which also depend on the subsequent arrangement and possible combination of individual layers to form heterostructures. These properties can be specifically used for the development of multifunctional devices, meeting the requirements of the advancing miniaturization of modern manufacturing technologies and the associated need to stabilize physical states even below critical layer thicknesses of conventional materials in the fields of electronics, magnetism and energy conversion. Differences in the structure of potential two-dimensional materials result in decisive influences on possible growth methods and possibilities for subsequent transfer of the thin films. In this review, we focus on recent advances in the rapidly growing field of two-dimensional materials, highlighting those with oxidic crystal structure like perovskites, garnets and spinels. In addition to a selection of well-established growth techniques and approaches for thin film transfer, we evaluate in detail their application potential as free-standing monolayers, bilayers and multilayers in a wide range of advanced technological applications. Finally, we provide suggestions for future developments of this promising research field in consideration of current challenges regarding scalability and structural stability of ultra-thin films.

2020 ◽  
Vol 233 ◽  
pp. 03005
Author(s):  
Jaime E. Santos ◽  
Mikhail Vasilevskiy ◽  
Nuno M.R. Peres ◽  
Antti-Pekka Jauho

We consider the problem of the radiation losses by fast-traveling particles traversing two-dimensional (2d) materials or thin films. After review¬ing the screening of electromagnetic fields by two dimensional conducting ma¬terials, we obtain the energy loss by a fast particle traversing such a material or film. In particular, we discuss the pattern of radiation emitted by monolayer graphene treated within a hydrodynamic approximation. These results are com¬pared with recent published results using similar approximations and, having in mind a potential application to particle detection, we briefly discuss how one can improve on the signals obtained by using other two-dimensional materials.


2020 ◽  
Vol 13 (05) ◽  
pp. 2030010 ◽  
Author(s):  
Pengkun Yin ◽  
Qingyu Lin ◽  
Yixiang Duan

At present, two-dimensional (2D) materials have shown great application potential in numerous fields based on their physical chemical and electronic properties. Raman spectroscopy and derivative techniques are effective tools for characterizing 2D materials. Raman spectroscopy conveys lots of knowledge on 2D materials, including layer number, doping type, strain and interlayer coupling. This review summarized advanced applications of Raman spectroscopy in 2D materials. The challenges and possible applied directions of Raman spectroscopy to 2D materials are discussed in detail.


2021 ◽  
Author(s):  
Mubashir A. Kharadi ◽  
Gul Faroz A. Malik ◽  
Farooq A. Khanday

2D materials like transition metal dichalcogenides, black phosphorous, silicene, graphene are at the forefront of being the most potent 2D materials for optoelectronic applications because of their exceptional properties. Several application-specific photodetectors based on 2D materials have been designed and manufactured due to a wide range and layer-dependent bandgaps. Different 2D materials stacked together give rise to many surprising electronic and optoelectronic phenomena of the junctions based on 2D materials. This has resulted in a lot of popularity of 2D heterostructures as compared to the original 2D materials. This chapter presents the progress of optoelectronic devices (photodetectors) based on 2D materials and their heterostructures.


2021 ◽  
Author(s):  
Shihao Su ◽  
Xinwei Wang ◽  
Jianming Xue

Two-dimensional (2D) materials such as graphene and molybdenum disulfide have been demonstrated with a wide range of applications in electronic devices, chemical catalysis, single-molecule detection, and energy conversion. In the...


Nanophotonics ◽  
2020 ◽  
Vol 0 (0) ◽  
Author(s):  
Xuezhi Ma ◽  
Nathan Youngblood ◽  
Xiaoze Liu ◽  
Yan Cheng ◽  
Preston Cunha ◽  
...  

AbstractA fascinating photonic platform with a small device scale, fast operating speed, as well as low energy consumption is two-dimensional (2D) materials, thanks to their in-plane crystalline structures and out-of-plane quantum confinement. The key to further advancement in this research field is the ability to modify the optical properties of the 2D materials. The modifications typically come from the materials themselves, for example, altering their chemical compositions. This article reviews a comparably less explored but promising means, through engineering the photonic surroundings. Rather than modifying materials themselves, this means manipulates the dielectric and metallic environments, both uniform and nanostructured, that directly interact with the materials. For 2D materials that are only one or a few atoms thick, the interaction with the environment can be remarkably efficient. This review summarizes the three degrees of freedom of this interaction: weak coupling, strong coupling, and multifunctionality. In addition, it reviews a relatively timing concept of engineering that directly applied to the 2D materials by patterning. Benefiting from the burgeoning development of nanophotonics, the engineering of photonic environments provides a versatile and creative methodology of reshaping light–matter interaction in 2D materials.


Nanophotonics ◽  
2020 ◽  
Vol 9 (8) ◽  
pp. 2315-2340 ◽  
Author(s):  
Junli Wang ◽  
Xiaoli Wang ◽  
Jingjing Lei ◽  
Mengyuan Ma ◽  
Cong Wang ◽  
...  

AbstractDue to the unique properties of two-dimensional (2D) materials, much attention has been paid to the exploration and application of 2D materials. In this review, we focus on the application of 2D materials in mode-locked fiber lasers. We summarize the synthesis methods for 2D materials, fiber integration with 2D materials and 2D materials based saturable absorbers. We discuss the performance of the diverse mode-locked fiber lasers in the typical operating wavelength such as 1, 1.5, 2 and 3 μm. Finally, a summary and outlook of the further applications of the new materials in mode-locked fiber lasers are presented.


Nanoscale ◽  
2021 ◽  
Author(s):  
Xianghui Zhang ◽  
Andre Beyer

The discovery of graphene has triggered a great interest in inorganic as well as molecular two-dimensional (2D) materials. In this review, we summarize recent progress in the mechanical characterization of...


2021 ◽  
Vol 13 (1) ◽  
Author(s):  
Mei Zhao ◽  
Sijie Yang ◽  
Kenan Zhang ◽  
Lijie Zhang ◽  
Ping Chen ◽  
...  

AbstractNonlayered two-dimensional (2D) materials have attracted increasing attention, due to novel physical properties, unique surface structure, and high compatibility with microfabrication technique. However, owing to the inherent strong covalent bonds, the direct synthesis of 2D planar structure from nonlayered materials, especially for the realization of large-size ultrathin 2D nonlayered materials, is still a huge challenge. Here, a general atomic substitution conversion strategy is proposed to synthesize large-size, ultrathin nonlayered 2D materials. Taking nonlayered CdS as a typical example, large-size ultrathin nonlayered CdS single-crystalline flakes are successfully achieved via a facile low-temperature chemical sulfurization method, where pre-grown layered CdI2 flakes are employed as the precursor via a simple hot plate assisted vertical vapor deposition method. The size and thickness of CdS flakes can be controlled by the CdI2 precursor. The growth mechanism is ascribed to the chemical substitution reaction from I to S atoms between CdI2 and CdS, which has been evidenced by experiments and theoretical calculations. The atomic substitution conversion strategy demonstrates that the existing 2D layered materials can serve as the precursor for difficult-to-synthesize nonlayered 2D materials, providing a bridge between layered and nonlayered materials, meanwhile realizing the fabrication of large-size ultrathin nonlayered 2D materials.


1991 ◽  
Vol 239 ◽  
Author(s):  
J. Ruud ◽  
D. Josell ◽  
A. L. Greer ◽  
F. Spaepen

ABSTRACTA new design for a thin film microtensile tester is presented. The strain is measured directly on the free-standing thin film from the displacement of laser spots diffracted from a thin grating applied to its surface by photolithography. The diffraction grating is two-dimensional, allowing strain measurement both along and transverse to the tensile direction. In principle, both Young's modulus and Poisson's ratio of a thin film can be determined. Ag thin films with strong <111> texture were tested. The measured Young moduli agreed with those measured on bulk crystals, but the measured Poisson ratios were low, most likely due to slight transverse folding of the film that developed during the test.


Author(s):  
P. Chraska ◽  
V. Brozek ◽  
B.J. Kolman ◽  
J. Ilavsky ◽  
K. Neufuss ◽  
...  

Abstract Porosity regulates the deposit's properties and therefore methods for its control are of a vital industrial importance. Thermal spraying can produce deposits in a wide range of porosities by selection of a spray process itself, by selection of spray parameters, feedstock size and chemistry, etc. Manufacturing of deposits with controlled porosity may be difficult if the selection of spray processes and materials is limited. Special methods of deposition or/and subsequent post processing may be therefore necessary. These methods are studied in the presented work. All spraying was done with the water-stabilized plasma (WSP®) system PAL 160. Thick deposits and free-standing parts were sprayed from alumina, zircon, metal Al and Ni powders and their combinations. Porosity was characterized by number of techniques such as gas permeability, water immersion, MIP, SEM and SANS. Mechanical properties were characterized by the Young's modulus. Special methods of deposition, such as spraying of mixtures of ceramics and metals were successfully used. Either sandwiched-structures with alternating layers of ceramics and metals were sprayed (for the sealing purpose) or mechanical mixtures of ceramic and metallic feedstock were sprayed. Several post-processing methods were used to change porosity volumes or other materials characteristics. To increase the porosity the metallic phases were subsequently removed by leaching or by annealing at temperatures above the melting point of metal. A number of sealing materials (organic and inorganic) were used to seal the pores by infiltration at ambient or higher pressures. The results show, that significant changes of porosity volume and, especially, of the gas permeability are possible. Another tested method was annealing/calcination of deposits, which resulted in an increase or decrease of porosity, depending on deposit's chemistry and annealing conditions. Results show that all used post processings are capable of significant changes of deposit microstructure and that they may be successfully applied in practice.


Sign in / Sign up

Export Citation Format

Share Document